EP0757094A2 - Composition détergente contenant des disuccinates d'imine - Google Patents

Composition détergente contenant des disuccinates d'imine Download PDF

Info

Publication number
EP0757094A2
EP0757094A2 EP96111591A EP96111591A EP0757094A2 EP 0757094 A2 EP0757094 A2 EP 0757094A2 EP 96111591 A EP96111591 A EP 96111591A EP 96111591 A EP96111591 A EP 96111591A EP 0757094 A2 EP0757094 A2 EP 0757094A2
Authority
EP
European Patent Office
Prior art keywords
acid
units
weight
polymer
salts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP96111591A
Other languages
German (de)
English (en)
Other versions
EP0757094B1 (fr
EP0757094A3 (fr
Inventor
Torsten Dr. Groth
Winfried Dr. Joentgen
Hans-Joachim Traenckner
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanxess Deutschland GmbH
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Publication of EP0757094A2 publication Critical patent/EP0757094A2/fr
Publication of EP0757094A3 publication Critical patent/EP0757094A3/fr
Application granted granted Critical
Publication of EP0757094B1 publication Critical patent/EP0757094B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3719—Polyamides or polyimides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids

Definitions

  • the invention relates to combinations of iminodisuccinate derivatives and polymers with recurring succinyl units and detergents or cleaning agents containing this combination.
  • zeolites, layered silicates and mixtures of zeolite with alkali silicates, carbonates and polymeric polycarboxylates are primarily used as phosphate substitutes.
  • complexing agents such as salts of nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA) and phosphonic acids e.g. HEDP used. These mostly selective complexing agents have the task of eliminating heavy metal ions that have a negative effect on the washing process (see Ullmann 1987, Vol.
  • EP-A-291 869 describes phosphate-free builders combinations of polymeric polycarboxylate, aminoalkane polyphosphonate, 1-hydroxyethane-1,1-diphosphonate (HEDP) and zeolite, with certain weight ratios of the first three compounds achieving synergistic prevention of fiber incrustations.
  • DE-A-4 024 552 describes detergents or cleaning agents which consist of a combination of 3-hydroxy-2,2'-iminodisuccinic acid, its soluble salts and zeolite and are said to show a high level of complexing power for alkaline earth metal and heavy metal ions.
  • the compositions contain 0.01% to 20% by weight of 3-hydroxy-2,2'-iminodisuccinic acid, 5 to 50% by weight of zeolite and 30% of a polymeric polycarboxylate.
  • DE-A-311 440 also discloses phosphate-free builder systems for detergents and cleaning agents which, in addition to 15 to 60% by weight of zeolite, also 1 to 30% by weight of 3-hydroxy-2,2'-iminodisuccinic acid or its salts and Contains 1 to 20 wt .-% amorphous and / or crystalline silicates.
  • US-A-3 697 453 describes a phosphate-free washing and cleaning agent which contains iminodisuccinic acid and / or a water-soluble salt thereof as a builder.
  • the proportion of iminodisuccinic acid in the detergent is 10 to 50% by weight.
  • DE-A-3 739 610 discloses the preparation of 3,3'-dihydroxy-2,2'-iminodisuccinic acid and its use as a complexing agent for alkaline earth metals in detergents and cleaning agents.
  • EP-A-454 651 and EP-A-612 842 describe the use of polyaspartic acid in builder systems of phosphate-free detergents in combination with zeolites.
  • Polyaspartic acid is used here as a cobuilder substitute for polymeric polycarboxylates.
  • the object of the invention was to provide detergents and substances suitable therefor which are improved with regard to biodegradability and technical performance.
  • the polymers to be used according to the invention are understood to mean the corresponding free acids, their salts, but also derivatives of the acids, in particular anhydrides, amides and esters.
  • the recurring unit B1 based on the sum of the units B1 and A1, is at least 50%, in particular at least 70%.
  • polyaspartic acids according to the invention also include those which have been chemically modified under the chosen reaction conditions with respect to the corresponding starting compounds.
  • the average molecular weight (Mw) can vary within a wide range, polyaspartic acids with molecular weights between 500 and 100,000 g / mol being usable, but preferred are 1,000 to 50,000 g / mol or, even better, 1,000 to 30,000 g / mol.
  • the molecular weight is determined by gel permeation chromatography (GPC) on Shodex OH-PAK as the stationary phase and with 0.15 M NaCl + 200 ppm NaN 3 as the eluent solution. Calibration can best be carried out with pure polyaspartic acid, for example from Sigma, whose molecular weight was determined by an absolute measurement method, for example LALLS.
  • the invention further relates to washing and / or cleaning agents which, in particular as a builder, contain the combination according to the invention of an iminodisuccinate derivative and a polymer with recurring succinyl units.
  • the weight ratio of polymers with repeating succinyl units to the iminodisuccinate derivative is preferably between 1: 6 and 2: 1.
  • the polymers with recurring succinyl units to be used according to the invention are essentially polyaspartic acids.
  • the polymers can be prepared by known processes, for example according to US Pat. No. 4,839,461, US Pat. No. 5,371,180, US Pat. No. 5,288,783, J. Org. Chem., 24, p 1662-1666 (1959) and J. Org. Chem., 26, 1084 (1961).
  • Phosphate-free detergents and cleaning agents which contain the builder system according to the invention show good primary washability and improved secondary washability combined with less incrustation and an increased degree of whiteness of the fabric.
  • the invention accordingly also relates to a phosphate-free washing and cleaning agent which preferably contains 0.5 to 40% by weight of an iminodisuccinate derivative of structure A and preferably 0.5 to 25% by weight of a polymer with repeating succinyl units as builders.
  • zeolite and / or amorphous and / or crystalline alkali silicates can optionally be present.
  • the builder system according to the invention shows a very good complexing ability for alkaline earth ions and heavy metal ions which interfere with the washing process, as well as a high dispersing ability for dirt particles and a growth-inhibiting effect on alkaline earth metal microcrystallites (crystal nuclei) which have already formed. These properties also have a positive effect on the stabilization of bleaches and enzymes.
  • the builder system shows easy biodegradability, since in addition to inorganic constituents it contains only iminodisuccinate derivatives of structure A and polyaspartic acids, which have good biodegradability according to the OECD guide lines for testing chemicals (1981).
  • the detergents and cleaning agents according to the invention can also contain other customary builders and complexing agents, for example phosphonates, the polycarboxylic acids preferably used in the form of their sodium salts, such as adipic acid, succinic acid, glutaric acid, aminocarboxylic acids, nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), provided that such use is used is not objectionable for ecological reasons, and contain mixtures of these and (co) polymeric polycarboxylic acids or polycarboxylates, but they are not necessary to improve the secondary washing ability. In the context of this invention, use can therefore also be dispensed with.
  • the polycarboxylic acids preferably used in the form of their sodium salts such as adipic acid, succinic acid, glutaric acid, aminocarboxylic acids, nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA)
  • Detergents and cleaning agents according to the invention can therefore optionally contain up to 20% by weight of sodium citrate, in particular 0.5 to 15% by weight of sodium citrate.
  • the soluble salts are preferably used. These are the cations which contain those from the group of the ammonium and alkali metal ions. One, two, three or all four carboxylic acid groups can be in the salt form.
  • the water-soluble alkali metal salts or the polysuccinimides partially hydrolyzed with alkali metal should preferably be used.
  • the zeolites which may be used are used in the usual hydrated, finely crystalline form. Their water content is preferably between 19 and 22% by weight. They have practically no particles larger than 30 ⁇ m and preferably consist at least 80% of particles smaller than 10 ⁇ m. Their calcium binding capacity, which is determined according to the information in German patent application 2,412,837, is in the range from 100 to 200 mg CaO / g. Zeolite NaA is particularly suitable, as is zeolite NaX and mixtures of NaA and NaX. Quantities and weight ratios which relate to the zeolite builder are - within the scope of this invention - unless otherwise stated - based on anhydrous active substance.
  • the solid silicates can be amorphous and / or crystalline. They can be used as powder or granules.
  • Preferred alkali silicates are the sodium silicates, in particular the amorphous sodium silicates, with a Na 2 O: SiO 2 molar ratio of 1: 2 to 1: 2.8.
  • Such amorphous alkali silicates are commercially available, for example, under the name Portil (Henkel).
  • Crystalline sheet silicates of the formula (I) NaMSixO 2 + 1xyH 2 O, in which M represents sodium, x assumes the values 2 or 3, and y a number, are preferably used as crystalline silicates, which may be present alone or in a mixture with amorphous silicates is from 0 to 20. Both ⁇ - and ⁇ -sodium disilicates Na 2 Si 2 O 5 are particularly preferred.
  • the layered silicates SKS 6 and SKS 7 from Hoechst should also be mentioned here, for example.
  • the builders combinations according to the invention can also contain sodium carbonate as the alkali reserve.
  • the sodium carbonate content can preferably be reduced compared to conventional phosphate-free detergents, since the constituents according to the invention (polyaspartic acid / iminodisuccinic acid derivatives) themselves have a buffering action and therefore also form a certain alkali reserve.
  • the combinations according to the invention can also contain further constituents, for example inorganic, in particular neutral reacting salts.
  • the combinations are sprayed with liquid to wax-like components, for example silicone oils and paraffin oils, but preferably with nonionic surfactants.
  • the agents according to the invention can, for example, known additives commonly used in washing and cleaning agents Contains surfactants, bleaching agents and bleach activators, salts that react alkaline in water, solubility improvers such as conventional hydrotropes or polyalkylene glycols, e.g. polyethylene glycols, foam inhibitors, optical brighteners, enzymes, enzyme stabilizers, small amounts of neutral filler salts as well as colorants and fragrances, opacifiers or pearlescent agents.
  • solubility improvers such as conventional hydrotropes or polyalkylene glycols, e.g. polyethylene glycols, foam inhibitors, optical brighteners, enzymes, enzyme stabilizers, small amounts of neutral filler salts as well as colorants and fragrances, opacifiers or pearlescent agents.
  • the content of the agents in anionic and nonionic surfactants including soap is preferably 10 to 35% by weight, advantageously 12 to 28% by weight and in particular 15 to 25% by weight.
  • Preferred surfactants of the sulfonate type are C 5 -C 13 alkylbenzenesulfonates, olefin sulfonates, ie mixtures of alkene and hydroxyalkanesulfonates, and disulfonates, such as are obtained, for example, from C 12 -C 18 monoolefins with a terminal or internal double bond by sulfonating with gaseous Sulfur trioxide and subsequent alkaline or acidic hydrolysis of the sulfonation products is considered.
  • alkanesulfonates obtained from C 12 -C 18 alkanes, for example by sulfochlorination or sulfoxidation with subsequent hydrolysis or neutralization.
  • esters of ⁇ -sulfofatty acids are also suitable, for example the ⁇ -sulfonated methyl esters of hydrogenated coconut, palm kernel or tallow fatty acids.
  • esters of ⁇ -sulfo fatty acids which are produced by ⁇ -sulfonation of the methyl esters of fatty acids of plant and / or animal origin with 8 to 20 C atoms in the fatty acid molecule and subsequent neutralization to form water-soluble mono-salts.
  • ⁇ -sulfonated esters of hydrogenated coconut, palm kernel or tallow fatty acids, and sulfonation products of unsaturated fatty acids, for example oleic acid are also present in small amounts, preferably in amounts not above about 2 to 3% by weight could be.
  • ⁇ -sulfofatty acid alkyl esters are preferred which have an alkyl chain with no more than 4 carbon atoms in the ester group, for example methyl esters, ethyl esters, propyl esters and butyl esters.
  • MES methyl esters of ⁇ -sulfofatty acids
  • anionic surfactants are the ⁇ -sulfofatty acids obtainable by ester cleavage of the ⁇ -sulfofatty acid alkyl esters or their di-salts.
  • the mono-salts of the ⁇ -sulfofatty acid alkyl esters are obtained in their industrial production as an aqueous mixture with limited amounts of di-salts.
  • the di-salt content Such surfactants are usually below 50% by weight of the anionic surfactant mixture, for example up to about 30% by weight. Mixtures of mono-salts and di-salts with further surfactants, for example with alkylbenzenesulfonate or alkyl sulfates, are also preferred.
  • sulfonated fatty acid glycerol esters are sulfonated fatty acid glycerol esters.
  • Fatty acid glycerol esters are to be understood as the mono-, di- and triesters and their mixtures as obtained in the production by esterification of glycerol with 1 to 3 moles of fatty acid or in the reaction of triglycerides with 0.3 to 2 moles of glycerol.
  • Preferred sulfated fatty acid glycerol esters are the sulfonation products of saturated fatty acids having 6 to 22 carbon atoms, for example caproic acid, caprylic acid, capric acid, myristic acid, lauric acid, palmitic acid, steraric acid or behenic acid.
  • fats and oils i.e. natural mixtures of different fatty acid glycerol esters
  • suitable feedstocks are palm oil, palm kernel oil, palm stearin, olive oil, turnip oil, coriander oil, sunflower oil, cottonseed oil, peanut oil, linseed oil, lard oil or lard. Due to their high natural content of saturated fatty acids, it has proven to be particularly advantageous to start from coconut oil, palm kernel oil or beef tallow.
  • the sulfonation of the saturated fatty acids with 6 to 22 carbon atoms or the mixtures of fatty acid glycerol esters with iodine numbers less than 5, which contain fatty acid with 6 to 22 carbon atoms, is preferably carried out by reaction with gaseous sulfur trioxide and subsequent neutralization with aqueous bases, as described in the international patent application WO 91/9009 is specified.
  • the sulfonation products are a complex mixture which contains mono-, di- and triglyceride sulfonates with an ⁇ -position and / or internal sulfonic acid grouping.
  • sulfonated fatty acid salts glyceride sulfates, glycerine sulfates, glycerin and soaps are formed. If one starts from the sulfonation of saturated fatty acids or hardened fatty acid glycerol ester mixtures, the proportion of the ⁇ -sulfonated fatty acid disalts can be up to about 60% by weight, depending on the procedure.
  • Suitable surfactants of the sulfate type are the sulfuric acid monoesters from primary alcohols of natural and synthetic origin.
  • Preferred alk (en) yl sulfates are the sulfuric acid half-esters of the C 12 -C 18 fatty alcohols, for example from coconut oil alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol or the C 10 -C 20 oxa alcohols, and those secondary alcohols of this chain length .
  • alk (en) yl sulfates of the chain length mentioned which contain a synthetic, petrochemical-based straight-chain alkyl radical which have a degradation behavior analogous to that of the adequate compounds based on oleochemical raw materials.
  • C 16 -C 18 alk (en) yl sulfates are particularly preferred from the point of view of washing technology. It can also be particularly advantageous, and particularly advantageous for machine washing agents, to use C 16 -C 18 -alk (en) yl sulfates in combination with lower melting anionic surfactants and in particular with those anionic surfactants which have a lower Krafft point and relatively low ones Washing temperatures of, for example, room temperature to 40 ° C. show a low tendency to crystallize.
  • the agents therefore contain mixtures of short-chain and long-chain fatty alkyl sulfates, preferably mixtures of C 12 -C 14 fatty alkyl sulfates or C 12 -C 16 fatty alkyl sulfates with C 16 -C 18 fatty alkyl sulfates.
  • not only saturated alkyl sulfates but also unsaturated alkenyl sulfates with an alkenyl chain length of preferably C 16 -C 22 are used.
  • Mixtures of saturated sulfated fatty alcohols predominantly consisting of C 16 and unsaturated sulfated fatty alcohols predominantly consisting of C 18 are particularly preferred.
  • Weight ratios of alkyl sulfates to alkenyl sulfates from 10: 1 to 1: 2 and in particular from about 5: 1 to 1: 1 are preferred.
  • the sulfuric acid monoesters of the straight-chain or branched C 7 -C 21 alcohols ethoxylated with 1 to 9 mol ethylene oxide such as 2-methyl-branched C 9 -C 11 alcohols with an average of 3.5 mol ethylene oxide (EO) or C 12 - C 18 fatty alcohols with 2 to 4 EO are suitable. Because of their high foaming behavior, they are used in detergents only in relatively small amounts, for example in amounts of 1 to 5% by weight.
  • Preferred anionic surfactants are also the salts of alkylsulfosuccinic acid, which are also referred to as sulfosuccinates or as sulfosuccinic acid esters, and the monoesters and / or diesters of sulfosuccinic acid with alcohols, preferably Represent fatty alcohols and especially ethoxylated fatty alcohols.
  • Preferred sulfosuccinates contain C 8 -C 18 fatty alcohol residues or mixtures of these: Particularly preferred sulfosuccinates contain a fatty alcohol residue which is derived from ethoxylated fatty alcohols, which in themselves are nonionic surfactants (description see below).
  • alk (en) ylsuccinic acid with preferably 8 to 18 carbon atoms in the alk (en) yl chain or salts thereof.
  • Preferred granular detergents or cleaning agents contain, as anionic surfactants, alkylbenzenesulfonates and / or alkyl sulfate, preferably fatty alkyl sulfate, and / or sulfated fatty acid glycerol esters, the weight ratio of sulfated fatty acid glycerol esters to alkylbenzenesulfonate and / or alkyl sulfate 1: 9 to 4: 1 and in particular 2: 5 to 2 : 1 is.
  • Suitable anionic surfactants are, in particular, soaps, preferably in amounts from 0.2 to 8 and in particular from 0.5 to 5% by weight.
  • Saturated fatty acid soaps are suitable, such as the salts of lauric acid, myristic acid, palmitic acid or stearic acid, and in particular soap mixtures derived from natural fatty acids, for example coconut, palm kernel or tallow fatty acids.
  • soap mixtures are preferred which are composed of 50 to 100% by weight of saturated C 12 -C 18 fatty acid soaps and 0 to 50% by weight of oleic acid soap.
  • the anionic surfactants can be in the form of their sodium, potassium or ammonium salts and also as soluble salts of organic bases, such as mono-, di- or triethanolamine.
  • the anionic surfactants are preferably in the form of their sodium or potassium salts, in particular in the form of the sodium salts.
  • the granular detergents or cleaning agents also contain nonionic surfactants in addition to the anionic surfactants, preferably in amounts of 1 to 15% by weight, in particular in amounts of 2 to 12% by weight.
  • Preferred nonionic surfactants are alkoxylated, advantageously liquid ethoxylated, in particular primary alcohols with preferably 9 to 18 carbon atoms and an average of 1 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical can be linearly or preferably methyl-branched in the 2-position, or can contain linear and methyl-branched radicals in the mixture, as are usually present in oxo alcohol radicals.
  • EO ethylene oxide
  • alcohol ethoxylates with linear residues of alcohols of native origin with 12 to 18 carbon atoms, for example from coconut oil, tallow oil or oleyl alcohol, and an average of 2 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12 -C 14 alcohols with 3 EO or 4 EO, C 9 -C 11 alcohol with 7 EO, C 13 -C 15 alcohols with 3 EO, 5 EO, 7 EO or 8 EO, C 12 -C 18 alcohols with 3 EO, 5 EO or 7 EO and mixtures thereof, such as mixtures of C 12 -C 14 alcohol with 3 EO and C 12 -C 18 alcohol with 5 EO.
  • the degrees of ethoxylation given represent statistical averages, which can be an integer or a fraction for a specific product.
  • Preferred alcohol ethoxylates have a narrow homolog distribution.
  • alkyl glycosides can also be used as further nonionic surfactants.
  • bleaching agents which serve as bleaching agents and supply H 2 O 2 in water
  • sodium perborate tetrahydrate and sodium perborate monohydrate are of particular importance.
  • Further bleaching agents which can be used are, for example, sodium percarbonate, peroxypyrophosphates, citrate perhydrates and H 2 O 2 -producing peracid salts or peracids, such as perbenzoates, peroxophthalates, diperazelaic acid or diperdodecanedioic acid.
  • the bleaching agent content of the agents is preferably 5 to 25% by weight and in particular 10 to 20% by weight, with perborate monohydrate being advantageously used.
  • bleach activators can be incorporated into the preparations.
  • these are N-acyl or O-acyl compounds which form organic peracids with H 2 O 2 , preferably N, N'-tetraacylated diamines, furthermore carboxylic acid anhydrides and esters of polyols such as glucose pentaacetate.
  • the bleach activators contain bleach activators in the usual range, preferably between 1 and 10% by weight and in particular between 3 and 8% by weight.
  • Particularly preferred bleach activators are N, N, N ', N'-tetraacetylethylenediamine and 1,5-diacetyl-2,4-dioxo-hexahydro-1,3,5-triazine.
  • Graying inhibitors have the task of keeping the dirt detached from the fiber suspended in the liquor and thus prevent graying.
  • Water-soluble colloids are suitable for this, for example the water-soluble salts of polymeric carboxylic acids, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or cellulose or salts of acidic sulfuric acid esters of cellulose or starch.
  • Water-soluble polyamides containing acidic groups are also suitable for this purpose. Soluble starch preparations and starch products other than those mentioned above can also be used, e.g. degraded starch, aldehyde starches, etc. Polyvinylpyrrolidone can also be used.
  • cellulose ethers such as carboxymethyl cellulose, methyl cellulose, hydroxyalkyl cellulose and mixed ethers such as methyl hydroxyethyl cellulose, methyl hydroxyporpyl cellulose, methyl carboxymethyl cellulose and mixtures thereof are preferably used, for example in amounts of 0.1 to 5% by weight, based on the composition.
  • the foaming power of the surfactants can be increased or decreased by combining suitable types of surfactants; a reduction can also be achieved by adding non-surfactant-like substances.
  • Suitable foam inhibitors are, for example, soaps of natural or synthetic origin, which have a high proportion of C 18 -C 24 fatty acids.
  • Suitable non-surfactant-like foam inhibitors are, for example, organopolysiloxanes and their mixtures with microfine, optionally silanized silica, and paraffins, waxes, microcrystalline waxes and their mixtures with silanized silica or bistearylethylenediamide.
  • foam inhibitors are also used with advantages, for example those made of silicones, paraffins or waxes.
  • the foam inhibitors in particular silicone or paraffin-containing foam inhibitors, are preferably bound to a granular, water-soluble or dispersible carrier substance.
  • Suitable enzymes are those from the class of proteases, lipasses, amylases, cellulases or mixtures thereof. Enzymes obtained from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis and Streptomyces griseus are particularly suitable. Proteases of the subtilisin type and in particular proteases which are obtained from Bacillus lentus are preferably used. Enzyme mixtures, for example of protease and amylase or protease and lipase or protease and cellulase or Protease, amylase and lipase or protease, lipase and cellulase, of particular interest. Oxidases have also proven to be suitable in some cases. The enzymes can be adsorbed on carriers and / or embedded in coating substances in order to protect them against premature decomposition. The proportion of the enzymes, enzyme mixtures or enzyme granules can be, for example, about 0.2 to about 2% by weight.
  • the agents can contain enzyme stabilizers.
  • enzyme stabilizers For example, 0.5 to 1% by weight sodium formate can be used. It is also possible to use proteases which are stabilized with soluble calcium salts and a calcium content of preferably about 1.2% by weight, based on the enzyme.
  • boron compounds for example boric acid, boron oxide, borax and other alkali metal borates, such as the salts of orthoboric acid (H 3 BO 3 ), metaboric acid (HBO 2 ) and pyrobic acid (tetraboric acid H 2 B 4 O 7 ), is particularly advantageous.
  • the agents can contain, as optical brighteners, derivatives of their diaminostilbenedisulfonic acid or their alkali metal salts. Suitable are e.g. Salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl-6-amino) stilbene-2,2'-disulfonic acid or compounds of the same structure which instead of the morpholino group have a Carry a diethanolamino group, a methylamino group, an anilino group or a 2-methoxyethylamino group.
  • brighteners of the substituted diphenylstyryl type may be present, e.g.
  • the granular detergents or cleaning agents according to the invention can have a bulk density of between approximately 300 and 1100 g / l. Granules are preferred which have a bulk density above 450 g / l, in particular between 500 and 1100 g / l.
  • Both the combinations according to the invention and the washing or cleaning agents according to the invention can be prepared in a conventional manner, for example by mixing, granulating, extruding and / or by spray drying an aqueous slurry and, if appropriate, then adding temperature-sensitive components.
  • washing or Detergents can be used separately manufactured builders in the form of a spray-dried or granulated compound as an admixture to other granular components of the detergent or cleaning agent. It is also possible to incorporate the builders and complexing agents into the agents individually in a conventional manner and in any order.
  • a stock solution is made from the liquid components.
  • the powdered constituents are weighed for each washing test and added to the stock solution at the beginning of the washing process.
  • the graying including color graying
  • the inorganic and organic incrustation are measured.
  • the organic incrustation is determined by extraction with methanol.
  • the dirt test fabric test specimens were washed once, dried and carefully ironed smoothly on the left side that was not to be measured.
  • the cleaning effect was determined based on DIN 44 983-T21 point 4.1 by measuring the reflectance on the washed dirty fabrics.
  • the mean value and the corresponding confidence interval for 95% statistical certainty were calculated from the total measured individual remission values for each tissue type.
  • Tables 1 and 2 The results of the washing action at 3.2 mmol / l (18 ° d) water hardness are shown in Tables 1 and 2.
  • Table 1 Primary washing results (remission values) product Test fabric detergent formulation according to the invention comparison wfk-10 C 61.9 ⁇ 0.5 61.1 ⁇ 1.8 wfk-20 C.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
EP96111591A 1995-07-31 1996-07-18 Composition détergente contenant des disuccinates d'imine Expired - Lifetime EP0757094B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19528059A DE19528059A1 (de) 1995-07-31 1995-07-31 Wasch- und Reinigungsmittel mit Iminodisuccinaten
DE19528059 1995-07-31

