EP0980492A1 - Behälter für gasförmigen brennstoff unter hohem druck und verfahren zur herstellung - Google Patents

Behälter für gasförmigen brennstoff unter hohem druck und verfahren zur herstellung

Info

Publication number
EP0980492A1
EP0980492A1 EP98924418A EP98924418A EP0980492A1 EP 0980492 A1 EP0980492 A1 EP 0980492A1 EP 98924418 A EP98924418 A EP 98924418A EP 98924418 A EP98924418 A EP 98924418A EP 0980492 A1 EP0980492 A1 EP 0980492A1
Authority
EP
European Patent Office
Prior art keywords
core
internal container
shell
tank
honeycomb
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP98924418A
Other languages
English (en)
French (fr)
Inventor
Angelo Toma
Bernard Auche
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lynx Automobiles International SA
Original Assignee
Lynx Automobiles International SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR9705729A external-priority patent/FR2765633B1/fr
Priority claimed from FR9714517A external-priority patent/FR2771033A1/fr
Application filed by Lynx Automobiles International SA filed Critical Lynx Automobiles International SA
Publication of EP0980492A1 publication Critical patent/EP0980492A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C1/00Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
    • F17C1/02Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge involving reinforcing arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C1/00Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
    • F17C1/14Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge constructed of aluminium; constructed of non-magnetic steel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C1/00Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge
    • F17C1/16Pressure vessels, e.g. gas cylinder, gas tank, replaceable cartridge constructed of plastics materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00Use of gas-solvents or gas-sorbents in vessels
    • F17C11/007Use of gas-solvents or gas-sorbents in vessels for hydrocarbon gases, such as methane or natural gas, propane, butane or mixtures thereof [LPG]
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0147Shape complex
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2201/00Vessel construction, in particular geometry, arrangement or size
    • F17C2201/01Shape
    • F17C2201/0147Shape complex
    • F17C2201/0157Polygonal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0602Wall structures; Special features thereof
    • F17C2203/0604Liners
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0646Aluminium
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0636Metals
    • F17C2203/0648Alloys or compositions of metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0658Synthetics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0658Synthetics
    • F17C2203/066Plastics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2203/00Vessel construction, in particular walls or details thereof
    • F17C2203/06Materials for walls or layers thereof; Properties or structures of walls or their materials
    • F17C2203/0634Materials for walls or layers thereof
    • F17C2203/0658Synthetics
    • F17C2203/0663Synthetics in form of fibers or filaments
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2205/00Vessel construction, in particular mounting arrangements, attachments or identifications means
    • F17C2205/03Fluid connections, filters, valves, closure means or other attachments
    • F17C2205/0302Fittings, valves, filters, or components in connection with the gas storage device
    • F17C2205/0323Valves
    • F17C2205/0332Safety valves or pressure relief valves
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/21Shaping processes
    • F17C2209/2109Moulding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/22Assembling processes
    • F17C2209/221Welding
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2209/00Vessel construction, in particular methods of manufacturing
    • F17C2209/22Assembling processes
    • F17C2209/227Assembling processes by adhesive means
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/033Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2221/00Handled fluid, in particular type of fluid
    • F17C2221/03Mixtures
    • F17C2221/032Hydrocarbons
    • F17C2221/035Propane butane, e.g. LPG, GPL
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/01Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the phase
    • F17C2223/0146Two-phase
    • F17C2223/0153Liquefied gas, e.g. LPG, GPL
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/035High pressure (>10 bar)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2223/00Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel
    • F17C2223/03Handled fluid before transfer, i.e. state of fluid when stored in the vessel or before transfer from the vessel characterised by the pressure level
    • F17C2223/036Very high pressure (>80 bar)
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2250/00Accessories; Control means; Indicating, measuring or monitoring of parameters
    • F17C2250/04Indicating or measuring of parameters as input values
    • F17C2250/0404Parameters indicated or measured
    • F17C2250/0408Level of content in the vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2265/00Effects achieved by gas storage or gas handling
    • F17C2265/06Fluid distribution
    • F17C2265/066Fluid distribution for feeding engines for propulsion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17CVESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C2270/00Applications
    • F17C2270/01Applications for fluid transport or storage
    • F17C2270/0165Applications for fluid transport or storage on the road
    • F17C2270/0168Applications for fluid transport or storage on the road by vehicles
    • F17C2270/0178Cars

