EP0704769A1 - Elektrophotographischer Toner - Google Patents

Elektrophotographischer Toner Download PDF

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Publication number
EP0704769A1
EP0704769A1 EP95306186A EP95306186A EP0704769A1 EP 0704769 A1 EP0704769 A1 EP 0704769A1 EP 95306186 A EP95306186 A EP 95306186A EP 95306186 A EP95306186 A EP 95306186A EP 0704769 A1 EP0704769 A1 EP 0704769A1
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EP
European Patent Office
Prior art keywords
toner
particle
titanium oxide
fine
fine titanium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP95306186A
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English (en)
French (fr)
Inventor
Masahiko c/o Mita Industrial Co. Ltd. Kubo
Takatomo c/o Mita Industrial Co. Ltd. Fukomoto
Hiroyuki c/o Mita Industrial Co. Ltd. Murakami
Takashi c/o Mita Industrial Co. Ltd. Nishino
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Kyocera Mita Industrial Co Ltd
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Mita Industrial Co Ltd
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Publication date
Application filed by Mita Industrial Co Ltd filed Critical Mita Industrial Co Ltd
Publication of EP0704769A1 publication Critical patent/EP0704769A1/de
Withdrawn legal-status Critical Current

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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/0821—Developers with toner particles characterised by physical parameters
    • G03G9/0823—Electric parameters
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09708—Inorganic compounds
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G9/00—Developers
    • G03G9/08—Developers with toner particles
    • G03G9/097—Plasticisers; Charge controlling agents
    • G03G9/09708—Inorganic compounds
    • G03G9/09716—Inorganic compounds treated with organic compounds

