EP0674580A1 - Verbesserter biaxial orientierter copolyesterfilm für magnetischen aufzeichnungsträger - Google Patents

Verbesserter biaxial orientierter copolyesterfilm für magnetischen aufzeichnungsträger

Info

Publication number
EP0674580A1
EP0674580A1 EP93901467A EP93901467A EP0674580A1 EP 0674580 A1 EP0674580 A1 EP 0674580A1 EP 93901467 A EP93901467 A EP 93901467A EP 93901467 A EP93901467 A EP 93901467A EP 0674580 A1 EP0674580 A1 EP 0674580A1
Authority
EP
European Patent Office
Prior art keywords
biaxially oriented
film
protrusions
film according
oriented copolyester
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP93901467A
Other languages
English (en)
French (fr)
Other versions
EP0674580A4 (de
Inventor
Cynthia Bennett
E-Won Choe
John Anthony Flint
Bodo Kuhmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Polyester Film GmbH
Original Assignee
Hoechst AG
Hoechst Celanese Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Hoechst Celanese Corp filed Critical Hoechst AG
Publication of EP0674580A1 publication Critical patent/EP0674580A1/de
Publication of EP0674580A4 publication Critical patent/EP0674580A4/de
Withdrawn legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
    • G11B5/739—Magnetic recording media substrates
    • G11B5/73923—Organic polymer substrates
    • G11B5/73927—Polyester substrates, e.g. polyethylene terephthalate
    • G11B5/73935—Polyester substrates, e.g. polyethylene terephthalate characterised by roughness or surface features, e.g. by added particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
    • G11B5/739—Magnetic recording media substrates
    • G11B5/73923—Organic polymer substrates
    • G11B5/73927—Polyester substrates, e.g. polyethylene terephthalate
    • G11B5/73929—Polyester substrates, e.g. polyethylene terephthalate comprising naphthalene ring compounds, e.g. polyethylene naphthalate substrates
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
    • G11B5/00—Recording by magnetisation or demagnetisation of a record carrier; Reproducing by magnetic means; Record carriers therefor
    • G11B5/62—Record carriers characterised by the selection of the material
    • G11B5/73—Base layers, i.e. all non-magnetic layers lying under a lowermost magnetic recording layer, e.g. including any non-magnetic layer in between a first magnetic recording layer and either an underlying substrate or a soft magnetic underlayer
    • G11B5/739—Magnetic recording media substrates
    • G11B5/73923—Organic polymer substrates
    • G11B5/73927—Polyester substrates, e.g. polyethylene terephthalate
    • G11B5/73931—Two or more layers, at least one layer being polyester
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514—Oriented
    • B32B2307/518—Oriented bi-axially