Definitions

  • the present invention relates to a fuel tank intended to contain a fuel at high pressure, such as liquefied petroleum gas and natural gas for vehicles, as well as to a method for manufacturing such a tank.
  • Profiled aircraft fuel tanks are already known from document US-A-5,042,751. These tanks have a sandwich structure comprising parts of a honeycomb core layer, between two inner and outer layers. .
  • the structure always includes a layer intended to absorb the forces and which may consist in part of one of the layers of the sandwich structure.
  • the honeycomb core is placed inside this casing layer in the parts which work in compression and on the outside in the parts which work in tension.
  • the construction of a reservoir of determined shape therefore includes an analysis phase for determining the regions which work in compression and those which work in tension. After this analysis, the reservoir can be produced by forming a partial honeycomb structure inside in the parts which work in compression and on the outside in the parts which work in tension.
  • the core layer is discontinuous and comprises at least an internal part and an external part.
  • the invention relates to a tank for high pressure fuel, such as liquefied petroleum gas or natural gas for vehicles, the configuration of which can be adapted to the space available in a vehicle, and which does not require any force analysis. which must apply to the tank since the whole of a honeycomb layer is formed outside of the internal layer which is in contact with the fuel.
  • high pressure fuel such as liquefied petroleum gas or natural gas for vehicles
  • the invention thus relates to a tank for fuel at high pressure, such as liquefied petroleum gas or natural gas for vehicles, the pressure of which is much higher than atmospheric pressure;
  • the reservoir comprises an airtight internal container which is not sufficiently resistant to the high pressure of the fuel so as not to deform, and a support shell placed entirely outside the internal container, surrounding the largest part of the external surface of the internal container and placed in contact with this surface, the shell comprising a honeycomb core, the two large faces of which are fixed to two adjacent sheet-shaped members.
  • the material of the honeycomb core is chosen from aluminum and light alloys, aramid resins, polyethylene terephthalate, polyetheretherketones, composite materials made of plastics and fibers, and cardboard.
  • the reinforcing fibers can be of any type commonly used for reinforcing structures of plastic materials, and of any texture, and they are in particular carbon or even glass fibers.
  • the configuration of the cells of the honeycomb core is advantageously chosen from the hexagonal, rectangular and triangular configurations.
  • the honeycomb core has different thicknesses at at least two different locations in the shell. According to another advantageous characteristic, the honeycomb core is formed from different materials at at least two different locations of the support shell.
  • one of the sheet-shaped members to which a face of the core is fixed constitutes a wall of the internal container.
  • the internal container carries at least one accessory which is hermetically attached to it, and the shell has a discontinuity at the location of the accessory.
  • the accessory is chosen, for example, from a fuel gauge, a filling orifice plug, an adsorbent filling orifice, a safety valve, a fuel outlet pipe, a fuel return pipe, a fuel introduction conduit and any combination of such elements.
  • the internal container has a reinforced part
  • the shell has a discontinuity at the location of the reinforced part
  • the reservoir also comprises an external protective coating applied to the sheet-shaped member of the support shell which is opposite to the side of the internal container.
  • the support shell is produced in the form of two half-shells.
  • the tank In the case of natural gas for vehicles, it is advantageous for the tank to contain an adsorbent intended to retain natural gas, such as activated carbon or a zeolite.
  • the invention also relates to a method of manufacturing a reservoir according to the preceding paragraphs, which comprises the manufacture of an internal container in the desired configuration, the production of a support shell in the configuration of the internal container, by laying and shaping of a honeycomb core between two surfaces with interposition of a bonding material between the core and the two surfaces, and by hardening of the bonding material.
  • the shaping is carried out using an internal mold and an external mold, the core being placed between two sheet-shaped members.
  • the shaping is carried out between an external mold and the internal container, the core being placed between two sheet-shaped members.
  • the shaping is carried out using an external mold and the internal container, and the core is placed between a sheet-shaped member and the internal container.
  • the curing of the bonding material is carried out by heating.
  • the manufacture of the support shell comprises the separate manufacture of two half-shells, then their association with an internal container.
  • FIG. 1 is a perspective view of an example of a high pressure fuel tank according to the invention
  • Figure 2 is a perspective view of the tank of Figure 1, in inverted form
  • Figure 3 is a partial section of part of the tank, indicated by the section line 3—3 in Figure 2
  • FIG. 4 schematically represents the structure of a tank wall according to the invention