Publications (3)

Publication Number Publication Date
EP0757094A2 true EP0757094A2 (fr) 1997-02-05
EP0757094A3 EP0757094A3 (fr) 1998-10-21
EP0757094B1 EP0757094B1 (fr) 2003-10-01

Family

ID=7768294

Family Applications (1)

Application Number Title Priority Date Filing Date
EP96111591A Expired - Lifetime EP0757094B1 (fr) 1995-07-31 1996-07-18 Composition détergente contenant des disuccinates d'imine

Country Status (15)

Country Link
US (1) US5977053A (fr)
EP (1) EP0757094B1 (fr)
JP (1) JPH0948995A (fr)
KR (1) KR100406227B1 (fr)
AT (1) ATE251211T1 (fr)
AU (1) AU703102B2 (fr)
CA (1) CA2182158C (fr)
CZ (1) CZ225796A3 (fr)
DE (2) DE19528059A1 (fr)
DK (1) DK0757094T3 (fr)
ES (1) ES2208709T3 (fr)
HU (1) HUP9602096A3 (fr)
NO (1) NO311842B1 (fr)
PL (1) PL315446A1 (fr)
PT (1) PT757094E (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030661A1 (fr) * 1997-01-09 1998-07-16 Bayer Aktiengesellschaft Procede pour nettoyer des surfaces
EP0940495A1 (fr) * 1998-03-05 1999-09-08 Bayer Aktiengesellschaft Procédé pour le lavage et le blanchiment simultanés de fibres naturelles et de produits textiles les contenant
WO1999067442A1 (fr) * 1998-06-24 1999-12-29 Aware Chemicals L.L.C. Procede de traitement prealable d'une piece metallique en vue d'une mise en peinture
EP1045022A1 (fr) * 1999-04-15 2000-10-18 Greither, Peter Utilisation de gélatine en agent de lavage
WO2001046371A1 (fr) * 1999-12-21 2001-06-28 Unilever Plc Compositions detergentes
WO2001088077A1 (fr) * 2000-05-15 2001-11-22 Unilever Plc Compositions detergentes
EP2045317A1 (fr) * 2007-10-04 2009-04-08 Lanxess Deutschland GmbH Moyen de lavage et de nettoyage liquide
EP3666871A1 (fr) * 2018-12-12 2020-06-17 Henkel AG & Co. KGaA Détergent ou agent de nettoyage contenant de l'iminodisuccinate et/ou de l'iminotrisuccinate

