EP0445699B1 - Procédé et dispositif de fabrication de surfaces trempées - Google Patents
Procédé et dispositif de fabrication de surfaces trempées Download PDFInfo
- Publication number
- EP0445699B1 EP0445699B1 EP91103226A EP91103226A EP0445699B1 EP 0445699 B1 EP0445699 B1 EP 0445699B1 EP 91103226 A EP91103226 A EP 91103226A EP 91103226 A EP91103226 A EP 91103226A EP 0445699 B1 EP0445699 B1 EP 0445699B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- workpiece
- magnetic field
- molten metal
- energy beam
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 47
- 239000002184 metal Substances 0.000 claims description 47
- 239000011261 inert gas Substances 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 229910052721 tungsten Inorganic materials 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 2
- 230000000149 penetrating effect Effects 0.000 claims 1
- 238000002474 experimental method Methods 0.000 description 7
- 230000004907 flux Effects 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 230000005672 electromagnetic field Effects 0.000 description 4
- 238000007373 indentation Methods 0.000 description 4
- 229910001141 Ductile iron Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000017525 heat dissipation Effects 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 206010067482 No adverse event Diseases 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000009828 non-uniform distribution Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/06—Surface hardening
- C21D1/09—Surface hardening by direct application of electrical or wave energy; by particle radiation
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/30—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for crankshafts; for camshafts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S148/00—Metal treatment
- Y10S148/902—Metal treatment having portions of differing metallurgical properties or characteristics
- Y10S148/903—Directly treated with high energy electromagnetic waves or particles, e.g. laser, electron beam
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S148/00—Metal treatment
- Y10S148/902—Metal treatment having portions of differing metallurgical properties or characteristics
- Y10S148/904—Crankshaft
Definitions
- This invention relates to a method of forming a chilled layer of a workpiece by remelting and hardening treatment and an apparatus for performing the method.
- a workpiece such as, for example, a cam of a camshaft for driving valves of an automotive engine
- a beam containing heat energy is directed toward the surface. The energy beam is moved entirely or partially over the surface of the workpiece so as to form a molten metal layer on the surface.
- the energy beam is oscillated, or reciprocally moved, over the surface, while the workpiece, such as a cam of a camshaft, rotates about its axis of rotation so as to remelt a desired area of the surface of the workpiece, thereby forming a molten metal layer on the surface.
- the molten metal layer is cooled and hardened, or chilled, with time.
- the surface is formed with a hardened, or chilled, layer.
- an apparatus such as that which is known from, for example, Japanese Unexamined Patent Publication No.60 - 258421, includes a plasma torch as means for generating a beam containing heat energy, which oscillates, or reciprocally moves, over the surface of the workpiece.
- a magnetic coil oriented by the plasma torch, generates a magnetic field in order to cause the energy beam to oscillate between the extreme ends of the molten metal layer to be formed.
- the energy beam when the plasma torch reverses the direction of movement at the extreme ends, reduces its speed and stops momentarily, so as to distribute higher heat energy to marginal portions of the surface than to the central portion. Because of this non-uniform distribution of heat energy, the chilled layer formed in the surface of the workpiece is non-uniform in its widthwise thickness. More specifically, the chilled layer is thicker, or deeper, at the opposite marginal portions than at the central portion.
- FIG. 1 where the distribution of depth, or thickness, in a transverse direction of a chilled layer, formed on a cam surface of a camshaft by the conventional remelting and hardening treatment, is shown.
- a chilled layer 3 of the cam surface 2 of the cam 1 has a depth which is deeper at opposite extreme end portions 4, where the energy beam reverses its direction of movement, than at the central portion 6.
- DE-B-1 224 885 discloses a method for the manufacture of cast ingots by melting-off a melt-stock electrode wherein a magnetic field is applied in parallel to the axis of the electrode. The magnetic field causes a distribution of heat energy towards the outer portions of the zone molten by an electric arc.
