EP1082880A1 - Beheizter spiegel,insbesondere bestimmt für fahrzeuge,und verfahren zur herstellung derselben - Google Patents
Beheizter spiegel,insbesondere bestimmt für fahrzeuge,und verfahren zur herstellung derselbenInfo
- Publication number
- EP1082880A1 EP1082880A1 EP99926422A EP99926422A EP1082880A1 EP 1082880 A1 EP1082880 A1 EP 1082880A1 EP 99926422 A EP99926422 A EP 99926422A EP 99926422 A EP99926422 A EP 99926422A EP 1082880 A1 EP1082880 A1 EP 1082880A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- film
- conductive
- mirror according
- metal
- mirror
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 239000011521 glass Substances 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 30
- 238000000151 deposition Methods 0.000 claims description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 15
- 230000008021 deposition Effects 0.000 claims description 15
- 239000010936 titanium Substances 0.000 claims description 15
- 229910052719 titanium Inorganic materials 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 11
- 239000011241 protective layer Substances 0.000 claims description 9
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 8
- 238000007650 screen-printing Methods 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000004332 silver Substances 0.000 claims description 8
- 239000002313 adhesive film Substances 0.000 claims description 5
- 239000005871 repellent Substances 0.000 claims description 5
- 238000003466 welding Methods 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052802 copper Inorganic materials 0.000 claims description 3
- 239000010949 copper Substances 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 3
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 claims description 2
- 230000000873 masking effect Effects 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000003825 pressing Methods 0.000 claims 1
- 239000000126 substance Substances 0.000 claims 1
- 238000005496 tempering Methods 0.000 claims 1
- 239000010410 layer Substances 0.000 description 12
- 230000008901 benefit Effects 0.000 description 11
- 239000000463 material Substances 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000004040 coloring Methods 0.000 description 5
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000010257 thawing Methods 0.000 description 2
- 238000007669 thermal treatment Methods 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007495 chemical tempering process Methods 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/84—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields
- H05B3/845—Heating arrangements specially adapted for transparent or reflecting areas, e.g. for demisting or de-icing windows, mirrors or vehicle windshields specially adapted for reflecting surfaces, e.g. bathroom - or rearview mirrors
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B2214/00—Aspects relating to resistive heating, induction heating and heating using microwaves, covered by groups H05B3/00, H05B6/00
- H05B2214/02—Heaters specially designed for de-icing or protection against icing
Definitions
- the present invention relates to a heated mirror. Its most widespread but not exclusive applications are in the automotive field and in the field of transportation in general as rear-view mirrors. Background Art
- Rear-view mirrors manufactured with conventional technologies in fact are affected, especially during the winter period, by the inconvenience of misting or, worse still, frosting and icing on their external surface.
- the resistive element substantially consists of a coil formed by an electric conductor which is applied to the rear of the reflective surface and has, at its ends, terminals for connection to an electric power source.
- the reflective surface does not have per se particular conductive characteristics and is unable to independently generate the heat required to demist the mirror; said heat must instead be supplied by the resistive element.
- the reflective layer regardless of its position (at the front or at the rear), can actually be a hindrance to the flow of heat: it is in fact an interface which has different physical characteristics with respect to glass, and it is necessary to take this additional layer into account as regards heat transmission.
- the heating time is therefore obviously longer with respect to a system which has no additional layers between the heating system and the surface to be heated.
- the heat generated by the resistive coil can, over time, degrade the characteristics of the adhesive of the film, no longer ensuring good thermal contact between the glass and the conductive film; accordingly, the efficiency of the entire heating system can be compromised and degraded over time. Disclosure of the Invention
- the aim of the present invention is to provide a mirror which allows to perform defrosting and/or demisting in a time which is not longer than achieved with conventional mirrors.
- an object of the present invention is to provide a heated mirror which is capable of ensuring excellent viewing of the reflected image and, in case of strong lighting, for example in the presence of headlights, better visibility than conventional mirrors.
- Another object of the present invention is to provide a heated mirror which ensures good heating uniformity on the entire surface thereof.