Families Citing this family (312)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6346648B1 (en) * 2000-01-28 2002-02-12 Applied Carbo Chemicals Inc Amphoteric surfactants based upon epoxy succinic acid
US6642193B1 (en) * 2000-01-28 2003-11-04 Applied Carbochemicals Inc Carboxylated surfactants in personal care applications
US6642192B1 (en) * 2000-01-28 2003-11-04 Applied Carbochemicals Inc Amphoteric surfactants based upon epoxy succinic acid in personal care applications
GB0013501D0 (en) 2000-06-02 2000-07-26 Unilever Plc Detergent compositions
DE10034102A1 (de) * 2000-07-13 2002-01-24 Beiersdorf Ag Kosmetische oder dermatologische Zubereitungen in Form von Gelen, enthaltend Iminodibernsteinsäure
DE10034101A1 (de) * 2000-07-13 2002-01-24 Beiersdorf Ag Kosmetische oder dermatologische Zubereitungen in Form von Emulsionen, enthaltend Iminodibernsteinsäure
DE10037850A1 (de) * 2000-08-01 2002-02-21 Herbert P Jennissen Verfahren zur Herstellung bioaktiver Implantatoberflächen
US20040052826A1 (en) * 2000-09-11 2004-03-18 Elena Fernandez-Kleinlein Cosmetic and pharmaceutical compositions and their use
WO2002019981A2 (fr) * 2000-09-11 2002-03-14 Johnson & Johnson Gmbh Compositions cosmetiques et pharmaceutiques et leur utilisation
DE10100720A1 (de) * 2001-01-10 2002-07-11 Beiersdorf Ag Kosmetische und dermatologische waschaktive Zubereitungen, enthaltend eine wirksame Menge an Iminodibernsteinsäure und/oder ihren Salzen
DE10142927A1 (de) * 2001-09-01 2003-03-20 Beiersdorf Ag Erhöhung der Stabilität von kosmetischen Zubereitungen durch Zusatz von Iminodibernsteinsäure
DE10142931A1 (de) * 2001-09-01 2003-03-27 Beiersdorf Ag Erhöhung der hautbefeuchtenden Eigenschaften von Polyolen
DE10142932A1 (de) * 2001-09-01 2003-03-27 Beiersdorf Ag Erhöhung der Stabilität von lecithin-und chitosanhaltigen Formulierungen durch Zusatz von Iminodibernsteinsäure
US6444635B1 (en) * 2002-03-21 2002-09-03 Colgate-Palmolive Company Liquid cleaning composition having an improved preservative system
US6455487B1 (en) * 2002-03-21 2002-09-24 Colgate Palmolive Company Liquid cleaning composition containing a preservative and an effective chelating agent
US20050187132A1 (en) * 2002-09-12 2005-08-25 Volker Blank Detergent composition which has been compacted under pressure
US20060014869A1 (en) * 2004-07-14 2006-01-19 Lanxess Corporation Dye cleaner, and method for cleaning colorant delivery systems
JP2008511744A (ja) * 2004-09-24 2008-04-17 ザ プロクター アンド ギャンブル カンパニー 低密度洗剤顆粒の形成方法
DE102004050562A1 (de) * 2004-10-15 2006-05-04 Henkel Kgaa Aufnahmefähige Partikel
DE102004053015A1 (de) * 2004-11-03 2006-05-04 Lanxess Deutschland Gmbh Rußreiniger
JP2008521995A (ja) * 2004-11-30 2008-06-26 エルジー ハウスホールド アンド ヘルス ケア エルティーディー． 衣類の肌触りを向上させることができる粉末洗剤組成物及びその製造方法
GB0502056D0 (en) * 2005-02-01 2005-03-09 Unilever Plc Modified sodium carbonate carrier meterial
PT1874914E (pt) 2005-04-21 2013-01-14 Colgate Palmolive Co Composição de detergente líquido
EP1754777B1 (fr) * 2005-08-19 2010-10-20 The Procter & Gamble Company Composition détèrgente solide comprenant sulphonate d'alkylbenzene, sel de carbonate, et carboxylate polymerique
GB0522658D0 (en) 2005-11-07 2005-12-14 Reckitt Benckiser Nv Composition
US20080070823A1 (en) * 2006-09-15 2008-03-20 Philip Gorlin Liquid Detergent Composition
US7749949B2 (en) * 2006-12-15 2010-07-06 Colgate-Palmolive Company Liquid detergent composition comprising an acrylic polymer/ propylene glycol ether of methyl glucose mixture
GB0700929D0 (en) 2007-01-18 2007-02-28 Reckitt Benckiser Nv Dosage element and a method of manufacturing a dosage element
KR101392380B1 (ko) * 2007-02-21 2014-05-07 주식회사 엘지생활건강 산성형태의 수용성 고분자를 함유하는 분말세제 입자 및그의 제조방법
US20080242581A1 (en) * 2007-04-02 2008-10-02 Colgate-Palmolive Company Liquid Detergent With Refractive Particle
ES2465228T5 (es) * 2008-02-08 2022-03-18 Procter & Gamble Proceso para fabricar una bolsa soluble en agua
US8066818B2 (en) * 2008-02-08 2011-11-29 The Procter & Gamble Company Water-soluble pouch
US20090209447A1 (en) * 2008-02-15 2009-08-20 Michelle Meek Cleaning compositions
MX2011004801A (es) 2008-11-11 2011-06-16 Danisco Inc Composiciones y metodos que comprenden una variante de subtilisina.
US8969282B2 (en) * 2009-02-05 2015-03-03 American Sterilizer Company Low odor, hard surface sporicide
US8969283B2 (en) * 2009-02-05 2015-03-03 American Sterilizer Company Low odor, hard surface sporicides and chemical decontaminants
GB0906281D0 (en) 2009-04-09 2009-05-20 Reckitt Benckiser Nv Detergent compositions
GB0915572D0 (en) 2009-09-07 2009-10-07 Reckitt Benckiser Nv Detergent composition
CN102648277B (zh) 2009-09-25 2015-05-20 诺维信公司 蛋白酶变体的用途
CN102648273B (zh) 2009-09-25 2017-04-26 诺维信公司 枯草蛋白酶变体
GB0917740D0 (en) 2009-10-09 2009-11-25 Reckitt Benckiser Nv Detergent composition
WO2011076897A1 (fr) 2009-12-22 2011-06-30 Novozymes A/S Utilisation de variants d'amylase à basse température
EP2501792A2 (fr) 2009-12-29 2012-09-26 Novozymes A/S Polypeptides amplifiant la detergence
GB201003892D0 (en) 2010-03-09 2010-04-21 Reckitt Benckiser Nv Detergent composition
US9107433B2 (en) 2010-04-26 2015-08-18 Novozymes A/S Enzyme granules
GB201010580D0 (en) 2010-06-23 2010-08-11 Reckitt Benckiser Nv Machine dishwashing compositions and methods
GB201014328D0 (en) 2010-08-27 2010-10-13 Reckitt Benckiser Nv Detergent composition comprising manganese-oxalate
GB201019623D0 (en) 2010-11-19 2010-12-29 Reckitt Benckiser Nv Coated bleach materials
GB201019628D0 (en) 2010-11-19 2010-12-29 Reckitt Benckiser Nv Dyed coated bleach materials
GB201021541D0 (en) 2010-12-21 2011-02-02 Reckitt Benckiser Nv Bleach catalyst particle
GB201104244D0 (en) 2011-03-14 2011-04-27 Reckitt Benckiser Nv Detergent composition with improved drying performance
WO2012175401A2 (fr) 2011-06-20 2012-12-27 Novozymes A/S Composition particulaire
MX349517B (es) 2011-06-24 2017-08-02 Novozymes As Polipeptidos que tienen actividad de proteasa y polinucleotidos que codifican los mismos.
BR122020009747B1 (pt) 2011-06-30 2021-07-20 Novozymes A/S Polipeptídeo e alfa-amilase variantes, composição detergente, e, utilização de uma alfa- amilase variante
EP2732018B1 (fr) 2011-07-12 2017-01-04 Novozymes A/S Granules d'enzyme stables au stockage
JP2014531895A (ja) 2011-08-15 2014-12-04 ノボザイムス アクティーゼルスカブ セルラーゼ活性を有するポリペプチドおよびそれをコードするポリヌクレオチド
US20140227738A1 (en) 2011-09-22 2014-08-14 Novozymes A/S Polypeptides Having Protease Activity and Polynucleotides Encoding Same
CN103957929B (zh) 2011-11-25 2017-06-30 诺维信公司 具有溶菌酶活性的多肽和编码所述多肽的多核苷酸
WO2013076269A1 (fr) 2011-11-25 2013-05-30 Novozymes A/S Variants de subtilase et polynucléotides codants pour ceux-ci
JP2015504660A (ja) 2011-12-20 2015-02-16 ノボザイムス アクティーゼルスカブ サブチラーゼ変異体およびそれをコードするポリヌクレオチド
CN110777016A (zh) 2011-12-29 2020-02-11 诺维信公司 具有脂肪酶变体的洗涤剂组合物
CN104350149A (zh) 2012-01-26 2015-02-11 诺维信公司 具有蛋白酶活性的多肽在动物饲料和洗涤剂中的用途
US20130196890A1 (en) * 2012-01-30 2013-08-01 Reckitt Benckiser Llc Stable, viscous, peroxide containing lavatory treatment compositions
WO2013120948A1 (fr) 2012-02-17 2013-08-22 Novozymes A/S Variants de subtilisine et polynucléotides codant ces derniers
EP2823026A1 (fr) 2012-03-07 2015-01-14 Novozymes A/S Composition détergente et substitution d'azurants optiques dans des compositions détergentes
CN107988181A (zh) 2012-04-02 2018-05-04 诺维信公司 脂肪酶变体以及编码其的多核苷酸
AR090971A1 (es) 2012-05-07 2014-12-17 Novozymes As Polipeptidos que tienen actividad de degradacion de xantano y polinucleotidos que los codifican
US20150132831A1 (en) 2012-05-16 2015-05-14 Novozymes A/S Compositions Comprising Lipase and Methods of Use Thereof
EP2861749A1 (fr) 2012-06-19 2015-04-22 Novozymes Bioag A/S Réduction enzymatique de la teneur en hydroperoxydes
BR112014031882A2 (pt) 2012-06-20 2017-08-01 Novozymes As uso de um polipeptídeo isolado, polipeptídeo, composição, polinucleotídeo isolado, construto de ácido nucleico ou vetor de expressão, célula hospedeira de expressão recombinante, métodos para produção de um polipeptídeo, para melhoria do valor nutricional de uma ração animal, e para o tratamento de proteínas, uso de pelo menos um polipeptídeo, aditivo de ração animal, ração animal, e, composição detergente
CN104471048B (zh) 2012-07-12 2018-11-16 诺维信公司 具有脂肪酶活性的多肽及编码它的多核苷酸
US8871699B2 (en) 2012-09-13 2014-10-28 Ecolab Usa Inc. Detergent composition comprising phosphinosuccinic acid adducts and methods of use
US9994799B2 (en) 2012-09-13 2018-06-12 Ecolab Usa Inc. Hard surface cleaning compositions comprising phosphinosuccinic acid adducts and methods of use
US20140308162A1 (en) 2013-04-15 2014-10-16 Ecolab Usa Inc. Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing
US9752105B2 (en) 2012-09-13 2017-09-05 Ecolab Usa Inc. Two step method of cleaning, sanitizing, and rinsing a surface
US9023784B2 (en) 2012-09-13 2015-05-05 Ecolab Usa Inc. Method of reducing soil redeposition on a hard surface using phosphinosuccinic acid adducts
DE102012022566A1 (de) 2012-11-17 2014-05-22 Clariant International Ltd. Waschmittelzusammensetzung enthaltend Manganoxalat und Carboxymethyloxybernsteinsäure (CMOS) und/oder deren Salze
TR201910918T4 (tr) 2012-12-07 2019-08-21 Novozymes As Bakterilerin yapışmasının önlenmesi.
WO2014090940A1 (fr) 2012-12-14 2014-06-19 Novozymes A/S Élimination de souillures issues de la peau
EP2934177B1 (fr) 2012-12-21 2017-10-25 Novozymes A/S Polypeptides possédant une activité protéasique et polynucléotides codant pour ceux-ci
EP2941485B1 (fr) 2013-01-03 2018-02-21 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
CN105189724A (zh) 2013-03-14 2015-12-23 诺维信公司 含有酶和抑制剂的水溶性膜
WO2014147127A1 (fr) 2013-03-21 2014-09-25 Novozymes A/S Polypeptides ayant une activité lipase et polynucléotides les codant
WO2014177709A1 (fr) 2013-05-03 2014-11-06 Novozymes A/S Microencapsulation d'enzymes détergentes
EP4717756A2 (fr) 2013-05-14 2026-04-01 Novozymes A/S Variantes de lipase et compositions détergentes
CN105209613A (zh) 2013-05-17 2015-12-30 诺维信公司 具有α淀粉酶活性的多肽
EP3004315A2 (fr) 2013-06-06 2016-04-13 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
US10378001B2 (en) 2013-06-27 2019-08-13 Novozymes A/S Subtilase variants and compositions comprising same
US20160145596A1 (en) 2013-06-27 2016-05-26 Novozymes A/S Subtilase Variants and Polynucleotides Encoding Same
RU2015156280A (ru) 2013-07-04 2017-08-09 Новозимс А/С Полипептиды, обладающие эффектом против переосаждения, и полинуклеотиды, кодирующие их
WO2015004102A1 (fr) 2013-07-09 2015-01-15 Novozymes A/S Polypeptides à activité lipase et polynucléotides codant pour ceux-ci
WO2015014803A1 (fr) 2013-07-29 2015-02-05 Novozymes A/S Variants de protéases et polynucléotides les codant
CN105358686A (zh) 2013-07-29 2016-02-24 诺维信公司 蛋白酶变体以及对其进行编码的多核苷酸
WO2015049370A1 (fr) 2013-10-03 2015-04-09 Novozymes A/S Composition détergente et utilisation de celle-ci
EP2857485A1 (fr) 2013-10-07 2015-04-08 WeylChem Switzerland AG Poche à compartiments multiples comprenant des compositions de nettoyage sans alkanolamine, processus de lavage et utilisation de produits de lavage et de nettoyage de textiles et plats
