EP0440620A1 - Produit semi-fini pour contacts electriques, constitue d'un materiau composite a base d'argent et d'oxyde d'etain, et procede de metallurgie des poudres pour sa fabrication. - Google Patents

Produit semi-fini pour contacts electriques, constitue d'un materiau composite a base d'argent et d'oxyde d'etain, et procede de metallurgie des poudres pour sa fabrication.

Info

Publication number
EP0440620A1
EP0440620A1 EP89903734A EP89903734A EP0440620A1 EP 0440620 A1 EP0440620 A1 EP 0440620A1 EP 89903734 A EP89903734 A EP 89903734A EP 89903734 A EP89903734 A EP 89903734A EP 0440620 A1 EP0440620 A1 EP 0440620A1
Authority
EP
European Patent Office
Prior art keywords
component
oxide
powder
semi
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP89903734A
Other languages
German (de)
English (en)
Other versions
EP0440620B1 (fr
EP0440620B2 (fr
Inventor
Ursula Mayer
Roland Michal
Karl E Saeger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Doduco Solutions GmbH
Original Assignee
Doduco GmbH and Co KG Dr Eugen Duerrwaechter
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6350773&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP0440620(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Doduco GmbH and Co KG Dr Eugen Duerrwaechter filed Critical Doduco GmbH and Co KG Dr Eugen Duerrwaechter
Priority to AT89903734T priority Critical patent/ATE102387T1/de
Publication of EP0440620A1 publication Critical patent/EP0440620A1/fr
Publication of EP0440620B1 publication Critical patent/EP0440620B1/fr
Application granted granted Critical
Publication of EP0440620B2 publication Critical patent/EP0440620B2/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C32/00—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/001—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides
    • C22C32/0015—Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with only oxides with only single oxides as main non-metallic constituents
    • C22C32/0021—Matrix based on noble metals, Cu or alloys thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/12—Metallic powder containing non-metallic particles
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00—Contacts
    • H01H1/02—Contacts characterised by the material thereof
    • H01H1/021—Composite material
    • H01H1/023—Composite material having a noble metal as the basic material
    • H01H1/0237—Composite material having a noble metal as the basic material and containing oxides
    • H01H1/02372—Composite material having a noble metal as the basic material and containing oxides containing as major components one or more oxides of the following elements only: Cd, Sn, Zn, In, Bi, Sb or Te
    • H01H1/02376—Composite material having a noble metal as the basic material and containing oxides containing as major components one or more oxides of the following elements only: Cd, Sn, Zn, In, Bi, Sb or Te containing as major component SnO2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H11/00—Apparatus or processes specially adapted for the manufacture of electric switches
    • H01H11/04—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
    • H01H11/048—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts by powder-metallurgical processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10—Processes characterised by the sequence of their steps
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/12021—All metal or with adjacent metals having metal particles having composition or density gradient or differential porosity
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/12028—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/1216—Continuous interengaged phases of plural metals, or oriented fiber containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12014—All metal or with adjacent metals having metal particles
    • Y10T428/1216—Continuous interengaged phases of plural metals, or oriented fiber containing
    • Y10T428/12167—Nonmetal containing

