EP0734883A1 - Verfahren zur Oberflächenbehandlung von Aluminium für Druckplatten - Google Patents
Verfahren zur Oberflächenbehandlung von Aluminium für Druckplatten Download PDFInfo
- Publication number
- EP0734883A1 EP0734883A1 EP96105119A EP96105119A EP0734883A1 EP 0734883 A1 EP0734883 A1 EP 0734883A1 EP 96105119 A EP96105119 A EP 96105119A EP 96105119 A EP96105119 A EP 96105119A EP 0734883 A1 EP0734883 A1 EP 0734883A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- abrasive
- less
- aluminum support
- equal
- slurry
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 40
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 32
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000002002 slurry Substances 0.000 claims abstract description 30
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 8
- 238000004381 surface treatment Methods 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 238000007788 roughening Methods 0.000 description 5
- 230000007547 defect Effects 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000008262 pumice Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052586 apatite Inorganic materials 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41N—PRINTING PLATES OR FOILS; MATERIALS FOR SURFACES USED IN PRINTING MACHINES FOR PRINTING, INKING, DAMPING, OR THE LIKE; PREPARING SUCH SURFACES FOR USE AND CONSERVING THEM
- B41N3/00—Preparing for use and conserving printing surfaces
- B41N3/04—Graining or abrasion by mechanical means
Definitions
- the present invention relates to a method for treating the surface of an aluminum support for a printing plate, and particularly to a method for treating the surface of an aluminum support which is low in running costs and excellent in printing performance.
- An aluminum plate has been widely used as a support for a lithographic printing plate, and a treatment of roughening the surface of the support, that is, a so-called graining treatment has been given thereto in order to improve the adherence between the support and a photosensitive layer and to give water retentivity to a non-picture portion.
- the wire graining is also apt to make graining uneven, and therefore it is seldom used currently.
- supports excellent in performance can be obtained continuously by brushing aluminum supports by means of a rotating brush with abrasive slurry (so-called pumice generally obtained from valcanic ashes, or alumina or the like.
- the abrasive slurry has a certain hardness, that is, the hardness of which is not less than 6 in new Mohs scale.
- the minimum-side-to-maximum-side ratio of grain of the abrasive slurry is less than 0.4 and the grain sharpest angle of which is less than 45°.
- the abrasive inserts the support and brought thereby causes a trouble in the next step because the abrasive is so hard, or often so sharp.
- the valley portion is considerably deep in comparison with any other method, so that the mountain portions form very sharply projecting burrs. Therefore, sometimes, the printing performance is lowered particularly in "stains”, and it costs much to exchange the brush exhausted by abrasion, and to dispose the exhausted abrasive, and so on.
- the present invention has been made to solve the foregoing problems in the brush graining, and therefore an object of the present invention was to provide a method for treating the surface of an aluminum plate for a printing plate, in which a support having a good printing performance without any "stains” and with improved “narrowing of shadowed portions” can be manufactured at a low cost and stably.
- the present invention has been acheived by the provision of a method for treating the surface of an aluminum support for a printing plate through the brush-graining surface treatment technique in which slurry of abrasive is rubbed against the support by means of an abrasive brush to perform graining on a surface of the support, characterized in that abrasive having a new Mohs scale which is equal to or greater than 2 but less than 6 is used.
- a method for treating the surface of an aluminum support for a printing plate through the brush-grain surface treatment technique in which slurry of abrasive is rubbed against the support by means of an abrasive brush to perform graining on a surface of the support, characterized in that said abrasive includes grains having a minimum-side-to-maximum-side ratio is not less than 0.4, and having the sharpest angle equal to or greater than 45°.
- a method for treating the surface of an aluminum support for a printing plate through the brush-graining surface treatment technique in which slurry of abrasive is rubbed against the support by means of an abrasive brush to perform graining on a surface of the support, characterized in that aluminum hydroxide is used for said abrasive.
- the average grain size of said abrasive is set to be equal to or greater than 5 ⁇ m but less than 200 ⁇ m, and the density of said abrasive slurry is set to be equal to or greater than 5 weight per cent but less than 90 weight per cent.
- Figure is a schematic side view showing a process for treating the surface of an aluminum support for a printing plate according to the present invention.
- Figure is a schematic side view showing a process for the surface of an aluminum support for a printing plate according to the present invention.
- an aluminum support 1 is supported by pass rollers 2 so as to be subjected to surface treatment mechanically with abrasive brushes 3 and abrasive slurry 4.
- the abrasive slurry 4 is applied to the surface of the aluminum support 1 by a circulating pump 6 through a pipe 20, rubbed by the abrasive brushes 3 against the aluminum support 1, and then returned from a receiver 22 to a circulating tank 5 through an abrasive slurry return pipe 7.