Definitions

  • This invention relates to an electrophotographic toner. More particularly, it relates to an electrophotographic toner having a small particle size, which is used to attain a high image quality of the image formed.
  • a two-component developer comprising a toner and a magnetic carrier is used for the development in image forming apparatuses such as electrostatic copying machine, laser beam printer and the like.
  • the toner to be used for the two-component developer is normally produced by blending a colorant (e.g. carbon black, etc.), an electric charge controlling material, etc. in a fixing resin, and then kneading, pulverizing, classifying and granulating the mixture to give a particle having a predetermined particle size. Further, regarding such an electrophotographic toner, a surface treatment is conducted by adhering an additive of a fine particle having a particle size smaller than that of a toner particle on the surface of the toner particle so as to improve the fluidity, charging properties and charging stability.
  • a colorant e.g. carbon black, etc.
  • an electric charge controlling material e.g., etc.
  • classifying and granulating the mixture e.g., etc.
  • a surface treatment is conducted by adhering an additive of a fine particle having a particle size smaller than that of a toner particle on the surface of the toner particle so as to improve the fluidity, charging properties and charging stability.
  • a toner having a small particle size of not more than 9 ⁇ m has been put into practical use for the purpose of attaining a higher image quality of the image formed.
  • a toner having a small particle size is inferior in fluidity in comparison with a conventional one, there is a problem that the toner is liable to cause blocking to form a toner agglomerate.
  • the toner having a small particle size is unstable in charging properties in comparison with a conventional one, there is a also problem that toner scattering due to charging failure, or image failure (e.g. fog caused by adhering the toner on the blank space area of the image formed, etc.) is liable to arise.
  • the fine silica particle mainly serves to improve the fluidity of the toner particle and to increase the charged amount of the whole toner.
  • the fine titanium oxide particle serves to make the charged amount of the whole toner particle uniform by assisting the movement of electric charges between toner particles to prevent a highly charged toner having the charged amount exceeding a predetermined charged amount, a weakly charged toner having the charged amount less than the predetermined charged amount and a inversely charged toner to be charged to an inverse polarity from generating, thereby stabilizing the charging properties of the toner.
  • the fine silica particle in the additive for the surface treatment there can be normally used a hydrophobic fine silica particle which can impart the moisture resistance and shelf stability to the toner.
  • the hydrophobic fine silica particle include a fine silica particle having a high hydrophobicity obtained by burning and hydrolyzing a volatile silicon compound (e.g. silicon tetrachloride, etc.) in a vapor phase and treating a silanol group on the surface of the particle of the resulting fumed silica with organosilane (e.g. dichlorodimethylsilane, etc.) or organosiloxane (e.g.
  • any conventional hydrophobic fine silica particle is liable to agglomerate and does not easily adhere on the surface of the toner particle, uniformly, it is necessary to add a large amount of the fine silica particle to impart the sufficient fluidity to the toner particle.
  • the inventors have studied intensively about a hydrophobic fine silica particle for treating the surface of the toner, in order to accomplish the above object.
  • the amount of the hydrophobic fine silica particle required to obtain a predetermined charged amount is small and the amount of the hydrophobic fine silica particle to be adhered on the surface of the fine titanium oxide particle is small when the toner particle is subjected to the surface treatment using the hydrophobic fine silica particle and, therefore, the effect for assisting the movement of electric charges between toner particles is not disturbed.
  • the electrophotographic toner of this invention comprises a toner particle and an additive for treating a surface of the toner, the additive comprising a combination of a hydrophobic fine silica particle treated with hexamethyldisilazane and at least one of the following fine titanium oxide particles (a) to (c):
  • the fine titanium oxide particle treated with the polyhydric alcohol to be used in combination with the hydrophobic fine silica particle treated with hexamethyldisilazane does not easily agglomerate and can adhere uniformly on the surface of the toner particle together with the hydrophobic silica, so that it is superior in effect for assisting the movement of electric charges between toner particles.
  • the fine titanium oxide particle having a resistivity of 106 to 108 ⁇ cm has a suitable electric charge moving capability to the toner particle, the movement of electric charges between toner particles is smoothly conducted and, therefore, it is superior in effect for making the charged amount of the whole toner uniform.
