EP0934356A1 - Compositions de polyolefine resistantes au feu - Google Patents

Compositions de polyolefine resistantes au feu

Info

Publication number
EP0934356A1
EP0934356A1 EP97911834A EP97911834A EP0934356A1 EP 0934356 A1 EP0934356 A1 EP 0934356A1 EP 97911834 A EP97911834 A EP 97911834A EP 97911834 A EP97911834 A EP 97911834A EP 0934356 A1 EP0934356 A1 EP 0934356A1
Authority
EP
European Patent Office
Prior art keywords
composition
phosphate
tris
flame retardant
additive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97911834A
Other languages
German (de)
English (en)
Inventor
Elisabeth S. Papazoglou
Frederick R. Scholer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
FMC Corp
Original Assignee
FMC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by FMC Corp filed Critical FMC Corp
Publication of EP0934356A1 publication Critical patent/EP0934356A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/02—Halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene

Definitions

  • This invention relates to flame resistant polyolefin compositions, to methods for improving the flame resistance of polyolefins, and to flame retardant additive compositions suitable for use in the aforesaid methods.
  • Polyoleflns such as polypropylene and copolymers of polypropylene find use in a variety of applications. In many of these it is preferred or mandatory to incorporate an additive into the polyolefin which improves its flame resistance (retardance) - sometimes abbreviated herein as "FR".
  • FR flame resistance
  • a number of flame retardant additives are known and used but all suffer from the disadvantage that their incorporation detracts from the product's physical properties, may cause problems in processing the polymer and may shorten the useful life of the product.
  • the use of flame retardant additives in polymers is usually a compromise between the desire for a particular degree of flame retardancy and the need to detract as little as possible from the desirable properties of the polymer.
  • UL Underwriters Laboratory
  • Subject 94 vertical burn test a specimen (5.0 x 1 / 8 or V 16 inches) is exposed vertically to a Bbunsen flame for 10 seconds. The specimen is ignited at the bottom and burns up. If the specimen self-extinguishes within 30 seconds another 10 second application is made. Flaming droplets are allowed to fall on dry absorbent surgical cotton located 12 inches below the sample. If the average burning time is less than 5 seconds and the drips do not ignite the cotton the material is classified as 94V-0. If the time is less than 25 seconds and the drips do not ignite the cotton thisere material is classified 94V-1. If the sample is extinguishing but the cotton is ignited the material is classified as 94 V-2.
  • a V-O rated polypropylene can be produced by incorporating known flame retardant additives. However, at least in the quantities needed to provide a V-O rated compositions these additives detract from the physical properties of the polymer. When used in these quantities these additives bloom from the polymer. Blooming or plating out is the separation of the additive from the polymer matrix which shows up as a surface film on the moulded specimen. It can occur during cooling of the article in the mold, or can be induced via heat ageing at elevated temperatures and extended times. The blooming issue is more than a simple appearance problem.
  • the flame retardant additive diffusing out of the polymer creates problems as to the extent of the composition maintaining its FR performance over time. Many electrical applications of the flame retardant polymer required RTI (Relative Thermal Index) ratings, which involve 18 month heat ageing of the samples while maintaining physical properties and FR performance. If the additive blooms out of the polymer, this RTI rating cannot be achieved.
  • RTI Relative Thermal Index
  • Tris (trihaloneopentyl) phosphates especially tris (tribromo neopentyl) phosphate.
  • These additives are melt blendable into polypropylene and thereby attractive in so far as they have minimal impact upon the properties and the processing of the polymer. They can be very easily extruded with polypropylene in preblends or through separate feeders. Being free flowing powders they readily mix with polypropylene and at processing temperatures melt and mix with polypropylene resin giving a uniform product. Their exceptional heat stability allows processing stability and storage stability as well as performance permanence in the molded specimens.
  • Japanese Patent Application Hei-8-32797 describes flame retardant polymer compositions comprising tris (tribromoneopentyl) phosphate, a second halogen containing flame retardant and an anti-oxidant.