Definitions

  • This invention relates to an improved biaxially oriented copolyester film for thin metallic magnetic recording media. More specifically, this invention relates to a biaxially oriented copolyester film which has a smooth surface and excellent running characteristics onto which a magnetic recording layer can be coated to form a thin film magnetic recording media.
  • the copolyester employed contains at least 25 mole percent of its diester or diacid being 4,4'- bibenzoic acid. The remainder of the copolyester may be formed from other diacids or diesters as is known in the art. 21 Prior Art
  • the surface of the substrate is preferably as smooth as possible.
  • the smoothness of the film surface is a detriment.
  • smoothness of the film surface results in poor slipperiness between film surfaces and causes the phenomenon of blocking.
  • the surface of the substrate support is required to be smooth on the side that will carry the magnetic recording layer and rough on the surface which will contact adjacent surfaces upon winding.
  • PET (polyethylene terephthalate) substrates with improved surfaces are disclosed for instance in European Patent Application 0 203 604 or German Patent Application 34 14 310, but these films have inherent problems with other demands on improved tape substrates.
  • Another demand associated with the magnetic tape industry is the desire to create thinner and thinner magnetic recording media tape. This will permit more and more information to be stored in the same space or in a smaller volume, while allowing better images for video tape and more crisp sounds in audio tape. Good mechanical properties of the substrate are desirable so that the magnetic recording film can be reduced in thickness. Accordingly, there is a demand for high stiffness (tensile modulus) and strength so that the thinness of the film can be decreased.
  • Another aim of the present invention is to produce a smooth surface on a substrate with excellent running characteristics and good abrasion resistance such that the substrate can be further processed to make excellent magnetic recording film.
  • the present invention relates to a biaxially oriented mono- or multilayer copolyester film wherein the two surfaces of the film have different surface roughness, characterized in that at least one layer essentially consists of PENBB and the first surface of the film has large protrusions with a diameter of 0.2 to 2 ⁇ m and the second surface has either no protrusions or small protrusions with a diameter smaller than the ones of the large protrusions on the first surface.
  • the invention relates to a biaxially oriented PENBB film (B) having fine particulate filler media incorporated therein to provide surface roughness.
  • One or both sides of the film may carry a cover layer (layer A and optional layer C), which modifies the roughness of the surface.
  • One side of this film (A) is smoother than the other (side B or C), the smoother side A being suitable for coating with high density magnetic recording layers such as of the metallic type.
  • Layer C if present, serves to improve the abrasion resistance.
  • the present invention relates to a biaxially oriented PENBB film, wherein one surface (A) is smooth and the other surface (B or C) has large protrusions with an average diameter of 0.2 to 2 ⁇ m and an average height of 2 to 20 nm arranged at a density of least 10 3 but less than
  • Suitable copolyesters for the present invention must contain at least 25 mole percent of the diester or diacid of 4,4'-bibenzoic acid or 4,4'-dimethyl- naphthalate, containing the following repeat unit:
  • BB-containing copolyesters are called PENBB.
  • the remainder of the copolyester may be formed from other dicar ⁇ boxylic acids or their ester equivalents, such as terephthalic acid, isophthalic acid, phthalic acid, naphthalene-2,6-dicarboxylic acid, 1 ,4-cyclohexane dicarboxylic acid, di-(4-phenyl)-acetylene dicarboxylic acid, sebacic acid, malonic acid, adipic acid, azelaic acid, glutaric acid, suberic acid, succinic acid, and the like, or mixtures of these.
  • Naphthalane-2,6-dicarboxylic acid or its ester equivalent is the preferred portion for the remainder of the co ⁇ polyester.
  • Suitable diols employed in the present invention include ethylene glycol, diethylene glycol, polyethylene glycol, butane diol, 1 ,5 pentane diol, 1 ,6- hexane diol, naphthalene glycol, 1 , 10-dexane dioi, 1 ,4-cyclohexane dimethy- lol, and the like.
  • Ethylene glycol is the preferred glycol.
  • Useable PENBB copolyester of the present invention can comprise, for example, polyethylene terephthalate/4,4'-bibenzoate, polybutylene terepht- ha late/4, 4'-bibenzoate, polypropylene terepht ha late/4, 4'-bibenzoate, polyethylene naphthalate/4,4'-bibenzoate, polyethylene terephthalate/- azealate/4,4'-bibenzoate,polyethyleneterephthalate/adipate/4,4'-bibenzoate, polyethylene terephthalate/ 4,4'-bibenzoate, and the like.
  • the PENBB comprises a copolyester prepared from ethylene glycol and a mixture of roughly equimolar amounts (i.e. molar ratio 6:4 to 4: 6) of the dialkyl esters of 4,4'-bibenzoic acid and
  • a polycondensation reaction is carried out according to known processes.
  • the diacids or their ester equivalents and the glycols are mixed uniformly and heated to approximately 200°C in the presence of a trans- esterification catalyst, as is well known in the art.
  • the reaction yields oligomeric or low molecular weight polyester which is subsequentially subjected to the polycondensation reaction in the presence of polyconden ⁇ sation catalysts.
  • stabilizers, antioxidants, delustrants, pigments, fillers, and antistatic agents may be uniformly mixed with the raw materials or copolyester.
  • Suitable catalysts are manganese, cobalt, magnesium, zinc, calcium compounds, etc. as well known in the art.
  • the preferred transesterification catalyst, where employed, is based on manganese and/or cobalt.