  • the fine titanium oxide particle wherein an absolute charged amount obtained when it is charged by mixing with a magnetic carrier to be used for charging the toner particle is 5 to 80 ⁇ C/g and a charging polarity is the same as that of the toner, has a suitable electric charge moving capability to the toner particle, similar to the fine titanium oxide particle having a resistivity of 106 to 108 ⁇ cm. Therefore, the movement of electric charges between toner particles is smoothly conducted so that it is superior in effect for making the charged amount of the whole toner uniform.
  • the electrophotographic toner of this invention comprising at least one of the above three sorts of fine titanium oxide particles in combination with the above hydrophobic fine silica particle is superior in fluidity, charging properties and charging stability.
  • Fig. 1 is a perspective view illustrating an apparatus for evaluating the fluidity of a toner.
  • the hydrophobic fine silica particles to be used in this invention may be those in which a silanol group on the surface of the silica fine particle is treated with hexamethyldisilazane.
  • Examples of the hydrophobic fine silica particle include Aerogyl R812 and RX200 manufactured by Nihon Aerogyl Co., Ltd.
  • silica fine particle which is the raw material for the above hydrophobic fine silica particle
  • a fumed silica obtained by burning and hydrolyzing a volatile silicon compound (e.g. silicon tetrachloride, etc.) in a vapor phase as described above.
  • a volatile silicon compound e.g. silicon tetrachloride, etc.
  • the silica fine particle may be reacted with hexamethyldisilazane in a reaction column of a fluid bed.
  • the hydrophobic fine silica particle is superior in effect for improving the fluidity of the toner particle, as described above, because it does not easily agglomerate in comparison with a conventional hydrophobic silica. Further, it exhibits a high hydrophobicity because the silanol group is scarcely present on the surface thereof and, therefore, the moisture-resistance and shelf stability of the toner can be extremely improved.
  • the particle size of the hydrophobic fine silica particle is not specifically limited in this invention, but the average particle size of a primary particle is preferably about 5 to 50 nm in view of the production process when using the above fumed silica. Further, it is preferred that the particle size distribution is sharp within a range of the above particle size, in order to obtain stable charging characteristics and fluidity.
  • the particle size of the hydrophobic fine silica particle is smaller than the above range, the hydrophobic fine silica particles are likely to agglomerate.
  • the average particle size of the hydrophobic fine silica particle (primary particle) is preferably 7 to 30 nm, more preferably 10 to 20 nm, in order to obtain a toner having stable charging characteristics and fluidity.
  • the amount of the hydrophobic fine silica particle to be added is preferably about 0.01 to 5 parts by weight, more preferably 0.05 to 2 parts by weight, most preferably 0.1 to 1 parts by weight, based on 100 parts by weight of the toner particle.
  • the amount of the hydrophobic fine silica particle When the amount of the hydrophobic fine silica particle is smaller than the above range, the effect for improving the fluidity of the toner particle tends to become insufficient, thereby causing blocking to form a toner agglomerate. Further, since no effect for increasing the charged amount of the whole toner is obtained, the charged amount of the toner tends to become insufficient, thereby causing image failure such as decrease in image density of the image formed.
  • the amount of the hydrophobic fine silica particle exceeds the above range, the charged amount of the whole toner tends to become too large.
  • the excessive hydrophobic fine silica particle is liable to adhere on the surface of the fine titanium oxide particle to prevent the fine titanium oxide particle from adhering on the surface of the toner particle, thereby obtaining the insufficient effect for assisting the movement of electric charges between toner particles.
  • the distribution of the charged amount is widen to generate the highly charged toner, weakly charged toner and inversely charged toner, thereby causing image failure such as toner scattering, fog, etc.
  • fine titanium oxide particle to be used in this invention there are fine titanium oxide particles (a) to (c) as described above.
  • the fine titanium oxide particle (a) can be obtained by sintering, pulverizing and classifying a titanium oxide particle to give a fine titanium particle, followed by treating the surface of the fine particle with a polyhydric alcohol.
  • polyhydric alcohol examples include trimethylolpropane represented by the formula: CH3-CH2-C(CH2OH)3 (1) and pentaerythritol represented by the formula: C(CH2OH)4 (2)
  • the polyhydric alcohol may be added at the final stage of the pulverization of the titanium oxide particle, followed by mixing. This mixing enables a hydroxyl group of the polyhydric alcohol to bond to a hydrophilic group of a fine titanium oxide particle newly produced by the pulverization, thereby deteriorating agglomeration properties of the fine titanium oxide particle.