Definitions

  • Semi-finished product for electrical contacts made of a composite material based on silver-tin oxide and powder metallurgical process for its production
  • the invention relates to a semi-finished product for electrical contacts made of a composite material based on silver-tin oxide and a powder metallurgical process for its production.
  • the invention relates to a method with the features specified in the preamble of claim 1 or from a semi-finished product with the features specified in the preamble of claim 14.
  • contact materials from silver-tin oxide by powder metallurgy, namely by mixing a silver powder with a tin oxide powder, forming silver-tin oxide blanks by pressing and sintering the Powder mixing, and shaping the blanks by extrusion or by extrusion and rolling.
  • a silver-cadmium oxide contact material such a powder-metallurgically manufactured material, if it also contains small amounts of tungsten oxide or molybdenum oxide, can perform approximately equally well in the contact heating and better in the AC4 service life test, in the AC3 service life - but he does not pass the test.
  • Semi-finished products for electrical contacts which consist of a powder-metal lurgically produced composite material based on silver-tin oxide with the addition of at least one further metal oxide (molybdenum oxide, tungsten oxide, bismuth titanate) and a carbide component (tungsten carbide and / or molybdenum carbide), are from DE -32 32 627 C2 known From EP 0 170 812 A2 it is known to melt an AgSnBiCu alloy from silver, tin, bismuth and copper, to produce an alloy powder by pressure spraying the melt, to oxidize it internally and to form contact pieces therefrom by pressing and sintering. Compared with contact pieces made of silver-cadmium oxide, these contact pieces show approximately the same degree of heating and have a longer life in the AC3 test, but a shorter service life in the AC4 test.
  • DE-29 29 630 AI it is known to produce a silver-tin oxide composite powder by a pyrolytic process and to form contact pieces from this composite powder by pressing and sintering. Compared to contact pieces made of silver-cadmium oxide contact pieces, these contact pieces have a longer service life, but more contact heating and poorer processability. From the same DE-29 29 630 it is also known to additionally store tungsten oxi or molybdenum oxide in the composite powder. This can reduce contact heating, but at the same time the service life in the AC3 test is reduced.
  • DE-AS 26 59 012 discloses a powder metallurgical process for producing a contact material made of silver with two different metal oxides embedded, in which two silver-metal oxide composite powders are mixed, pressed and sintered, of which one composite powder is only one Metal oxide and the other composite powder contains only the other metal oxide. Representation of the invention;
  • the object of the present invention is to provide a semifinished product for electrical contacts based on silver-tin oxide which, despite a content of very small tin oxide particles, can be easily processed by extrusion and rolling and at the same time with regard to
  • the semi-finished product according to the invention consists of a composite material which is characterized by a special rough structure in combination with a special fine structure.
  • the rough structure is given by the fact that in the composite material oxide-rich areas, in which all metal oxide or the vast majority of the metal oxide component is concentrated, alternate with low-oxide areas that contain only a small proportion of the metal oxide component or are even oxide-free.
  • the low-oxide regions contain at most a small proportion of metal oxide, finely distributed in a matrix formed from the material of the first component.
  • the oxide-rich areas contain the lion's share of the metal oxide component (in a concentration that is far higher than the usual average metal oxide concentration in a contact material on silver-tin oxide).
  • the fine structure of the composite material is given by a finely dispersed oxide distribution in the oxide-rich areas of the composite material forming the coarse structure, if appropriate also in the low-oxide areas, provided that metal oxides are present in these.
  • the entire metal oxide component is concentrated in the used composite powder, so that the other "powder, which contains the predominant portion of the silver or mainly silver-containing alloy (first Kompo ⁇ component), is completely free of oxide.
  • first Kompo ⁇ component the predominant portion of the silver or mainly silver-containing alloy
  • change in the composite material ranges , in which the metal oxide component is concentrated, with areas that are completely free of the metal oxide component.
  • the semifinished product according to the invention is characterized by improved deformability. However, this is not bought through an increased tendency to weld or through a reduced service life or through an increased electrical contact resistance.
  • This surprisingly favorable behavior of the contact material produced according to the invention is probably due to the fact that the contact material of known contact materials based on silver-tin oxide is not characterized by a changed total oxide content, but rather by the fact that this total oxide content verifies in a new way in the material ⁇ has been divided, namely in such a way that areas with a high metal oxide concentration in the material of the first component alternate with areas of low or vanishing metal oxide concentration in the material of the first component, the size of these areas depending on the size of the powder particles due to the powder metallurgical production from which the composite material is produced. In the areas of the composite material in which the metal oxide component is present, it should be present in a very fine distribution according to the invention.
  • the total content of the metal oxide component in the semifinished product can and should be between 5 and 25%
  • the second powder which contains most of the silver or silver alloy
  • this second powder which can be a composite powder or a powder mixture
  • the content of the tin oxide and any further oxides which may be provided should not exceed 3% by weight (based on the weight of this second powder). This Portion could be added individually or as a composite powder.
  • contact pieces produced from the semifinished product according to the invention have lower electrical contact transition resistance than conventionally produced contact pieces of the same composition and thus show less contact heating, which is a further essential advantage of the invention.
  • this is due to the fact that the tin oxide accumulates less strongly on the contacting surface in the case of contact pieces according to the invention, the tin oxide content, which is only finely dispersed in some areas, being favorable for the switching behavior, e.g. has a low tendency to weld.
  • contacts made from the semifinished product according to the invention suffer less erosion than contact pieces of the same composition made in a conventional manner.