  • the preferred polycondensation catalysts would be such compounds as antmony oxide. Such catalysts are well known and conventional in the prior art.
  • U.S. Patent No. 3,008,934 discloses copolyesters containing as acid derived units 4,4'-bibenzoate and a host of other dicarboxylates including 2,6- naphthalic dicarboxylate. It also discloses oriented fibers and films prepared from these copolyesters, however, biaxially oriented PENBB films are not disclosed or envisioned . In particular, those films with improved stiffness (tensile modulus) and tensile strength in both MD and TD as well as thermostability and dimensional stability in comparison to PET film are not disclosed in U.S. Patent No. 3,008,934.
  • the PENBB film of the present invention can be manufactured by an extrusion process.
  • the IV value inherent viscosity, as measured in a 1 : 1 weight-ratio mixture of pentafluorophenol an ⁇ hexafluoroisopropanol at a concentration of 0.2 g/dl and a temperature of 25 ° C
  • the IV value of the PENBB polymer after extrusion be > 0.5 dl/g and preferably > 0.55 dl/g.
  • the copolyester resin is first heated to a molten stage then extruded through a wide slot die in the form of an amorphous sheet onto a polished, revolving casting drum.
  • the amorphous sheet extrudate is rapidly cooled or "quenched " to form a cast sheet of copolyester.
  • the cast sheet is removed from the casting drum and axially stretched in one direction, either in the direction of the film travel (machine direction) or perpendicular to the machine direction (transverse direction), while being heated to a temperature between the glass transition temperature and about 30°C above the cold crystallization temperature (both temperatures being easily measured by differential scanning colorimetry, DSC) .
  • the PENBB film of this invention is biaxially oriented (stretched in both machine direction and the transverse direction) .
  • the total stretch ratio in the machine direction and the transverse direction lie between 1 : 2 and 1 : 10, preferably between 1 :2.5 and 1 : 5.
  • the product of the total stretch ratios should be between 1 - 30 and preferably between 5 - 20.
  • Biaxial drawing is performed such that the birefringeance is ⁇ 0.2, preferably ⁇ 0.1 to ensure adequately isotropic properties.
  • Birefringeance as mentioned herein is the absolute value of the difference between the maximum and minimum refractive indices in the plane of the film, as measured on common in ⁇ struments such as Abbe refractometer, optical bench or compensators.
  • a heat setting step occurs to lock in the properties of the film.
  • the heat setting step occurs at a temperature between the cold crystallization temperature and the melt temperature of the copolyester composition. After heat setting, the film may be wound on a roll.
  • the film prefferably has a final total thickness between 2 and 3
  • the main feature of the biaxially oriented PENBB film of this invention is that the surface of the rougher side (B or C) contains: (a) many large protrusions with a diameter of 0.2 to 2 ⁇ m, and a height from about 2 to 20 nm; and (b) optionally many small protrusions with a diameter of about 1 0 to about 100 nm and a height of about 1 to 1 0 nm.
  • the other (smoother) side A may contain such small protrusions but should contain no large ones.
  • a thin metallic film as a magnetic recording layer is to be applied .
  • the density of the distribution of the large and small protrusions is also important.
  • the density of distribution for the large protrusions is at least 1 0 3 but at less than 10 6 /mm 2 .
  • the density of distribution for the small protrusions is from 1 0 6 to 1 0 9 /mm 2 . If these large and small protrusions on the surfaces of the copolyester substrate satisfy these conditions, noise in resulting magnetic metal recording layer applied to side A is drastically reduced, and the resultant magnetic film has markedly superior noise level with excellent running properties, thermal stability, and appropriate thickness reduction.
  • the large protrusions have a diameter of 0.5 to 2 ⁇ m, especially 0.5 to 1 .5 ⁇ m and a height of 5 to 20 nm, especially 7 to 1 5 nm, and the density of this distribution is from 1 0 4 to 1 0 5 /mm 2 .
  • the small protrusions preferably have a diameter of 50 to 1 00 nm and a height from about 1 to 1 0 nm, especially 2 to 7 nm, and the density of distribution of small protrusions is from 10 7 - 10 8 /mm 2 .
  • the diameter, height and distribution density of the large and small protrusions on the surface of the PENBB film of the present invention are measured by the following methods.
  • the film surface is photo ⁇ graphed through a differential interference microscope and the diameters of the protrusions are measured on the basis of the photograph at a magnifi- cation of about 400 X with an average value being calculated .
  • the surface is photogra ⁇ phed with a scanning electron microscope at a magnification of about 45,000 X.
  • the average diameter is calculated from that of 20 protrusions.
  • the distance from the peak to the bottom of the protrusions is measured by the use of a profilo- meter having a high precision stylus contacting the surface of the biaxially oriented PENBB film of the present inventions.
  • the height is measured with a scanning electron microscope using a magnification of about 80,000 X in the planar direction and about 800,000 to 2,400,000 X in the vertical direction. The average height is calculated from 1 0 protrusions.
  • suitable particles to provide good handling and winding properties of the film are as follows.
  • Such fine particles can be:
  • silicates containing at least 30 % by weight of Si0 2 [for ex ⁇ ample, amorphous or crystalline clay minerals, aluminosilicates (including calcined products or hydrates), chrysotile, zirconium, flyash, etc.];
  • titanates of Mg, Ca, Ba, Zn, Cd, Pb, Sr, Mn, Fe, Co and Ni titanates of Mg, Ca, Ba, Zn, Cd, Pb, Sr, Mn, Fe, Co and Ni
  • chromates of Ba and Pb carbon (such as carbon black and graphite)