  • the anti-oxidant is said to be an essential ingredient of these compositions in order to impart good color protection to the product.
  • the organic halogen compound is said to be present to impart flame retardancy.
  • tris (trihaloneopentyl) phosphates such as tris (tribromo neopentyl) phosphate in combination with a relatively small quantity of certain other halogenated co-additives results in a synergistic interaction between the phosphate and the halogenated co-additive.
  • a synergist such as antimony trioxide
  • a polyolefin composition which can achieve V-0 rating in the UL 94 test is produced.
  • compositions of this invention do not require the presence of an anti-oxidant to provide an acceptable color in the finished product. Moreover they may be non-blooming, i.e. the flame retardants/additives do not exude from the polymer during processing to give an unacceptable sticky product which is a common problem in other known flame retardant polyolefin compositions.
  • the halogenated co-additive which is used in combination with the tris (trihaloneopentyl) phosphate is one having at least one halogen atom bound to an aliphatic carbon atom as part of its molecular structure.
  • the co-additive is one which has at least one hydrogen atom bound to a carbon atom, which is in the beta position in relation to at least one halogen atom
  • the additive will be selected so as to be compatible with the polyolefin, sufficiently non-volatile as to be non blooming, and not to detract from the other useful properties of the polymer in the quantities in which it is used. Although a large number of compounds might be useful, preferred compounds are those already known to be useful as additives in polyolefin compositions.
  • the co-additive is preferably a flame retardant other than a tris (trihaloneopentyl) phosphate.
  • the co-additive is a brominated flame retardant.
  • a large number of halogenated compounds are known to be useful as flame retardants in polymers. Those which contain only halogen atoms bound to atoms (usually carbon atoms) which form part of an aromatic ring system are not useful in the compositions of this invention Those which comprise halogen atoms bound to an atom which does not form part of an aromatic ring are potentially useful
  • Examples of known commercially available flame retardants which may be useful in the compositions of this invention include tetrabromo bis phenol-A-bis (2,3 dibromopropyl ether) [which is available from the Great Lakes Chemical Corporation as PE-68, tetrabromo bis phenol-S bis (2,3 dibromopropyl ether (which is available as Non-Nen-52 from Manac Inc of Japan), adducts of hexachloropentadiene and cyclo octadiene (one of which is available as Dechlorane Plus from Oxychem Inc, ethylene bis (bis bromonorborane) dicarboximide (which is available from Albermarle Corporation as BN451 ), dibromoethyldibromocylclohexane which is available from the Ethyl Corporation as BCL 462, pentabromo chlorocyclohexane which is available from the Ethyl Corporation as FR651 P, FM
  • At least some of the flame retardant co-additives can be effective alone as flame retardant additives for polyolefms When used in large quantities, e g more than 10% by weight of the composition, these co-additives in combination with antimony trioxide (sometimes abbreviated herein as "autimony") at a 2 1 or 3 1 weight ratio of additive to antimony, can achieve a V-O rating in the UL 94 test When used in these quantities these co-additives bloom from the polymer
  • co-additives which are useful in the compositions of this invention are preferably those which are stable to processing at the temperature used to process the compositions
  • certain co-additives such as hexabromocyclo-dodecane (HBCD), although they fulfill the criteria of having at least one hydrogen bound to a carbon atom which is in the Beta position relative to at least one hydrogen atom, are less preferred for use in polypropylene compositions of this invention because they degrade at the temperatures at which polypropylene is processed Such degradation is obvious in terms of volatile emission during processing, and also discoloration of the plastic part This problem is especially acute in the production of complex parts involving high residence times in the mold, or where high pressures are involved
  • the tris (trihaloneopentyl) phosphate ester flame retardant useful in the compositions of this invention preferably comprises a compound selected from tris (t ⁇ chloroneopentyl) phosphate, tris (chlorodibromo) neopentyl phosphate, tris (dichlorobromo) neopentyl phosphate, tris- (tribromoneopentyl) phosphate and any mixtures of two or more thereof.