- EP-A-0 161 624 discloses a method of producing a cast iron camshaft comprising the steps of rotating the camshaft at a predetermined speed, applying a high-density energy source over the entire sliding surface of a cam, driving the energy source relatively to the surface of the camshaft, and cooling the cam by dissipation of the localized heat through the camshaft itself.
- An object of the present invention is to provide a method of forming a uniform chilled layer thickness on a surface of a workpiece by remelting and hardening treatment, and an apparatus for performing the method as defined in claims 1, 6 and 9.
- the surface of a metal workpiece is remelted by an energy beam generated by, for instance, a laser, a tungsten inert gas (TIG) arc generator or the like, bearing heat energy so as to form a molten metal layer on the surface of the workpiece.
- an energy beam generated by, for instance, a laser, a tungsten inert gas (TIG) arc generator or the like, bearing heat energy so as to form a molten metal layer on the surface of the workpiece.
- TIG tungsten inert gas
- both the energy beam and magnetic field over the surface of the work between opposite extreme ends of a layer which is to be chilled causes a flow of the molten metal from the extreme ends of the molten metal layer toward the center, so that the molten metal layer is formed with a uniform thickness and solidifies, forming a chilled layer with a uniform thickness.
- means for generating the magnetic field comprises a magnetic coil, such as, in particular, an A.C. electromagnetic coil.
- the A.C. electromagnetic coil provides a magnetic field which changes alternately in opposite magnetic directions. This alternately changing magnetic field enhances the agitation of molten metal.
- FIG. 2 an apparatus for forming a chilled layer on a surface of a workpiece by remelting and hardening treatment in accordance with a preferred embodiment of the present invention is shown.
- the apparatus is shown as used to form a chilled layer in the surface of a cam of a camshaft for, for instance, driving valves of an automotive engine.
- the camshaft 20 having cams 21 (only one of which is shown) of ductile iron to be treated and formed with a chilled layer in the cam surface 22, which is roughly ground, is turned at a constant speed about an axis of rotation 24 thereof by a conventional mechanical drive mechanism 18.
- the apparatus comprises molten metal layer forming means 10, for melting the cam surface 22 of the cam 21 and agitating, or stirring, the melted metal of the cam surface 22.
- the molten metal layer forming means 10 comprises a heat energy generator 11, such as a laser beam generator, an electron beam generator, a tungsten inert gas (TIG) arc generator or the like, for generating a beam of heat energy, and a magnetic field generator, such as an A.C. electromagnetic coil 15.
- the heat energy generator 11, such as a tungsten inert gas (TIG) arc generator (which is hereinafter referred to as a beam torch), has a cylindrical hollow housing 12 and an electrode 13 housed in the housing 12 with its cone-shaped tip 14 projecting outside the housing 12.
- the electromagnetic coil 15, having a cylindrical hollow coil body, is coaxially mounted on the housing 12 of the beam torch 11.
- the molten metal layer forming means 10 is oscillated, or reciprocally moved, by a conventional mechanical drive mechanism 19 in a direction of the axis of rotation 24 of the camshaft 20 at a constant speed so as to cause a two dimensional relative movement with respect to the surface 22 of the cam 21 of the camshaft 20.
- the electromagnetic coil 15 is energized, or magnetized, by an alternating current from an alternating power supply 30.
- the molten metal layer 3' solidifies with time, and is hardened, thereby forming a chilled layer 3 (see Figure 3) in the cam surface 22.
- the electrode 13 directs the energy beam 31 to the cam surface 22 of the cam 21 rotating about the axis of rotation 24 so as to trace a locus 28, thereby forming the molten metal layer circumferentially over the peripheral surface 22 of the cam 21.
- the molten metal layer forming means 10 While the electrode 13 is energized and radiates and directs the energy beam 31, the molten metal layer forming means 10 also magnetizes the magnetic coil 15 with the alternating current so as to generate a magnetic field.
- the magnetic coil 15 when magnetized, generates a magnetic field 32 across the cam surface 22 of the cam 21.