  • glass (glass powder and glass beads) carbonates of Ca and Mg
  • fluorspar fluorspar
  • sulfides of Zn and Mo sulfides of Zn and Mo
  • fine particles made of cross-linked polymers such as polystyrenes, polyacrylates or polymethacrylates.
  • Particles may be of one type or mixtures of several types.
  • the shape of the particles can be irregular, flaky, spherical or elongated.
  • the inert solid fine particles preferably have average diameter of 0.05 to 2 ⁇ m, especially 0.05 to 1 ⁇ m.
  • the above- described surface topography is produced by incorporating the larger inert solid fine particles in the base layer of the biaxially oriented PENBB film (layer B) and the optional smaller inert solid fine particles in the cover layers (A and C) .
  • the cover layers make up between 0.05 and 20 % of the total thickness of the film, wherein the required thickness depends on the type of the larger inert fine particles in use and can be determined by simple experimentation.
  • the larger inert solid fine particles should not contain more than 5 % by weight, and especially not more than 2% by weight of particles more than 1 ⁇ m in diameter.
  • the amount of the larger inert fine particles to be incorpora- ted into the copolyester is generally 0.005 to 1 % by weight, preferably 0.005 to 0.5% by weight, based on the weight of the copolyester.
  • the larger inert solid fine particles can be dispersed within the copolyester by a variety of known methods.
  • the inert solid fine particles can be added in the form of glycol slurry during the ester interchange or transification reaction.
  • the particles can be added to the reaction chamber just before or during the polycondensation reaction such that the particles are uniformly dispersed throughout the copolyester. Incorporation of the inert solid fine particles produces the larger protrusions on the film surface in layer B or C after stretching and heat setting the PENBB film.
  • the optional smaller protrusions are produced by including smaller inert fine particles in the cover layers A and C.
  • Such optional smaller fine particles generally have an average diameter of 10 to 100 nm, preferably 50 to 100 nm. Because the cover layers A and C are relatively thin, it is essential that the optional smaller fine particles do not contain an excessive amount of larger particles, i.e. the amount of particles larger than 0.3 ⁇ m should make up less than 5 weight-% of the total smaller fine particles.
  • the cover layers A or C can be produced by either of two methods, coating the film, preferably in-line, with a polymeric dispersion or solution or by coextruding the base film with layers of other polymer(s), preferably a polyester and more preferably a copolyester.
  • the smaller fine particles are optionally contained in the coating dispersion or solution or the coextruded polymer.
  • they are preferably dispersed in a method similar to that used for the larger fine inert particles in layer B.
  • a coating composition composed of inorganic or organic smaller inert solid fine particles and organic polymeric binder is applied to one or both the first surfaces of the film which has been stretched in at least one direction, preferably between the draws for biaxially ' orienting the PENBB film.
  • the inert solid fine particles incorporated or uniformly blended with the copolyester referred to above may also be employed for the coating composition, however, the size restrictions for the smaller inert fine particles noted above apply.
  • the coating composition may be solvent-based or aqueous-based .
  • an aqueous based coating composition is employed .
  • the polymeric binder is preferably water soluble or water dispersable.
  • Known aqueous-based coating compositions based on modified polyester copolymers, acrylates, methacrylates, melamine resin, polyvinylalcohol, polyethers, starches, cellulosics, etc. are acceptable.
  • Solvent based coatings employing polyurethane, polyvinylalcohol, melamine resin, epoxy resins, as are conventional and known in the art are a:so satisfactory.
  • the amount of smaller inert solid fine particles in the organic polymeric binder may vary depending upon the degree of biaxial orientation employed . Generally, a suitable amount of smaller inert solid fine particles is 0 to 50 parts by weight and more preferably 20 to 30 parts by weight, per 1 00 parts by weight of the organic polymeric binder employed .
  • the coating composition may also contain suitable additives such as cross-linking agents, polymeriza ⁇ tion catalysts, heat stabilizers or UV absorbers, anti-static agents, surface active agents or filler dispersion or lubricants in effective amounts.
  • the suitable amount of the organic polymeric binder is generally 1 to 20% by weight of the coating composition and preferably 2 to 1 0% by weight of the coating composition.
  • the coating thickness on the surface of the biaxially oriented PENBB film, on a dry weight basis is generally 1 to 5 mg/m 2 , and preferably 1 to 2.5 mg/m 2 .
  • the coaxing composition can be applied by means of roll coating, gravure coating, air knife coating, meniscus coating, reverse gravure coating, or dipping Drying and curing the coated film may be carried out at a temperature suffic . nt to quickly evaporate the solvent or aqueous portion of the coating composition . When the coating is applied between draws of the biaxially oriented film, generally the last draw and the heatset- ting stage of the process for producing the biaxially oriented PENBB film is sufficient to evaporate the solvent and the water.
  • melts of these layers are supplied to multimanifold coextrusion die, where they are combined with the melt for layer B, and the combined eit layers are extruded onto a chill roll .
  • the coextruded polymer may be any thermoplastic polymer which will survive the film making and drawing processes of the biaxially oriented copolyester film, and exhibit sufficient adhesion to the copolyester layer B.
  • polyesters and copolyesters are used for coextruded layers A and