  • the most preferred flame retardant is tris (tribromoneopentyl) phosphate. This compound is sold under the trademark and designation "Reoflam PB 370" by the FMC Corporation.
  • this invention is a polyolefin resin composition having improved flame retardant properties based on the presence in the resin of at least one tris (trihaloneopentyl) phosphate and at least one halogen containing co-additive having at least one halogen atom bound to an aliphatic carbon atom as part of its molecular structure, which co-additive is stable at the temperature at which the polyolefin is processed.
  • these co-additives have at least one hydrogen bound to a carbon which is adjacent to that carrying a halogen substituent.
  • polystyrene resins useful in this invention (sometimes also referred to as
  • polyolefin resins may be derived from a variety of monomers especially from propylene, ethylene, butene, isobutylene, pentene, hexene, heptene, octene, 2-methyl propene, 2-methyl butene, 4-methylpentene, 4-methyl hexene, 5-methyl hexene, bicyclo (2,2,1 )-2-heptene, butadiene, pentadiene, hexadiene, isoprene, 2,3 dimethyl butadiene, 3,1 methyl pentadiene 1 ,3,4 vinyl cyclo hexene, vinyl cyclohexene, cyclopentadiene, styrene and methyl styrene.
  • the polyolefins include copolymers produced from any of the foregoing monomers and the like, and further include homopolymer blends, copolymer blends, and homopolymer-copolymer
  • the preferred polyolefins are polypropylene and polyethylene, including atactic, syndiotactic and isotactic polypropylene and polyethylene, low density polyethylene, high density polyethylene, linear low density polyethylene, block copolymers of ethylene and propylene, and random copolymers of ethylene and propylene.
  • These polyolefins may be produced using a variety of catalytic processes.
  • the polyolefins useful in this invention may be produced by any of these processes including metallocene catalysed processes.
  • the polymers may have a range of melt indexes (Ml) but will typically have Ml values in the range 4 to 30.
  • Ml melt indexes
  • compositions of this invention will normally comprise from 1 % to 20 % by weight of tris (trihaloneopentyl) phosphate, preferably from 3% to 10% by weight of the phosphate.
  • the ratio of the weight of tris (trihaloneopentyl) phosphate to the weight of co-additives may vary through a wide range, e.g., say from 10:1 to 1 :10 and preferably from 4:1 to 1 :4. In the preferred embodiments this ratio will be in the range 4 :1 to 1 :2 and most preferably 4:1 to 1 :1.
  • compositions of this invention preferably comprise at least one conventional synergist such as antimony trioxide, sodium antimonate, antimony pentoxide, zinc stannate, hydroxystannate and zinc borate, or any mixtures of two or more thereof.
  • the preferred conventional synergists are antimony trioxide and zinc borate.
  • the zinc borate synergist should have a suitably high degradation temperature for use in the compositions of this invention.
  • An example of a suitable commercially available zinc borate is the product sold as Firebrake 415.
  • the ratio of the weight of the conventional synergist (antimony trioxide) to the weight of co-additive in the composition is in the range 1 :5 to 1 :1 and more preferably in the range 1 :3 to 1 :1.
  • the synergistic interaction between the phosphate flame retardant and the co-additive is increased if the amount of synergist is within these preferred ranges. Larger amounts of the conventional synergist may be employed but in general this is less preferred.
  • the quantity of t ⁇ s-(tr ⁇ haloneopentyl) phosphate, co-additive flame retardant and synergist employed may be optimised using routine experimentation to achieve particular goals in a particular polymer
  • the nature of the polymer and the degree of flame retardancy desired exert a significant effect
  • the cost of polymer and its intended use also exert an influence on the amounts of t ⁇ s-(t ⁇ haloneopentyl) phosphate, co-additive flame retardant and synergist, which are employed
  • compositions of this invention may be compounded using techniques well known in the art It is important to achieve uniformity of the formulation if the optimum flame retardant performance is to be obtained
  • the use of a twin screw extruder is preferred to the use of a single screw extruder
  • the extrusion temperature should not be so high as to accentuate the difference between the viscosities of the polyolefin and the additives Extrusion temperatures below 230°C are generally preferable