- the magnetic field 32 interacts with the energy beam 31, causing the energy beam 31 to flare, and thereby generates a force 40, well known as a Lorentz force, in the melted metal layer 3', as is shown in Figure 4. While the molten metal of the layer 3' is cooled and solidified, it is agitated, or stirred, by the force 40.
- the force 40 acts on the molten metal layer 3' in opposite, i.e. , clockwise and counterclockwise, directions, as viewed in Figure 4. These directions change alternately. Accordingly, the molten metal is vibrated substantially in a vertical direction and is, therefore, vigorously agitated, or stirred, so that the molten metal layer 3' is more precisely uniform in thickness. Agitating the molten metal with the Lorentz force 40 promotes heat-dissipation more rapidly from the molten metal layer, so as to accelerate the solidification of the molten metal layer 3'.
- Moving the electromagnetic means 10 in the axial direction causes a flow of the molten metal from the outer side of molten metal layer 3' toward the center.
- the speed of the energy beam 31 drops, and the beam may momentarily stop, in the axial direction, at the opposite extreme ends of the molten metal layer 3', the molten metal layer 3' becomes uniform in depth, or thickness, so as to form a uniform thickness of chilled layer 3, as is shown in Figure 5.
- FIG. 6 showing a chilled layer 43 formed in the cam surface 22 of the cam 21 by the use of a conventional apparatus which has no magnetic coil.
- the chilled layer 43 is thicker at the opposite extreme side portions 42, where the energy beam drops its speed, or stops, than at the central portion 44, and causes a difference in depth, or thickness, therebetween, which is shown by a reference character d . Comparing the chilled layer 3 shown in Figure 5 to the chilled layer 43 shown in Figure 6, the effect of an apparatus in accordance with the present invention is apparent.
- the table of Figure 7 shows the width of the chilled layer of the cam top surface, in mm, the thickness, or depth, A of the chilled layer of the cam top surface from a designed cam top surface (see Figure 8) in mm, the depth of indentation B of the cam top surface from the designed cam top surface (see Figure 8), in mm, and the hardness of chilled layer of the cam top surface, in Hv units, for each experiment.
- the width of the chilled layer increasingly varies with an increase in flux densities of the electromagnetic field generated by the electromagnetic coil.
- Changes in thickness or depth A of the chilled layer, the depth of indentation B and the hardness of the chilled layer are small and within a range where no adverse effects on the function of the cam are caused.
- Figure 9 shows a diagram in terms of the relationship between the flux densities of the electromagnetic field and the width of the chilled layer for the experiments.
- the A.C. current frequency is preferably approximately 1.5 and 6.0 Hz.
- the change in direction of the Lorentz force 40 is insufficient for the molten metal to be agitated and to flow, so that the molten metal does not dissipate heat rapidly.
- the Lorentz force 40 changes direction too frequently, so as to impede the flow of molten metal. This also causes an stagnation in heat-dissipation.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
Claims (12)
- Appareil destiné à produire une couche trempée dans une surface d'une pièce à usiner par traitement de remise en fusion et de trempe, comprenant:des premiers moyens d'entraînement pour mettre en rotation la pièce à usiner à une vitesse prédéterminée ;des moyens de production d'énergie thermique destinés à produire et à diriger un faisceau d'énergie sur la surface de la pièce à usiner de façon à remettre la surface en fusion ; etdes seconds moyens d'entraînement destinés à produire une vitesse prédéterminée de mouvement des moyens de production d'énergie thermique par rapport à la surface de la pièce à usiner, permettant de former la couche trempée dans la surface de la pièce; caractérisé en ce quel'appareil comprend de plus des moyens de production de champ magnétique pour produire un champ magnétique coaxial au faisceau d'énergie et qui pénètre dans la surface de la pièce à usiner tandis que les moyens de production d'énergie thermique produisent le faisceau d'énergie de sorte que le faisceau d'énergie s'enflamme ; eten ce que les seconds moyens d'entraînement provoquent une vitesse prédéterminée de mouvement à la fois des moyens de production d'énergie thermique et des moyens de production de champ magnétique.