- a further object of the invention is to provide a heated mirror which can be manufactured in a shorter time than conventional models and by means of simpler and quicker assembly steps.
- a further object of the invention is to provide a heated mirror which can be manufactured at very low costs.
- a further object of the invention is to provide a heated mirror which allows to vary the coloring of the reflective surface thereof.
- a further object of the present invention is to provide a heated mirror which ensures a longer life time than conventional mirrors.
- a further object of the invention is to provide a heated mirror in which deterioration of the reflective surface caused by the action of weather is prevented.
- a further object of the present invention is to provide a heated mirror which ensures good electric and optical characteristics over time.
- a further object of the invention is to provide a heated mirror which can operate even with very low temperatures (down to -50°C).
- a still further object is to provide a heated mirror which has a lighter structure than conventional models and at the same time has a higher mechanical strength, thus reducing the risk of breakage due to impact.
- a heated mirror characterized in that it comprises a glass body on one face whereof a film of an electrically conductive metal is deposited so as to form an actual reflective surface, two conductive busbars being associated with said metal film and being suitable to allow the flow of an electric current in said film.
- Figure 1 is a sectional view of a first embodiment of the mirror according to the invention, with the heating coating applied on the glass body of the mirror, at the side whereon the rays of light are directly incident;
- Figure 2 is a sectional view of a second embodiment of the mirror according to the invention, with the heating coating applied on the glass body of the mirror, at a side which is opposite to the one whereon the rays of light are incident;
- Figure 3 is a cross-sectional view of the mirror according to the invention, with the conductive elements arranged according to a first embodiment
- Figure 4 is a cross-sectional view of the mirror according to the invention, with the conductive elements arranged according to a second embodiment. Ways of carrying out the invention
- a heated mirror according to the present invention comprises a glass body 1 which in this case has a planar structure and which, in this constructive solution, has a reduced thickness of approximately 1-2 mm.
- the planar glass body 1 can be conveniently curved with currently used methods in order to obtain a mirror which has a cylindrical, spherical or aspheric shape.
- two conductive busbars 3 are provided, of a per se known type, obtained by means of a per se known screen-printing process, using silver paste in this case.
- the screen-printed silver paste that constitutes the pair of busbars 3 is preferably dried by means of a thermal treatment in order to improve the adhesion thereof to the glass body 1.
- a coating surface 2 is delimited, by masking the complementary surface, according to per se known treatment methods, on the same rear face of the glass body 1 on which the conductive busbars 3 have been screen-printed. Thereafter, the glass body 1 is placed inside a deposition chamber, of a per se known type, in order to deposit onto the rear face thereof a thin titanium film 2 which thus constitutes the actual reflective surface of the mirror.
- the thin titanium film 2 is deposited according to a technique commonly known as Vacuum Arc Deposition.
- the thin titanium film is a single layer.
- the two conductive busbars are meant to constitute electrodes of the heated mirror; for this purpose, they are welded to conducting terminals (preferably made of copper or silver) in order to allow connection to an electric power source, which can be, very simply, the battery of a motor vehicle.
- the protective layer can be composed of multiple layers of different materials in other embodiments.
- the protective layer must also conveniently insulate the welding regions between the terminals and the conductive busbars in order to prevent the generation of electrical discharges if water is present.
- the glass body 1 is then placed in a controlled environment (i.e., in an environment wherein the relative humidity, the temperature and all the other environmental conditions are kept within preset limits) so that the protective layer of paint dries.
- the heated mirror thus obtained is characterized in that the pure titanium film constitutes the reflective surface and simultaneously acts as a resistive element, since after the appropriate connection of the two conductive busbars 3 to the electric power source it allows the direct flow of an electric current and accordingly generates heat by means of the Joule effect.
- the heat can then be transmitted directly toward the front face of the mirror, since there is no interposed material that slows its transmission.
- the heat is practically unaffected by any dispersion from the rear face of the mirror 2 toward the outside environment thanks to the presence of the layer of protective paint, which also acts as a heat insulator.
