Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M133/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
  • C10M133/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
  • C10M133/16—Amides; Imides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
  • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
  • C10M129/26—Carboxylic acids; Salts thereof
  • C10M129/28—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M129/38—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
  • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
  • C10M137/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having no phosphorus-to-carbon bond
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M137/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus
  • C10M137/12—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing phosphorus having a phosphorus-to-carbon bond
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
  • C10M141/08—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M141/00—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
  • C10M141/10—Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic phosphorus-containing compound
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
  • C10M2207/10—Carboxylix acids; Neutral salts thereof
  • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
  • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/08—Amides [having hydrocarbon substituents containing less than thirty carbon atoms]
  • C10M2215/082—Amides [having hydrocarbon substituents containing less than thirty carbon atoms] containing hydroxyl groups; Alkoxylated derivatives
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/086—Imides [having hydrocarbon substituents containing less than thirty carbon atoms]
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
  • C10M2215/24—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions having hydrocarbon substituents containing thirty or more carbon atoms, e.g. nitrogen derivatives of substituted succinic acid
  • C10M2215/28—Amides; Imides
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
  • C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
  • C10M2219/022—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of hydrocarbons, e.g. olefines
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
  • C10M2223/04—Phosphate esters
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
  • C10M2223/04—Phosphate esters
  • C10M2223/042—Metal salts thereof
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
  • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2010/00—Metal present as such or in compounds
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2010/00—Metal present as such or in compounds
  • C10N2010/12—Groups 6 or 16
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
  • C10N2040/00—Specified use or application for which the lubricating composition is intended
  • C10N2040/02—Bearings

Definitions

• the present invention relates to the use of friction modifiers to reduce micropitting of metal surfaces such as gear teeth, and to lubricant compositions comprising friction modifiers.
• Micropitting is a type of surface damage which occurs predominantly in rolling-sliding contacts of hard steel surfaces. Sometimes called “frosting”, “greystaining” or “peeling” it typically occurs in rolling element bearings and most often on gear teeth, where it poses a significant practical problem. Micropitting may lead to higher noise, to significant rapid wear and to more serious surface damage, such as scuffing and even to tooth fracture in gears.
• Conventional lubricants are used to reduce friction when metal surfaces move in contact with each other but they do not prevent the occurrence of micropitting.
• Original equipment manufacturers require lubricants which can lead to a reduction in the amount of micropitting when compared with the conventional lubricants. It is an object of the present invention to meet this need.
• a micropitting test has been established by the FZG Institute in Germany and is called the FZG micropitting test. This test is run on gears sets with the same metallurgy and surface profile/roughness as gears used in the field. The conditions of the test (high load/low speed) are the optimum conditions for micropitting to occur. Equipment manufacturers believe that the FZG micropitting test correlates well with field experience.
• the FZG micropitting test is carried out using a standardized FZG test rig according to CEC L-07-A-71, with C type case hardened gears of minimum 0.4 Ra surface roughness.
• the test has a stepwise phase to investigate build up of micropitting and an endurance phase to investigate resistance to micropitting.
• the stepwise phase runs from load stage 5 to load stage 10, each stage lasting 16 hours.
• the profile of the gears is measured prior to testing and during the test.
• the variation from the original gear profile (the profile deviation) is calculated.
• the percentage micropitting the percentage of gear tooth which is micropitted
• the weight loss from the gears is run for 80 hours at load stage 8 and then at load stage 10 until failure.
• the deviation from the original profile maximum 20 microns
• the level of micropitting and the weight loss are measured.
• a result which would be particularly acceptable to the industry would be a pass at load stage 10 in the stepwise phase of the test. This corresponds to a profile deviation of less than 7.5 ⁇ m, micropitting of less than 15% (approx) and weight loss of less than 15 mg (approx) after load stage 10. Extended performance in the endurance phase is also desirable.
• the present invention is based on the surprising appreciation that certain friction modifiers may be included in lubricant compositions with the result that an improvement in micropitting performance is observed when the lubricant compositions are used, i.e. there is reduced micropitting. Accordingly, the present invention concerns the use of at least one friction modifier to reduce micropitting of a metal surface, which comprises lubricating the metal surface with a lubricant composition comprising the at least one friction modifier, wherein the at least one friction modifier is selected such that micropitting is reduced when the metal surface is so lubricated.
• the metal surface may be the surface of a gear tooth, in which case the at least one friction modifier may be added to a formulated gear lubricant composition.
• friction modifier is used to describe additive compounds which are conventionally used in lubricant compositions to reduce friction.