  • polyesters and copolyesters may be, for example, poly- ethylene terephthalate and its copolymers with other diacids, such as isophthalic acid, 5-sodium sulfoisophthalic acid, phthalic acid, adipic acid, sebacic acid, naphthalene 2, 6-dicarboxylic acid and/or 4,4'-bibenzoic acid, etc.
  • Layers A and optional layer C may be made up of the same or different polymers with the same or different particle content. Layer C, if present, preferably is thinner than layer A.
  • the coated or coextruded smooth surface A of the biaxially oriented PENBB film has a surface roughness value R a not greater than 5 nm and R 2 not greater than 100 nm.
  • the rougher surface B or C of the coated or coextruded biaxially oriented PENBB film of the present invention has a surface roughness (R a ) generally from 2 to 1 00 nm, and preferably from 3 to 20 nm.
  • the average of the difference between the highest peaks and lowest valleys (R z ) of the surface is generally from 20 to 1 ,000 nm and preferably from 30 to 200 nm.
  • R a is measured by using a high precision surface roughness tester - profilometer.
  • a sample of film approximately 1 .25 cm in length is employed and the profilometer is drawn across the surface of the film under a load 30 mg with a cut-off of 0.08 mm using a stylus with a radius of 2 ⁇ m.
  • the surface roughness is an average of at least 4 measured values. The average surface roughness
  • the peak-to-valley average surface roughness (R 2 ) is measured using the profilometer, load, stylus, and cut-off previously mentioned.
  • the average of the difference between the high peaks and low valleys is generally the average of 5 measurements.
  • Tensile properties were determined in a tensile testing machine produced by Zwick GmbH of Ulm, Germany, using the following parameters: sample dimensions 1 50 x 1 5 mm testing length 1 00 mm draw rate (modulus) 1 0 mm/min draw rate (tensile strength) and elongation 1 00 mm/min
  • Heat shrinkage was determined by measuring the dimensional change of a 100x1 00 mm square film sample after 1 5 minute exposure to 1 50 °C in a forced-air oven.
  • the residual melt is granulated .
  • the granules are white, opaque and crystalline.
  • An IV value of 0.56 dl/g is determined for the granules (measured at a concentration of 0.1 g/mi in pentafluorophenol/hexafluoroisopropanol [weight ration 1 : 1 ] at 25 °C) .
  • the granules are further condensed for 20 hours at 240 °C under vacuum in the solid phase. After this treatment the IV value is 1 .1 dl/g. The melting point (T is 270 °C.
  • Example 2 The same procedure as in Example 1 is followed, except that 289 parts by weight of dimethyl 2, 6-naphthalene dicarboxylate and 322 parts by weight of dimethyl-4,4'-bibenzoate are employed and 23 parts of a slurry of BaSO 4 particles in ethylene glycol is added to the transesterified mixture just before adding the triphenyl phosphate and antimony trioxide.
  • This slurry is prepared by dispersing 10 parts by weight of BaSO 4 with an average particle diameter of 1 .0 ⁇ m in 30 parts by weight of ethylene glycol.
  • the resulting copolyester contains 0.3 wt.-% BaS0 4 particles and melts at 281 °C.
  • the copolyesters prepared according to examples 1 and 2 are each melted in separate extruders, sent to a multimanifold slot die via 2 gear pumps, combined to form a two-layer film, where the polymer from example 1 forms the layer A and the polymer of example 2 forms the base layer B, and cooled on a chill roll to 20 °C.
  • the thus obtained amorphous film is heated to 1 25 °C and drawn by a factor of 3.5 in MD, then by 3.5 in TD.
  • the film is then heat set under restraint at 260 °C for 10 seconds to afford a two- layer biaxially oriented PENBB film 8 ⁇ m thick with a rough and a smooth side, which can be wound with no difficulty.
  • the thickness of layer A is 0.5 ⁇ m and that of layer B is 7.5 ⁇ m.
  • the mechanical properties are:
  • the shrinkage, measured after 25 min. treatment in a forced-air oven at 1 50 °C is 0.3 % in both MD and TD.
  • the water pickup of the film at 50 % r. h. and 25 °C is 0.04 %.
  • EXAMPLE 4 (comparative) A monolayer film is prepared from the copolyester according to Example 1 in a manner similar to example 3, except that only one extruder is used. After drawing, it is difficult to wind this film due to wrinkles and blocking.
  • the roughness R a of a portion of the film is:
  • a copolyester is prepared similarly to example 2, except that instead of BaSO 4 , kaolin particles with an average diameter of 0. 1 ⁇ m were added in amount to give a final concentration of 0.1 wt.-%.
  • An aqueous 2 wt.- % solids coating composition is prepared from aluminum acrylate, polyoxyethylene diol, polyoxyethylene diglycidyl ether, polyoxyethylene nonyl phenyl ether and colloidal silica with an average particle size of 75 nm in a weight ration of 1 0: 5 :2: 1 :9.
  • the copolyester is melted in an extruder at 310 °C and extruded as a monolayer film through a slot die onto a chill roll temperature controlled at 25 °C, using pinning to give an amorphous sheet.
  • the amorphous sheet is stretched in the longitudinal direction by a factor of 3.5 at a temperature of 1 25 °C.
  • the film is then coated on both sides of the film by means of gravure rolls carrying different amounts of coating, whereupon the film is stretched in the transverse direction by a factor of 3.5 at 1 25 °C, and heat set at 260 °C, to provide a three-layer, biaxially oriented PENBB film with a total thickness of 8 ⁇ m.
  • Layer A has a thickness of 20 nm and layer C a thickness of 2nm.
  • the film can be handled and wound easily without blocking, exhibiting excellent abrasion resistance.
  • the R a of surface A is 4 nm and that of surface C is 7 nm.
  • the R 2 of surface A is 60 nm and that of surface C is 80 nm.
  • Surface C has 20,000/mm 2 large protrusions with an average height of 1 1 nm and average diameter of 0.8 ⁇ m and 4 10 7 /mm 2 small protrusions with an average height of 4 nm and an average diameter of 70 nm.