EP2857486A1 (fr) 2013-10-07 2015-04-08 WeylChem Switzerland AG Poche à compartiments multiples comprenant des compositions de nettoyage, processus de lavage et utilisation de produits de lavage et de nettoyage de textiles et plats
EP2857487A1 (fr) 2013-10-07 2015-04-08 WeylChem Switzerland AG Poche à compartiments multiples comprenant des compositions de nettoyage, processus de lavage et utilisation de produits de lavage et de nettoyage de textiles et plats
EP3453757B1 (fr) 2013-12-20 2020-06-17 Novozymes A/S Polypeptides a activite de protease et polynucleotides les codant
US10208297B2 (en) 2014-01-22 2019-02-19 Novozymes A/S Polypeptides with lipase activity and polynucleotides encoding same for cleaning
CA2841024C (fr) 2014-01-30 2017-03-07 The Procter & Gamble Company Article de type doses unitaires
WO2015134729A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés destinés à améliorer les propriétés de matériaux textiles non-cellulosiques par l'utilisation d'endo-xyloglucane transférase
CN106062271A (zh) 2014-03-05 2016-10-26 诺维信公司 用于改进具有木葡聚糖内糖基转移酶的纤维素纺织材料的性质的组合物和方法
EP3521434A1 (fr) 2014-03-12 2019-08-07 Novozymes A/S Polypeptides à activité lipase et polynucléotides codant pour ceux-ci
US20170015950A1 (en) 2014-04-01 2017-01-19 Novozymes A/S Polypeptides having alpha amylase activity
MX376770B (es) 2014-04-11 2025-03-07 Novozymes As Composición detergente.
WO2015158237A1 (fr) 2014-04-15 2015-10-22 Novozymes A/S Polypeptides à activité lipase et polynucléotides codant pour ceux-ci
WO2017186943A1 (fr) 2016-04-29 2017-11-02 Novozymes A/S Compositions détergentes et leurs utilisations
AR100606A1 (es) 2014-05-27 2016-10-19 Novozymes As Variantes de lipasas y polinucleótidos que las codifican
WO2015181118A1 (fr) 2014-05-27 2015-12-03 Novozymes A/S Procédés de production de lipases
WO2015189371A1 (fr) 2014-06-12 2015-12-17 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ces derniers
CN106471110A (zh) 2014-07-03 2017-03-01 诺维信公司 改进的非蛋白酶类酶稳定化
EP3739029A1 (fr) 2014-07-04 2020-11-18 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
US10550381B2 (en) 2014-07-04 2020-02-04 Novozymes A/S Variant proteases and amylases having enhanced storage stability
GB201413859D0 (en) 2014-08-05 2014-09-17 Reckitt Benckiser Brands Ltd New automatic washing machine and method
WO2016079110A2 (fr) 2014-11-19 2016-05-26 Novozymes A/S Utilisation d'enzymes pour le nettoyage
WO2016079305A1 (fr) 2014-11-20 2016-05-26 Novozymes A/S Variants de alicyclobacillus et polynucléotides codant pour ceux-ci
US10260024B2 (en) 2014-12-04 2019-04-16 Novozymes A/S Liquid cleaning compositions comprising protease variants
CA2963331C (fr) 2014-12-04 2024-09-10 Novozymes A/S Variants de subtilase et polynucleotides codant pour ceux-ci
WO2016087401A1 (fr) 2014-12-05 2016-06-09 Novozymes A/S Variantes de lipase et polynucléotides codant pour ces dernières
EP4530348A3 (fr) 2014-12-15 2025-08-06 Basf Se Composition détergente comprenant des variants de subtilase
US11518987B2 (en) 2014-12-19 2022-12-06 Novozymes A/S Protease variants and polynucleotides encoding same
US10400230B2 (en) 2014-12-19 2019-09-03 Novozymes A/S Protease variants and polynucleotides encoding same
US20180112156A1 (en) 2015-04-10 2018-04-26 Novozymes A/S Laundry method, use of polypeptide and detergent composition
CN107636134A (zh) 2015-04-10 2018-01-26 诺维信公司 洗涤剂组合物
EP3298121B1 (fr) 2015-05-19 2019-03-20 Novozymes A/S Réduction d'odeur
US10858637B2 (en) 2015-06-16 2020-12-08 Novozymes A/S Polypeptides with lipase activity and polynucleotides encoding same
EP4071244A1 (fr) 2015-06-18 2022-10-12 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3106508B1 (fr) 2015-06-18 2019-11-20 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
CN107922896A (zh) 2015-06-30 2018-04-17 诺维信公司 衣物洗涤剂组合物、用于洗涤的方法和组合物的用途
MX394221B (es) 2015-07-01 2025-03-24 Novozymes As Metodos de reduccion de olor.
EP3950939A3 (fr) 2015-07-06 2022-06-08 Novozymes A/S Variantes de la lipase et polynucleotides les codant
CA2991114A1 (fr) 2015-09-17 2017-03-23 Novozymes A/S Polypeptides presentant une activite de degradation de xylanase et polynucleotides codant pour ceux-ci
US11053486B2 (en) 2015-09-17 2021-07-06 Henkel Ag & Co. Kgaa Detergent compositions comprising polypeptides having xanthan degrading activity
EP3359657B1 (fr) 2015-10-07 2020-04-01 Novozymes A/S Polypeptides
EP4324919A3 (fr) 2015-10-14 2024-05-29 Novozymes A/S Variants polypeptidiques
EP3362558A1 (fr) 2015-10-14 2018-08-22 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides codant pour ceux-ci
CN108291178B (zh) 2015-10-28 2020-08-04 诺维信公司 包含淀粉酶变体和蛋白酶变体的洗涤剂组合物
WO2017089366A1 (fr) 2015-11-24 2017-06-01 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides codant pour ceux-ci
WO2017093318A1 (fr) 2015-12-01 2017-06-08 Novozymes A/S Procédés de production de lipases
ES2932192T3 (es) 2015-12-07 2023-01-16 Henkel Ag & Co Kgaa Composiciones para el lavado de vajilla que comprenden polipéptidos que tienen actividad beta-glucanasa y sus usos
EP3397061A1 (fr) 2015-12-28 2018-11-07 Novozymes BioAG A/S Prégermination par traitement thermique de spores bactériennes
WO2017162836A1 (fr) 2016-03-23 2017-09-28 Novozymes A/S Utilisation d'un polypeptide ayant une activité dnase pour le traitement de tissus
EP3440180B1 (fr) 2016-04-08 2020-11-11 Novozymes A/S Compositions detergentes et leurs utilisations
WO2017210188A1 (fr) 2016-05-31 2017-12-07 Novozymes A/S Compositions stabilisées de peroxyde liquide
CN109715792A (zh) 2016-06-03 2019-05-03 诺维信公司 枯草杆菌酶变体和对其进行编码的多核苷酸
US11203732B2 (en) 2016-06-30 2021-12-21 Novozymes A/S Lipase variants and compositions comprising surfactant and lipase variant
WO2018002261A1 (fr) 2016-07-01 2018-01-04 Novozymes A/S Compositions détergentes
US10662417B2 (en) 2016-07-05 2020-05-26 Novozymes A/S Pectate lyase variants and polynucleotides encoding same
WO2018007573A1 (fr) 2016-07-08 2018-01-11 Novozymes A/S Compositions détergentes contenant de la galactanase
CA3027272C (fr) 2016-07-13 2022-06-21 The Procter & Gamble Company Variants dnase de bacillus cibi et leurs utilisations
EP3485008B1 (fr) 2016-07-18 2024-01-31 Novozymes A/S Variantes de lipase, polynucléotides les codant et leur utilisation
WO2018037065A1 (fr) 2016-08-24 2018-03-01 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants i d'endoglucanase gh9
CA3031609A1 (fr) 2016-08-24 2018-03-01 Novozymes A/S Variants d'endoglucanase gh9 et polynucleotides codant pour de tels variants
CN109563498A (zh) 2016-08-24 2019-04-02 汉高股份有限及两合公司 包含黄原胶裂解酶变体i的洗涤剂组合物
US11512300B2 (en) 2016-08-24 2022-11-29 Novozymes A/S Xanthan lyase variants and polynucleotides encoding same
CN110023474A (zh) 2016-09-29 2019-07-16 诺维信公司 酶用于洗涤的用途、洗涤方法和器皿洗涤组合物
WO2018060475A1 (fr) 2016-09-29 2018-04-05 Novozymes A/S Granule contenant des spores
US20210284933A1 (en) 2016-10-25 2021-09-16 Novozymes A/S Detergent compositions
CN110072986B (zh) 2016-11-01 2023-04-04 诺维信公司 多核心颗粒
EP3551740B1 (fr) 2016-12-12 2021-08-11 Novozymes A/S Utilisation de polypeptides
WO2018177936A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides ayant une activité dnase
CN110651040A (zh) 2017-03-31 2020-01-03 诺维信公司 具有dna酶活性的多肽
US11149233B2 (en) 2017-03-31 2021-10-19 Novozymes A/S Polypeptides having RNase activity
US11208639B2 (en) 2017-03-31 2021-12-28 Novozymes A/S Polypeptides having DNase activity
CN114480034A (zh) 2017-04-04 2022-05-13 诺维信公司 糖基水解酶
EP3607040A1 (fr) 2017-04-04 2020-02-12 Novozymes A/S Compositions de poypeptides et utilisations associées
EP3607039A1 (fr) 2017-04-04 2020-02-12 Novozymes A/S Polypeptides
ES2728758T3 (es) 2017-04-05 2019-10-28 Henkel Ag & Co Kgaa Composiciones de detergente que comprenden mananasas bacterianas
EP3385362A1 (fr) 2017-04-05 2018-10-10 Henkel AG & Co. KGaA Compositions détergentes comprenant des mannanases fongiques
WO2018184818A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184816A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
US20200190438A1 (en) 2017-04-06 2020-06-18 Novozymes A/S Cleaning compositions and uses thereof
EP3607044B1 (fr) 2017-04-06 2024-11-13 Novozymes A/S Compositions détergentes et leurs utilisations
EP3967756B1 (fr) 2017-04-06 2025-03-05 Novozymes A/S Compositions détergentes et leurs utilisations
WO2018185269A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3478811B1 (fr) 2017-04-06 2019-10-16 Novozymes A/S Compositions détergentes et leurs utilisations
MX2019011764A (es) 2017-04-06 2019-11-28 Novozymes As Composiciones limpiadoras y usos de las mismas.
WO2018202846A1 (fr) 2017-05-05 2018-11-08 Novozymes A/S Compositions comprenant une lipase et un sulfite
EP3401385A1 (fr) 2017-05-08 2018-11-14 Henkel AG & Co. KGaA Composition détergente comprenant un polypeptide comprenant un domaine de liaison aux glucides
WO2018206535A1 (fr) 2017-05-08 2018-11-15 Novozymes A/S Domaine de liaison aux glucides et polynucléotides codant pour celui-ci
EP3645692B1 (fr) 2017-06-30 2025-12-31 Novozymes A/S Composition de suspension enzymatique
WO2019018976A1 (fr) 2017-07-24 2019-01-31 Rhodia Operations Composition détergente contenant des enzymes
CA3070749A1 (fr) 2017-08-24 2019-02-28 Novozymes A/S Variants d'endoglucanase gh9 et polynucleotides codant pour de tels variants
US20210130744A1 (en) 2017-08-24 2021-05-06 Henkel Ag & Co. Kgaa Detergent composition comprising xanthan lyase variants ii
US11624059B2 (en) 2017-08-24 2023-04-11 Henkel Ag & Co. Kgaa Detergent compositions comprising GH9 endoglucanase variants II
US11359188B2 (en) 2017-08-24 2022-06-14 Novozymes A/S Xanthan lyase variants and polynucleotides encoding same
WO2019057758A1 (fr) 2017-09-20 2019-03-28 Novozymes A/S Utilisation d'enzymes pour améliorer l'absorption d'eau et/ou la blancheur
EP3684899A1 (fr) 2017-09-22 2020-07-29 Novozymes A/S Nouveaux polypeptides
EP4567094A3 (fr) 2017-09-27 2026-01-07 Novozymes A/S Variants de lipase et compositions de microcapsules comprenant de tels variants de lipase
EP3697881B1 (fr) 2017-10-16 2024-12-18 Novozymes A/S Granulés de poudrage faible
CN111542589A (zh) 2017-10-16 2020-08-14 诺维信公司 低粉化颗粒
WO2019076800A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Compositions de nettoyage et leurs utilisations
HUE057832T2 (hu) 2017-10-27 2022-06-28 Procter & Gamble Polipeptid-variánsokat tartalmazó mosószerkészítmények
EP3701017A1 (fr) 2017-10-27 2020-09-02 Novozymes A/S Variants de dnase
DE102017125559A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine ii enthalten
DE102017125560A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine iii enthalten
WO2019086530A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
EP3704240A1 (fr) 2017-11-01 2020-09-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
DE102017125558A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine i enthalten
EP3704220B1 (fr) 2017-11-01 2026-04-15 Novozymes A/S Méthodes de nettoyage des dispositifs medicaux
CN111670248A (zh) 2017-12-04 2020-09-15 诺维信公司 脂肪酶变体以及编码其的多核苷酸
DK3720955T5 (da) 2017-12-08 2024-08-26 Novozymes As Alfa-amylasevarianter og polynukleotider, der koder for dem
EP3749759A1 (fr) 2018-02-08 2020-12-16 Novozymes A/S Variants de lipase et compositions en comprenant