- the grain size of the abrasive slurry becomes smaller so that the surface treatment becomes difficult if the slurry once used for surface treatment is used again as it is.
- abrasive and water are supplied to the circulating tank 5 through pipes 12 and 13, respectively. Consequently, a part of the abrasive slurry flows to an overflow tank 5a.
- the overflowed abrasive is classified by a cyclone 8 so that large-grain abrasive is returned to the circulating tank 5 while the remainder small-grain abrasive is discharged to the outside of the system through an abrasive slurry discharge pipe 10.
- the discharged abrasive is solid/liquid separated by a centrifuge separator 11, and used small-grain-size abrasive 14 is extracted as grains so as to be treated.
- the hardness of abrasive used as brush graining is lower than any conventional one.
- 10 kinds of minerals are selected in accordance with the hardness used as Mohs scale in the field of minerals, and a surface is scraped with the thus selected minerals one by one sequentially so that if there is a damage, it is determined that the surface is softer than the mineral.
- the hardness of the abrasive has been selected to be not less than 5 in Mohs scale conventionally, it is selected to be equal to or greater than 2 but less than 6 in new Mohs scale according to the present invention.
- the new Mohs scale is defined by adding 5 kinds so that the old scale between 1 and 10 are widened to between 1 and 15. In the sections 1-15 of the new Mohs scale, 1-6 are the same as those in the old Mohs scale.
- the hardness equal to or greater than 2 but less than 6 means the hardness corresponding to No. 2 gypsum, No. 3 calcite, No. 4 fluorite and No. 5 apatite, respectively.
- the minimum-side-to-maximum-side ratio (as three-dimensional size ratio) of the grain should be 0.4 or more, which has been regarded as good conventionally, and the sharpest angle of grains to be used should be 45° or more.
- the grain inserts the surface of the aluminum support so that the grain is brought into the next step causing a trouble as a result.
- the minimum-side-to-maximum-side ratio of the grain is equal to or greater than 0.4, preferably not less than 0.5 but not more than 1, and the sharpest angle of the grain should be equal to or greater than 45°, preferably not less than 60° but not more than 120°.
- Aluminum hydroxide may be adopted as the abrasive having the above-mentioned characteristics.
- the average size of grains of the abrasive is equal to or greater than 5 ⁇ m but less than 200 ⁇ m. It is desirable that the density of the abrasive slurry is equal to or greater than 5 weight per cent but less than 90 weight per cent. If the average size of grains of the abrasive is equal to or greater than 5 ⁇ m but less than 200 ⁇ m, graining with desired surface roughness can be attained. If the average size of grains of the abrasive is less than 5 ⁇ m, the roughness is insufficient, and if it is not less than 200 ⁇ m, the surface becomes too rough. The more preferable range of the average size of grains of the abrasive is from 8 ⁇ m to 100 ⁇ m.
- the density of the abrasive slurry is less than 5 weight per cent, the surface roughness becomes insufficient so that the surface is apt to be damaged by the brush, while if it is not less than 90 weight per cent, it becomes difficult to handle the slurry.
- the more preferable range of the density is from 10 weight per cent to 60 weight per cent.
- Aluminum hydroxide (new Mohs scale 3), pumice (new Mohs scale 5) and alumina (new Mohs scale 12) having properly selected three-dimensional size and the selected sharpest angle of grains were used as abrasive in the surface treatment process shown in Figure, and the surfaces of aluminum supports for printing plates were treated with the respective abrasive.
- Table 1 shows the relationship between the grain shapes and the printing performances at that time.
- Aluminum hydroxide was used in Examples 1 and 2, and satisfied the conditions that the abrasive has a new Mohs scale which is equal to or greater than 2 but less than 6, and that aluminum hydroxide is used for the abrasive.
- Alumina was used in Examples 3 and 4. Although the new Mohs scale thereof was high in this case, the three-dimensional size ratio and the sharpest angle of grains satisfied the conditions that the abrasive includes grains having a minimum-side-to-maximum-side ratio not less than 0.4, and having a sharpest angle equal to or greater than 45°.