  • the particle size of the fine titanium oxide particle (a) is not specifically limited in this invention, but the average particle size of the primary particle thereof is preferably about 10 to 200 nm.
  • the average particle size of the fine titanium oxide particle is preferably 20 to 100 nm, more preferably 30 to 80 nm, in order to obtain a toner having stable charging characteristics and fluidity.
  • a convenient amount of the fine titanium oxide particle to be added is about 0.01 to 10 parts by weight, preferably 0.05 to 3 parts by weight, more preferably 0.1 to 2 parts by weight, based on 100 parts by weight of the toner particle.
  • the amount of the fine titanium oxide particle When the amount of the fine titanium oxide particle is smaller than the above range, the charged amount of the whole toner tends to become too large and, at the same time, the effect for assisting the movement of electric charges between toner particles becomes insufficient. Therefore, the distribution of the charged amount is widen to generate the highly charged toner, weakly charged toner and inversely charged toner, thereby causing image failure such as toner scattering, fog, etc.
  • the fine titanium oxide particle of (b) is limited to those which have a resistivity within a range of 106 to 108 ⁇ cm.
  • the resistivity of the fine titanium oxide particle When the resistivity of the fine titanium oxide particle is smaller than the above range, the charged amount of the whole toner tends to decrease, thereby causing image failure such as decrease in image density of the image formed.
  • the resistivity exceeds the above range, the effect for assisting the movement of electric charges between toner particles is liable to become insufficient and, at the same time, the distribution of the charged amount is widen to generate the highly charged toner, weakly charged toner and inversely charged toner, thereby causing image failure such as toner scattering, fog, etc.
  • the kind of a treating agent for imparting a hydrophobicity to the surface of the fine titanium oxide particle may be changed, or the amount of the treating agent to be added may be adjusted.
  • the treating agent are various coupling agents such as silane, titanate, aluminum and zircoaluminate coupling agents, or silicone oil.
  • a dry process comprising adding dropwise or spraying a treating agent alone or a diluted solution thereof while the fine titanium oxide particle is forcibly stirred with a blender, mixing additionally, drying the mixture in an oven, stirring again with a blender and then pulverizing.
  • a wet process comprising mixing a fine titanium oxide particle with a treating agent in appropriate organic solution, drying the mixture and then pulverizing.
  • the resistivity of the fine titanium oxide particle can also be adjusted by changing the amount of antimony and tin oxide to be added in the coated layer so as to adjust the conductivity.
  • the particle size of the fine titanium oxide particle of (b) is not specifically limited, but the average particle size of the primary particle thereof is preferably about 10 to 200 nm, more preferably 20 to 100 nm, most preferably 30 to 80 nm, because of the same reason as that of the above fine titanium oxide particle (a).
  • the amount of the above fine titanium oxide particle to be added is preferably about 0.01 to 10 parts by weight, more preferably 0.05 to 3 parts by weight, most preferably 0.1 to 2 parts by weight, based on 100 parts by weight of the toner particle, because of the same reason as that described above.
  • the fine titanium oxide particle of the above (c) is limited to those in which an absolute charged amount obtained when it is charged by mixing with a magnetic carrier to be used for charging the toner particle is 5 to 80 ⁇ C/g and a charging polarity is the same as that of the toner. That is, in case of fine titanium oxide particle for negatively charged toner, the charged amount is limited within a range of -5 to -80 ⁇ C/g. In case of fine titanium oxide particle for positively charged toner, the charged amount is limited within a range of +5 to +80 ⁇ C/g.
  • the absolute charged amount When the absolute charged amount is smaller than the above range or the charged polarity is contrary to that of the toner, the charged amount of the whole toner is decreased, thereby causing image failure such as decrease in image density of the image formed.
  • the absolute charged amount exceeds the above range, the charged amount of the whole toner tends to become too large and, at the same time, the distribution of the charged amount is widen to generate the highly charged toner, weakly charged toner and inconversely charged toner, thereby causing image failure such as toner scattering, fog, etc.
  • the absolute charged amount of the fine titanium oxide particle is preferably 8 to 70 ⁇ C/g within the above range, more preferably 10 to 60 ⁇ C/g.
  • the charged amount defined herein is not an inherent absolute value of the fine titanium particle, but a relative value which varies depending upon the kind of a magnetic carrier to be used, as described above. That is, there may be used a fine titanium oxide particle wherein the absolute charged amount becomes within the above range when it is charged by mixing with the magnetic carrier to be actually used for charging the toner particle.
