EP0708932A1 - Photographisches element mit verringerter restanfärbung - Google Patents

Photographisches element mit verringerter restanfärbung

Info

Publication number
EP0708932A1
EP0708932A1 EP94921905A EP94921905A EP0708932A1 EP 0708932 A1 EP0708932 A1 EP 0708932A1 EP 94921905 A EP94921905 A EP 94921905A EP 94921905 A EP94921905 A EP 94921905A EP 0708932 A1 EP0708932 A1 EP 0708932A1
Authority
EP
European Patent Office
Prior art keywords
dispersion
scavenger
crystalline solid
disulfonamidophenol
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP94921905A
Other languages
English (en)
French (fr)
Inventor
Mary Christine Brick
Norma Bettina Platt
Paul Leo Zengerle
Jeffery Louis Hall
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of EP0708932A1 publication Critical patent/EP0708932A1/de
Withdrawn legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C1/00—Photosensitive materials
    • G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
    • G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
    • G03C7/392—Additives
    • G03C7/39208—Organic compounds
    • G03C7/39212—Carbocyclic
    • G03C7/39216—Carbocyclic with OH groups

Definitions

  • This invention relates to a method of reducing dye stain in a photographic element and to a photographic element having reduced dye stain.
  • scavengers for oxidized developing agents to photographic elements to allow the scavenger to interact with the oxidized developing agent and prevent unwanted reaction between oxidized developer and components of the photographic element.
  • scavengers for oxidized developing agent known in the art are disulfonamidophenol derivatives disclosed in U.S. Patents Nos. 4,205,987 to Erikson et al, 4,447,523 to Ross et al and 4,952,474 to Tsukahara et al.
  • One aspect of this invention comprises a photographic element comprising a support having thereon at least one silver halide emulsion layer, and a layer, which is the same or different from the silver halide layer, comprising crystalline solid particles consisting essentially of a disulfonamidophenol oxidized developer scavenger dispersed in an aqueous medium.
  • Another aspect of the present invention comprises a process for preparing a crystalline solid particle dispersion of a disulfonamidophenol oxidized developer scavenger, comprising the steps of: (a) milling crystalline solid particles of the scavenger in an aqueous medium in the presence of a dispersing agent and in the substantial absence of an organic solvent to form a first dispersion; and
  • a further aspect of this invention comprises a process of preparing a photographic element which comprises the steps of: (a) milling the crystalline solid of the scavenger in an aqueous medium in the presence of a dispersing agent and in the substantial absence of an organic solvent to form a first dispersion;
  • This invention provides a method of reducing undesired dye stain in a photographic element when a disulfonamidophenol oxidized developer scavenger is used. This is achieved by the use of the scavenger in the form of a crystalline solid particle dispersion.
  • disulfonamidophenol oxidized developer scavengers are used as conventional oil-in-water dispersions, and their use in the form of crystalline solid particle dispersions has not, up to now, been described or suggested.
  • disulfonamidophenol oxidized developer scavengers useful in the practice of the present invention are well known and can be prepared by synthesis techniques known in the art.
  • Preferred disulfonamidophenol scavengers have the formula:
  • R and R! represents a substituted or unsubstituted alkyl or aryl group
  • G is hydroxy or an alkali labile precursor thereof; each of R ⁇ and R3 is individually alkyl of 1 to 30 carbon atoms, aryl of 6 to 30 carbon atoms or heterocyclic of 5 to 30 carbon atoms containing one or more ring hetero atoms; and each of R ⁇ , R5 and R ⁇ is individually hydrogen, halogen, alkyl of 1 to 30 carbon atoms, alkoxy of 1 to 30 carbon atoms or aryloxy of 6 to 30 carbon atoms; each of Ar 1 and Ar 2 independently is an aryl group; and each of R 7 , R 8 , and R 9 independently is a monovalent group such as hydrogen, a halogen atom, an alkyl group, a cycloalkyl group, an aralkyl group, an aryl group, an alkenyl group, an alkynyl group, a heterocyclic group, an alkoxy group, an alkylthio group, or an acylamino group, each of which may
  • Particularly preferred disulfonamidophenol scavengers are compounds of the formula:
  • the scavenger compounds should be crystalline solids and substantially water insoluble at coating conditions, which generally involve temperatures from 10 C to 50 C, and pH from 5.0 to 7.0.