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  • Laminated Bodies (AREA)
  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Magnetic Record Carriers (AREA)
EP93901467A 1992-12-09 1992-12-09 Verbesserter biaxial orientierter copolyesterfilm für magnetischen aufzeichnungsträger. Withdrawn EP0674580A4 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1992/010706 WO1994013463A1 (en) 1992-12-09 1992-12-09 Improved biaxially oriented copolyester film for magnetic recording media

Publications (2)

Publication Number Publication Date
EP0674580A1 true EP0674580A1 (de) 1995-10-04
EP0674580A4 EP0674580A4 (de) 1995-11-22

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Application Number Title Priority Date Filing Date
EP93901467A Withdrawn EP0674580A4 (de) 1992-12-09 1992-12-09 Verbesserter biaxial orientierter copolyesterfilm für magnetischen aufzeichnungsträger.

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Country Link
EP (1) EP0674580A4 (de)
JP (1) JP2931849B2 (de)
WO (1) WO1994013463A1 (de)

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EP0787579B1 (de) * 1996-02-05 2002-10-09 Teijin Limited Biaxial orientierte Verbundfolie
DE10110432A1 (de) * 2001-03-05 2002-09-19 Mitsubishi Polyester Film Gmbh Amorphe, gedeckt eingefärbte Folie aus einem bibenzolmodifizierten Thermoplasten, Verfahren zu ihrer Herstellung und ihre Verwendung
KR102783233B1 (ko) * 2018-11-19 2025-03-19 도레이 카부시키가이샤 2축 배향 열가소성 수지 필름

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JP2931849B2 (ja) 1999-08-09
EP0674580A4 (de) 1995-11-22
WO1994013463A1 (en) 1994-06-23
JPH08505164A (ja) 1996-06-04

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