- the defects in the brush graining method were improved by the surface treatment method of the present invention, and the printing quality against "narrowing of shadowed portions" and "stains” was improved. Accordingly, the performance of printing could be improved conspicuously.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Printing Plates And Materials Therefor (AREA)
- Grinding-Machine Dressing And Accessory Apparatuses (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7357895 | 1995-03-30 | ||
| JP7357895 | 1995-03-30 | ||
| JP73578/95 | 1995-03-30 | ||
| JP33514895A JP3491245B2 (ja) | 1995-03-30 | 1995-12-22 | 印刷版用アルミニウム支持体の表面処理方法 |
| JP33514895 | 1995-12-22 | ||
| JP335148/95 | 1995-12-22 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0734883A1 true EP0734883A1 (de) | 1996-10-02 |
| EP0734883B1 EP0734883B1 (de) | 1999-11-03 |
Family
ID=26414721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19960105119 Expired - Lifetime EP0734883B1 (de) | 1995-03-30 | 1996-03-29 | Verfahren zur Oberflächenbehandlung von Aluminium für Druckplatten |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP0734883B1 (de) |
| JP (1) | JP3491245B2 (de) |
| DE (1) | DE69604956T2 (de) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0897810A1 (de) * | 1997-08-22 | 1999-02-24 | Fuji Photo Film Co., Ltd | Verfahren zur Oberflächenbehandelung eines Aluminiumträgers für Flachdruckplatten |
| EP0979738A1 (de) * | 1998-08-13 | 2000-02-16 | Fuji Photo Film Co., Ltd. | Verfahren und Vorrichtung zur Behandlung eines Aluminiumträgers für Flachdruckplatten |
| CN108927735A (zh) * | 2017-05-23 | 2018-12-04 | 天津滨海光热反射技术有限公司 | 一种节能型抛光装置及抛光粉溶液循环使用方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3891516A (en) * | 1970-08-03 | 1975-06-24 | Polychrome Corp | Process of electrolyically anodizing a mechanically grained aluminum base and article made thereby |
| FR2418059A1 (fr) * | 1978-02-28 | 1979-09-21 | Fromson H A | Procede destine a rendre des surfaces rugueuses et articles obtenus par mise en oeuvre de ce procede |
| EP0213371A2 (de) * | 1985-07-26 | 1987-03-11 | Fuji Photo Film Co., Ltd. | Verfahren zur Herstellung eines Aluminiumträgers für eine Flachdruckplatte |
| EP0704320A1 (de) * | 1994-09-30 | 1996-04-03 | Hoechst Aktiengesellschaft | Verfahren zum mechanischen Aufrauhen der Oberfläche eines Druckplattenträgers und Bürstenwalze zur Duchführung des Verfahrens |
-
1995
- 1995-12-22 JP JP33514895A patent/JP3491245B2/ja not_active Expired - Fee Related
-
1996
- 1996-03-29 DE DE1996604956 patent/DE69604956T2/de not_active Expired - Lifetime
- 1996-03-29 EP EP19960105119 patent/EP0734883B1/de not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3891516A (en) * | 1970-08-03 | 1975-06-24 | Polychrome Corp | Process of electrolyically anodizing a mechanically grained aluminum base and article made thereby |
| FR2418059A1 (fr) * | 1978-02-28 | 1979-09-21 | Fromson H A | Procede destine a rendre des surfaces rugueuses et articles obtenus par mise en oeuvre de ce procede |
| EP0213371A2 (de) * | 1985-07-26 | 1987-03-11 | Fuji Photo Film Co., Ltd. | Verfahren zur Herstellung eines Aluminiumträgers für eine Flachdruckplatte |
| EP0704320A1 (de) * | 1994-09-30 | 1996-04-03 | Hoechst Aktiengesellschaft | Verfahren zum mechanischen Aufrauhen der Oberfläche eines Druckplattenträgers und Bürstenwalze zur Duchführung des Verfahrens |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0897810A1 (de) * | 1997-08-22 | 1999-02-24 | Fuji Photo Film Co., Ltd | Verfahren zur Oberflächenbehandelung eines Aluminiumträgers für Flachdruckplatten |
| EP0979738A1 (de) * | 1998-08-13 | 2000-02-16 | Fuji Photo Film Co., Ltd. | Verfahren und Vorrichtung zur Behandlung eines Aluminiumträgers für Flachdruckplatten |
| CN108927735A (zh) * | 2017-05-23 | 2018-12-04 | 天津滨海光热反射技术有限公司 | 一种节能型抛光装置及抛光粉溶液循环使用方法 |
| CN108927735B (zh) * | 2017-05-23 | 2023-08-15 | 天津滨海光热反射技术有限公司 | 一种节能型抛光装置及抛光粉溶液循环使用方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08324143A (ja) | 1996-12-10 |
| DE69604956D1 (de) | 1999-12-09 |
| DE69604956T2 (de) | 2000-03-30 |
| EP0734883B1 (de) | 1999-11-03 |
| JP3491245B2 (ja) | 2004-01-26 |
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