  • the service life based on the AC3 and AC4 tests is longer than with comparable AgCdO contacts.
  • the predominant part of the metal oxide component must be concentrated and incorporated in the composite powder. Only the relatively small proportion of metal oxide that may still be present in the low-oxide areas of the composite material can, for example in the form of a pure oxide powder, can be mixed with the powder from the first component of the material. It is preferred that the same oxides are present in the low-oxide regions as in the oxide-rich regions.
  • the metal carbides (especially tungsten carbide and / or molybdenum carbide) still present in the second component and the metals not dissolved in the first component (especially tungsten and / or molybdenum) can be added to the powder mixture in the form of separate powders ; they are suitable in switching operation to promote the wetting of the tin oxide with silver and thereby to lower the contact transition resistance.
  • the composite powder can be produced by atomizing the melt of an alloy which contains metals of the first component, tin and optionally further oxidizable or non-oxidizable metals of the second component, and then oxidizing the oxidizable metals by the internal oxidation method. It is particularly advantageous to produce the composite powder by spraying an aqueous solution of salts of the metals of the first component and of tin in a hot, oxidizing atmosphere and thus pyrolytically decomposing the salts.
  • the process which is also known as spray pyrolysis, is described, for example, in US Pat. No. 3,510,291, in EP-0 012 202 A1 and in DE-29 29 630C2.
  • Metals intended for the composite powder are dissolved in a liquid and the solution is atomized in a hot reactor or into a flame, so that the solvent evaporates suddenly.
  • the resulting solid particles react with the oxygen in the oxidizing atmosphere in the flame or in the reactor at a temperature below the melting temperature of the dissolved metals, giving rise to powder particles in which the metals of the first component, ie the silver or the silver alloy, and the metal oxide component, ie essentially the tin oxide are bound together in a very fine distribution.
  • the metal oxide particles are mostly in sizes between 0.1 ⁇ m and 1 ⁇ m (diameter), which is advantageous for the method according to the invention.
  • composite powders produced by spray pyrolysis is also advantageous because spray pyrolysis in particular gives rise to powder particles which have a spherical or potato-like shape, which favors the formation of a deformable semi-finished product, because the spherical or potato-shaped particles are less resistant to plastic deformation of the contact material than irregularly jagged powder particles.
  • the oxidic and carbidic constituents which are optionally provided in addition to the tin oxide sometimes bring about a reduction in the contact point temperature in the switching operation and in some cases an extension of the service life of the contact pieces not only with small and medium current loads, but also in the heavy load range.
  • Molybdenum carbide and tungsten carbide act even in small amounts.
  • the additional carbides and oxides should not exceed 6% by weight of the contact material, so that it does not become too hard.
  • nickel may also be advantageous to add nickel to the composite material, which is not soluble in silver and is either mixed as a very fine powder with the powder formed from silver or a silver alloy, or else as a spray-pyrolytically produced silver-nickel powder is introduced.
  • the melt is sprayed with a corresponding silver-tin-bismuth alloy.
  • the silver-tin-bismuth alloy powder with a particle size smaller than 100 ⁇ m is oxidized internally for 6 hours at a temperature of 700 ° C in an oxidizing atmosphere.
  • 75 parts by weight of a commercially available silver powder with a particle size of less than 40 ⁇ m and 25 parts by weight of the silver-tin oxide-bismuth oxide composite powder are dry mixed for 1 hour, then isostatically pressed into blocks of approx. 50 kg weight and then sintered for 1.5 hours at a temperature of 830 ° C.
  • the block thus formed is placed in the recipient of an extrusion press and with a reduced cross-section to a strand with a cross-section of 10 x 75 mm 2 hot, at a temperature of approx. 850 ° C., extruded, then hot-plated with a 1.5 mm thick fine silver sheet, hot-rolled down to its final thickness of 2 mm and then processed further usual methods for contact wafers.
  • a silver-tin oxide composite powder with 32% by weight of tin oxide is produced by spraying an aqueous solution of silver nitrate and tin-II-chloride in one to
  • the silver-tin oxide composite material in the contact platelets has a tin oxide content of 8% by weight.
  • the second example is modified in such a way that 0.5% by weight of tungsten oxide (particle size smaller than 10 ⁇ m) and 0.3% by weight tungsten carbide (particle size smaller than 2.5 ⁇ m) are added to the powder mixture. Otherwise, the procedure is as in the second example.
  • the addition of the tungsten oxide and tungsten carbide leads to a lowering of the contact point temperature and to an extended service life of electrical contact pieces made from the semi-finished product. 4th example
  • a silver-tin oxide-tungsten oxide composite powder with 20% by weight of tin oxide and 0.5% by weight of tungsten oxide is produced by spraying an aqueous solution of silver nitrate, tin-II-chloride and tungsten-II-chloride in one to approx. 950 ° C. heated reactor with an oxygen-containing atmosphere, whereby a silver-tin oxide-tungsten oxide composite powder fails, in the powder particles of which the tin oxide and the tungsten oxide are present in a very fine distribution.
  • a silver-tin oxide composite powder with 30% by weight of tin oxide is produced as in the second example.
  • a silver-nickel composite powder with 2% by weight of nickel is produced by spraying an aqueous solution of silver nitrate and nickel-II-chloride in a reactor heated to about 950 ° C. with a protective gas atmosphere (eg argon), where a silver-nickel composite powder fails, in the powder particles of which the nickel is present in a very fine distribution.
  • a protective gas atmosphere eg argon
  • the fifth example can be modified in such a way that instead of a silver-nickel composite powder, a silver powder and a carbonyl-nickel powder are mixed with the silver-5 tin oxide composite powder. Otherwise, the procedure is as in the fifth example.
  • the attached figure shows schematically the structure of a composite material produced according to the second example, in which silver-tin oxide regions 1, which are usually smaller than 50 ⁇ m, lie in a silver matrix made from the oxide-free silver powder particles.
  • Semi-finished products manufactured according to the invention are particularly suitable for contact pieces in low-voltage switching devices, e.g. in motor contactors.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Manufacturing & Machinery (AREA)
  • Contacts (AREA)
  • Powder Metallurgy (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Manufacture Of Switches (AREA)

