EP0512328A1 - Composition nettoyante inoffensive vis à vis des produits alimentaires - Google Patents

Composition nettoyante inoffensive vis à vis des produits alimentaires Download PDF

Info

Publication number: EP0512328A1
Authority: EP; European Patent Office
Prior art keywords: composition; acid ester; mono; emulsifier; sorbitol
Prior art date: 1991-05-06
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Withdrawn

Application number

EP92106925A

Other languages

German (de)

English (en)

Inventor

Patrizia Barone

Michael T. Endres

Shanker B. Patel

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Bayer Corp

Original Assignee

Miles Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1991-05-06

Filing date

1992-04-23

Publication date

1992-11-11

1992-04-23 Application filed by Miles Inc filed Critical Miles Inc

1992-11-11 Publication of EP0512328A1 publication Critical patent/EP0512328A1/fr

Status Withdrawn legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 48
238000004140 cleaning Methods 0.000 title claims abstract description 26
235000013305 food Nutrition 0.000 title abstract description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 27
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 19
239000004094 surface-active agent Substances 0.000 claims abstract description 14
235000019499 Citrus oil Nutrition 0.000 claims abstract description 12
239000010500 citrus oil Substances 0.000 claims abstract description 12
239000003995 emulsifying agent Substances 0.000 claims abstract description 11
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims abstract description 7
229910000288 alkali metal carbonate Inorganic materials 0.000 claims abstract description 5
150000008041 alkali metal carbonates Chemical class 0.000 claims abstract description 5
-1 alkali metal bicarbonate Chemical class 0.000 claims description 16
DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 12
235000014113 dietary fatty acids Nutrition 0.000 claims description 12
239000000194 fatty acid Substances 0.000 claims description 12
229930195729 fatty acid Natural products 0.000 claims description 12
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 10
235000019333 sodium laurylsulphate Nutrition 0.000 claims description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 9
239000000600 sorbitol Substances 0.000 claims description 9
229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 8
235000021360 Myristic acid Nutrition 0.000 claims description 7
150000004665 fatty acids Chemical group 0.000 claims description 7
TUNFSRHWOTWDNC-UHFFFAOYSA-N tetradecanoic acid Chemical class CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 claims description 7
235000019501 Lemon oil Nutrition 0.000 claims description 6
239000000975 dye Substances 0.000 claims description 6
239000003205 fragrance Substances 0.000 claims description 6
239000010501 lemon oil Substances 0.000 claims description 6
DNISEZBAYYIQFB-PHDIDXHHSA-N (2r,3r)-2,3-diacetyloxybutanedioic acid Chemical compound CC(=O)O[C@@H](C(O)=O)[C@H](C(O)=O)OC(C)=O DNISEZBAYYIQFB-PHDIDXHHSA-N 0.000 claims description 5
LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 claims description 5
235000021314 Palmitic acid Nutrition 0.000 claims description 5
235000021355 Stearic acid Nutrition 0.000 claims description 5
IPCSVZSSVZVIGE-UHFFFAOYSA-N palmitic acid group Chemical group C(CCCCCCCCCCCCCCC)(=O)O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims description 5
229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 5
235000017557 sodium bicarbonate Nutrition 0.000 claims description 5
229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
150000003899 tartaric acid esters Chemical class 0.000 claims description 5
229920001214 Polysorbate 60 Polymers 0.000 claims description 4
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
125000004432 carbon atom Chemical group C* 0.000 claims description 3
230000032050 esterification Effects 0.000 claims description 3
238000005886 esterification reaction Methods 0.000 claims description 3
229910052783 alkali metal Inorganic materials 0.000 claims description 2
239000003755 preservative agent Substances 0.000 claims description 2
231100000252 nontoxic Toxicity 0.000 abstract description 3
230000003000 nontoxic effect Effects 0.000 abstract description 3
238000002360 preparation method Methods 0.000 abstract description 2
239000002689 soil Substances 0.000 description 14
238000009472 formulation Methods 0.000 description 9
238000012360 testing method Methods 0.000 description 9
239000004615 ingredient Substances 0.000 description 7
239000007788 liquid Substances 0.000 description 7
239000000463 material Substances 0.000 description 6
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
229920001213 Polysorbate 20 Polymers 0.000 description 4