WO2019154951A1 (fr) 2018-02-08 2019-08-15 Novozymes A/S Lipases, variants de lipase et compositions associées
US20210102184A1 (en) 2018-02-23 2021-04-08 Henkel Ag & Co. Kgaa Detergent composition comprising xanthan lyase and endoglucanase variants
US20210002588A1 (en) 2018-03-13 2021-01-07 Novozymes A/S Microencapsulation Using Amino Sugar Oligomers
WO2019180111A1 (fr) 2018-03-23 2019-09-26 Novozymes A/S Variants de subtilase et compositions les comprenant
EP3781660A1 (fr) 2018-04-17 2021-02-24 Novozymes A/S Polypeptides ayant une activité de liaison des hydrates de carbone dans des compositions détergentes et leur utilisation pour réduire les plis de textiles ou de tissus
EP3781680A1 (fr) 2018-04-19 2021-02-24 Novozymes A/S Variants améliorés de cellulase
CN118460512A (zh) 2018-04-19 2024-08-09 诺维信公司 稳定化的纤维素酶变体
GB201809123D0 (en) 2018-06-04 2018-07-18 Reckitt Benckiser Finish Bv Composition
EP3814472A1 (fr) 2018-06-28 2021-05-05 Novozymes A/S Compositions détergentes et leurs utilisations
EP3814473A1 (fr) 2018-06-29 2021-05-05 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020002255A1 (fr) 2018-06-29 2020-01-02 Novozymes A/S Variants de subtilase et compositions les comprenant
US12012573B2 (en) 2018-07-02 2024-06-18 Novozymes A/S Cleaning compositions and uses thereof
EP3818138B1 (fr) 2018-07-03 2025-05-14 Henkel AG & Co. KGaA Compositions de nettoyage enzymatiques et leurs utilisations
EP3818140A1 (fr) 2018-07-06 2021-05-12 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020008024A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
GB201814188D0 (en) 2018-08-31 2018-10-17 Reckitt Benckiser Finish Bv Automatic dishwashing product
WO2020070063A2 (fr) 2018-10-01 2020-04-09 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020070209A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage
EP3861094A1 (fr) 2018-10-02 2021-08-11 Novozymes A/S Composition de nettoyage
WO2020070014A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage comprenant un tensioactif anionique et un polypeptide ayant une activité rnase
WO2020070249A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Compositions de nettoyage
WO2020070199A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Polypeptides ayant une activité de dégradation de l'alpha-mannane et polynucléotides codant pour ceux-ci
EP3864122A1 (fr) 2018-10-09 2021-08-18 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3864123A1 (fr) 2018-10-09 2021-08-18 Novozymes A/S Compositions de nettoyage et leurs utilisations
CN112996894A (zh) 2018-10-11 2021-06-18 诺维信公司 清洁组合物及其用途
EP3647397A1 (fr) 2018-10-31 2020-05-06 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersions iv
EP3647398B1 (fr) 2018-10-31 2024-05-15 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersines v
CA3114123A1 (fr) * 2018-11-07 2020-05-14 Kemira Oyj Composition destinee a etre utilisee en tant que stabilisateur de peroxyde
GB201818827D0 (en) 2018-11-19 2019-01-02 Reckitt Benckiser Finish Bv Composition
CN113302270A (zh) 2018-12-03 2021-08-24 诺维信公司 低pH粉末洗涤剂组合物
EP3891277A1 (fr) 2018-12-03 2021-10-13 Novozymes A/S Composition de détergent en poudre
EP3898919A1 (fr) 2018-12-21 2021-10-27 Novozymes A/S Sachet de détergent comprenant des métalloprotéases
CN113366103A (zh) 2018-12-21 2021-09-07 诺维信公司 具有肽聚糖降解活性的多肽以及编码其的多核苷酸
EP3702452A1 (fr) 2019-03-01 2020-09-02 Novozymes A/S Compositions détergentes comprenant deux protéases
GB201903318D0 (en) 2019-03-11 2019-04-24 Reckitt Benckiser Finish Bv Product
JP7725365B2 (ja) 2019-03-21 2025-08-19 ノボザイムス アクティーゼルスカブ α－アミラーゼ変異体及びこれをコードするポリヌクレオチド
WO2020201403A1 (fr) 2019-04-03 2020-10-08 Novozymes A/S Polypeptides ayant une activité bêta-glucanase, polynucléotides codant pour celles-ci et leur utilisation dans des compositions nettoyantes et détergentes
US12247237B2 (en) 2019-04-10 2025-03-11 Novozymes A/S Polypeptide variants
WO2020208056A1 (fr) 2019-04-12 2020-10-15 Novozymes A/S Variants stabilisés d'un glycoside hydrolase
EP3994255A1 (fr) 2019-07-02 2022-05-11 Novozymes A/S Variants de lipase et compositions de ceux-ci
EP3997202A1 (fr) 2019-07-12 2022-05-18 Novozymes A/S Émulsions enzymatiques pour détergents
WO2021037878A1 (fr) 2019-08-27 2021-03-04 Novozymes A/S Composition comprenant une lipase
CN114787329A (zh) 2019-08-27 2022-07-22 诺维信公司 洗涤剂组合物
EP4031644A1 (fr) 2019-09-19 2022-07-27 Novozymes A/S Composition détergente
WO2021064068A1 (fr) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprenant au moins deux domaines de liaison aux hydrates de carbone
US20220411773A1 (en) 2019-12-20 2022-12-29 Novozymes A/S Polypeptides having proteolytic activity and use thereof
KR20220119609A (ko) 2019-12-20 2022-08-30 헨켈 아게 운트 코. 카게아아 디스페르신 vi을 포함하는 세정 조성물
WO2021122120A2 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines viii
AU2020405786A1 (en) 2019-12-20 2022-08-11 Henkel Ag & Co. Kgaa Cleaning compositions comprising dispersins IX
WO2021122117A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Composition de nettoyage comprenant une dispersine et une carbohydrase
EP4077617B1 (fr) 2019-12-20 2026-03-18 Novozymes A/S Compositions d'enzymes liquides stabilisées sans bore
WO2021130167A1 (fr) 2019-12-23 2021-07-01 Novozymes A/S Compositions enzymatiques et utilisations associées
WO2021148364A1 (fr) 2020-01-23 2021-07-29 Novozymes A/S Compositions enzymatiques et leurs utilisations
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
WO2021204838A1 (fr) 2020-04-08 2021-10-14 Novozymes A/S Variants de module de liaison d'hydrate de carbone
US20230167384A1 (en) 2020-04-21 2023-06-01 Novozymes A/S Cleaning compositions comprising polypeptides having fructan degrading activity
EP3907271A1 (fr) 2020-05-07 2021-11-10 Novozymes A/S Composition de nettoyage, utilisation et procédé de nettoyage
EP4158011A1 (fr) 2020-05-26 2023-04-05 Novozymes A/S Variants de subtilase et compositions les comprenant
EP4172298A1 (fr) 2020-06-24 2023-05-03 Novozymes A/S Utilisation de cellulases pour retirer d'un textile les acariens de la poussière
EP3936593A1 (fr) 2020-07-08 2022-01-12 Henkel AG & Co. KGaA Compositions de nettoyage et leurs utilisations
EP4204551B1 (fr) 2020-08-25 2025-09-17 Novozymes A/S Variants de xyloglucanase de la famille 44
WO2022043563A1 (fr) 2020-08-28 2022-03-03 Novozymes A/S Variants de protéase dégradant le polyester
US20250346879A1 (en) 2020-10-07 2025-11-13 Novozymes A/S Alpha-amylase variants
WO2022084303A2 (fr) 2020-10-20 2022-04-28 Novozymes A/S Utilisation de polypeptides ayant une activité de dnase
WO2022090320A1 (fr) 2020-10-28 2022-05-05 Novozymes A/S Utilisation de lipoxygénase
JP2023547450A (ja) 2020-10-29 2023-11-10 ノボザイムス アクティーゼルスカブ リパーゼ変異体及びそのようなリパーゼ変異体を含む組成物
EP4244325A1 (fr) 2020-11-13 2023-09-20 Novozymes A/S Composition détergente comprenant une lipase
WO2022106404A1 (fr) 2020-11-18 2022-05-27 Novozymes A/S Combinaison de protéases
WO2022106400A1 (fr) 2020-11-18 2022-05-27 Novozymes A/S Combinaison de protéases immunochimiquement différentes
EP4032966A1 (fr) 2021-01-22 2022-07-27 Novozymes A/S Composition enzymatique liquide avec piégeur de sulfite
US20240124805A1 (en) 2021-01-28 2024-04-18 Novozymes A/S Lipase with low malodor generation
EP4039806A1 (fr) 2021-02-04 2022-08-10 Henkel AG & Co. KGaA Composition détergente comprenant des variants de xanthane lyase et d'endoglucanase à stabilité améliorée
EP4291646A2 (fr) 2021-02-12 2023-12-20 Novozymes A/S Variants d'alpha-amylase
US20250075152A1 (en) 2021-02-12 2025-03-06 Novozymes A/S Stabilized biological detergents
US11795416B2 (en) * 2021-02-17 2023-10-24 Henkel Ag & Co. Kgaa Synergistic effects of iminodisuccinic acid on an ethanol and PEG400 blend for rheology control
EP4053256A1 (fr) 2021-03-01 2022-09-07 Novozymes A/S Utilisation d'enzymes pour améliorer le dépôt de parfum
EP4305146A1 (fr) 2021-03-12 2024-01-17 Novozymes A/S Variants polypeptidiques
EP4060036A1 (fr) 2021-03-15 2022-09-21 Novozymes A/S Variantes de polypeptides
WO2022194673A1 (fr) 2021-03-15 2022-09-22 Novozymes A/S Variants de la dnase
WO2022199418A1 (fr) 2021-03-26 2022-09-29 Novozymes A/S Composition détergente à teneur en polymère réduite
EP4359518A1 (fr) 2021-06-23 2024-05-01 Novozymes A/S Polypeptides d'alpha-amylase
CN118871559A (zh) 2021-12-21 2024-10-29 诺维信公司 包含脂肪酶和加强剂的组合物
WO2023117888A1 (fr) 2021-12-21 2023-06-29 Basf Se Passeport de produit chimique pour données d'émission
EP4206309A1 (fr) 2021-12-30 2023-07-05 Novozymes A/S Particules de protéines à blancheur améliorée
US20250179393A1 (en) 2022-03-02 2025-06-05 Novozymes A/S Use of xyloglucanase for improvement of sustainability of detergents
WO2023165950A1 (fr) 2022-03-04 2023-09-07 Novozymes A/S Variants de dnase et compositions
EP4504885A1 (fr) 2022-04-08 2025-02-12 Novozymes A/S Variants et compositions d'hexosaminidase
EP4544015A2 (fr) 2022-06-24 2025-04-30 Novozymes A/S Variants de lipase et compositions comprenant de tels variants de lipase
WO2024046952A1 (fr) 2022-08-30 2024-03-07 Novozymes A/S Perfectionnements apportés ou se rapportant à des composés organiques
EP4623056A1 (fr) 2022-11-22 2025-10-01 Novozymes A/S Granulés colorés ayant une stabilité de colorant améliorée
JP2026508744A (ja) 2022-12-05 2026-03-12 ノボザイムス アクティーゼルスカブ プロテアーゼバリアント、及びそれをコードするポリヌクレオチド
EP4630529A1 (fr) 2022-12-05 2025-10-15 Novozymes A/S Composition comprenant une lipase et un peptide
GB202218868D0 (en) 2022-12-14 2023-01-25 Reckitt Benckiser Finish Bv Solid unit dose detergent composition
CN120265743A (zh) 2022-12-14 2025-07-04 诺维信公司 改善的脂肪酶（gcl1）变体
CN120344647A (zh) 2022-12-23 2025-07-18 诺维信公司 包含过氧化氢酶和淀粉酶的洗涤剂组合物
EP4655371A1 (fr) 2023-01-23 2025-12-03 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP4683990A1 (fr) 2023-03-21 2026-01-28 Novozymes A/S Compositions détergentes à base de biotensioactifs
WO2024213513A1 (fr) 2023-04-12 2024-10-17 Novozymes A/S Compositions comprenant des polypeptides ayant une activité de phosphatase alcaline
EP4702114A2 (fr) 2023-04-26 2026-03-04 Novozymes A/S Composition de nettoyage et procédé de nettoyage
WO2025002934A1 (fr) 2023-06-28 2025-01-02 Novozymes A/S Composition détergente comprenant des lipases
CN121420051A (zh) 2023-07-07 2026-01-27 诺维信公司 用于去除蛋白质污渍的洗涤方法
WO2025088003A1 (fr) 2023-10-24 2025-05-01 Novozymes A/S Utilisation de xyloglucanase pour remplacer un azurant optique
WO2025103765A1 (fr) 2023-11-17 2025-05-22 Novozymes A/S Monooxygénases polysaccharidiques lytiques et leur utilisation dans un détergent
WO2025114053A1 (fr) 2023-11-30 2025-06-05 Novozymes A/S Biopolymères destinés à être utilisés dans un détergent
WO2025153046A1 (fr) 2024-01-19 2025-07-24 Novozymes A/S Compositions détergentes et leurs utilisations
WO2025257254A1 (fr) 2024-06-12 2025-12-18 Novozymes A/S Lipases et variants de lipase et leur utilisation
WO2026017636A1 (fr) 2024-07-17 2026-01-22 Novozymes A/S Compositions comprenant une combinaison d'enzymes
WO2026046881A1 (fr) 2024-08-26 2026-03-05 Novozymes A/S Compositions comprenant une hexosaminidase et une protéase
WO2026068782A1 (fr) 2024-09-30 2026-04-02 Novozymes A/S Variants de protéase et polynucléotides codant pour ceux-ci

