EP1115833A1 - Tensidzusammensetzung - Google Patents

Tensidzusammensetzung

Info

Publication number: EP1115833A1
Authority: EP; European Patent Office
Prior art keywords: composition; less; weight; composition according; liquid detergent
Prior art date: 1998-09-25
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP99947291A

Other languages

English (en)

French (fr)

Other versions

EP1115833B1 (de

Inventor

Dirk Johannes Unilever Research Vlaardingen BIJL

Johannes C. Unilever Res. Vlaardingen PAS VAN DE

Charles C. Unilever Res. Vlaardingen VERBURG

Johannes J. Unilever Res. Vlaardingen VERHAGEN

Pieter Unilever Res. Vlaardingen VERSLUIS

Petronella C. Unilever Res.Vlaardingen WISSENBURG

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever PLC

Unilever NV

Original Assignee

Unilever PLC

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1998-09-25

Filing date

1999-09-08

Publication date

2001-07-18

1999-09-08 Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC

1999-09-08 Priority to EP99947291A priority Critical patent/EP1115833B1/de

2001-07-18 Publication of EP1115833A1 publication Critical patent/EP1115833A1/de

2004-12-15 Application granted granted Critical

2004-12-15 Publication of EP1115833B1 publication Critical patent/EP1115833B1/de

2019-09-08 Anticipated expiration legal-status Critical

Status Expired - Lifetime legal-status Critical Current

Links

239000000203 mixture Substances 0.000 title claims abstract description 129
239000003599 detergent Substances 0.000 title claims abstract description 59
239000007788 liquid Substances 0.000 claims abstract description 66
229920000642 polymer Polymers 0.000 claims abstract description 28
238000004090 dissolution Methods 0.000 claims abstract description 27
238000000034 method Methods 0.000 claims abstract description 10
230000008569 process Effects 0.000 claims abstract description 8
238000005191 phase separation Methods 0.000 claims abstract description 4
238000002360 preparation method Methods 0.000 claims abstract description 4
239000000463 material Substances 0.000 claims description 34
239000004094 surface-active agent Substances 0.000 claims description 27
239000003792 electrolyte Substances 0.000 claims description 20
239000007787 solid Substances 0.000 claims description 16
239000000344 soap Substances 0.000 claims description 15
-1 polyalkyleneoxydes Polymers 0.000 claims description 13
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 7
150000004676 glycans Chemical class 0.000 claims description 6
229920001282 polysaccharide Polymers 0.000 claims description 6
239000005017 polysaccharide Substances 0.000 claims description 6
239000003945 anionic surfactant Substances 0.000 claims description 5
229920002307 Dextran Polymers 0.000 claims description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 4
229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 4
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
239000005977 Ethylene Substances 0.000 claims description 3
239000002202 Polyethylene glycol Substances 0.000 claims description 3
JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 3
229920001577 copolymer Polymers 0.000 claims description 3
229920000058 polyacrylate Polymers 0.000 claims description 3
229920001223 polyethylene glycol Polymers 0.000 claims description 3
239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
150000002191 fatty alcohols Chemical class 0.000 claims description 2
239000011780 sodium chloride Substances 0.000 claims description 2
HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 claims description 2
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 15
229910052708 sodium Inorganic materials 0.000 description 15
239000011734 sodium Substances 0.000 description 15
125000000217 alkyl group Chemical group 0.000 description 9
239000004615 ingredient Substances 0.000 description 9
239000012071 phase Substances 0.000 description 9
238000005185 salting out Methods 0.000 description 7
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
239000004927 clay Substances 0.000 description 6
239000007795 chemical reaction product Substances 0.000 description 5
150000001875 compounds Chemical class 0.000 description 5
229910052700 potassium Inorganic materials 0.000 description 5
239000011591 potassium Substances 0.000 description 5
230000009467 reduction Effects 0.000 description 5
239000000243 solution Substances 0.000 description 5
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
229920002125 Sokalan® Polymers 0.000 description 4
229910021536 Zeolite Inorganic materials 0.000 description 4
239000002253 acid Substances 0.000 description 4
150000001298 alcohols Chemical class 0.000 description 4
239000003795 chemical substances by application Substances 0.000 description 4
239000003240 coconut oil Substances 0.000 description 4
235000019864 coconut oil Nutrition 0.000 description 4
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
239000004744 fabric Substances 0.000 description 4
239000002736 nonionic surfactant Substances 0.000 description 4
239000000047 product Substances 0.000 description 4
GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 4
239000010457 zeolite Substances 0.000 description 4
229910019142 PO4 Inorganic materials 0.000 description 3
ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
150000007513 acids Chemical class 0.000 description 3
229910052783 alkali metal Inorganic materials 0.000 description 3
125000000129 anionic group Chemical group 0.000 description 3