239000008367 deionised water Substances 0.000 description 4
229910021641 deionized water Inorganic materials 0.000 description 4
238000002156 mixing Methods 0.000 description 4
235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 4
239000007921 spray Substances 0.000 description 4
235000005979 Citrus limon Nutrition 0.000 description 3
244000131522 Citrus pyriformis Species 0.000 description 3
230000007794 irritation Effects 0.000 description 3
239000003921 oil Substances 0.000 description 3
235000019198 oils Nutrition 0.000 description 3
XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 2
CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 description 2
239000004255 Butylated hydroxyanisole Substances 0.000 description 2
235000019485 Safflower oil Nutrition 0.000 description 2
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
230000004913 activation Effects 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
239000003963 antioxidant agent Substances 0.000 description 2
230000003078 antioxidant effect Effects 0.000 description 2
235000019282 butylated hydroxyanisole Nutrition 0.000 description 2
CZBZUDVBLSSABA-UHFFFAOYSA-N butylated hydroxyanisole Chemical compound COC1=CC=C(O)C(C(C)(C)C)=C1.COC1=CC=C(O)C=C1C(C)(C)C CZBZUDVBLSSABA-UHFFFAOYSA-N 0.000 description 2
229940043253 butylated hydroxyanisole Drugs 0.000 description 2
235000020971 citrus fruits Nutrition 0.000 description 2
210000003298 dental enamel Anatomy 0.000 description 2
238000000034 method Methods 0.000 description 2
239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
235000010241 potassium sorbate Nutrition 0.000 description 2
239000004302 potassium sorbate Substances 0.000 description 2
229940069338 potassium sorbate Drugs 0.000 description 2
239000003813 safflower oil Substances 0.000 description 2
235000005713 safflower oil Nutrition 0.000 description 2
230000036556 skin irritation Effects 0.000 description 2
NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 2
239000000126 substance Substances 0.000 description 2
238000009736 wetting Methods 0.000 description 2
238000010953 Ames test Methods 0.000 description 1
231100000039 Ames test Toxicity 0.000 description 1
244000089742 Citrus aurantifolia Species 0.000 description 1
235000008733 Citrus aurantifolia Nutrition 0.000 description 1
240000000560 Citrus x paradisi Species 0.000 description 1
206010015946 Eye irritation Diseases 0.000 description 1
241001251094 Formica Species 0.000 description 1
241001443715 Fusarium oxysporum f. sp. conglutinans Species 0.000 description 1
206010040880 Skin irritation Diseases 0.000 description 1
235000011941 Tilia x europaea Nutrition 0.000 description 1
230000001154 acute effect Effects 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
239000003240 coconut oil Substances 0.000 description 1
235000019864 coconut oil Nutrition 0.000 description 1
239000006184 cosolvent Substances 0.000 description 1
239000002274 desiccant Substances 0.000 description 1
239000003599 detergent Substances 0.000 description 1
230000009977 dual effect Effects 0.000 description 1
230000002708 enhancing effect Effects 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
238000000605 extraction Methods 0.000 description 1
231100000013 eye irritation Toxicity 0.000 description 1
239000010685 fatty oil Substances 0.000 description 1
230000037406 food intake Effects 0.000 description 1
235000011389 fruit/vegetable juice Nutrition 0.000 description 1
235000012055 fruits and vegetables Nutrition 0.000 description 1
239000003906 humectant Substances 0.000 description 1
239000004571 lime Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
239000003550 marker Substances 0.000 description 1
239000004530 micro-emulsion Substances 0.000 description 1
230000000149 penetrating effect Effects 0.000 description 1
238000005191 phase separation Methods 0.000 description 1
229920000136 polysorbate Polymers 0.000 description 1
238000007127 saponification reaction Methods 0.000 description 1
231100000475 skin irritation Toxicity 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
239000000243 solution Substances 0.000 description 1
239000003381 stabilizer Substances 0.000 description 1
239000000758 substrate Substances 0.000 description 1
239000010409 thin film Substances 0.000 description 1
231100000331 toxic Toxicity 0.000 description 1
230000002588 toxic effect Effects 0.000 description 1
230000002110 toxicologic effect Effects 0.000 description 1
231100000027 toxicology Toxicity 0.000 description 1
239000000052 vinegar Substances 0.000 description 1
235000021419 vinegar Nutrition 0.000 description 1
125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
229920002554 vinyl polymer Polymers 0.000 description 1
239000000080 wetting agent Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/74—Carboxylates or sulfonates esters of polyoxyalkylene glycols