  • Figure 5 shows a detail of the tank of Figure 1, along the section line 5—5
  • Figure 6 shows a detail of the tank of Figure 1, along the section line 6—6 of Figure 6
  • FIG. 7 is a partial section illustrating the manufacture of part of the reservoir of FIGS. 1 and 2.
  • liquid fuel tank consisting of liquefied petroleum gas
  • a motor vehicle comprising an internal combustion engine, for example an injection engine.
  • the reservoir is described with reference to Figures 1 to 7.
  • the tank according to the invention has an "arbitrary" shape, that is to say which can be adapted to a space specially provided for this purpose in an automobile.
  • a high pressure fuel tank can be made with the same external configuration as a gas tank made for an automobile of the same model.
  • This characteristic is very important because, up to now, given the high pressure which such a tank can reach (operating pressure reaching 100 bar and even 200 bar under certain conditions), spherical or cylindrical tanks have been used; in fact, these configurations are best suited to the collection of pressures.
  • these tanks were made of composite materials with a plastic binder reinforced with fibers, wound or not, or of glass cloth or other materials, in spherical or cylindrical form.
  • the reservoir can have any shape, and the one shown in FIGS. 1 and 2 has essentially a parallelepiped shape having a cut corner and a recess in an arc delimiting a tunnel for the passage of a pipe. exhaust which can reach a high temperature.
  • Figure 4 which is a very schematic view of part of the wall of the tank of Figures 1 and 2, shows an internal container 10 whose role is to be hermetic to the fuel contained, but which is not intended to absorb high pressure.
  • the internal container can be formed from sheet metal a few tenths of a millimeter thick or from an aluminum alloy sheet 1.5 to 3 mm thick.
  • this honeycomb structure comprises a core 14 placed between two members 16, 18 which are integral with the core 14.
  • the core 14 can be formed of a metallic material, advantageously of aluminum or of light alloy, but also of any resistant resin, for example of aramid resin, of polyethylene terephthalate. , polyetheretherketone, etc. ; however, the core material can also be a composite material, a plastic reinforced with fibers, or even cardboard, preferably impregnated with a resin, for example phenolic.
  • the nature of the core material is therefore not important insofar as this material has the necessary mechanical resistance when it is incorporated into the support shell and where it gives the flexibility necessary to obtain the desired shape during of shell construction.
  • the sheets forming the external members 16, 18 which are secured to the core 14 can be formed from any material known for honeycomb structures, for example. example of metallic sheets, in particular aluminum or light alloy, plastic sheets, etc.
  • a condition which the material of the core 14 and the material of the sheets 16, 18 must fulfill is that they can be fixed together by a bonding material so that the structure obtained has the advantageous mechanical properties well known of nest structures. bees.
  • these adhesives depend on the nature of the material of the core and that of the material of the sheets 16, 18, and on the conditions of attachment of the sheets to the core. Mention may be made of phenolic, epoxy and bis-maleimide adhesives by way of non-limiting examples.
  • the bonding material there are a very large number of them and it is convenient for the bonding material to be in the form of a film applied to the surface of the core or of a sheet when placed in cooperation. Hardening of the bonding material, for example by heating or by any other process causing hardening, polymerization or drying, secures the core material and sheet-like members.
  • the core material can be fixed directly to the internal container 10, without interposition of the sheet-shaped member 18.
  • the support shell surrounding the internal container does not necessarily cover the entire internal container in a sealed manner. Indeed, as indicated in Figures 3 and 5, the shell may have discontinuities at already reinforced locations of the internal container.
  • the internal container 10 is closed by welding two lips 20 which are practically perpendicular to the surface of the container 10. Consequently, at the level of these welded lips, the container is already reinforced and has a high mechanical resistance.
  • the shell 12 can therefore be interrupted at this welded connection.
  • This provision is also indicated on the FIGS. 1 and 2 in which the shell is actually formed of two half-shells placed on either side of a continuous welded joint formed by the lips 20.
  • FIG. 5 represents another example of discontinuity of the shell 12 of the reservoir.
  • the internal container 10 comprises a sleeve 22, having a flange applied against the internal face of the container 10 and held by an external flange 24 tightened on the sleeve.
  • This flange sleeve 22 can for example form an opening for the introduction of an adsorbent. It can also form a nozzle for the connection of an accessory, such as a fuel filling tube, an adsorbent introduction tube, a valve or a gauge.
  • the structure of the internal container 10 is sufficiently reinforced for the presence of the shell to be superfluous. Consequently, the shell is largely hollowed out and allows free access to this location of the internal container.
  • the reservoir contains an adsorbent because, for the same quantity of natural gas present, the pressure is much lower.