- Appareil selon la revendication 1, dans lequel les moyens de production d'énergie thermique comprennent un générateur d'arc au tungstène et à gaz inerte.
- Appareil selon la revendication 1, dans lequel les moyens de production d'énergie thermique comprennent un générateur de faisceau laser.
- Appareil selon la revendication 1, dans lequel les moyens de production de champ magnétique comprennent une bobine électromagnétique.
- Appareil selon la revendication 4, dans lequel les moyens de production de champ magnétique comprennent une bobine électromagnétique en courant alternatif.
- Appareil destiné à produire une couche trempée dans une surface d'une pièce à usiner par traitement de remise en fusion et de trempe, comprenant:des premiers moyens d'entraînement pour mettre en rotation la pièce à usiner à une vitesse prédéterminée iune baguette d'électrode destinée à produire et à diriger un faisceau d'énergie sur la surface de la pièce à usiner de façon à remettre la surface en fusion etdes seconds moyens d'entraînement pour provoquer un mouvement de la baguette d'électrode par rapport à la surface, formant ainsi la couche trempée dans la surface de la pièce à usiner caractérisé en ce que l'appareil comprend de plusune bobine électromagnétique coaxiale avec la baguette d'électrode pour produire un champ magnétique pénétrant dans la surface de la pièce à usiner tandis que la baguette d'électrode produit le faisceau d'énergie de sorte que le faisceau d'énergie s'enflamme eten ce que les seconds moyens d'entraînement provoquent un mouvement à la fois de la baguette d'électrode et de la bobine électromagnétique.
- Appareil selon la revendication 6, caractérisé en ce que la baguette d'électrode comprend une électrode d'arc au tungstène et à gaz inerte.
- Appareil selon la revendication 4, dans lequel la bobine électromagnétique comprend une bobine électromagnétique en courant alternatif.
- Procédé pour produire une couche trempée dans une surface d'une pièce à usiner en dirigeant un faisceau d'énergie pour remettre la surface en fusion avec la chaleur de facon à former une couche de métal fondu dans la surface d'une pièce à usiner et refroidir et tremper la couche de métal fondu, formant ainsi la couche trempée dans la surface, caractérisé par les étapes consistant à :produire un champ magnétique coaxial au faisceau d'énergie de façon à ce que ce faisceau d'énergie s'enflamme, agitant ainsi le métal fondu de la couche de métal fondu; etprovoquer un mouvement de va-et-vient prédéterminé du faisceau d'énergie par rapport à la surface de la pièce à usiner au cours de l'opération de remise en fusion de la surface de façon à obtenir un écoulement du métal en fusion à partir d'un côté extrême de la couche de métal fondu vers le centre de la couche de métal fondu, permettant ainsi de former une couche trempée d'épaisseur uniforme. uniforme.
- Procédé selon la revendication 9, dans lequel le champ magnétique est modifié dans la direction magnétique de façon alternée à une fréquence entre environ 1,5 et 6,0 Hz.
- Procédé selon la revendication 10, dans lequel le champ magnétique est produit en continu par une bobine électromagnétique.