• the friction modifiers which are useful in practising the present invention are all known in the art.
• any given friction modifier in reducing micropitting may be assessed by comparing the amount of micropitting observed when a metal surface is lubricated with a lubricant composition comprising the friction modifier with the amount of micropitting observed when an identical metal surface is lubricated (under the same conditions) using the corresponding lubricant composition from which the friction modifier of interest has been omitted.
• the FZG micropitting test may be used to assess the relative performance of lubricant compositions.
• the at least one friction modifier may be selected such that, when measured at 130°C using a high frequency reciprocating rig (HFRR) under the conditions described in SAE Technical Paper 961142, a lubricant which comprises the friction modifier and which has a viscosity grade of ISO 220 has a coefficient of friction of 0.100 or less.
• HFRR high frequency reciprocating rig
• Lubricant compositions which have a viscosity grade of ISO 220 and which are useful in screening friction modifiers may be prepared by blending a conventional sulphur-and phosphorus-containing gear additive package with a base oil having a viscosity of between 1.98 x 10 -4 to 2.42 x 10 -4 m 2 /s (198 to 242 cSt) at 40°C.
• Suitable additive packages include those comprising from 15-75 wt%, preferably from 45-65 wt%, of a sulfurized isobutylene, from 0-25 wt%, preferably from 3-15 wt%, of a phosphorus-containing antiwear agent, from 0-60 wt%, preferably from 5-25 wt% of a carboxylic-type or Mannich-type ashless dispersant, from 0-20 wt%, preferably from 1-10 wt% of corrosion and rust inhibitors, from 0-20 wt%, preferably from 1-10 wt%, of surface active agents and diluent oil.
• Such additive packages are commercially available.
• the additive package is used at conventional treat rates.
• a suitable base oil to use in formulating the compositions includes a blend of 51 wt% ESSO 600SN and 49 wt% of 2500 Brightstock. Useful additive package are described in EP-A-0744456 and EP-A-0812901.
• a number of different classes of friction modifiers have been found to be useful in the present invention. Mention may be made of phosphonate esters, phosphite esters, aliphatic succinimides, molybdenum compounds and acid amides.
• Useful phosphonate esters include O,O-di-(primary alkyl) acyclic hydrocarbyl phosphonates in which the primary alkyl groups are the same or different each independently containing 1 to 4 carbon atoms and in which the acyclic hydrocarbyl group bonded to the phosphorus atom contains 12 to 24 carbon atoms and is a linear hydrocarbyl group free of acetylenic unsaturation.
• These compounds thus comprise O,O-dimethyl hydrocarbyl phosphonates, O,O-diethyl hydrocarbyl phosphonates, O,O-dipropyl hydrocarbyl phosphonates, O,O-dibutyl hydrocarbyl phosphonates, O,O-diiso-butyl hydrocarbyl phosphonates, and analogous compounds in which the two alkyl groups differ, such as, for example, O-ethyl-O-methyl hydrocarbyl phosphonates, O-butyl-O-propyl hydrocarbyl phosphonates, and O-butyl-O-isobutyl hydrocarbyl phosphonates, wherein in each case the hydrocarbyl group is linear and is saturated or contains one or more olefinic double bonds, each double bond preferably being an internal double bond.
• a preferred friction modifier in this class is dimethyloctadecyl phosphonate. Phosphonate esters useful in the present invention are described in USP 4,158,633.
• Useful phosphite esters are described in WO88/04313. These include dihydrocarbyl hydrogen phosphites in which the hydrocarbyl groups are the same or different linear aliphatic hydrocarbyl groups free of acetylenic unsaturation each independently containing 8 to 24 carbon atoms, and amine salts of these phosphites.
• the phosphites typically contain linear aliphatic hydrocarbyl groups, each of which contains 12 to 24, preferably 16 to 20 carbon atoms. It is also preferred that at least 50% of the hydrocarbyl groups in the dihydrocarbyl hydrogen phosphite contain at least one internal double bond. It is preferred to use dioleylphosphite.
• Preferred amine salts of the foregoing dihydrocarbyl hydrogen phosphites are those in which the aliphatic group of the amine is a linear primary aliphatic group having 8 to 24 carbon atoms, for example 16 to 20 carbon atoms, and in which at least 50% of the aliphatic groups contain one or more internal double bonds.
• Useful succinimides include those of formula: in which Z is a group R 1 R 2 CH- in which R 1 and R 2 are the same or different each independently representing straight- or branched-chain hydrocarbon groups containing from 1 to 34 carbon atoms and the total number of carbon atoms in the groups R 1 and R 2 is from 11 to 35. Such compounds are described in EP-A-0020037, EP-A-0389237 and EP-A-0776964.