Definitions

United States Patent No 4,620,937 discloses a liquid mixture of distilled, stabilized citric oil; vinegar and water.
the citric oil typically includes distilled D-Limonene, at a minimum of 50% and preferably at the 80% level; fatty acids and a non-ionic detergent for increased cleaning effectiveness.
This formulation can cause eye irritations upon repeated long term contact, however.
Futhermore, in US Patent No. 4,620,937 the addition of Aloe Vera juice to the formulation to protect the user's hands during use and to reduce the risk of skin irritation, is recommended.
the present invention is an essentially aqueous, non-toxic, cleaning composition which comprises:
a highly effective cleaning composition can be prepared using ingredients that are suitable for ingestion by humans to thereby provide a powerful cleaner which is suitable for cleaning foods and surfaces that come into contact with foods.
the cleaning composition is based upon cold pressed citrus oil as a cleaning and fragrance enhancing agent. This material is obtained by an ambient pressure extraction of the citrus fruits' peel. Various citrus fruits such as oranges, grapefruit, limes and lemons are suitable sources for this ingredient. Lemon oil is preferred for use in the present formulation which will typically contain from 0.05 to 10.0 weight percent (preferably 0.3 to 1.4%) of the citrus oil.
the composition also contains an alkali metal carbonate and/or bicarbonate to control the composition's pH as well as to provide a source of alkalinity for the saponification of fatty oils.
an alkali metal carbonate and/or bicarbonate to control the composition's pH as well as to provide a source of alkalinity for the saponification of fatty oils.
there is present a combination of sodium carbonate and sodium bicarbonate wherein the weight ratio of carbonate to bicarbonate is from 1:9 parts carbonate to 1:10 parts bicarbonate.
the amounts and ratio of carbonate and bicarbonate are preferably selected so as to provide a composition having a pH of from 8.5 to 10.4 which is regarded as particularly safe for contact with human tissue.
the present cleaning composition contains an emulsifier/surfactant system comprising:
the emulsifier/surfactant system which typically makes up from 0.15 to 5.0 (preferably 2.0 to 4.0) weight percent of the cleaning composition, serves the purpose of allowing the finished composition to wet out, penetrate and lift the soil from the surface being cleaned. It also emulsifies the soil to keep it in solution so that it can be wiped up with minimal, if any, redeposition.
this system is key to the physical stability of the finished composition which is a microemulsion which requires sufficient levels of certain emulsifiers to keep it clear and prevent phase separation.
the sodium lauryl sulfate in the system provides wetting, penetrating and soil lifting attributes.
the other three ingredients are all emulsifiers which suspend the lifted soils.
the preferred fatty acid ester of polyoxyethylene (where the fatty acid can contain from 12 to 18 carbon atoms) is prepared by esterification of sorbitol with primarily lauric fatty acid under conditions which cause the splitting of water from the sorbitol.
the material is condensed with approximately 20 moles of ethylene oxide per mole of sorbitol to give it water solubility and can be obtained under the trade name Tween®, from ICI America Inc. This material will normally make up from 0.05 to 80 (preferably 50 to 65) weight percent of the emulsifier/surfactant system.
the ethoxylated mono or diglyceride are characterized by polyoxyethylene mono and diglycerides of stearic, palmitic and myristic acids.
This material which can be obtained under the tradename Durfax®, from Durkee, is normally present in an amount of from 0.05 to 20.0 (preferably 4 to 7) weight percent of the emulsifier/surfactant system.
the tartaric acid ester of a mono or diglyceride which is normally used in an amount of from 0.05 to 20 (preferably 4 to 7) weight percent of the emulsifier/surfactant system is preferably a diacetyl tartaric acid ester of a monoglyceride and can be obtained under the trade name Panodan® from Grinsted Products Inc.
emulsifier surfactant system from 0.05 to 40.0 weight percent (preferably 25 to 35) weight percent based on the emulsifier/surfactant of sodium lauryl sulfate which serves as a wetting agent to penetrate greasy, oily soils and help to lift them from the surface being cleaned.
Additional essential ingredients of the present cleaning composition are from 0.5 to 15.0 (preferably 2.5 to 7.0) weight percent ethanol which serves the dual function of drying agent and stabilizing agent to assist in maintaining the clarity of the finished composition.
0.05 to 2.0 (preferably 0.2 to 0.8) weight percent propylene glycol which acts primarily as a cosolvent to aid in the wetting out and lifting of soils. It also imparts some shine to the substrate and since it is a humectant, it contributes to a soft hand feel.
non-essential materials such as fragrances, preservatives and dyes provided that they are selected from those which are regarded as safe for use on food bearing surfaces.
a cleaning formulation was prepared according to the present invention containing the following ingredients: Deionized Water 91.3293% Trisodium citrate dihydrate 0.2500 Potassium sorbate 0.0500 Sodium bicarbonate 0.3000 Sodium carbonate 0.2000 Sodium lauryl sulfate (Stepanol WA-100®, Stepan) 0.5000 Ethanol 5.0000 IFF Fragrance #6703-AP (lemon) 0.1500 Cold pressed lemon oil (#3410-Sunkist) 0.5000 Butylated Hydroxyanisole (antioxidant) 0.0200 Polyoxyethylene (20) sorbitan monolaurate, Tween 20® 1.0000 Polyoxyethylene (20) mono and diglycerides of stearic, palmetic and myristic acids (Durfax EOM®-Durkee) 0.1000 Diacetyl tartaric acid ester of a monoglyceride (Panodan TR® -Grinsted Product Inc.) 0.1000 Propylene glycol 0.5000 F.D. & C. Yellow #6 (
the formulation was prepared by the following procedure:
Example I The formulation of Example I was tested for its ability to remove various solid from hard surfaces in the following manner:
Example I From the data of Table 1, it can be determined that the formulation prepared as described in Example I has cleaning power equivalent to that of the comparison cleaner. A difference of 3 to 5 ml with 15 to 25 wipes is not a significant difference in this test. This was confirmed via a consumer usage panel in which typical consumers compared a formula similar to that of Example I to the used comparison cleaner. Results from this study showed that consumers do not perceive a difference in cleaning performance between the composition of the present invention and the used comparison cleaner.
the cleaning composition of the present invention was subjected to various toxicological tests to determine its safety for use as an all purpose cleaner in areas where food preparation takes place. The results of these tests are summarized in Table 2. TABLE 2 Test Result Acute Oral Limit Test (50,000 mg/kg) >50,000 mg/kg Ocular Irritation (no irritation) Dermal Irritation (no irritation) Ames Test Neg w/activation Neg w/o activation