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1903703C3 (de) * 1969-01-25 1971-12-02 Basf Ag UEberzugsmittel zum Herstellen elektrisch abscheidbarer UEberzuege
DE3626672A1 (de) * 1986-08-07 1988-02-11 Bayer Ag Polyasparaginamidsaeure
DE3717227A1 (de) * 1987-05-21 1988-12-01 Henkel Kgaa Phosphatfreies waschmittel mit reduzierter inkrustierungstendenz
DE3739610A1 (de) * 1987-11-23 1989-06-01 Basf Ag Nitrilo-di-aepfel-mono-essigsaeuren, verfahren zu ihrer herstellung und ihre verwendung
US4992463A (en) * 1988-07-20 1991-02-12 Monsanto Company Thienyl peptide mimetic compounds which are useful in inhibiting platelet aggregation
DE4024552A1 (de) * 1990-08-02 1992-02-06 Henkel Kgaa Derivat der aminobernsteinsaeure als komplexierungsmittel
US5168884A (en) * 1991-04-12 1992-12-08 Philip Morris Incorporated Smoking articles using novel paper wrapper
US5362412A (en) * 1991-04-17 1994-11-08 Hampshire Chemical Corp. Biodegradable bleach stabilizers for detergents
DK0513948T3 (da) * 1991-05-15 1998-10-26 Hampshire Chemical Corp Sammensætninger indeholdende biologisk nedbrydelige chelateringsmidler til rensning af hårde overflader
JPH05302289A (ja) * 1992-02-26 1993-11-16 Nippon Shokubai Co Ltd 漂白剤組成物及び漂白方法
JPH05287690A (ja) * 1992-04-02 1993-11-02 Nippon Shokubai Co Ltd クラフトパルプ製造工程における蒸解釜内のスケール付着防止方法
JPH05287685A (ja) * 1992-04-02 1993-11-02 Nippon Shokubai Co Ltd セルロース系繊維の染色方法
US5288783A (en) * 1992-05-14 1994-02-22 Srchem Incorporated Preparation of salt of polyaspartic acid by high temperature reaction
US5266237A (en) * 1992-07-31 1993-11-30 Rohm And Haas Company Enhancing detergent performance with polysuccinimide
FR2696473A1 (fr) * 1992-10-06 1994-04-08 Rhone Poulenc Chimie Composition détergente incorporant un biopolymère polyimide hydrolysable en milieu lessiviel.
TW239160B (fr) * 1992-10-27 1995-01-21 Procter & Gamble
IT1263963B (it) * 1993-02-24 1996-09-05 Enichem Spa Composizioni per il lavaggio di materiali tessili
DE4311440A1 (de) * 1993-04-07 1994-10-13 Henkel Kgaa Gerüststoff für Wasch- oder Reinigungsmittel
DE4322410A1 (de) * 1993-07-06 1995-01-12 Bayer Ag Verfahren zur Herstellung von Polysuccinimid und Polyasparaginsäure