  • the crystalline solid particle dispersion can be formed by precipitating or reprecipitating the compound in the form of a dispersion in the presence of one or more dispersing agents, or by well known milling techniques. Reprecipitating techniques which involve dissolving the scavenger and precipitating by changing the solvent and/or pH in the presence of a dispersing agent are well known in the art. Reprecipitating techniques are described, for example, in US Application Serial No. 07/812,503 by Texter, et al, filed 12/20/91, and are herein incorporated by reference.
  • Milling techniques are also well known in the art, and examples include ball milling, media milling, attritor milling, jet milling or colloid milling the scavenger in the presence of a dispersing agent.
  • the dispersing agent is preferably an anionic, nonionic or zwitterionic surfactant, or a water soluble homopolymer or copolymer. Mixtures of two or more dispersing agents can be used in the practice of this invention.
  • the total amount of dispersing agent can vary over a wide range, generally from about 1% to about 200%, preferably about 5% to about 100%, the percentages being by weight, based on the weight of the scavenger.
  • Particularly preferred dispersing agents are an alkali metal salt of an alkarylene sulfonic acid, such as the sodium salt of dodecyl benzene sulfonic acid, the sodium salt of isopropylnaphthalene sulfonic acid or a mixture of monomers, dimers, trimers and tetramers of the sodium salt of isopropylnaphthalene sulfonic acid; an alkali metal salt of an alkyl sulfuric acid, such as sodium decyl sulfate or sodium dodecyl sulfate; or an alkali metal salt of an alkyl sulfosuccinate, such as sodium bis (2-ethylthexyl) succinic sulfonate, diethylpentyl sodium sulfosuccinate, dimethylpentyl sodium sulfosuccinate.
  • an alkali metal salt of an alkarylene sulfonic acid such as the sodium
  • milling media is used to prepare the dispersion
  • the mill is charged with the media such as, for example, spheres of silica, sand, zirconium oxide, zirconium silicate, alumina, titania, glass, etc.
  • the bead sizes typically range from 0.25 to 3.0 millimeters (mm) in diameter.
  • the scavenger particles in the dispersion should have mean diameters from 0.01 to 10.0 micrometers ( ⁇ m) and preferably from 0.05 to 5.0 micrometers ( ⁇ m) .
  • the use of solid particle dispersions in imaging are described, for example in, US Patent No. 4,006,025 to Swank et al and US Patent No.
  • the scavenger compounds can be used in the ways and for the purposes that scavengers for oxidized developing agent are employed in the art. They can be incorporated in a silver halide emulsion layer of the photographic element or in a separate layer of the element. When incorporated in a separate layer, that layer is preferably an interlayer between silver halide emulsion layers although it can be an undercoat layer coated below all of the silver halide emulsion layers or an overcoat layer coated above all of the silver halide emulsion layers.
  • the two silver halide layers preferably comprise a coupler that can react with oxidized developer such as a color developer to form or release a photographically useful group.
  • oxidized developer such as a color developer
  • photographically useful groups are known in the art and may be groups such as dyes, development modifiers such as development inhibitors, and the like.
  • the amount of scavenger compound employed will depend upon the particular purpose for which the scavenger is to be used and the degree of scavenging desired. Typically useful results are obtained when the scavenger is employed in an amount of between about 5 and 1000 mg/sq. meter per layer.
  • the vehicle for the crystalline solid particle dispersion can be essentially any photographic vehicle, such as gelatin and other hydrophilic colloids, or various synthetic polymers such as polyvinyl alcohol or acrylamide polymers.
  • Photographic vehicles commonly employed in silver halide photographic elements are described in Research Disclosure. December 1978, Item No. 17643, Section IX, the disclosure of which is incorporated herein by reference.
  • the photographic elements of the present invention can be simple black-and-white or monochrome elements comprising a support bearing a layer of the silver halide emulsion, or they can be multi-layer and/or multicolor elements. They can be designed for processing with separate solutions or for in-camera processing.
  • Multicolor elements contain dye image forming units sensitive to each of the three primary regions of the spectrum. Each unit can be comprised of a single emulsion layer or of multiple emulsion layers sensitive to a given region of the spectrum.