Abstract

Le produit semi-fini décrit comporte une microstructure dans laquelle des régions contenant peu ou pas d'oxyde métallique alternent avec des régions dans lesquelles la totalité ou la majeure partie du constituant oxyde métallique est finement répartie. Est également décrit un procédé de métallurgie des poudres pour fabriquer ledit produit.
EP89903734A 1988-03-26 1989-03-22 Produit semi-fini pour contacts electriques, constitue d'un materiau composite a base d'argent et d'oxyde d'etain, et procede de metallurgie des poudres pour sa fabrication Expired - Lifetime EP0440620B2 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT89903734T ATE102387T1 (de) 1988-03-26 1989-03-22 Halbzeug fuer elektrische kontakte aus einem verbundwerkstoff auf silber-zinnoxid-basis und pulvermetallurgisches verfahren zu seiner herstellung.

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE3810311 1988-03-26
DE3810311 1988-03-26
PCT/EP1989/000316 WO1989009478A1 (fr) 1988-03-26 1989-03-22 Produit semi-fini pour contacts electriques, constitue d'un materiau composite a base d'argent et d'oxyde d'etain, et procede de metallurgie des poudres pour sa fabrication

Publications (3)

Publication Number Publication Date
EP0440620A1 true EP0440620A1 (fr) 1991-08-14
EP0440620B1 EP0440620B1 (fr) 1994-03-02
EP0440620B2 EP0440620B2 (fr) 1998-06-03

Family

ID=6350773

Family Applications (1)

Application Number Title Priority Date Filing Date
EP89903734A Expired - Lifetime EP0440620B2 (fr) 1988-03-26 1989-03-22 Produit semi-fini pour contacts electriques, constitue d'un materiau composite a base d'argent et d'oxyde d'etain, et procede de metallurgie des poudres pour sa fabrication

Country Status (9)

Country Link
US (1) US5360673A (fr)
EP (1) EP0440620B2 (fr)
JP (1) JPH03504615A (fr)
CN (1) CN1022934C (fr)
CA (1) CA1339713C (fr)
DD (1) DD283571A5 (fr)
DE (2) DE3909384A1 (fr)
ES (1) ES2012293A6 (fr)
WO (1) WO1989009478A1 (fr)