  • a conventional measuring method which has hitherto been known, such as blow off method, for the measurement of the charged amount.
  • the method for adjusting the charged amount of the fine titanium oxide particle there can be suitably employed a method using the fact that the charged amount varies depending upon the resistivity of the fine titanium oxide particle. That is, the resistivity of the fine titanium oxide particle may be adjusted so that the charged amount may be within the above range when it is mixed with the magnetic carrier to be actually used for charging the toner particle.
  • the particle size of the fine titanium oxide particle of (c) is not specifically limited, but the average particle size of the primary particle thereof may be about 10 to 200 nm, preferably 20 to 100 nm, more preferably 30 to 80 nm, because of the same reason as that of the above fine titanium oxide particle (a).
  • the amount of the above fine titanium oxide particle to be added is preferably about 0.01 to 10 parts by weight, more preferably 0.05 to 3 parts by weight, most preferably 0.1 to 2 parts by weight, based on 100 parts by weight of the toner particle, because of the same reason as that described above.
  • the toner particle to be used in this invention there can be used any known toner which has hitherto been used in the dry development process.
  • a toner is normally produced by dispersing an additive such as colorant in a fixing resin.
  • the fixing resin examples include styrene polymer, acrylic polymer, styrene-acrylic polymer, olefin polymer (e.g. chlorinated polystyrene, polypropylene, ionomer, etc.), poly(vinyl chloride), polyester, polyamide, polyurethane, epoxy resin, diallyl phthalate resin, silicone resin, ketone resin, poly(vinyl butyral) resin, phenol resin, rosin-modified phenol resin, xylene resin, rosin-modified maleic resin, rosin ester and the like.
  • the acrylic polymer or styrene-acrylic polymer is preferred in view of ease of pulverization and ease of control of the molecular weight distribution. In case of toner for full color, a polyester having excellent color mixture properties is preferred.
  • Examples of the colorant to be dispersed in the fixing resin include acetylene black, carbon black, aniline black and the like.
  • magenta there can be used magenta, cyan and yellow pigments.
  • magenta colorant examples include C.I. Pigment Red 49, C.I. Pigment Red 57, C.I. Pigment Red 81, C.I. Pigment Red 122, C.I.Solvent Red 19, C.I Solvent Red 49, C.I. Solvent Red 52, C.I. Basic Red 10, C.I. Dispers Red 15, etc., which are classified according to the color index.
  • quinacridone pigments such as C.I. Pigment Red 122 are suitably used in view of tint of the magenta colorant.
  • Examples of the cyan colorant include C.I. Pigment Blue 15, C.I. Pigment Blue 16, C.I. Solvent Blue 55, C.I. Solvent Blue 70, C.I. Direct Blue 25, C.I. Direct Blue 86, etc., which are classified according to the color index.
  • copper phthalocyanine pigments such as C.I. Pigment Blue 15 are suitably used in view of tint of the cyan colorant.
  • yellow colorant examples include azo pigments such as C.I. Pigment Yellow 1, C.I. Pigment Yellow 5, C.I. Pigment Yellow 12, C.I. Pigment Yellow 15, C.I. Pigment Yellow 17, etc., which are classified with the color index; inorganic pigments such as yellow iron oxide, yellow ocher, etc.
  • the dye examples include nitro dyes such as C.I. Acid Yellow 1, etc.; oil-soluble dyes such as C.I. Solvent Yellow 2, C.I. Solvent Yellow 6, C.I. Solvent Yellow 14, C.I. Solvent Yellow 15, C.I. Solvent Yellow 16, C.I. Solvent Yellow 19, C.I. Solvent Yellow 21, etc.
  • benzidine pigments such as C.I. Pigment Yellow 12 are suitably used in view of tint of the yellow colorant.
  • An amount of the colorant to be added is preferably 1 to 30 parts by weight, more preferably 2 to 20 parts by weight, based on 100 parts by weight of the fixing resin.
  • Examples of the typical additive other than colorant include electric charge controlling materials, offset inhibitors and the like.
  • the electric charge controlling material is blended for controlling friction charging properties of the toner, and classified into two types, i.e. electric charge controlling materials for controlling positive and negative electric charges, according to charging characteristics of the toner.
  • Examples of the electric charge controlling material for controlling positive electric charge include organic compounds containing a basic nitrogen atom, such as basic dye, aminopyrine, pyrimidine compound, polynuclear polyamino compound, aminosilanes and the like.
  • Examples of the electric charge controlling material for controlling negative electric charge include oil-soluble dyes [e.g. nigrosine base (C.I. 5045), oil black (C.I. 26150), spiron black, etc.], metal-containing azo pigments, metal naphthenate salts, metal salts of alkyl salicylate, fatty acid soaps, resin acid soaps and the like.
  • oil-soluble dyes e.g. nigrosine base (C.I. 5045), oil black (C.I. 26150), spiron black, etc.