• the radical Z may be, for example, 1-methylpentadecyl, 1-propyltridecenyl, 1-pentyltridecenyl, 1-tridecylpentadecenyl or 1-tetradecyleicosenyl.
• the number of carbon atoms in the groups R 1 and R 2 is from 16 to 28 and more commonly 18 to 24. It is especially preferred that the total number of carbon atoms in R 1 and R 2 is about 20 or about 22.
• the succinimide is a 3 - C 18-24 alkenyl-2,5-pyrrolidindione. A sample of this succinimide contains a mixture of alkenyl groups having from 18 to 24 carbon atoms.
• molybdenum compounds are described in USP 5,650,381. These compounds are typically substantially free of active sulphur. Examples of suitable compounds include glycol molybdate complexes as described in U.S.P. 3,285,942, overbased alkali metal and alkaline earth metal sulfonates, phenates and salicylate compositions containing molybdenum such as those disclosed in U.S.P. 4,832,857, molybdenum complexes prepared by reacting a fatty oil, a diethanolamine and a molybdenum source as described in U.S.P.
• Molybdenum salts such as the carboxylates are a preferred group of molybdenum compounds.
• the molybdenum salts used in this invention may be completely dehydrated (complete removal of water during preparation), or partially dehydrated. They may be salts of the same anion or mixed salts, meaning that they are formed from more than one type of acid.
• suitable anions there can be mentioned chloride, carboxylate, nitrate, sulfonate, or any other anion.
• the molybdenum carboxylate is preferably that of a monocarboxylic acid such as those having from about 4 to 30 carbon atoms.
• Such acids can be hydrocarbon aliphatic, alicyclic or aromatic carboxylic acids.
• Monocarboxylic aliphatic acids having about 4 to 18 carbon atoms are preferred, particularly those having an alkyl group of about 6 to 18 carbon atoms.
• the alicyclic acids may generally contain from 4 to 12 carbon atoms.
• the aromatic acids generally contain one or two fused rings and contain from 7 to 14 carbon atoms wherein the carboxyl group may or may not be attached directly to the ring.
• the carboxylic acid can be a saturated or unsaturated fatty acid having from about 4 to 18 carbon atoms.
• Examples of carboxylic acids that may be used to prepare the molybdenum carboxylates include butyric acid, valeric acid, caproic acid, heptanoic acid, cyclohexanecarboxylic acid, cyclodecanoic acid, naphthenic acid, phenyl acetic acid, 2-methylhexanoic acid, 2-ethylhexanoic acid, suberic acid, octanoic acid, nonanoic acid, decanoic acid, undecanoic acid, lauric acid, tridecanoic acid, myristic acid, pentadecanoic acid, palmitic acid, linolenic acid, heptadecanoic acid, stearic acid, oleic acid, nonadecanoic acid, eicosanoic acid, heneicosanoic acid, docosanoic acid and erucic acid.
• the preferred molybdenum carboxylate is molyb
• Useful carboxylic acid amides include aliphatic monocarboxylic acid amides. These may be represented by the formula (R 3 CO)N(R 4 )(R 5 ) in which R 3 represents an alkyl or alkenyl group having 8 to 24 carbon atoms and R 4 and R 5 which may be the same or different are each independently hydrogen or alkyl of up to 7 carbon atoms. Typically, R 3 represents a C 14-18 alkyl radical. Amides of this type are described in USP 4,280,916. A preferred friction modifier falling within this class is oleyamide.
• Friction modifiers which are useful in the present invention are commercially available or may be prepared by the adaptation or application of known methods.
• the amount of the at least one friction modifier which is used is at least sufficient for it to exert its intended function of reducing micropitting.
• the friction modifier(s) is/are generally used at conventional treat rates.
• the total concentration of friction modifier used is 0.125 to 1% by weight based on the total weight of the lubricant composition.
• the total amount of friction modifier is 0.15 to 0.75% by weight, more preferably about 0.5% by weight.
• friction modifiers may be used.
• friction modifiers of the same or different type may be used in combination.
• satisfactory results have been obtained using combinations of dimethyloctadecyl phosphonate and a 3-C 18-24 alkenyl-2,5-pyrrolidindione.
• the total amount of friction modifier is as described above.
• the at least one friction modifier employed is sufficiently soluble in the lubricant composition at the treat rate at which it is used. It is also important that the at least one friction modifier is sufficiently compatible with the additional components commonly found in lubricating compositions. Such components include dispersants, detergents, antioxidants, extreme pressure agents, antiwear agents, foam inhibitors, viscosity index improvers and pour point depressants. These additives are themselves used in conventional amounts.
