EP0689583B1 - Composition pour le nettoyage des fours - Google Patents
Composition pour le nettoyage des fours Download PDFInfo
- Publication number
- EP0689583B1 EP0689583B1 EP94909120A EP94909120A EP0689583B1 EP 0689583 B1 EP0689583 B1 EP 0689583B1 EP 94909120 A EP94909120 A EP 94909120A EP 94909120 A EP94909120 A EP 94909120A EP 0689583 B1 EP0689583 B1 EP 0689583B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- composition
- hand
- methyl ether
- glycol methyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 238000004140 cleaning Methods 0.000 title claims abstract description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 9
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- JDSQBDGCMUXRBM-UHFFFAOYSA-N 2-[2-(2-butoxypropoxy)propoxy]propan-1-ol Chemical compound CCCCOC(C)COC(C)COC(C)CO JDSQBDGCMUXRBM-UHFFFAOYSA-N 0.000 claims abstract description 5
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims abstract description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004480 active ingredient Substances 0.000 claims abstract 2
- 239000011877 solvent mixture Substances 0.000 claims abstract 2
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 12
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000004665 fatty acids Chemical class 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000013543 active substance Substances 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 claims description 2
- 239000006260 foam Substances 0.000 claims description 2
- 239000003205 fragrance Substances 0.000 claims description 2
- 229910021647 smectite Inorganic materials 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000003381 stabilizer Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 abstract description 2
- 229940072033 potash Drugs 0.000 abstract description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 2
- 235000015320 potassium carbonate Nutrition 0.000 abstract description 2
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 2
- 239000010935 stainless steel Substances 0.000 abstract description 2
- 210000003298 dental enamel Anatomy 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000004872 foam stabilizing agent Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 230000037406 food intake Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/652—Mixtures of anionic compounds with carboxylic amides or alkylol amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0057—Oven-cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1266—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
Definitions
- the cleaning products for ovens currently on the market essentially have, in weight ratios, 5 to 10% solvents and 10 to 15% basic raw materials, which are generally characterized by a mixture of an alkaline base such as soda or pattas and one or more amines of monoethanolamine are formed.
- Such products have been developed with a satisfactory effectiveness for cleaning the classic enamel stoves, but not for cleaning the so-called self-cleaning stoves (catalysis, pyrolysis).
- the present invention has for its object to remedy this situation by proposing a new composition for cleaning the stoves, which has the advantages of the known composition for cleaning classic enamel stoves, but at the same time with the property that they are satisfactory for the Cleaning the new ovens made of non-oxidizing steel and "grill / hot air" ovens is usable.
- composition according to the invention When used as a spray, particularly strong foaming is achieved.
- the composition has between 10 and 15 percent by weight of solvent, the amount of propylene glycol ether preferably being about 2 to 4 times higher than the amount of dipropylene glycol ether.
- the composition can have between 0.5 and 10% by weight sodium carbonate (soda). Taking into account the safety of use and to better prevent the risk of accidents caused by contact or ingestion of these products, manufacturers have been trying for several years to reduce the maximum amount of caustic and pickling substances contained in the compositions intended for cleaning ovens.
- the cleaning agent according to the invention shows its effectiveness with a sodium carbonate content already below 2%, and it is advantageous not to exceed this limit.
- the basic base material preferably consists of a mixture of 0.5 to 2% sodium carbonate and 2 to 10, preferably 2 to 6% by weight of amine, preferably monoethanolamine.
- the composition has between 0.5 and 2% of a thickener, for example Smectitton.
- a thickener for example Smectitton.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Claims (9)
- Composition de nettoyage de fours contenant comme constituants actifs pour une part une substance de base basique, formée d'au moins une base alcaline comme du carbonate de sodium et/ou une ou plusieurs amines et pour l'autre part un solvant difficilement volatil,
caractérisée en ce que
la composition renferme de 10 à 30 % en poids d'un mélange de solvants qui est formé, pour une part, d'éther méthylique de propylèneglycol et, pour l'autre part, d'éther méthylique de dipropylèneglycol, dans laquelle le rapport pondéral de l'éther méthylique de propylèneglycol à l'éther méthylique de dipropylèneglycol se situe entre 30:70 et 90:10. - Composition selon la revendication 1,