  • a suitable masterbatch composition will comprise the polyolefin, from 5 to 20% (preferably from 10 to 20%) by weight of the tris (trihaloneopentyl) phosphate, and from 10 to 20% by weight of the co-additive Such masterbatch compositions are believed to be novel and constitute another aspect of this invention
  • Oxygen Index is defined as the minimum concentration of oxygen, expressed as volume percent, in a mixture of oxygen and nitrogen that will just support flaming combustion of a material initially at room temperature under specified conditions Although oxygen index cannot always be successfully correlated with large scale testing, it is one of the most useful and widely used small scale tests for screening formulations
  • the Oxygen Index was measured according to the methods described in ASTM D-2863
  • the equipment used for measuring oxygen index consists of a heat resistant glass tube with a brass base A specimen holder supports the specimen and holds it vertically in the center of the column A tube with a small orifice having an open gas flame suitable for inserting into the open end of the column is used as an ignition source
  • the dimensions of the specimens are 5" long, 1/4" wide and 1/8" thick
  • the specimen is clamped vertically and its top is ignited with an ignition flame
  • the flow valves are calibrated to introduce the desired oxygen concentration into the column
  • the specimen is allowed to burn for a specified time or length of sample, whichever occurs first. For solid plastic
  • Ol (percent) (100 x O 2 )/(O 2 + N 2 )
  • Example 1 Example 2 Example 3 Example 4 Example 5
  • Examples 1 and 2 are compositions of this invention.
  • Example 3, 4 and 5 are comparative examples in which no co-additive is used.
  • a typical level of phosphate of 5% along with 2.5% antimony (a ratio of 2:1 flame retardant to antimony, very common in brominated FRs) yields a V-2 rating in both 1/8" and 1/16" samples.
  • Increasing the level of phosphate to 10% (Example 5) does not change the rating.
  • the Oxygen Index also remains unchanged.
  • Increasing phosphate to 10% and using a very high antimony content (1:1 ratio) is not helping the UL rating and reduces the oxygen index. Therefore from examples 3,4 and 5 it is clear that acceptable usage levels of phosphate cannot produce V-0 rating in polypropylene at either 1/8" or 1/6" thickness samples.
  • Example 1 a blend of 3% Non-Nen 52 with 5% phosphate and 5% antimony (Example 1) gives V-O at both 1/16" and 1/8" thicknesses.
  • Example 2 a further increase in Non-Nen 52 and antimony at the level of 6% antimony and 4% Non-Nen 52, along with 5% phosphate does not improve the Ol further, but maintains the UL V-O rating at both 1/8" and 1/16".
  • BT-93 a co-additive (BT-93), which does not have halogen atoms attached to an aliphatic carbon atom as part of its molecular structure is not effective in improving the flame retardancy imparted by the tris (tribromoneopentyl) phosphate alone.
  • BT-93 is an abbreviation for ethylene bis(tetrabromophthalimide) sold by Albermarle Corporation as Saytex BT-93.
  • ABT Average Burning Time of the 5 samples tested during the UL - 94 test. A time of zero seconds indicates that the samples extinguish immediately.
  • the above Table demonstrates the sensitivity of the formulation to the specific load levels of FR components and synergists.
  • This example illustrates the use of Zinc Borate (ZnB) to substitute 40-60% of the antimony synergist.
  • the benefit of substituting Zinc Borate for antimony is the lighter final weight of a plastic part due to the specific gravity difference between Zinc Borate and antimony.
  • Molded plaques of the desired formulations (2"x2"x1/8") are oven aged at 100C (or any other test temperature) in a recirculating oven for a certain period of time (8 and 28 days).
  • plaques may or may not have visible blooming on the surface.
  • the plaques are placed into a 400 ml beaker containing approximately 50 ml of dichloromethane for 3 minutes under continuous stirring.
  • Dichloromethane does not dissolve or chemically attack polypropylene.
  • the short period of time is chosen so that only surface species are dissolved and none from the bulk of the polymer.
  • the blooming component is dissolved into the solvent and transferred to a pre-weighed cup.
  • the solvent is allowed to evaporate and the remaining residue is weighed. This residue is assumed to be totally bloomed flame retardant material.
  • Formulation 2 has visible bloom after 8 days and is not acceptable. Formulation 5 is considered non-blooming. Formulation 1 is marginal.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