  • the layers of the element, including the layers of the image-forming units, can be arranged in any desired order.
  • the emulsion or emulsions can be disposed as one or more segmented layers, e.g., as by the use of microvessels or microcells, as described in U.S. Patent No. 4,362,806 to Whitmore.
  • a preferred photographic element comprises a support bearing at least one blue-sensitive silver halide emulsion layer having associated therewith a yellow image dye-providing material, at least one green-sensitive silver halide emulsion layer having associated therewith a magenta image dye-providing material and at least one red- sensitive silver halide emulsion layer having associated therewith a cyan image dye-providing material, the element containing a scavenger of this invention.
  • the scavenger is in an interlayer between silver halide emulsion layers sensitive to the same or different silver halide emulsion layers.
  • the elements of the present invention can contain additional layers conventional in photographic elements, such as overcoat layers, spacer layers, filter layers, antihalation layers, pH lowering layers (sometimes referred to as acid layers and neutralizing layers), timing layers, opaque reflecting layer, opaque light-absorbing layers and the like.
  • the support can be any suitable support used with photographic elements. Typical supports include polymeric films, paper (including polymer-coated paper) , glass and the like. Details regarding supports and other layers of the photographic elements of this invention are contained in Research Disclosure, December 1978, Item 17643, referred to above.
  • the support can be coated with a magnetic recording layer as discussed in Research Disclosure 34390 of November 1992, the disclosure of which is incorporated herein by reference.
  • the light-sensitive silver halide emulsions employed in the photographic elements of this invention can include coarse, regular or fine grain silver halide crystals or mixtures thereof and can be comprised of such silver halides as silver chloride, silver bromide, silver bromo-iodide, silver chlorobromide, silver chloroiodide, silver chlorobromoiodide, and mixtures thereof.
  • the emulsions can be negative working or direct positive emulsions. They can form latent images predominantly on the surface of the silver halide grains or in the interior of the silver halide grains. They can be chemically and spectrally sensitized in accordance with usual practices.
  • the emulsions typically will be gelatin emulsions although other hydrophilic colloids can be used in accordance with usual practice. Details regarding the silver halide emulsions are contained in Research Disclosure. Item 17643, December 1978, and the references listed therein.
  • the photographic silver halide emulsions can contain other addenda conventional in the photographic art. Useful addenda are described, for example, in Research Disclosure, December 1978, Item 17643.
  • Useful addenda include spectral sensitizing dyes and desensitizers, antifoggants, masking couplers, DIR couplers, DIR compounds, anti-stain agents, image dye stabilizers, absorbing materials, coating aids, plasticizers and lubricants, and the like.
  • the dye image-providing material employed in the photographic element can be incorporated in the silver halide emulsion layer or in a separate layer associated with the emulsion layer.
  • the dye image-providing material can be any of a number known in the art, such as dye-forming couplers, bleachable dyes, dye developers and redox dye- releasers, and the particular one employed will depend on the nature of the element and the type of image desired.
  • Dye image-providing materials employed with conventional color materials designed for processing with separate solutions are preferably dye-forming couplers; i.e., compounds which couple with oxidized developing agent to form a dye.
  • Preferred couplers which form cyan dye images are phenols and naphthols.
  • Preferred couplers which form magenta dye images are pyrazolones and pyrazolotriazoles.
  • Preferred couplers which form yellow dye images are benzoylacetanilides and pivalylacetanilides.
  • Dye image-providing materials useful in diffusion transfer film units contain a dye moiety and a monitoring moiety.
  • the monitoring moiety in the presence of an alkaline processing solution and as a function of silver halide development, is responsible for a change in mobility of the dye moiety.
  • These dye image-providing materials can be initially mobile and rendered immobile as a function of silver halide development, as described in U.S. Pat. No. 2,983,606. Alternatively, they can be initially immobile and rendered mobile, in the presence of an alkaline processing solution, as a function of silver halide development. This latter class of materials include redox dye-releasing compounds.
  • the monitoring group is a carrier from which the dye is released as a direct function of silver halide development or as an inverse function of silver halide development.