  • metal-containing azo pigments e.g. nigrosine base (C.I. 5045), oil black (C.I. 26150), spiron black, etc.
  • metal-containing azo pigments e.g. nigrosine base (C.I. 5045), oil black (C.I. 26150), spiron black, etc.
  • metal-containing azo pigments e.g. nigrosine base (C.I.
  • the amount of the electric charge controlling material to be added is preferably 0.1 to 10 parts by weight, more preferably 0.5 to 8 parts by weight, based on 100 parts by weight of the fixing resin.
  • the offset inhibitor is blended in order to impart the offset inhibition effect to the toner.
  • the offset inhibitor include aliphatic hydrocarbons, aliphatic metal salts, higher fatty acids, fatty acid esters or a partially saponified material thereof, silicone oil, various wax.
  • aliphatic hydrocarbons having an weight-average molecular weight of about 1,000 to 10,000 are preferred.
  • low-molecular weight polypropylene, low-molecular weight polyethylene, paraffin wax, low-molecular weight olefin polymer of an olefin unit having 4 or more carbon atoms, silicone oil, etc. may be suitable used alone or in combination thereof.
  • the amount of the offset inhibitor to be added is preferably 0.1 to 10 parts by weight, more preferably 0.5 to 8 parts by weight, based on 100 parts by weight of the fixing resin.
  • a magnetic toner as an one-component developer can be obtained.
  • the magnetic substance is a substance which is strongly magnetized by a magnetic field in the direction thereof. It is preferred that the magnetic substance to be used in this invention is a fine particle having a particle size of not more than 1 ⁇ m, particularly about 0.01 to 1 ⁇ m, which is chemically stable.
  • typical magnetic substances include iron oxides such as magnetite, hematite, ferrite, etc.; metals such as iron, cobalt, nickel, etc.; alloys of these metals with aluminium, cobalt, copper, lead, magnesium, tin, zinc, antimony, beryllium, bismuth, cadmium, calcium, manganese, selenium, titanium, tungsten and vanadium; or a mixture thereof.
  • the amount of the magnetic substance powder to be added is preferably 20 to 300 parts by weight, more preferably 50 to 150 parts by weight, based on 100 parts by weight of the fixing resin.
  • additives such as stabilizers, etc. may be blended in the appropriate amount.
  • the particle size of the toner particle is not specifically limited in this invention. However, it is preferred to use a small particle size toner having an average particle size of not more than 9 ⁇ m, in order to obtain an image having a high image quality, as described above.
  • the average particle size of the small particle size toner is preferably 4 to 9 ⁇ m, more preferably 6 to 8 ⁇ m, within the above range, in view of the improvement of the image quality.
  • this invention can also be applied to a normal toner other than the small particle size toner, and therefore the average particle size of the toner particle may exceeds the above range.
  • the electrophotographic toner of this invention is produced by treating a surface of the toner with the above hydrophobic fine silica particle and fine titanium oxide particle.
  • the surface treatment is conducted by mixing the above respective components in the above amount to be added, followed by mixing with stirring.
  • the hydrophobic fine silica particles and titanium oxide can be uniformly adhered on the surface of the respective toner particles.
  • a mixing apparatus for example, there can be used various apparatuses which have hitherto been known, such as Henschel mixer, V type mixer and the like.
  • the hydrophobic fine silica particle and fine titanium oxide particle can also be mixed with the toner particle, simultaneously. However, in order to adhere both fine particles uniformly on the surface of the toner particle, respectively, it is preferred that one fine particle is mixed with the toner particle to adhere on the surface of the toner and, thereafter, the other fine particle is mixed with the above toner particle to adhere on the surface thereof.
  • the electrophotographic toner thus obtained can be suitably used for a one-component or two-component developer.
  • the electrophotographic toner of this invention which is obtained by subjecting the toner particle containing the magnetic substance (or no magnetic substance) to the above-described surface treatment, may be used as it is.
  • the electrophotographic toner of this invention which was subjected to the above-described surface treatment may be mixed with a carrier.
  • the carrier there can be used glass beads, oxidized or non-oxidized iron powders, magnetic substance particles of ferrite, cobalt, etc., or those of which surface is coated with synthetic resins (e.g. acrylic resin, styreneacrylic resin, fluororesin, silicone resin, polyester resin, etc.) and the like.
  • synthetic resins e.g. acrylic resin, styreneacrylic resin, fluororesin, silicone resin, polyester resin, etc.
  • the concentration of the toner is preferably 2 to 15 % by weight.
  • 100 parts by weight of a polyester resin as the fixing resin, 5 parts by weight of a quinacridone pigment as the colorant and 2 parts by weight of a zinc compound of salicylic acid as the electric charge controlling material for controlling negative electric charge were molten, kneaded, pulverized and classified to produce a toner particle having an average particle size of 8 ⁇ m, respectively.