caractérisée en ce que
la composition possède entre 10 et 15 % en poids de solvant, tandis que la quantité d'éther de propylèneglycol est de préférence 2 à 4 fois plus grande que la quantité d'éther de dipropylèneglycol. - Composition selon l'une des revendications 1 à 2,
caractérisée en ce que
la composition renferme entre 0,5 et 10 % en poids de carbonate de sodium. - Composition selon l'une des revendications 1 à 3,
caractérisée en ce que
la composition renferme moins de 2 % en poids de carbonate de sodium. - Composition selon la revendication 4,
caractérisée en ce que
la substance de base basique est un mélange de 0,5 à 2 % en poids de carbonate de sodium et de 2 à 6 % en poids d'amine, de préférence de la monoéthanolamine. - Composition selon l'une des revendications 1 à 5,
caractérisée en ce que
la composition renferme entre 0,5 et 2 % en poids d'un agent épaississant. - Composition selon l'une des revendications 1 à 6,
caractérisée en ce que
la composition renferme jusqu'à 2 % en poids d'un agent tensioactif. - Composition selon l'une des revendications 1 à 7,
caractérisée en ce que
le mélange renferme jusqu'à 2 % en poids d'un agent qui stabilise la mousse. - Composition selon l'une des revendications 1 à 8,
caractérisée en ce que
la composition renferme les constituants suivants :0,5 à 10 de préférence 0,2 à 2 % en poids de carbonate de sodium,2 à 10 de préférence 2 à 6 % en poids de Monoéthanolamine10 à 30 de préférence 10 à 15 % en poids d'un mélange de méthyléther de dipropylèneglycol et de méthyléther de Propylèneglycol,0,5 à 2 de préférence 1 % en poids d'un argile du type smectite,0 à 2 de préférence 0,1 à 1% en poids d'un amide d'acide gras,0 à 2 de préférence 0,1 à 1 % en poids de lauryl-éthersulfate de sodium,0 à 0,1 de préférence 0,05 % en poids de parfum et de l'eau.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9302951 | 1993-03-15 | ||
| FR9302951A FR2702775B1 (fr) | 1993-03-15 | 1993-03-15 | Composition pour le nettoyage des fours. |
| PCT/EP1994/000681 WO1994021776A1 (fr) | 1993-03-15 | 1994-03-07 | Composition pour le nettoyage des fours |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0689583A1 EP0689583A1 (fr) | 1996-01-03 |
| EP0689583B1 true EP0689583B1 (fr) | 1996-12-04 |
Family
ID=9444957
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP94909120A Expired - Lifetime EP0689583B1 (fr) | 1993-03-15 | 1994-03-07 | Composition pour le nettoyage des fours |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP0689583B1 (fr) |
| AT (1) | ATE145935T1 (fr) |
| DE (1) | DE59401211D1 (fr) |
| DK (1) | DK0689583T3 (fr) |
| ES (1) | ES2094650T3 (fr) |
| FR (1) | FR2702775B1 (fr) |
| GR (1) | GR3021915T3 (fr) |
| WO (1) | WO1994021776A1 (fr) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9401939D0 (en) * | 1994-02-02 | 1994-03-30 | Hunter John A I | Decarbonising liquid and powder therefor |
| DE69625066T2 (de) * | 1995-07-18 | 2004-01-29 | Johnson Diversey Inc | Konzentriertes wässriges reinigungsmittel zum entfetten |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1275740A (en) * | 1968-09-09 | 1972-05-24 | Johnson & Son Inc S C | Oven cleaning composition |
| AU499736B2 (en) * | 1975-01-24 | 1979-05-03 | American Cyanamid Company | Non-caustic oven cleaner |
| FR2571279B1 (fr) * | 1984-10-04 | 1987-01-30 | Dow Chemical France | Agent de rincage pour ensembles de pulverisation et atomisation, notamment a usage agricole, a base d'un ether de glycol derive du propylene glycol |
| US4686065A (en) * | 1986-05-23 | 1987-08-11 | Miles Laboratories, Inc. | Caustic based cleaning composition containing THFA and a propoxylated alcohol or phenol |
| JPS63234095A (ja) * | 1987-01-20 | 1988-09-29 | ザ ダウ ケミカル カンパニー | ガスタービン圧縮機清掃用組成物 |
| NZ224148A (en) * | 1987-04-10 | 1991-02-26 | Colgate Palmolive Co | Pre-spotting composition for food residue removal |
| US4943392A (en) * | 1988-06-03 | 1990-07-24 | The Procter & Gamble Company | Containing butoxy-propanol with low secondary isomer content |
| AU627734B2 (en) * | 1988-06-13 | 1992-09-03 | Colgate-Palmolive Company, The | Stable and homogeneous concentrated all purpose cleaner |
| AU4702289A (en) * | 1989-01-19 | 1990-07-26 | Sterling Drug Inc. | Hard surface cleaning composition |
-
1993
- 1993-03-15 FR FR9302951A patent/FR2702775B1/fr not_active Expired - Fee Related
-
1994
- 1994-03-07 AT AT94909120T patent/ATE145935T1/de not_active IP Right Cessation
- 1994-03-07 WO PCT/EP1994/000681 patent/WO1994021776A1/fr not_active Ceased
- 1994-03-07 EP EP94909120A patent/EP0689583B1/fr not_active Expired - Lifetime
- 1994-03-07 DE DE59401211T patent/DE59401211D1/de not_active Expired - Fee Related
- 1994-03-07 DK DK94909120.1T patent/DK0689583T3/da active
- 1994-03-07 ES ES94909120T patent/ES2094650T3/es not_active Expired - Lifetime
-
1996
- 1996-12-05 GR GR960403165T patent/GR3021915T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GR3021915T3 (en) | 1997-03-31 |
| FR2702775A1 (fr) | 1994-09-23 |
| FR2702775B1 (fr) | 1995-05-19 |
| WO1994021776A1 (fr) | 1994-09-29 |
| DE59401211D1 (de) | 1997-01-16 |
| DK0689583T3 (da) | 1997-04-28 |
| ATE145935T1 (de) | 1996-12-15 |
| ES2094650T3 (es) | 1997-01-16 |
| EP0689583A1 (fr) | 1996-01-03 |
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