  • Compounds which release dye as a direct function of silver halide development are referred to as negative-working release compounds, while compounds which release dye as an inverse function of silver halide development are referred to as positive-working release compounds.
  • the developing agents that can be used to develop the photographic elements of this invention, the oxidized form of which can be reduced by the scavengers of this invention, include hydroquinones, aminophenols, 3-pyrazolidones and phenylene diamines . Some of these developing agents, when used for certain applications, are referred to in the art as electron transfer agents.
  • the particular developing agent employed will depend on the particular type of photographic element to be processed. For example, phenylene diamines are the developers of choice for use with color photographic elements containing dye-forming couplers, while 3-pyrazolidones are preferably used with image transfer materials containing redox dye releasers .
  • Representative developing agents include: hydroquinone, N-methylaminophenol, l-phenyl-3- pyrazolidone, l-phenyl-4, 4-dimethyl-3-pyrazolidone, 1- phenyl-4-methyl-4-hydroxymethyl-3-pyrazolidone, N,N- diethyl-p-phenylenediamine, 3-methyl-N,N-diethyl-p- phenylenediamine, 3-methoxy-N,N-diethyl-p- phenylenediamine, N,N,N' ,N' -tetramethyl-p- phenylenediamine.
  • Dispersion A of a photographically useful disulfonamidophenol oxidized developer scavenger, Compound 1, was prepared by placing 120 g of Compound 1 in a 1-gallon glass jar containing 664 g distilled water, 16.0 g of a 75% aqueous solution of diethylhexyl sodium sulfosuccinate, commercially available as Aerosol OT from American Cyanamid, and 2000 ml of 1.8 mm zirconium oxide beads. The jar was rolled at a speed of 103 ft/min for 7 days. The milled slurry was mixed with gelatin and water to yield a dispersion containing 6% Compound 1 and 9% gelatin.
  • Dispersion B was prepared in the same manner as Dispersion A except it contained 8.0 g of a 75% aqueous solution of Aerosol OT, 60.0 g of a 10% aqueous solution of polyvinylpyrrolidone and 312.0 g distilled water.
  • a conventional oil-in-water dispersion, Dispersion C, of compound 1 was prepared by dissolving 12.0 g of compound 1 in 6.0 g of N, N-diethyl lauramide and 24.0 g of ethyl acetate at 60C, then combining with an aqueous phase consisting of 16.0 g gelatin, 6.0 g of a 10% solution of a mixture of monomers, dimers, trimers and tetramers of the sodium salt of isopropylnaphthalene sulfonic acid, commercially available as Alkanol-XC from DuPont, and 136.0 g distilled water. The mixture was then passed through a colloid mill 5 times, followed by evaporation of the ethyl acetate using a rotary evaporator and replacement with distilled water to yield a dispersion having 6.0% compound 1 and 8.0% gelatin.
  • Dispersion D was prepared the same as Dispersion C except N, N-di-n-butyl lauramide was substituted for N, N-diethyl lauramide.
  • Dispersion E was prepared the same as Dispersion D except 12.0 g of N, N-di-n-butyl lauramide and 130.0 g of water were used.
  • Dispersion F was prepared the same as Dispersion C except 1, 4-cyclohexylenedimethylene bis (2-ethylhexanoate) was substituted for N, N-diethyl lauramide.
  • Dispersion G was prepared the same as Dispersion C except N, N-diethyl lauramide was omitted from the formulation, and 142.0 g of distilled water was used.
  • a conventional oil-in-water dispersion, Dispersion H, of a photographically useful hydrazide oxidized developer scavenger, Compound 2 was prepared by dissolving 12.0 g of Compound 2 in 12.0 g of di-n- butylphthalate and 24.0 g of ethyl acetate at 60C, then combining with an aqueous phase consisting of 16.0 g gelatin, 6.0 g of a 10% solution of Alkanol-XC and 130.0 g distilled water. The mixture was then passed through a colloid mill 5 times, followed by evaporation of the ethyl acetate using a rotary evaporator and replacement with distilled water to yield a dispersion having 6.0% compound 2 and 8.0% gelatin.
  • Dispersion I was prepared the same as Dispersion H except 3.0 g N, N-diethyl lauramide was substituted for 12.0 g di-n-butylphthalate, and 139.0 g distilled water was used.