239000007844 bleaching agent Substances 0.000 description 3
125000004432 carbon atom Chemical group C* 0.000 description 3
150000007942 carboxylates Chemical class 0.000 description 3
150000001768 cations Chemical class 0.000 description 3
235000014113 dietary fatty acids Nutrition 0.000 description 3
239000000194 fatty acid Substances 0.000 description 3
229930195729 fatty acid Natural products 0.000 description 3
150000004665 fatty acids Chemical class 0.000 description 3
235000021317 phosphate Nutrition 0.000 description 3
150000003839 salts Chemical class 0.000 description 3
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 3
238000003860 storage Methods 0.000 description 3
OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
108090000790 Enzymes Proteins 0.000 description 2
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
229920000388 Polyphosphate Polymers 0.000 description 2
GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
229920002472 Starch Polymers 0.000 description 2
239000011149 active material Substances 0.000 description 2
150000001340 alkali metals Chemical class 0.000 description 2
150000003863 ammonium salts Chemical class 0.000 description 2
239000007864 aqueous solution Substances 0.000 description 2
230000008901 benefit Effects 0.000 description 2
SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 2
239000011575 calcium Substances 0.000 description 2
229910052791 calcium Inorganic materials 0.000 description 2
239000013078 crystal Substances 0.000 description 2
238000010790 dilution Methods 0.000 description 2
239000012895 dilution Substances 0.000 description 2
230000000694 effects Effects 0.000 description 2
239000002001 electrolyte material Substances 0.000 description 2
229940088598 enzyme Drugs 0.000 description 2
230000002349 favourable effect Effects 0.000 description 2
238000009472 formulation Methods 0.000 description 2
230000003301 hydrolyzing effect Effects 0.000 description 2
239000003752 hydrotrope Substances 0.000 description 2
239000012535 impurity Substances 0.000 description 2
SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
239000000693 micelle Substances 0.000 description 2
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
239000001205 polyphosphate Substances 0.000 description 2
235000011176 polyphosphates Nutrition 0.000 description 2
238000000518 rheometry Methods 0.000 description 2
150000004760 silicates Chemical class 0.000 description 2
239000000377 silicon dioxide Substances 0.000 description 2
229910021647 smectite Inorganic materials 0.000 description 2
235000010265 sodium sulphite Nutrition 0.000 description 2
235000019832 sodium triphosphate Nutrition 0.000 description 2
230000003019 stabilising effect Effects 0.000 description 2
239000003381 stabilizer Substances 0.000 description 2
239000008107 starch Substances 0.000 description 2
235000019698 starch Nutrition 0.000 description 2
125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 2
150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
230000008961 swelling Effects 0.000 description 2
239000003760 tallow Substances 0.000 description 2
239000004711 α-olefin Substances 0.000 description 2
WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
102000013142 Amylases Human genes 0.000 description 1
108010065511 Amylases Proteins 0.000 description 1
NNDHDYDFEDRMGH-CAEIVAEBSA-N Anthranoyllycoctonine Chemical compound C([C@]12CN(C3[C@@]4(O)[C@]5(O)[C@H]6[C@@H](OC)[C@@H]([C@H](C5)OC)C[C@H]6[C@@]3([C@@H]1[C@@H]4OC)[C@@H](OC)CC2)CC)OC(=O)C1=CC=CC=C1N NNDHDYDFEDRMGH-CAEIVAEBSA-N 0.000 description 1
240000008791 Antiaris toxicaria Species 0.000 description 1
BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
229910021532 Calcite Inorganic materials 0.000 description 1
229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
102000005575 Cellulases Human genes 0.000 description 1
108010084185 Cellulases Proteins 0.000 description 1
KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
244000060011 Cocos nucifera Species 0.000 description 1
235000013162 Cocos nucifera Nutrition 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
UXOXDDUEWZOAIW-UHFFFAOYSA-N Inuline Natural products CCN1CC2(CC(=O)Oc3ccccc3N)CCC(OC)C45C6CC7C(CC(O)(C6C7OC)C(O)(C(OC)C24)C15)OC UXOXDDUEWZOAIW-UHFFFAOYSA-N 0.000 description 1
OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
239000005642 Oleic acid Substances 0.000 description 1
ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
235000019483 Peanut oil Nutrition 0.000 description 1
102000035195 Peptidases Human genes 0.000 description 1
108091005804 Peptidases Proteins 0.000 description 1
ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
229920002535 Polyethylene Glycol 1500 Polymers 0.000 description 1
239000004365 Protease Substances 0.000 description 1
235000019484 Rapeseed oil Nutrition 0.000 description 1
DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
238000002441 X-ray diffraction Methods 0.000 description 1
239000000654 additive Substances 0.000 description 1
150000001335 aliphatic alkanes Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
150000008041 alkali metal carbonates Chemical class 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
125000002947 alkylene group Chemical group 0.000 description 1
229910000323 aluminium silicate Inorganic materials 0.000 description 1
150000001408 amides Chemical class 0.000 description 1
235000019418 amylase Nutrition 0.000 description 1
229940025131 amylases Drugs 0.000 description 1