- Procédé selon la revendication 11, dans lequel le champ magnétique est produit par une bobine électromagnétique en courant alternatif.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP53100/90 | 1990-03-05 | ||
| JP2053100A JPH03257116A (ja) | 1990-03-05 | 1990-03-05 | 再溶融硬化処理装置 |
| JP131640/90 | 1990-05-21 | ||
| JP13164090A JP3187037B2 (ja) | 1990-05-21 | 1990-05-21 | 再溶融硬化方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0445699A2 EP0445699A2 (fr) | 1991-09-11 |
| EP0445699A3 EP0445699A3 (en) | 1992-10-21 |
| EP0445699B1 true EP0445699B1 (fr) | 1996-06-12 |
Family
ID=26393812
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP91103226A Expired - Lifetime EP0445699B1 (fr) | 1990-03-05 | 1991-03-04 | Procédé et dispositif de fabrication de surfaces trempées |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US5114499A (fr) |
| EP (1) | EP0445699B1 (fr) |
| KR (1) | KR940004030B1 (fr) |
| DE (1) | DE69120102T2 (fr) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4430220C2 (de) | 1994-08-25 | 1998-01-22 | Fraunhofer Ges Forschung | Verfahren zur Steuerung der Laserstrahlintensitätsverteilung auf der Oberfläche zu bearbeitender Bauteile |
| US5468308A (en) * | 1994-08-22 | 1995-11-21 | The Torrington Company | Surface treated cast iron bearing element |
| US5906053A (en) * | 1997-03-14 | 1999-05-25 | Fisher Barton, Inc. | Rotary cutting blade having a laser hardened cutting edge and a method for making the same with a laser |
| US6857255B1 (en) | 2002-05-16 | 2005-02-22 | Fisher-Barton Llc | Reciprocating cutting blade having laser-hardened cutting edges and a method for making the same with a laser |
| US20120111458A1 (en) * | 2009-07-15 | 2012-05-10 | Boguslaw Grabas | Method of increasing heat exchange surfaces and active surfaces of metal elements including, in particular, heat exchange surfaces |
| EP3034225B1 (fr) * | 2014-12-17 | 2018-10-17 | Airbus Defence and Space GmbH | Procédé et appareil de commande de distorsion sur des pièces fabriquées de manière additive au moyen d'un fil et d'impulsions magnétiques |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL298244A (fr) * | 1962-09-24 | 1900-01-01 | ||
| DE1224885B (de) * | 1964-07-02 | 1966-09-15 | Heraeus Gmbh W C | Verfahren zur Herstellung von Schmelzbloecken im Vakuum-Lichtbogenofen |
| SU449456A1 (ru) * | 1972-12-01 | 1974-11-05 | Предприятие П/Я Г-4696 | Способ электроннолучевого оплавлени поверхности слитков |
| US4190760A (en) * | 1976-05-14 | 1980-02-26 | Kobe Steel, Ltd. | Welding apparatus with shifting magnetic field |
| JPS53140249A (en) * | 1977-04-09 | 1978-12-07 | Kobe Steel Ltd | Method and apparatus for welding |
| IT1219974B (it) * | 1981-06-25 | 1990-05-24 | Fischer Ag Georg | Procedimento di tempra a rifusione |
| JPS58196362A (ja) * | 1982-05-10 | 1983-11-15 | Toyota Motor Corp | 鋳鉄製カムシヤフト及びその製造方法 |
| JPS60204834A (ja) * | 1984-03-28 | 1985-10-16 | Honda Motor Co Ltd | カムシヤフトのカム部の再溶融硬化処理方法 |
| JPS60234169A (ja) * | 1984-05-07 | 1985-11-20 | Toyota Motor Corp | 再溶融チルカムシヤフトおよびその製造方法 |
| JPS60258421A (ja) * | 1984-05-21 | 1985-12-20 | Honda Motor Co Ltd | カムシヤフトの再溶融硬化処理方法 |
| JPS6117372A (ja) * | 1984-07-03 | 1986-01-25 | Mitsubishi Heavy Ind Ltd | 磁気撹拌横向溶接方法 |
-
1991
- 1991-03-04 DE DE69120102T patent/DE69120102T2/de not_active Expired - Fee Related
- 1991-03-04 KR KR1019910003477A patent/KR940004030B1/ko not_active Expired - Fee Related
- 1991-03-04 US US07/664,137 patent/US5114499A/en not_active Expired - Fee Related
- 1991-03-04 EP EP91103226A patent/EP0445699B1/fr not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE69120102T2 (de) | 1997-01-30 |
| US5114499A (en) | 1992-05-19 |
| KR910016947A (ko) | 1991-11-05 |
| KR940004030B1 (ko) | 1994-05-11 |
| EP0445699A3 (en) | 1992-10-21 |
| DE69120102D1 (de) | 1996-07-18 |
| EP0445699A2 (fr) | 1991-09-11 |
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