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1998030661A1 (fr) * 1997-01-09 1998-07-16 Bayer Aktiengesellschaft Procede pour nettoyer des surfaces
US6387189B1 (en) 1997-01-09 2002-05-14 Bayer Aktiengesellschaft Surface-cleaning method
EP0940495A1 (fr) * 1998-03-05 1999-09-08 Bayer Aktiengesellschaft Procédé pour le lavage et le blanchiment simultanés de fibres naturelles et de produits textiles les contenant
US6096097A (en) * 1998-03-05 2000-08-01 Bayer Aktiengesellschaft Simultaneous washing and bleaching of native fibres and textile products therefrom
WO1999067442A1 (fr) * 1998-06-24 1999-12-29 Aware Chemicals L.L.C. Procede de traitement prealable d'une piece metallique en vue d'une mise en peinture
US6432220B1 (en) 1998-06-24 2002-08-13 Aware Chemicals L.L.C. Process for the preliminary treatment of a metallic workpiece before coating
EP1045022A1 (fr) * 1999-04-15 2000-10-18 Greither, Peter Utilisation de gélatine en agent de lavage
WO2001046371A1 (fr) * 1999-12-21 2001-06-28 Unilever Plc Compositions detergentes
WO2001088077A1 (fr) * 2000-05-15 2001-11-22 Unilever Plc Compositions detergentes
EP2045317A1 (fr) * 2007-10-04 2009-04-08 Lanxess Deutschland GmbH Moyen de lavage et de nettoyage liquide
EP3666871A1 (fr) * 2018-12-12 2020-06-17 Henkel AG & Co. KGaA Détergent ou agent de nettoyage contenant de l'iminodisuccinate et/ou de l'iminotrisuccinate