  • the pressure in the tank is approximately 15 bar in the presence of activated carbon, while in the absence of the latter, the pressure would be approximately 200 bar.
  • activated carbon preferably having a specific surface of at least 1000 m 2 / g, and advantageously from 2000 to 3000 m 2 / g.
  • zeolites for example of type A, known for the storage of methane which can penetrate into the cages formed by the material.
  • FIGS. 1 and 2 It has been indicated in FIGS. 1 and 2 that the reservoir has a tunnel-shaped recess intended for the passage of a pipe or of an exhaust pipe.
  • a pipe or an exhaust pipe has a relatively high temperature when the vehicle is running, and the tank should therefore be protected as much as possible. against heat.
  • Figure 6 shows an embodiment used at this part of the tank.
  • the internal container 10 is covered with the shell which comprises, as indicated in FIG. 4, a honeycomb core 10, of determined thickness, and organs in the form of sheets 16 and 18, for example of aluminum alloy.
  • the core 14 is for example an aluminum honeycomb.
  • the thermal insulation properties are obtained on the one hand thanks to the insulating properties of the honeycomb material, and on the other hand, optionally, by incorporating a layer of a reflective material, for example a "skin" exterior that reflects at least 80% of infrared radiation.
  • a layer of a reflective material for example a "skin" exterior that reflects at least 80% of infrared radiation.
  • the sheet-shaped members 16 and 18 extend following the configuration of the internal container, but are separated by another core 14 '.
  • the core 14 has a thickness different from that of the core 14.
  • the core 14 may have a thickness close to 13 mm and the core 14 'a neighboring thickness 25 mm.
  • the core when it is to be placed in an area which can be relatively heated, is formed from a heat-resistant material, for example a heat-resistant plastic, such as a polyetheretherketone, or the material known under the trademark "Nomex".
  • a heat-resistant material for example a heat-resistant plastic, such as a polyetheretherketone, or the material known under the trademark "Nomex”.
  • Figure 7 shows how the shell can be shaped on a sharp edge.
  • the internal container 10 has a clean corner and the shell wraps around the internal container, after cutting a part of the internal sheet-shaped member 18, the honeycomb core is folding in on itself around the corner.
  • FIG. 1 shows a certain number of accessories associated with the tank when it is intended for liquefied petroleum gas.
  • a filling tube 22 a flange 24 carrying a fuel pump, with a check valve and an outlet tube and optionally a return tube, a flange 26 having a fuel return tube, a flange 28 carrying a safety valve, for example calibrated at 25 bar, etc.
  • the accessories which are generally essential are a fuel gauge, a filling tube, provided with a filling gauge (limiting the total volume of filling of the tank by the liquid, for example to 80%), a safety valve, a fuel outlet, possibly a fuel return, which can be separated or grouped in any desired manner.
  • a fuel filling tube 22 In the case of a natural gas tank for a vehicle, it is possible to use a fuel filling tube 22, a cover 24 of an orifice for introducing an adsorbent, a flange 26, another flange 28 bearing a safety valve, for example calibrated at 200 bar, etc.
  • the accessories which are generally essential in the case of an automobile consuming natural gas are a fuel gauge, a fuel filling tube, a safety valve, a fuel outlet, and possibly an inlet for d adsorbent, which can be separated or grouped in any desired manner. In the example shown in Figure 1, all the accessories are grouped on the upper face. However, this feature is not necessary because, as indicated above, these accessories can be placed in any convenient place.
  • manufacture of the internal container has been described by welding lips applied against one another, the manufacture of the internal container is in no way limited by this example. In fact, any manufacturing process is suitable as long as the internal container retains the fuel under pressure in a hermetic manner.
  • the invention also relates to the method of manufacturing such a tank.
  • the tank includes the internal container and the support shell which is fully placed outside the internal container.
  • the shell is delimited, inside, by the internal container in contact with which it is placed. Outside, it is delimited by a surface corresponding to the external configuration of the internal container, taking into account the thickness of the shell which can be variable, as indicated previously.
  • a mold is produced with the configuration of the external surface of each half-shell.
  • a sheet intended to form the external member 16 of the shell is applied to this external mold.
  • the honeycomb core 14 is applied to this sheet.
  • the core 14 is very flexible. It does not have to be in one piece. Indeed, several pieces of core can be juxtaposed, preferably with nesting of the edges.
  • it is not necessary that the core is formed of the same material, nor that it has the same thickness.
  • the inner container or a mold having the same shape as the inner container is applied so that pressure can be exerted on the two outer faces of the shell.
  • the shell then undergoes a hardening of the adhesive sheets, preferably by passage through an oven, advantageously with conservation of the pressure applied by the external mold and the internal container or the mold having the shape thereof.