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* Cited by examiner, † Cited by third party
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DE59302122D1 (de) * 1992-06-10 1996-05-09 Duerrwaechter E Dr Doduco Werkstoff für elektrische kontakte auf der basis von silber-zinnoxid oder silber-zinkoxid
DE4220925C2 (de) * 1992-06-25 1996-05-02 Siemens Ag Verfahren zur Herstellung von mit elektrischen Kontakten versehenen Formkörpern aus hochtemperatur-supraleitendem Material (HTSL) und nach diesem Verfahren hergestellter Formkörper
JP3441074B2 (ja) * 1992-09-16 2003-08-25 ドドウコ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コンパニー・ドクトル・オイゲン・デュルベヒテル 銀−錫酸化物または銀−亜鉛酸化物を基剤とする電気接点のための部材及びその製造方法
US5608766A (en) * 1993-10-29 1997-03-04 General Electric Company Co-deposition of palladium during oxide film growth in high-temperature water to mitigate stress corrosion cracking
US5846288A (en) * 1995-11-27 1998-12-08 Chemet Corporation Electrically conductive material and method for making
FR2916082B1 (fr) * 2007-05-11 2009-06-12 Schneider Electric Ind Sas Procede de fabrication d'un materiau pour pastille de contact electrique, pastille de contact realise par un tel procede
CN100552845C (zh) * 2007-09-27 2009-10-21 天津大学 银基氧化锡梯度电触头材料及制备方法
CN101911219B (zh) 2008-01-17 2015-12-16 日亚化学工业株式会社 导电性材料及其制造方法、电子设备、发光装置及其制造方法
DE102008056264A1 (de) * 2008-11-06 2010-05-27 Ami Doduco Gmbh Verfahren zur Herstellung eines Halbzeugs und Halbzeug für elektrische Kontakte sowie Kontaktstück
DE102008056263A1 (de) * 2008-11-06 2010-05-27 Ami Doduco Gmbh Verfahren zur Herstellung eines Halbzeugs und Halbzeug für elektrische Kontakte sowie Kontaktstück
CN102074278B (zh) * 2010-12-09 2011-12-28 温州宏丰电工合金股份有限公司 颗粒定向排列增强银基电触头材料的制备方法
CN102142325B (zh) * 2010-12-30 2013-04-03 温州宏丰电工合金股份有限公司 颗粒定向排列增强银基氧化物电触头材料及其制备方法
CN105374598A (zh) * 2015-11-05 2016-03-02 福达合金材料股份有限公司 一种粗氧化物颗粒银基电接触材料的制备方法
DE102016105437A1 (de) * 2016-03-23 2017-09-28 Doduco Gmbh Verfahren zur Herstellung eines Kontaktwerkstoffes auf Basis von Silber-Zinnoxid oder Silber-Sinkoxid sowie Kontaktwerkstoff
CN106350692B (zh) * 2016-09-23 2018-04-03 佛山市诺普材料科技有限公司 一种利用银镍合金废料制备银氧化镍的方法
JP7084730B2 (ja) * 2017-02-01 2022-06-15 Ｄｏｗａエレクトロニクス株式会社 銀合金粉末およびその製造方法
CN111961911B (zh) * 2020-07-24 2022-04-26 浙江耐迩合金科技有限公司 高抗熔焊性能银基电接触材料的制备方法
CN111961910B (zh) * 2020-07-24 2022-07-12 浙江耐迩合金科技有限公司 一种银氧化锡电接触材料的制备方法
EP4563547A1 (fr) 2023-11-29 2025-06-04 Any Color International Limited. Matériau émettant dans l'infrarouge lointain et son procédé de préparation

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Publication number Publication date
ES2012293A6 (es) 1990-03-01
EP0440620B1 (fr) 1994-03-02
CN1022934C (zh) 1993-12-01
CN1036991A (zh) 1989-11-08
WO1989009478A1 (fr) 1989-10-05
US5360673A (en) 1994-11-01
CA1339713C (fr) 1998-03-17
DD283571A5 (de) 1990-10-17
DE3909384A1 (de) 1989-10-19
DE58907140D1 (de) 1994-04-07
EP0440620B2 (fr) 1998-06-03
JPH03504615A (ja) 1991-10-09

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