  • oxidized developer dispersions were evaluated as set forth below in color negative photographic material prepared, exposed and processed according to conventional procedures .
  • Multilayer films were prepared, each comprising three color records separated by one or more interlayers, each of which contains a dispersion of oxidized developer scavenger.
  • the purpose of the interlayer is to prevent oxidized developer generated in one of the color layers from affecting any chemical reactions in another color layer.
  • the dye stain of concern is manifested by a spectral absorption at 640-660 nm. Therefore in evaluating the dispersions of this invention compared to conventional oil-in-water dispersions, the dispersions were incorporated into an interlayer positioned between green- and red-sensitive layers of a multilayer film structure.
  • the multilayer film structure contained additional color sensitive layers and interlayers .
  • the additional interlayers contained no oxidized developer scavenger, the oxidized developer scavenger being evaluated or a hydrazide oxidized developer scavenger (Cpd. 2) known to be non-staining at the relevant wavelength.
  • EXAMPLE 1 the oxidized developer scavenger Compound 1 dispersed as a crystalline solid particle dispersion, Dispersion A, is compared to a conventional oil-in-water dispersion of Compound 1, Dispersion C.
  • red-and green-sensitive layers are separated by an interlayer that contains the above dispersions as designated below.
  • the photographic element used as a CONTROL in this example contained no oxidized developer scavenger and contained the following relevant layers and materials: FILM STRUCTURE I
  • a COMPARISON film structure was prepared in the same manner as the CONTROL except that the interlayer contained 0.9688 g/square meter gelatin and 0.0431 g/square meter Compound 1 incorporated as Dispersion C, a conventional oil-in-water dispersion.
  • a film of the INVENTION was prepared in the same manner as the control except that the interlayer contains 0.9688 g/square meter gelatin and 0.0431 g/square meter Compound 1 incorporated as Dispersion A, a crystalline solid particle dispersion.
  • the photographic film elements prepared as above were tested for 645 nm dye aggregate as follows:
  • the presence (1) of the staining species can be estimated qualitatively by visual examination of the spectrum of a film sample. Quantifying the amount of 645 nm peak is done by the following differencing procedure.
  • the spectral density of the film element at 645 nm is recorded.
  • the film element is then treated in a persulfate bath to remove the staining species.
  • the 645 nm spectral density of the film element is again recorded, and the difference (2) between the two values is calculated.
  • Table I demonstrate that the dye stain present with the conventional oil- in-water dispersion, Dispersion C, is not present with the crystalline solid particle dispersion of this invention, Dispersion A.
  • the photographic film elements were tested for the ability of the interlayer formulation to prevent color contamination as follows:
  • each interlayer formulation may be determined by the following method.
  • the multilayer containing interlayers formulated with the control, comparison or invention dispersions was exposed to red or green light only.
  • the exposed color record is the only layer that developed and was designated the
  • EXAMPLE 2 the oxidized developer scavenger Compound 1 dispersed as crystalline solid particle dispersions, Dispersion A and Dispersion B, are compared to the conventional oil-in-water dispersion of Compound 1, Dispersion C.
  • red- and green-sensitive layers are separated by an interlayer that contains the dispersions as described below.
  • the photographic element used as a control in this example contains the following relevant layers and materials :
  • AgBrl tabular grain emulsion 4.1%I, 0.80x0.09 ⁇ m, sensitized with dye cpds 3 & 4, 0.87 mmole/Ag mole, 0.6458 g/m 2 magenta dye forming coupler, cpd 5, 0.4090 g/m 2 magenta dye forming coupler, cpd 6, 0.0678 g/m 2 non color forming DIR coupler, cpd 7, 0.0086 g/m 2 magenta dye forming coupler, cpd 8, 0.0107 g/m 2 gelatin, 1.4316 g/m 2 INTERLAYER: oxidized developer scavenger (DISPERSION H) , 0.0861 g/m 2 gelatin, 0.9688 g/m 2
  • the above film structure includes an interlayer which contains a non-staining hydrazide scavenger and is the CONTROL
  • a COMPARISON film structure was prepared in the same manner as the CONTROL except that in the interlayer, Dispersion H containing Compound 2, was replaced with 0.0431 g/square meter Compound 1 incorporated as a conventional oil-in-water dispersion, Dispersion C.