VNRZCPPHNPEBFC-UHFFFAOYSA-N anthranoyllycoctonine Natural products CCN1CC2(COC(=O)c3ccccc3N)CCC(OC)C45C2C(OC)C(O)(C14)C6(O)CC(OC)C7CC5(O)C6C7OC VNRZCPPHNPEBFC-UHFFFAOYSA-N 0.000 description 1
239000008346 aqueous phase Substances 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
239000002585 base Substances 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910021538 borax Inorganic materials 0.000 description 1
150000001642 boronic acid derivatives Chemical class 0.000 description 1
150000004649 carbonic acid derivatives Chemical class 0.000 description 1
239000004359 castor oil Substances 0.000 description 1
235000019438 castor oil Nutrition 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
125000002091 cationic group Chemical group 0.000 description 1
230000008859 change Effects 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
239000000460 chlorine Substances 0.000 description 1
229910052801 chlorine Inorganic materials 0.000 description 1
150000001860 citric acid derivatives Chemical class 0.000 description 1
238000004140 cleaning Methods 0.000 description 1
239000003086 colorant Substances 0.000 description 1
230000000052 comparative effect Effects 0.000 description 1
238000009833 condensation Methods 0.000 description 1
230000005494 condensation Effects 0.000 description 1
238000002425 crystallisation Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
238000010586 diagram Methods 0.000 description 1
GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
239000000975 dye Substances 0.000 description 1
238000001493 electron microscopy Methods 0.000 description 1
239000003995 emulsifying agent Substances 0.000 description 1
150000002170 ethers Chemical class 0.000 description 1
239000002979 fabric softener Substances 0.000 description 1
239000010433 feldspar Substances 0.000 description 1
239000007850 fluorescent dye Substances 0.000 description 1
229920001002 functional polymer Polymers 0.000 description 1
230000002070 germicidal effect Effects 0.000 description 1
ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
125000001165 hydrophobic group Chemical group 0.000 description 1
230000003165 hydrotropic effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
230000003993 interaction Effects 0.000 description 1
229940045996 isethionic acid Drugs 0.000 description 1
QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
230000002535 lyotropic effect Effects 0.000 description 1
238000004519 manufacturing process Methods 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000005259 measurement Methods 0.000 description 1
229910052751 metal Inorganic materials 0.000 description 1
239000002184 metal Substances 0.000 description 1
150000002763 monocarboxylic acids Chemical class 0.000 description 1
230000007935 neutral effect Effects 0.000 description 1
230000003472 neutralizing effect Effects 0.000 description 1
238000001683 neutron diffraction Methods 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
230000003287 optical effect Effects 0.000 description 1
230000003204 osmotic effect Effects 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000003346 palm kernel oil Substances 0.000 description 1
235000019865 palm kernel oil Nutrition 0.000 description 1
239000002245 particle Substances 0.000 description 1
239000000312 peanut oil Substances 0.000 description 1
239000002304 perfume Substances 0.000 description 1
150000004965 peroxy acids Chemical class 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
125000003703 phosphorus containing inorganic group Chemical group 0.000 description 1
229920005646 polycarboxylate Polymers 0.000 description 1
159000000001 potassium salts Chemical class 0.000 description 1
235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
238000001556 precipitation Methods 0.000 description 1
239000002243 precursor Substances 0.000 description 1
WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 1
239000002994 raw material Substances 0.000 description 1
230000008439 repair process Effects 0.000 description 1
WBHHMMIMDMUBKC-XLNAKTSKSA-N ricinelaidic acid Chemical compound CCCCCC[C@@H](O)C\C=C\CCCCCCCC(O)=O WBHHMMIMDMUBKC-XLNAKTSKSA-N 0.000 description 1
229960003656 ricinoleic acid Drugs 0.000 description 1
FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910000029 sodium carbonate Inorganic materials 0.000 description 1
235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
239000004289 sodium hydrogen sulphite Substances 0.000 description 1
DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 description 1
229960001922 sodium perborate Drugs 0.000 description 1
229940045872 sodium percarbonate Drugs 0.000 description 1
235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000004328 sodium tetraborate Substances 0.000 description 1
235000010339 sodium tetraborate Nutrition 0.000 description 1
KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
239000002689 soil Substances 0.000 description 1
241000894007 species Species 0.000 description 1
150000003890 succinate salts Chemical class 0.000 description 1
229910021653 sulphate ion Inorganic materials 0.000 description 1
239000000725 suspension Substances 0.000 description 1
229950009390 symclosene Drugs 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
VUYXVWGKCKTUMF-UHFFFAOYSA-N tetratriacontaethylene glycol monomethyl ether Chemical compound COCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO VUYXVWGKCKTUMF-UHFFFAOYSA-N 0.000 description 1
VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0021—Dye-stain or dye-transfer inhibiting compositions
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase