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Wood Science & Technology (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Detergent Compositions (AREA)

EP92106925A 1991-05-06 1992-04-23 Composition nettoyante inoffensive vis à vis des produits alimentaires Withdrawn EP0512328A1 (fr)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
US69589491A	1991-05-06	1991-05-06
US695894		1991-05-06

Publications (1)

Publication Number	Publication Date
EP0512328A1 true EP0512328A1 (fr)	1992-11-11

Family

ID=24794875

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP92106925A Withdrawn EP0512328A1 (fr)	1991-05-06	1992-04-23	Composition nettoyante inoffensive vis à vis des produits alimentaires

Country Status (4)

Country	Link
EP (1)	EP0512328A1 (fr)
JP (1)	JPH05140589A (fr)
CA (1)	CA2062075A1 (fr)
MX (1)	MX9202084A (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0619365A1 (fr) *	1993-04-07	1994-10-12	Sporrer, Erich	Composition nettoyante et procédé de sa fabrication
WO1998033400A1 (fr) *	1997-01-30	1998-08-06	Fruit Wash Oy	Composition detergente utilisable avec les aliments
GB2336374A (en) *	1998-04-14	1999-10-20	Reckitt & Colman Inc	Hard surface cleaning compositions
US6140284A (en) *	1998-04-14	2000-10-31	Reckitt Benekiser Inc.	Botanical oils as blooming agents in hard surface cleaning compositions
WO2002045530A3 (fr) *	2000-12-06	2003-02-20	Johnson Diversey Inc	Composition destinee au nettoyage des fruits, des legumes et des surfaces en contact avec les aliments
US6548085B1 (en) *	1998-04-15	2003-04-15	Woodstream Corporation	Insecticidal compositions and method of controlling insect pests using same
KR100389142B1 (ko) *	2000-10-11	2003-06-25	우강융	유자를 이용한 무공해 세제 및 그 제조방법
WO2003087283A1 (fr) *	2002-04-09	2003-10-23	Colgate-Palmolive Company	Composition liquide legere hautement mousseuse et eliminant la graisse, contenant au moins un extrait naturel
EP2345336A1 (fr) *	2010-01-15	2011-07-20	RUDOLF WILD GmbH & CO. KG	Composition de colorant
US9288977B2 (en)	2010-09-14	2016-03-22	Nof Corporation	Disinfectant detergent composition
WO2020058088A1 (fr) *	2018-09-18	2020-03-26	Unilever Plc	Composition détergente
WO2020058090A1 (fr) *	2018-09-18	2020-03-26	Unilever Plc	Composition détergente
WO2020058096A1 (fr) *	2018-09-18	2020-03-26	Unilever Plc	Composition détergente
CN112852559A (zh) *	2021-01-04	2021-05-28	保定冀中药业有限公司	一种中药制粒设备清洗剂及使用
WO2022165107A1 (fr) *	2021-01-29	2022-08-04	Danisco Us Inc	Compositions pour le nettoyage et procédés associés

