EP0401331A1 - Matiere premiere de cosmetique constituee de colle d'origine cerealiere - Google Patents

Matiere premiere de cosmetique constituee de colle d'origine cerealiere

Info

Publication number
EP0401331A1
EP0401331A1 EP90900100A EP90900100A EP0401331A1 EP 0401331 A1 EP0401331 A1 EP 0401331A1 EP 90900100 A EP90900100 A EP 90900100A EP 90900100 A EP90900100 A EP 90900100A EP 0401331 A1 EP0401331 A1 EP 0401331A1
Authority
EP
European Patent Office
Prior art keywords
extraction
stage
ethanol
glue
residue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP90900100A
Other languages
German (de)
English (en)
Inventor
Dieter Braun
Ernst STEINBÖCK
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dragoco Gerberding and Co GmbH
Original Assignee
Dragoco Gerberding and Co GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dragoco Gerberding and Co GmbH filed Critical Dragoco Gerberding and Co GmbH
Publication of EP0401331A1 publication Critical patent/EP0401331A1/fr
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
    • A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
    • A61K8/9783—Angiosperms [Magnoliophyta]
    • A61K8/9794—Liliopsida [monocotyledons]

Definitions

  • the present invention relates to a method for producing cosmetic raw materials from cereal glue, in particular from wheat glue, and the use thereof.
  • Products of this type are biological substances whose use in cosmetics is clearly preferred over all synthetic products, such as the various synthetic polymers used in particular for hair treatment.
  • protein products can be obtained from cereal glue which are stable in cosmetic preparations and are soluble in an aqueous alcoholic medium with an alcohol content below 70% by weight.
  • solvents for common cosmetic preparations are often based on these solvents or are even alcohol-free, there is a need for protein products that are soluble in such media, including aqueous media.
  • cereal glue is extracted in a first stage with a fat solvent and, after evaporating the extract, the extraction residue is extracted in a second stage with a polar, in particular water-containing solvent, preferably in the presence of small amounts of ammonia, and the protein mixture obtained in the process after separating the insoluble fractions from the solution by evaporating the solvent, leaving the residue and separating the excreted honey-like mass.
  • a polar, in particular water-containing solvent preferably in the presence of small amounts of ammonia
  • the cereal glue is, in a manner known per se, in a first process step with a fat solvent (e.g. Hexane), in particular, however, extracted relatively high-percentage alcohol and obtained a fat product from the solvent phase by evaporation in a yield of 0.5%.
  • a fat solvent e.g. Hexane
  • the extraction residue is then extracted in a second stage with a polar, in particular water-containing solvent (for example aqueous ethanol), preferably in the presence of small amounts of ammonia, a protein mixture dissolving which, after the insoluble constituents have been removed from the solution, by evaporating off the solvent , Leaving the residue and separating the excreted honey-like mass is obtained.
  • Wheat glue a protein-rich wheat flour fraction, is preferably used as the starting material for the product according to the invention.
  • corn, barley, oats or rye can also be used in an analogous manner.
  • ethanol preferably used as the extraction agent.
  • methanol preferably used as the extraction agent.
  • acetone in each case in dry form
  • cyclohexane is preferably used as the extraction agent.
  • wheat glue it is extracted, for example, with about six times the amount by weight of 96% ethanol.
  • the extraction in the first extraction stage is preferably carried out with stirring at an elevated temperature of about 40 ° C. for a period of 1-2 days, it being possible for this extraction to be repeated once or twice.
  • the mass is then centrifuged and filtered.
  • the filtrate or eluate of this extraction stage is then evaporated under mild conditions at a temperature up to 40 ° C. by thin-layer evaporation in vacuo or by vacuum distillation.
  • gliastin absolute is suitable in perfumes and aromas as a modifier with fixing properties or as a skin and hair care product.
  • the gliastin absolu is protected against oxidation with 0.5% tocopherol aceate. It is preferably used in an amount of 0.5 to 1% by weight, based on the finished product.