Definitions

an alkali metal soap of a long chain mono- or dicarboxylic acid for example one having from 12 to 18 carbon atoms.
Typical acids of this kind are oleic acid, ricinoleic acid, and fatty acids derived from castor oil, rapeseed oil, groundnut oil, coconut oil, palm kernel oil or mixtures thereof.
the sodium or potassium soaps of these acids can be used.
the level of soap is at least 1%, preferably at least 5% by weight of the composition, and at most 35%, preferably at most 25% by weight of the composition .
compositions according to the invention may comprise electrolyte material, some or all of which may be builder material. It is noted that for the purpose of the invention, the term electrolytes may include builder material .

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

EP99947291A 1998-09-25 1999-09-08 Tensidzusammensetzung Expired - Lifetime EP1115833B1 (de)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
EP99947291A EP1115833B1 (de)	1998-09-25	1999-09-08	Tensidzusammensetzung

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date	Title
EP98203232		1998-09-25
EP98203232		1998-09-25
EP99947291A EP1115833B1 (de)	1998-09-25	1999-09-08	Tensidzusammensetzung
PCT/EP1999/006624 WO2000018868A1 (en)	1998-09-25	1999-09-08	Detergent composition

Publications (2)

Publication Number	Publication Date
EP1115833A1 true EP1115833A1 (de)	2001-07-18
EP1115833B1 EP1115833B1 (de)	2004-12-15

Family

ID=8234158

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP99947291A Expired - Lifetime EP1115833B1 (de)	1998-09-25	1999-09-08	Tensidzusammensetzung

Country Status (11)