  • the shell After cooling, the shell, if it is not already secured to the internal container, can be fixed thereon in any convenient manner. It is for example possible to produce the two half-shells on both sides of the internal container, or on the contrary to produce the half-shells separately and then to fix them to the internal container. The fixing can be carried out by any chemical, mechanical, etc. means. known.
  • a protective material Numerous protective materials are known, ranging from a simple spraying of tar-based material, commonly applied at the bottom of car bodies, to materials with high technological properties, for example an aramid resin having a high impact resistance.
  • the reservoir according to the invention therefore comprises a support shell for an internal container which surrounds the major part of this internal container, but not necessarily all of it. It does not have to be waterproof, so it can have discontinuities, as described above. Fuel tightness is achieved using the internal container.
  • a tank was made having an internal container whose capacity was 90 1. This tank had a rectangular shape and its greatest thickness was 22 cm. The tank had inside a partition pierced with openings, towards its middle part. It was made of 1.5 mm thick aluminum foil.
  • a similar tank for natural gas for vehicles was formed from aluminum foil 3 mm thick.
  • the shell was formed from a honeycomb core with hexagonal cells having a thickness of 12.7 mm over almost its entire surface, the thickness being 25 mm at each of the two ends intended to be turned towards the front and rear of a motor vehicle.
  • the two sheet-like members of the honeycomb structure were 0.3mm thick aluminum alloy sheets.
  • the core was glued to the aluminum sheets by "Redux" 609 glue films from Ciba Geigy.
  • the thickness of the sheets was 0.5 mm.
  • Another honeycomb core material which is suitable for the production of reservoirs according to the invention is the "Flex-Core" material from Hexcel Composites which is particularly advantageous since it adapts bi-monthly to the shape of the tank, thanks to the particular shape of the partitions of its honeycomb structure.
  • the internal sheet-shaped members, the honeycomb core and the external sheet-shaped members were applied successively to the internal container, each time interposing a sheet of glue.
  • the assembly was then placed in a neoprene-based rubber bladder, intended for use at temperatures up to 300 ° C. (available for example from Hutchinson), and which was evacuated so that the elements of the shell are tightly applied against the inner container.
  • the whole was then kept at a temperature of 120 ° C. for one hour so that the adhesive hardened.
  • a protective coating of high impact aramid resin was then formed outside the tank.
  • the tank made with a sheet thickness of 1.5 mm was subjected to pressure tests. It withstood a pressure of 120 bar, well above the legal test pressure of 90 bar. By the standards of most countries, the pressure in liquefied petroleum gas tanks is limited to 25 bar by a safety valve.
  • the tank made with a sheet thickness of 3 mm was subjected to pressure tests. It withstood a pressure of 200 bar.
  • the pressure in natural gas tanks for vehicles is limited to 200 bar by a safety valve.
  • a tank according to the invention can be used easily in motor vehicles with a good margin of safety.
  • a tank the internal container of which is partitioned into watertight compartments.
  • One compartment is used to hold liquefied petroleum gas or other high pressure liquid fuel, and the other compartment is intended to contain gasoline or diesel fuel.
  • Each compartment is fitted with the corresponding accessories.
  • Such a tank allows the production of motor vehicles having circuits power supply that can function indifferently with two fuels.
  • the invention therefore allows the realization of a tank adapted to one location and one equipment used. For example, it allows the arrangement of different accessories in the most convenient locations.
  • the invention also applies to cylindrical or spherical tanks intended to contain natural gas for vehicles at a high pressure, for example of 200 bar, since the honeycomb structure also has the aforementioned advantageous properties of mechanical resistance and thermal protection.
  • the invention has only been described and shown as a preferential example and that any technical equivalence may be made in its constituent elements without going beyond its ambit.
  • the support shell is formed of two half-shells, it may comprise a single element or any number of elements, essentially depending on the shape desired for the tank, always placed outside the inner container.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Filling Or Discharging Of Gas Storage Vessels (AREA)
EP98924418A 1997-05-09 1998-05-11 Behälter für gasförmigen brennstoff unter hohem druck und verfahren zur herstellung Withdrawn EP0980492A1 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
FR9705729 1997-05-09
FR9705729A FR2765633B1 (fr) 1997-05-09 1997-05-09 Circuit d'alimentation et reservoir pour carburant de gaz liquefie, et procede de fabrication de reservoir
FR9714517A FR2771033A1 (fr) 1997-11-19 1997-11-19 Reservoir pour gaz naturel pour vehicule, et procede de fabrication de reservoir
FR9714517 1997-11-19
PCT/FR1998/000940 WO1998051962A1 (fr) 1997-05-09 1998-05-11 Reservoir pour carburant gazeux a pression elevee, et procede de fabrication de reservoir