  • the residue from the first extraction stage is brought into solution in a second stage with aqueous organic solvent, for example 50-75, in particular 62-68% aqueous ethanol, a protein product which is dissolved after the insoluble material has been separated off Share, evaporating the alcohol and leaving the residue as honey-like mass.
  • aqueous organic solvent for example 50-75, in particular 62-68% aqueous ethanol
  • the quantitative ratio of extractant to residue to be treated from the first extraction stage is preferably 6 to 6.5 to 1, the alcohol residue from the first process stage having to be taken into account.
  • the extraction of this second stage is preferably carried out in the presence of small amounts of ammonia, in particular an amount of 1 to 2% by weight, based on the extraction residue of the first stage.
  • reaction components are advantageously mixed with one another and then left to stand for at least 12 hours.
  • the solution obtained is treated with activated carbon or diatomaceous earth, filtered and freed from the alcohol under vacuum until it becomes cloudy.
  • the remaining solution is, if necessary ter full vacuum, cooled and left to stand. A tough mass settles out; the water phase is discarded and the residue is adjusted to about 20% by weight with 96% ethanol, remaining alcohol also having to be taken into account.
  • the protein product can optionally also be separated from the extraction solution of the second stage by cooling the solution to about ⁇ 20 ° C. or by diluting with distilled water in a ratio of about 1: 1 and leaving to stand at about + 2 ° C. to m ximal about 9 ° C can be obtained.
  • Alcohol (15 - 17%) and water are still present in the protein product.
  • the protein content, based on the weight of the product obtained, is about 22%.
  • the water additive must be adjusted to obtain a residue that is not too solid.
  • the protein product separated in this way can be freeze-dried and thereby obtained in solid form
  • the protein product obtained can be used as such or in hydrolysed form as a constituent of hair and skin care products.
  • the product is an extremely gently extracted extract of vegetable proteins in food purity. Due to its composition, this product, particularly with thin hair, can noticeably achieve more fullness and hold. The broad, nurturing effect is particularly evident from the aesthetic shine of the hair.
  • the film applied to the hair has a dirt-repellent effect, which can extend the washing intervals. After the treatment, combability is excellent, with no static charge being noticeable.
  • hair care hair tonic, lotions, friction, shampoos
  • skin care skin care
  • hair coloring hair tinting gel, hair tinting lotion
  • the product gives the hair more fullness and hold and has a nourishing effect.
  • the washing intervals are extended.
  • Static charge reduction Can also be used in barrier creams and in the food and pharmaceutical industries for chocolate and dragee varnishes, film formers for wound coverage.
  • Example 1 Production of a fat-free wheat gluten protein a) Separation of the fat portion from wheat glue
  • the centrifuge residue from example la is weighed, the non-separable ethanol residue is determined and taken into account for the further amounts of solvent.
  • phase A Suspend 12 kg of moist wheat gluten with approx. 50 kg of 96% ethanol (phase A).
  • phase B Preparation of the aqueous component: 25 kg of water + 0.75 concentrated ammonia solution (25%) (phase B).
  • Phase B is mixed into phase A with stirring; the mixture is then stirred for at least 20 min.
  • step 6 The solution from step 6 is filtered and ein ⁇ geengt largely substitutedampftist until the alcohol and a haze entries
  • the wheat gluten protein precipitates as a honey-like syrup.
  • the water phase is discarded and the honey-like. Part is adjusted with ethanol (96%) to approx. 18% by weight ethanol - taking into account the residual alcohol.
  • step 8 The solution of step 8 is set with o-phosphoric acid 'to pH 3.5; End product: approx. 50% with 22.5% protein and 20% alcohol.
  • Ethanol content approx. 18-20% by weight
  • Neo PCL self-emulsifying W / ö 25.0 A isopropyl myristate 5.0 lanolin anhvdr. 4.0
  • Neo Dragocid liquid 0.24 distilled water. 53.22 Perfume oil 0.50
  • Neo Dragocid liquid 0.24 distilled water. 54.00 perfume oil 0 r 50 4c) triaethanolamine salt of
  • the viscosity can be adjusted as desired.
  • Example 6 HAIRSTYL GEL A 1.5% (up to 3%) xanthan gum 35.0% isoproanol
  • D 0.5% DRAGOCO dye e.g. B. Chestnut 5/078625