  • 100 parts by weight of the toner particle obtained in the above production of the toner particle was mixed with a hydrophobic fine silica particle shown in Table 1, of which an amount is shown in the same Table 1, with stirring using a Henschel mixer. Further, a fine titanium oxide particle shown in Table 1 was added in an amount shown in the same table and the mixture was stirred to produce a negatively charged electrophotographic toner, respectively.
  • This apparatus comprises a hopper 1 on which a sample toner is placed, a toner feed roller 2 provided on a bottom opening 11 of the hopper 1 , and a pan 3 provided at the lower position of them.
  • the toner feed roller 2 is a metal cylinder having a diameter of 20 mm, and has the irregularities on the surface thereof.
  • the roller 2 is designed that the sample toner falls on the pan 3 from the hopper 1 when the roller 2 rotates.
  • a predetermined amount of the toner is placed on the hopper 1 and the toner feed roller 2 is allowed to rotate at a predetermined rate to determine the amount of the toner to be fallen on the pan 3 in a predetermined period of time, thereby evaluating the fluidity of the toner.
  • the rotating rate of the toner feed roller 2 was set at 3 rpm to measure the amount of the toner to be fallen on the pan 3 in a period of 5 minutes. The results show that, the more the amount of the toner fallen, the higher the fluidity of the toner is.
  • Each toner obtained in the above respective Examples and Comparative Examples was mixed with a coating carrier (obtained by coating the surface of a ferrite particle with a styrene-acrylic resin, average particle size: 65 ⁇ m) to prepare a two-component developer having a toner concentration of 4 % by weight.
  • An image was formed with the developer 20,000 times, using an electrostatic copying machine (model DC-4585, manufactured by Mita Industrial Co., Ltd.), and the image density of the blank space area of the final image formed was measured using a reflection densitometer (RD-918, manufactured by Macbeth Co.).
  • the state of the interior of the copying machine after forming the image 20,000 times was visually judged and evaluated according to the following criteria.
  • the toner of Example 1 of this invention which was subjected to the surface treatment using the hydrophobic fine silica particle treated with hexamethyldisilazane and fine titanium oxide particle treated with a polyhydric alcohol (trimethylolpropane), is superior in fluidity, and no image failure (e.g. toner scattering, fog, etc.) generates.
  • a polyhydric alcohol trimethylolpropane
  • Example 1 and Comparative Examples 1 to 7 According to the same manner as that described in Example 1 and Comparative Examples 1 to 7 except for using the fine titanium oxide particle having the resistivity [ ⁇ cm] shown in Table 2 in an amount shown in the same table, a negatively charged electrophotographic toner was prepared.
  • the toners obtained in the respective Examples and Comparative Examples were subjected to the above respective tests such as fluidity test, measurement of the fog density and observation of toner scattering, and characteristics thereof were evaluated. The results are shown in Table 2.
  • the toners of Examples 2 and 3 which were subjected to the surface treatment using the hydrophobic fine silica particle treated with hexamethyldisilazane and fine titanium oxide particle having a resistivity of 106 to 108 ⁇ cm, are superior in fluidity, and no image failure (e.g. toner scattering, fog, etc.) generates.
  • Example 1 According to the same manner as that described in Example 1 or Comparative Examples 1 to 7 except for using a fine titanium oxide particle having the charged amount [ ⁇ C/g] obtained when it is mixed the coating carrier shown in Table 3 in the amount shown in the same table, a negatively charged electrophotographic toner was prepared.
  • the toners obtained in the respective Examples and Comparative Examples were subjected to the above respective tests such as fluidity test, measurement of the fog density and observation of toner scattering, and properties thereof were evaluated. The results are shown in Table 3.
  • the toners of Examples 4 to 6 which were subjected to the surface treatment using the hydrophobic fine silica particle treated with hexamethyldisilazane and fine titanium oxide particle wherein an absolute charged amount obtained when it is charged by mixing with a coating carrier to be used for charging the toner particle is 5 to 80 ⁇ C/g and a charging polarity is the same as that of the toner, are superior in fluidity, and no image failure (e.g. toner scattering, fog, etc.) generates.
  • the electrophotographic toner of this invention can be superior in fluidity, charging properties and charging stability, because a specific hydrophobic fine silica particle is used in combination with a specific fine titanium oxide particle as an additive for subjecting a toner particle to a surface treatment. Accordingly, the construction of this invention can be suitably used for a small particle size electrophotographic toner for the purpose of attaining a high image quality.