- the layer of protective paint which also acts as a heat insulator.
- a heated mirror is obtained whose reflective surface has a different color and/or a different surface resistivity.
- the reflective surface is provided on the front face of the mirror so that it has water-repellent properties.
- the two conductive busbars 3 can be provided, as an alternative to deposition on glass, directly on said film made of an electrically conductive metallic material, so as to simplify all the operations for assembly to the conductive terminals for connection to the electric power source (see Figure 4).
- the conductive busbars 3 can be constituted by thin metal strips (made for example of copper, aluminum, silver, et cetera) which are applied to the metal film 2. Contact can be provided by pressure or, in other cases, by fixing the conductive busbars to an adhesive film to be applied to the layer of electrically conductive metal.
- the adhesive film which must of course be able to withstand the operating temperatures reached during the heating step, also has a useful safety function, since in case of accidental breakage of the mirror it prevents fragments from detaching.
- the conductive busbars 3 thus provided can be welded or fixed to suitable connectors in order to provide connection to the electric power supply system. In practice it has been observed that the present invention effectively achieves all of the intended aim and objects.
- the above-described heated mirror according to the present invention allows, in an equal time, to defrost a much larger surface than conventional mirrors.
- an important advantage of the present invention is that a heated mirror has been provided which is capable of ensuring optimum viewing of the reflected image and better visibility with respect to conventional types in case of strong lighting, such as for example in the presence of headlights.
- a further important advantage of the present invention is that a heated mirror has been provided which ensures good heating uniformity on the entire surface, since the titanium film itself constitutes not only the actual reflective surface but also the resistive element that generates heat by means of the Joule effect.
- a further advantage is that a heated mirror has been provided which can be manufactured in a shorter time than conventional models.
- a further advantage is certainly that it is possible to produce a heated mirror in practice at very low costs.
- a further advantage of the present invention is that a heated mirror has ben provided whose coloring is determined by the physical characteristics of the reflective surface.
- the present invention also achieves the advantage of providing a heated mirror which ensures a longer life time than conventional mirrors.
- a further advantage is that a heated mirror has been provided which is protected against degradation of the reflective surface caused by the action of weather.
- a further advantage of the present invention is that a heated mirror has been provided which ensures good electric and optical characteristics over time.
- a further advantage is that the above-described heated mirror can operate even with very low temperatures (down to -50°C) simply by varying the physical characteristics of the titanium film and without having to insert other resistive elements.
- a further advantage is that a heated mirror has been provided which has a lighter structure than conventional models and at the same time has a greater mechanical strength, so as to reduce the risk of impact breakage.
- the weight reduction and increase in mechanical strength can be achieved by means of a chemical tempering process. It should also be observed that the above-described mirror can be subjected to additional treatments, such as marking or painting, all of which are per se known, so as to accordingly provide equivalent configurations.
- Another alternative is achieved by providing a mirror according to the invention in which the reflective layer on the front face is obtained by deposition of the film made of an electrically conductive metal.
- the conductive reflective layer can be coated with a coating of titanium oxide with water-repellent characteristics, so that as a whole said layer is a single element with reflective, heating, water-repellent and color characteristics at the same time.