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JP2007023065A (ja) *	2005-07-12	2007-02-01	Sanei Gen Ffi Inc	精油含有組成物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP0040882A1 (fr) *	1980-05-27	1981-12-02	THE PROCTER & GAMBLE COMPANY	Compositions détergentes liquides
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1992
- 1992-02-28 CA CA002062075A patent/CA2062075A1/fr not_active Abandoned
- 1992-04-23 JP JP12934892A patent/JPH05140589A/ja active Pending
- 1992-04-23 EP EP92106925A patent/EP0512328A1/fr not_active Withdrawn
- 1992-05-04 MX MX9202084A patent/MX9202084A/es unknown

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EP0619365A1 (fr) *	1993-04-07	1994-10-12	Sporrer, Erich	Composition nettoyante et procédé de sa fabrication
WO1998033400A1 (fr) *	1997-01-30	1998-08-06	Fruit Wash Oy	Composition detergente utilisable avec les aliments
GB2336374A (en) *	1998-04-14	1999-10-20	Reckitt & Colman Inc	Hard surface cleaning compositions
US6140284A (en) *	1998-04-14	2000-10-31	Reckitt Benekiser Inc.	Botanical oils as blooming agents in hard surface cleaning compositions
US6548085B1 (en) *	1998-04-15	2003-04-15	Woodstream Corporation	Insecticidal compositions and method of controlling insect pests using same
KR100389142B1 (ko) *	2000-10-11	2003-06-25	우강융	유자를 이용한 무공해 세제 및 그 제조방법
WO2002045530A3 (fr) *	2000-12-06	2003-02-20	Johnson Diversey Inc	Composition destinee au nettoyage des fruits, des legumes et des surfaces en contact avec les aliments
WO2003087283A1 (fr) *	2002-04-09	2003-10-23	Colgate-Palmolive Company	Composition liquide legere hautement mousseuse et eliminant la graisse, contenant au moins un extrait naturel
EP2345336A1 (fr) *	2010-01-15	2011-07-20	RUDOLF WILD GmbH & CO. KG	Composition de colorant
US9288977B2 (en)	2010-09-14	2016-03-22	Nof Corporation	Disinfectant detergent composition
WO2020058088A1 (fr) *	2018-09-18	2020-03-26	Unilever Plc	Composition détergente
WO2020058090A1 (fr) *	2018-09-18	2020-03-26	Unilever Plc	Composition détergente
WO2020058096A1 (fr) *	2018-09-18	2020-03-26	Unilever Plc	Composition détergente
CN112739807A (zh) *	2018-09-18	2021-04-30	联合利华知识产权控股有限公司	洗涤剂组合物
CN112805362A (zh) *	2018-09-18	2021-05-14	联合利华知识产权控股有限公司	洗涤剂组合物
CN112955531A (zh) *	2018-09-18	2021-06-11	联合利华知识产权控股有限公司	洗涤剂组合物
CN112852559A (zh) *	2021-01-04	2021-05-28	保定冀中药业有限公司	一种中药制粒设备清洗剂及使用
CN112852559B (zh) *	2021-01-04	2022-03-18	保定冀中药业有限公司	一种中药制粒设备清洗剂及使用
WO2022165107A1 (fr) *	2021-01-29	2022-08-04	Danisco Us Inc	Compositions pour le nettoyage et procédés associés

Also Published As

Publication number	Publication date
MX9202084A (es)	1992-11-01
JPH05140589A (ja)	1993-06-08
CA2062075A1 (fr)	1992-11-07

Legal Events

Date	Code	Title	Description
1992-09-26	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
1992-11-11	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FR GB GR IT LI LU NL SE
1993-04-14	17P	Request for examination filed	Effective date: 19930216
1993-10-27	17Q	First examination report despatched	Effective date: 19930910
1995-03-24	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN
1995-05-17	18D	Application deemed to be withdrawn	Effective date: 19940719

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EP0512328A1 (fr)	1992-11-11	Composition nettoyante inoffensive vis à vis des produits alimentaires
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KR100453354B1 (ko)	2005-01-27	다용도세정제조성물
JPH11209797A (ja)	1999-08-03	クリーニング剤
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