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Botany (AREA)
  • Microbiology (AREA)
  • Mycology (AREA)
  • Cosmetics (AREA)
  • Peptides Or Proteins (AREA)

Abstract

Sont décrites la fabrication et l'utilisation de matières premières de cosmétique constituées de colle d'origine céréalière, notamment de froment. Les produits de ce type sont des substances biologiques dont l'emploi en cosmétique est nettement préféré aux produits synthétiques comme les divers polymères synthétiques utilisés notamment pour le traitement capillaire.
EP90900100A 1988-11-18 1989-11-17 Matiere premiere de cosmetique constituee de colle d'origine cerealiere Ceased EP0401331A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT283288 1988-11-18
AT2832/88 1988-11-18

Publications (1)

Publication Number Publication Date
EP0401331A1 true EP0401331A1 (fr) 1990-12-12

Family

ID=3540996

Family Applications (1)

Application Number Title Priority Date Filing Date
EP90900100A Ceased EP0401331A1 (fr) 1988-11-18 1989-11-17 Matiere premiere de cosmetique constituee de colle d'origine cerealiere

Country Status (3)

Country Link
EP (1) EP0401331A1 (fr)
JP (1) JPH03503169A (fr)
WO (1) WO1990005521A1 (fr)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2676936B1 (fr) * 1991-05-27 1993-11-05 Inocosm Laboratoires Procede de separation d'un compose riche en glycolipides lysophospholipides shingolipides et ceramides d'origine vegetale, ainsi que produits cosmetiques obtenus par la mise en óoeuvre de ce procede.
FR2701847B1 (fr) * 1993-02-23 1995-05-05 Coletica Compositions pharmaceutiques et cosmétiques à base d'albumine végétale, préparations contenant de telles compositions et procédé de préparation.
DE19801593A1 (de) * 1998-01-17 1999-07-22 Henkel Kgaa Lipoprotein-Cremes
GB9913765D0 (en) * 1999-06-14 1999-08-11 Procter & Gamble Hair care compoaitions
CN111936120A (zh) * 2018-03-08 2020-11-13 西姆莱斯股份公司 用于处理人类皮肤和/或毛发的包含蛋白质提取物的混合物

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH90702A (de) * 1917-07-13 1921-09-16 Sadakichi Satow Verfahren zur Gewinnung von Eiweissstoffen aus Pflanzen für die Herstellung von Gebrauchsartikeln.
FR2113539A5 (en) * 1970-11-05 1972-06-23 Anderson Clayton & Co Recovery of proteins from aq solns - washing with water-miscible solvent and removing it by washing the water
GB1526552A (en) * 1975-02-06 1978-09-27 Du Pont Canada Protein extraction from oats
US4370267A (en) * 1981-08-10 1983-01-25 A. E. Staley Manufacturing Company Fractionation and isolation of 7S and 11S protein from isoelectrically precipitated vegetable protein mixtures
US4716218A (en) * 1986-01-15 1987-12-29 Purdue Research Foundation Grain extraction milling

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9005521A1 *

Also Published As

Publication number Publication date
WO1990005521A1 (fr) 1990-05-31
JPH03503169A (ja) 1991-07-18

Similar Documents

Publication Publication Date Title
DE69904807T2 (de) Verwendung von mindestens einem proteinextrakt aus pflanzensamen von der moringagattung und entsprechende kosmetische oder pharmazeutische zusammensetzung
DE69611754T2 (de) Hydrochalconderivate, sie enthaltende kosmetische zusammensetzungen, und verfahren zur herstellung von beiden
EP0949902B1 (fr) Preparation cosmetique avec additif peptidique
DE69426156T2 (de) Antiakne-präparat das ein extrakt des poria cocos wolf enthalt
DE69108256T2 (de) Anwendug der saponine von medicago für die herstellung von kosmetischen oder pharmazeutischen namentlich dermatologischen zusammensetzungen welche die erneuerung der epidermis fördern,das wiederwachstum der haare stimulieren oder ihren ausfall verzögern.
DE69100591T2 (de) Kosmetische mittel, die einen extrakt des ölkuchens der sonnenblume (helianthus annuus) enthalten.
EP1087749A2 (fr) Preparation cosmetique de principes actifs a facteur eleve de protection contre les radicaux libres
US6216707B1 (en) Use of at least an Irvingia gabonensis extract in a cosmetic and/or pharmaceutical product
DE69830397T2 (de) Verwendung eines adansonia-gattung extraktes
DE60000286T2 (de) Lipide enthaltende sojaextrakte, verfahren zu deren herstellung und pharmazeutische und kosmetische zusammensetzung
DE69500125T2 (de) Extrakt von Immergrünsamen und ihn enthaltende Zusammensetzung
DE69216188T2 (de) Kosmetika und Pharmazeutika enthaltend Extensin
EP0401331A1 (fr) Matiere premiere de cosmetique constituee de colle d'origine cerealiere
EP1107776B1 (fr) Extrait sec de henne, procede permettant de l'obtenir et son utilisation
DE60129721T2 (de) Zusammensetzung zur verminderung neutralen fetts im blut
DE69316216T2 (de) Rohextrakte der blaualge, herstellungsmethode und verwendung in der kosmetologie und dermatologie
JPS60246305A (ja) 化粧料
DE19830004B4 (de) Kosmetische Wirkstoffzubereitung mit hohem Radikalschutzfaktor und deren Verwendung
DE69211696T2 (de) Extrakt aus marrubium vulgare enthaltende zusammensetzungen zur pigmentierung der haut oder der haare
DE2355850A1 (de) Proteinzusammensetzung und verfahren zu deren herstellung
DE102004028805A1 (de) Mittel zur Förderung der Collagenbildung
DE60225239T2 (de) Caramide, Zusammensetzungen die diese enthalten und ihre Verwendungen
DE69803169T2 (de) Verwendung eines bambaraerdnuss-samenextraktes in einer kosmetischen zusamensetzung
EP1140005B1 (fr) Utilisation d'un extrait d'une plante appartenant au genre cecropia
EP1244425B1 (fr) Procede de production d'un extrait de boues marines a usage cosmetique

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): BE CH DE ES FR GB IT LI NL

17P Request for examination filed

Effective date: 19901114

17Q First examination report despatched

Effective date: 19930423

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN REFUSED

18R Application refused

Effective date: 19931118