Le retard à l'inflammation que confère aux résines de polyoléfine le tris(trihalonéopentyl)phosphate est accru par l'incorporation d'un co-additif comprenant un composé contenant de l'halogène, qui est stable à la température de traitement du polymère. Les co-additifs préférés sont d'autres ignifugeants destinés à des polyoléfines. L'utilisation d'une combinaison appropriée de phosphate, d'un co-additif ignifugeant, et de préférence d'un synergiste trioxyde d'antimoine ou borate de zinc, permettent d'obtenir des compositions de polyoléfine qui sont exemptes d'efflorescences, et qui atteignent une évaluation V-O dans le test UL94.
EP97911834A 1996-10-22 1997-10-21 Compositions de polyolefine resistantes au feu Withdrawn EP0934356A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US2898496P 1996-10-22 1996-10-22
US28984P 1996-10-22
US95193197A 1997-10-16 1997-10-16
US951931 1997-10-16
PCT/US1997/019001 WO1998017718A1 (fr) 1996-10-22 1997-10-21 Compositions de polyolefine resistantes au feu

Publications (1)

Publication Number Publication Date
EP0934356A1 true EP0934356A1 (fr) 1999-08-11

Family

ID=26704353

Family Applications (1)

Application Number Title Priority Date Filing Date
EP97911834A Withdrawn EP0934356A1 (fr) 1996-10-22 1997-10-21 Compositions de polyolefine resistantes au feu

Country Status (5)

Country Link
EP (1) EP0934356A1 (fr)
JP (1) JP2001502741A (fr)
CN (1) CN1234047A (fr)
AU (1) AU4911997A (fr)
WO (1) WO1998017718A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE312873T1 (de) * 1999-08-06 2005-12-15 Pabu Services Inc Intumeszenz-polymerzusammensetzung
US6737456B2 (en) 2001-02-27 2004-05-18 Bromine Compounds Ltd. Fire-retardant polyolefin compositions
JP2002322322A (ja) * 2001-02-27 2002-11-08 Bromine Compounds Ltd 難燃性ポリオレフィン組成物
CN106103992B (zh) * 2014-03-14 2018-05-11 三菱电机株式会社 压缩机以及制冷循环装置
JP6283294B2 (ja) * 2014-09-29 2018-02-21 出光ライオンコンポジット株式会社 ポリオレフィン系難燃性樹脂組成物
JP6522432B2 (ja) * 2015-06-04 2019-05-29 出光ライオンコンポジット株式会社 難燃性ポリオレフィン系樹脂組成物
CN108017839A (zh) * 2017-12-27 2018-05-11 南京鸿瑞塑料制品有限公司 一种耐折叠阻燃pp复合材料及其制备方法

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US3772232A (en) * 1971-06-30 1973-11-13 Monsanto Chemicals Flame-retardant polymers
JPH0832797B2 (ja) * 1989-12-18 1996-03-29 大八化学工業株式会社 難燃性重合体組成物
JP3124563B2 (ja) * 1991-01-31 2001-01-15 理研ビニル工業株式会社 難燃性ポリプロピレン樹脂組成物及びシート
JPH05148386A (ja) * 1991-11-28 1993-06-15 Dainippon Ink & Chem Inc 難燃性熱可塑性樹脂組成物
JPH07102137A (ja) * 1993-09-30 1995-04-18 Dai Ichi Kogyo Seiyaku Co Ltd 難燃性スチレン系樹脂組成物

Non-Patent Citations (1)

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Title
See references of WO9817718A1 *

Also Published As

Publication number Publication date
CN1234047A (zh) 1999-11-03
WO1998017718A1 (fr) 1998-04-30
AU4911997A (en) 1998-05-15
JP2001502741A (ja) 2001-02-27

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