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  • Inorganic Chemistry (AREA)
  • Developing Agents For Electrophotography (AREA)
EP95306186A 1994-09-22 1995-09-05 Elektrophotographischer Toner Withdrawn EP0704769A1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP228068/94 1994-09-22
JP6228068A JPH0895285A (ja) 1994-09-22 1994-09-22 電子写真用トナー

Publications (1)

Publication Number Publication Date
EP0704769A1 true EP0704769A1 (de) 1996-04-03

Family

ID=16870697

Family Applications (1)

Application Number Title Priority Date Filing Date
EP95306186A Withdrawn EP0704769A1 (de) 1994-09-22 1995-09-05 Elektrophotographischer Toner

Country Status (5)

Country Link
EP (1) EP0704769A1 (de)
JP (1) JPH0895285A (de)
KR (1) KR960011576A (de)
CN (1) CN1129815A (de)
TW (1) TW335461B (de)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0896252A1 (de) * 1997-08-04 1999-02-10 Ricoh Company, Ltd. Toner zur Entwicklung elektrostatischer Bilder und Bildaufzeichnungsmethode
EP0844536A3 (de) * 1996-11-26 2000-10-04 Canon Kabushiki Kaisha Bilderzeugungsverfahren
US8202502B2 (en) 2006-09-15 2012-06-19 Cabot Corporation Method of preparing hydrophobic silica
US8435474B2 (en) 2006-09-15 2013-05-07 Cabot Corporation Surface-treated metal oxide particles
US8455165B2 (en) 2006-09-15 2013-06-04 Cabot Corporation Cyclic-treated metal oxide
US8465718B2 (en) * 2007-07-26 2013-06-18 Industrial Technology Research Institute Superhydrophobic and self-cleaning powders having micron-scale diameter and nano-scale surface roughness and fabrication method thereof
US10407571B2 (en) 2006-09-15 2019-09-10 Cabot Corporation Hydrophobic-treated metal oxide

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3595631B2 (ja) * 1996-07-31 2004-12-02 キヤノン株式会社 静電荷像現像用トナー
KR100409079B1 (ko) * 2001-01-17 2003-12-11 주식회사 엘지화학 고 전사 효율을 가지는 토너 조성물 및 그 제조방법
JP2004109898A (ja) * 2002-09-20 2004-04-08 Ricoh Co Ltd 負帯電性トナー
AU2003266697A1 (en) * 2002-10-02 2004-04-23 Matsushita Electric Industrial Co., Ltd. Carrier for electrophotography
JP2009015260A (ja) * 2007-07-09 2009-01-22 Sharp Corp トナー用外添剤、それを用いたトナーおよび画像形成装置
JP5102125B2 (ja) * 2008-06-27 2012-12-19 株式会社リコー 静電荷像現像用白色トナー、二成分現像剤、画像形成方法、画像形成装置、プロセスカートリッジ
CN104849971A (zh) * 2015-05-28 2015-08-19 湖北鼎龙化学股份有限公司 彩色调色剂及其制备方法、以及调色剂颗粒流动性的测试方法
US20190035521A1 (en) * 2016-01-20 2019-01-31 The University Of Tokyo Magnetic substance, magnetic toner, and magnetic powder

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4828954A (en) * 1986-08-14 1989-05-09 Fuji Xerox Co., Ltd. Toner composition with treated inorganic powder
EP0564002A1 (de) * 1988-03-08 1993-10-06 Canon Kabushiki Kaisha Toner für die Entwicklung elektrostatischer Bilder
US5272040A (en) * 1991-04-09 1993-12-21 Minolta Camera Kabushiki Kaisha Toner for developing electrostatic latent images

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4828954A (en) * 1986-08-14 1989-05-09 Fuji Xerox Co., Ltd. Toner composition with treated inorganic powder
EP0564002A1 (de) * 1988-03-08 1993-10-06 Canon Kabushiki Kaisha Toner für die Entwicklung elektrostatischer Bilder
EP0606100A1 (de) * 1988-03-08 1994-07-13 Canon Kabushiki Kaisha Zweikomponentenentwickler
US5272040A (en) * 1991-04-09 1993-12-21 Minolta Camera Kabushiki Kaisha Toner for developing electrostatic latent images

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0844536A3 (de) * 1996-11-26 2000-10-04 Canon Kabushiki Kaisha Bilderzeugungsverfahren
EP0896252A1 (de) * 1997-08-04 1999-02-10 Ricoh Company, Ltd. Toner zur Entwicklung elektrostatischer Bilder und Bildaufzeichnungsmethode
US8202502B2 (en) 2006-09-15 2012-06-19 Cabot Corporation Method of preparing hydrophobic silica
US8435474B2 (en) 2006-09-15 2013-05-07 Cabot Corporation Surface-treated metal oxide particles
US8455165B2 (en) 2006-09-15 2013-06-04 Cabot Corporation Cyclic-treated metal oxide
US10407571B2 (en) 2006-09-15 2019-09-10 Cabot Corporation Hydrophobic-treated metal oxide
US8465718B2 (en) * 2007-07-26 2013-06-18 Industrial Technology Research Institute Superhydrophobic and self-cleaning powders having micron-scale diameter and nano-scale surface roughness and fabrication method thereof

Also Published As

Publication number Publication date
TW335461B (en) 1998-07-01
JPH0895285A (ja) 1996-04-12
KR960011576A (ko) 1996-04-20
CN1129815A (zh) 1996-08-28

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