Publications (1)

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EP0980492A1 true EP0980492A1 (de) 2000-02-23

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EP98924418A Withdrawn EP0980492A1 (de) 1997-05-09 1998-05-11 Behälter für gasförmigen brennstoff unter hohem druck und verfahren zur herstellung

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EP (1) EP0980492A1 (de)
AU (1) AU7662598A (de)
WO (1) WO1998051962A1 (de)

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Publication number Priority date Publication date Assignee Title
EP1737557A4 (de) * 2004-04-21 2009-01-07 Angstore Technologies Ltd Speichersysteme für adsorbierbaren brennstoff und herstellungsverfahren dafür

Family Cites Families (5)

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Publication number Priority date Publication date Assignee Title
US2609068A (en) * 1949-03-11 1952-09-02 Glenn L Martin Co Metal foil honeycomb core
FR2129032A5 (de) * 1971-03-12 1972-10-27 Creusot Loire
AT370226B (de) * 1980-12-24 1983-03-10 Waagner Biro Ag Verbundkonstruktion fuer behaelterwaende
US5042751A (en) * 1987-04-06 1991-08-27 Tre Corporation Pressure vessel with a non-circular axial cross-section
EP0527564B1 (de) * 1991-07-29 1996-05-29 ROLLS-ROYCE plc Druckgasbehälter

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9851962A1 *

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WO1998051962A1 (fr) 1998-11-19
AU7662598A (en) 1998-12-08

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