  • a second multilayer film of the invention, INVENTION 2-2 was prepared in the same manner as the CONTROL except that in the interlayer, Dispersion H containing Compound 2 was replaced with 0.0431 g/square meter Compound 1 incorporated as Dispersion B, a crystalline solid particle dispersion in accordance with this invention.
  • the multilayer films prepared above were tested for 645 nm dye aggregate as set forth in Example 1 above. As reported in Table II, the crystalline solid particle dispersions of INVENTION 2-1 and INVENTION 2-2 retain less stain than the COMPARISON so that their performance is equal to or better than the nonstaining CONTROL and better than the COMPARISON.
  • interlayers present in the multilayer film element contained a non-staining hydrazide scavenger which does not affect the results of the evaluation. These interlayers were not varied in Example 2.
  • the oxidized developer scavenger Compound 1 dispersed as a crystalline solid particle dispersion, Dispersion B is compared to conventional oil-in-water dispersions of Compound 1, as Dispersion F, Dispersion G, Dispersion E and Dispersion D.
  • Red- and green-sensitive layers are separated by an interlayer that contains the dispersions as described below.
  • the photographic element used as COMPARISON 3-1 in this example contains the following layers and materials: FILM STRUCTURE III GREEN SENSITIVE LAYER: AgBrl tabular grain emulsion, 4.1% I,
  • INTERLAYER oxidized developer scavenger (DISPERSION F) , 0.0431 g/m 2 gelatin, 0.9688 g/m 2
  • a second multilayer comparative film COMPARISON 3-2 was prepared in the same manner as COMPARISON 3-1, except that in the interlayer, the conventional oil-in-water dispersion of Compound 1, Dispersion F, is replaced with 0.0431 g/square meter Compound 1 incorporated as a conventional oil-in-water dispersion, Dispersion G.
  • COMPARISON 3-3 was prepared in the same manner as COMPARISON 3-1, except that in the interlayer, the conventional oil-in-water dispersion of Compound 1 Dispersion F is replaced with 0.0431 g/square meter Compound 1 incorporated as a conventional oil-in-water dispersion, Dispersion E.
  • a fourth multilayer comparative film, COMPARISON 3-4 was prepared in the same manner as COMPARISON 3-1 except that in the interlayer, the conventional oil-in-water dispersion of Compound 1 Dispersion F is replaced with 0.0431 g/square meter Compound 1 incorporated as a conventional oil-in-water dispersion, Dispersion D.
  • INVENTION was prepared in the same manner as COMPARISON 3-1 except that in the interlayer, the conventional oil-in-water dispersion of Compound 1, Dispersion F, is replaced with 0.0431 g/square meter Compound 1 incorporated as a crystalline solid particle dispersion in accordance with this invention Dispersion B.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Chemical & Material Sciences (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Silver Salt Photography Or Processing Solution Therefor (AREA)
EP94921905A 1994-05-16 1994-05-16 Photographisches element mit verringerter restanfärbung Withdrawn EP0708932A1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1994/005448 WO1995031753A1 (en) 1994-05-16 1994-05-16 Photographic element having reduced dye stain

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EP0708932A1 true EP0708932A1 (de) 1996-05-01

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JP (1) JPH09500984A (de)
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Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1193129A (en) * 1982-06-18 1985-09-10 Robert E. Ross Photographic elements containing scavengers for oxidized developing agents
JPS6146950A (ja) * 1984-08-10 1986-03-07 Fuji Photo Film Co Ltd 写真感光材料
US5198517A (en) * 1991-08-06 1993-03-30 Eastman Kodak Company Polymeric scavengers for oxidized developing agents and photographic elements containing the same
US5192646A (en) * 1991-12-09 1993-03-09 Eastman Kodak Company Photographic elements having sulfoxide coupler solvents and addenda to reduce sensitizing dye stain
US5300394A (en) * 1992-12-16 1994-04-05 Eastman Kodak Company Dispersions for imaging systems

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9531753A1 *

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WO1995031753A1 (en) 1995-11-23
JPH09500984A (ja) 1997-01-28

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