Also Published As

Publication number Publication date
NO311842B1 (no) 2002-02-04
ES2208709T3 (es) 2004-06-16
DK0757094T3 (da) 2003-12-22
KR970006470A (ko) 1997-02-21
DE19528059A1 (de) 1997-02-06
HUP9602096A2 (en) 1997-04-28
NO963190D0 (no) 1996-07-30
DE59610743D1 (de) 2003-11-06
PT757094E (pt) 2004-02-27
CA2182158C (fr) 2008-09-23
AU703102B2 (en) 1999-03-18
EP0757094B1 (fr) 2003-10-01
HU9602096D0 (en) 1996-09-30
US5977053A (en) 1999-11-02
NO963190L (no) 1997-02-03
CZ225796A3 (en) 1997-02-12
CA2182158A1 (fr) 1997-02-01
JPH0948995A (ja) 1997-02-18
PL315446A1 (en) 1997-02-03
EP0757094A3 (fr) 1998-10-21
HUP9602096A3 (en) 1999-03-01
ATE251211T1 (de) 2003-10-15
AU6067796A (en) 1997-02-06
KR100406227B1 (ko) 2004-03-26

Similar Documents

Publication Publication Date Title
EP0757094B1 (fr) Composition détergente contenant des disuccinates d'imine
WO1995020029A1 (fr) Adjuvant pour detergents et nettoyants
EP0746599A1 (fr) Produit de lavage a adjuvants au silicate amorphes
EP0682692B1 (fr) Adjuvant pour detergents ou nettoyants
EP0658189B1 (fr) Produits de lavage et de nettoyage contenant des adjuvants
WO1994029419A1 (fr) Detergents contenant des acides amines et/ou leurs sels
EP0656051B1 (fr) Adjuvants pour agents de lavage
EP0656050B1 (fr) Adjuvants pour agents de lavage
DE4311440A1 (de) Gerüststoff für Wasch- oder Reinigungsmittel
EP0647261B1 (fr) Granule de lavage et de nettoyage
EP0682693B1 (fr) Adjuvant pour detergents ou nettoyants
EP0713524A1 (fr) Detergent contenant des ethers cellulosiques non ioniques
EP0853655B1 (fr) Combinaisons d'adjuvants de lavage renfermant des copolymeres d'acroleine et d'acetate de vinyle, produits de lavage et de nettoyage contenant lesdites combinaisons et leur production
EP0705328A1 (fr) Agents de lavage a proprietes inhibitrices de la decoloration
WO1999010471A1 (fr) Detergents solides contenant des sulfates d'ester de polyglycol d'acide gras et adjuvants solides
DE4305396A1 (de) Gerüststoff für Wasch- und Reinigungsmittel
DE19502166A1 (de) Alkoxybernsteinsäurederivate, Gerüststoffkombinationen, Wasch- und Reinigungsmittel, die diese enthalten sowie deren Herstellung
WO1996011251A1 (fr) Detergents ou nettoyants comportant des adjuvants amorphes de type silicate
WO1996034845A1 (fr) Derives d'acide saccharique servant d'adjuvants dans des detergents ou nettoyants
WO1999043774A1 (fr) Detergent et nettoyant pulverulent a granulaire
WO1995020034A1 (fr) Adjuvant pour detergents et nettoyants

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH DE DK ES FI FR GB IE IT LI NL PT SE

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AT BE CH DE DK ES FI FR GB IE IT LI NL PT SE

17P Request for examination filed

Effective date: 19990421

17Q First examination report despatched

Effective date: 20020412

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAH Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOS IGRA

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH DE DK ES FI FR GB IE IT LI NL PT SE

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: NV

Representative=s name: DR. LUSUARDI AG

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: GERMAN

REF Corresponds to:

Ref document number: 59610743

Country of ref document: DE

Date of ref document: 20031106

Kind code of ref document: P

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20031113

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

ET Fr: translation filed
REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2208709

Country of ref document: ES

Kind code of ref document: T3

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20040702

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20050630

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IE

Payment date: 20050712

Year of fee payment: 10

REG Reference to a national code

Ref country code: GB

Ref legal event code: 732E

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20060713

Year of fee payment: 11

Ref country code: CH

Payment date: 20060713

Year of fee payment: 11

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060718

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20060731

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20060912

Year of fee payment: 11

REG Reference to a national code

Ref country code: PT

Ref legal event code: PC4A

Owner name: LANXESS DEUTSCHLAND GMBH, DE

Effective date: 20061109

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070118

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 20070118

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

NLS Nl: assignments of ep-patents

Owner name: LANXESS DEUTSCHLAND GMBH

Effective date: 20070305

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: BAYER AG

Free format text: BAYER AG# #51368 LEVERKUSEN (DE) -TRANSFER TO- BAYER AG# #51368 LEVERKUSEN (DE)

REG Reference to a national code

Ref country code: CH

Ref legal event code: PUE

Owner name: LANXESS DEUTSCHLAND GMBH

Free format text: BAYER AG# #51368 LEVERKUSEN (DE) -TRANSFER TO- LANXESS DEUTSCHLAND GMBH# #51369 LEVERKUSEN (DE)

BERE Be: lapsed

Owner name: *LANXESS DEUTSCHLAND G.M.B.H.

Effective date: 20070731

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070731

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070731

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20080821

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: TP

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20080718

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20080723

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20070718

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20090718

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20100331

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090718

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20090720

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20090720

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20100707

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20100708

Year of fee payment: 15

Ref country code: DE

Payment date: 20100714

Year of fee payment: 15

Ref country code: AT

Payment date: 20100712

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20100712

Year of fee payment: 15

REG Reference to a national code

Ref country code: NL

Ref legal event code: V1

Effective date: 20120201

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 251211

Country of ref document: AT

Kind code of ref document: T

Effective date: 20110718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120201

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 59610743

Country of ref document: DE

Effective date: 20120201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20120201

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110731

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110718

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110719