Landscapes
- Optical Elements Other Than Lenses (AREA)
- Rear-View Mirror Devices That Are Mounted On The Exterior Of The Vehicle (AREA)
- Mirrors, Picture Frames, Photograph Stands, And Related Fastening Devices (AREA)
- Chemically Coating (AREA)
- Surface Treatment Of Glass (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT98PD000134A ITPD980134A1 (it) | 1998-05-28 | 1998-05-28 | Struttura di specchio riscaldabile, particolarmente per veicoli, e pro cedimento per la sua realizzazione |
| ITPD980134 | 1998-05-28 | ||
| PCT/EP1999/003627 WO1999062303A1 (en) | 1998-05-28 | 1999-05-26 | Heated mirror, particularly for vehicles, and method for manufacturing it |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1082880A1 true EP1082880A1 (de) | 2001-03-14 |
Family
ID=11392236
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99926422A Withdrawn EP1082880A1 (de) | 1998-05-28 | 1999-05-26 | Beheizter spiegel,insbesondere bestimmt für fahrzeuge,und verfahren zur herstellung derselben |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1082880A1 (de) |
| AU (1) | AU4368899A (de) |
| BR (1) | BR9910767A (de) |
| IT (1) | ITPD980134A1 (de) |
| WO (1) | WO1999062303A1 (de) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1307365B1 (it) * | 1999-03-25 | 2001-11-06 | Giovanni Manfre | Specchio retrovisore ad angolo di visuale ampio e ridotta distorsioned'immagine,per veicoli. |
| US6834969B2 (en) * | 2002-05-31 | 2004-12-28 | Schefenacker Vision Systems France S.A. | Heated mirror |
| RU2248681C2 (ru) * | 2003-05-22 | 2005-03-20 | Казанский государственный технологический университет | Зеркало с обогревом |
| DE20316736U1 (de) * | 2003-10-30 | 2004-09-23 | Muchar, Manfred, Dipl.-Kaufm. | Beheizbarer Außenspiegel |
| RU2262215C1 (ru) * | 2004-01-26 | 2005-10-10 | Казанский государственный технологический университет | Зеркало с обогревом |
| FR2874416A1 (fr) * | 2004-08-17 | 2006-02-24 | Eric Muchembled | Dispositif pour rendre chauffant les isolants thermiques par reflectivite |
| FR2903563B1 (fr) * | 2006-07-07 | 2008-08-22 | Saint Gobain | Miroir chauffant electrique |
| DE102007013598B3 (de) * | 2007-03-21 | 2008-05-08 | Mekra Lang Gmbh & Co. Kg | Spiegelscheibe mit einem Substrat aus Kunststoff, ein Verfahren zu deren Herstellung sowie einen Außenspiegel mit einer solchen Spiegelscheibe |
| RU2426280C1 (ru) * | 2010-06-17 | 2011-08-10 | Государственное образовательное учреждение высшего профессионального образования "Казанский государственный технологический университет" | Зеркало с обогревом |
| RU2499370C1 (ru) * | 2012-06-19 | 2013-11-20 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Казанский национальный исследовательский технологический университет" | Зеркало с обогревом |
| ES2641312B1 (es) * | 2016-05-06 | 2018-09-05 | Advanced Nanotechnologies S.L. | Dispositivo de calefacción que comprende un sustrato laminar, procedimiento de obtención de este y puerta para vehículo que comprende un dispositivo de calefacción |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1391425A (en) * | 1971-06-09 | 1975-04-23 | Glaverbel | Electrically heated panels |
| US5155625A (en) * | 1989-03-24 | 1992-10-13 | Murakami Kaimeido Co., Ltd. | Water-drop-repellent mirror including a vibration plate and heating means |
| CA2153061A1 (en) * | 1993-11-04 | 1995-05-11 | Pentel Kabushiki Kaisha | Mirror with heater |
-
1998
- 1998-05-28 IT IT98PD000134A patent/ITPD980134A1/it unknown
-
1999
- 1999-05-26 WO PCT/EP1999/003627 patent/WO1999062303A1/en not_active Ceased
- 1999-05-26 BR BR9910767-8A patent/BR9910767A/pt not_active IP Right Cessation
- 1999-05-26 AU AU43688/99A patent/AU4368899A/en not_active Abandoned
- 1999-05-26 EP EP99926422A patent/EP1082880A1/de not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9962303A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| BR9910767A (pt) | 2001-02-13 |
| AU4368899A (en) | 1999-12-13 |
| ITPD980134A1 (it) | 1999-11-28 |
| WO1999062303A1 (en) | 1999-12-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
| 17P | Request for examination filed |
Effective date: 20001120 |
|
| AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): DE ES FR GB IT SE |
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| 17Q | First examination report despatched |
Effective date: 20040920 |
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| GRAP | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOSNIGR1 |
|
| STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
| 18D | Application deemed to be withdrawn |
Effective date: 20060124 |