• the base oil which is used to formulate lubricant compositions useful in the present invention may be natural or synthetic, or a blend thereof. Useful base oils are known in the art.
• the lubricant compositions are formulated in known manner by blending the individual components.
• the at least one friction modifier responsible for improving the micropitting performance may be added at the time the lubricant is formulated. Alternatively, the at least one friction modifier may be added as a top treat to improve or boost the micropitting performance of an existing formulated lubricant composition.
• the invention also provides lubricant compositions which exhibit excellent micropitting performance relative to conventional lubricants.
• the invention provides a lubricant composition comprising an O,O-di-(primary alkyl)acyclic hydrocarbyl phosphonate as described above and a succinimide as described above.
• the composition comprises dimethyloctadecyl phosphonate and a 3-C 18-24 alkenyl-2-pyrrolidindione.
• the composition comprises a molybdenum carboxylate, such as molybdenum octanoate, and a sulfurized isobutylene extreme pressure agent.
• the compositions may also include one or more of the other additive components described above.
• Lubricant compositions were prepared by blending the components listed in Table 1 below.
• the sulphur- and phosphorus-containing gear additive package had the following composition:
• the coefficient of friction for each composition was measured at 130°C using an HFRR operated under the conditions described in SAE Technical Paper 961142 (ball diameter 6mm, load 4N, frequency 20 Hz, stroke length 1mm; ball and flat ANSI 52100 steel).
• the HFRR coefficient of friction for each composition is given in Table 2.
• Each composition was also subjected to the FZG micropitting test in accordance with CEC L-07-A-71. The results obtained in this test are also shown in Table 2.
• the FZG result is given as a load stage result (in the stepwise phase).
• a profile deviation of 7.5 ⁇ m is used to differentiate a pass or fail result at any given load stage.
• Runs 1 and 2 give “10 fail” and “9 fail” results respectively which means that the profile deviation exceeded 7.5 ⁇ m after load stage 10 (Run 1) and load stage 9 (Run 2).
• Runs 4-7 on the other hand give an FZG result of "10 pass” which means that the profile deviation has not exceeded 7.5 ⁇ m after load stage 10.
• the lubricant composition used in Runs 1 and 2 is a conventional gear lubricant. This gives reasonable micropitting protection, the 7.5 ⁇ m threshold being exceeded after load stage 10 (Run 1) or 9 (Run 2). For Run 3 the micropitting test was aborted after load stage 6 because the composition tested was found to contain precipitate. This emphasises the need for the friction modifiers used to be fully soluble/compatible in lubricant at the treat rate at which they are used.
• the compositions used in Runs 4-7 illustrate the present invention and give improved FZG results of "10 pass” when compared with the conventional lubricant compositions of Runs 1 and 2. A consistent "10 pass” result would be very acceptable in the industry. Runs 4-7 also showed acceptably low levels of percentage micropitting and weight loss.
• a friction modifier which is known to exhibit poor micropitting protection was included in a lubricant composition having a viscosity grade ISO 220 and the resulting composition tested using the HFRR test (in accordance with SAE Technical Paper 961142).
• the composition gave an HFRR result of 0.114, i.e. well above the threshold value of 0.100.
• the HFRR screening procedure was repeated using compositions using a different sulphur- and phosphorus-containing gear additive package.
• the base oil was ESSO ISO 220.
• the viscosity grade of the formulated compositions was ISO 220.
• the treat rate of the various components and the HFRR results obtained are shown in Table 3 below.
• COMPONENT RUN 9 10 Dimethyloctadecyl phosphonate - 0.25% 3-C 18-24 alkenyl 2,5-pyrollidindione - 0.25% S/P Containing gear pack 2.0% 2.0% HFRR 0.105 0.070
• the HFRR result for Run 9 of in excess of 0.100 is consistent with the HFRR results for Runs 1 and 2 in Table 1.
• the composition used in Run 10 included a combination of friction modifiers which are known to give improved micropitting performance (see the result for Run 6 in Table 2).
• the HFRR result for Run 10 is less than 0.100. This is consistent with the HFRR result obtained for Run 6 in Table 2 where a different gear additive package was used in formulating the composition under test. This shows that the HFRR screening procedure remains predictive of useful friction modifiers even when different gear additive packages are used in formulating the lubricant compositions.

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• 1998
  • 1998-04-09 GB GBGB9807843.9A patent/GB9807843D0/en not_active Ceased
• 1999
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