Country	Link
EP (1)	EP1115833B1 (de)
CN (1)	CN1354784A (de)
AT (1)	ATE284949T1 (de)
AU (1)	AU6080699A (de)
BR (1)	BR9913923A (de)
CA (1)	CA2345644A1 (de)
DE (1)	DE69922672T2 (de)
ES (1)	ES2230892T3 (de)
TR (1)	TR200100847T2 (de)
WO (1)	WO2000018868A1 (de)
ZA (1)	ZA200101410B (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CN100469861C (zh) *	2004-11-11	2009-03-18	大连三达奥克化学有限公司	油田污水过滤罐滤料再生清洗剂及再生清洗工艺
WO2011017223A1 (en)	2009-07-31	2011-02-10	Akzo Nobel N.V.	Hybrid copolymer compositions for personal care applications
CA2642970C (en) *	2006-03-22	2013-09-24	The Procter & Gamble Company	Liquid treatment compositions comprising pearlescent agents
NO20073834L (no)	2006-07-21	2008-01-22	Akzo Nobel Chemicals Int Bv	Sulfonerte podede kopolymerer
ES2325048B1 (es) *	2008-02-21	2010-04-19	Palc Chemical Española, S.L	Composicion detergente de consistencia jabonosa, y proceso para su ob tencion.
US9139798B2 (en) *	2008-10-15	2015-09-22	Method Products, Pbc	Liquid cleaning compositions
US9879204B2 (en)	2010-03-17	2018-01-30	Method Products, Pbc	Liquid cleaning compositions with lower freezing point
US8636918B2 (en)	2011-08-05	2014-01-28	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide hybrid polymer composition and methods of controlling hard water scale
US8853144B2 (en)	2011-08-05	2014-10-07	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide graft polymer composition and methods of improving drainage
US8679366B2 (en)	2011-08-05	2014-03-25	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide graft polymer composition and methods of controlling hard water scale
US8841246B2 (en)	2011-08-05	2014-09-23	Ecolab Usa Inc.	Cleaning composition containing a polysaccharide hybrid polymer composition and methods of improving drainage
JP2014532791A (ja)	2011-11-04	2014-12-08	アクゾノーベルケミカルズインターナショナルベスローテンフエンノートシャップＡｋｚｏＮｏｂｅｌＣｈｅｍｉｃａｌｓＩｎｔｅｒｎａｔｉｏｎａｌＢ．Ｖ．	ハイブリッド樹状コポリマー、その組成物及びそれを製造する方法
US9051406B2 (en)	2011-11-04	2015-06-09	Akzo Nobel Chemicals International B.V.	Graft dendrite copolymers, and methods for producing the same
US8945314B2 (en)	2012-07-30	2015-02-03	Ecolab Usa Inc.	Biodegradable stability binding agent for a solid detergent
US9365805B2 (en)	2014-05-15	2016-06-14	Ecolab Usa Inc.	Bio-based pot and pan pre-soak

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US4452717A (en) *	1980-04-09	1984-06-05	Lever Brothers Company	Built liquid detergent compositions and method of preparation
ATE10647T1 (de) *	1981-09-01	1984-12-15	Unilever Nv	Fluessige waschmittel-detergenz-zusammensetzung.
CA1323280C (en) *	1987-07-31	1993-10-19	Mario Bulfari	Liquid detergent compositions
GB8823655D0 (en) *	1988-10-07	1988-11-16	Unilever Plc	Liquid detergent compositions
GB2256646A (en) *	1991-06-11	1992-12-16	Unilever Plc	Liquid detergent composition
JP3516449B2 (ja) *	1992-09-09	2004-04-05	ユニリーバー・ナームローゼ・ベンノートシヤープ	改良型硬質表面洗剤

1999
- 1999-09-08 CN CN99811308.5A patent/CN1354784A/zh active Pending
- 1999-09-08 EP EP99947291A patent/EP1115833B1/de not_active Expired - Lifetime
- 1999-09-08 BR BR9913923-5A patent/BR9913923A/pt not_active Application Discontinuation
- 1999-09-08 TR TR2001/00847T patent/TR200100847T2/xx unknown
- 1999-09-08 CA CA002345644A patent/CA2345644A1/en not_active Abandoned
- 1999-09-08 AU AU60806/99A patent/AU6080699A/en not_active Abandoned
- 1999-09-08 WO PCT/EP1999/006624 patent/WO2000018868A1/en not_active Ceased
- 1999-09-08 DE DE69922672T patent/DE69922672T2/de not_active Expired - Fee Related
- 1999-09-08 ES ES99947291T patent/ES2230892T3/es not_active Expired - Lifetime
- 1999-09-08 AT AT99947291T patent/ATE284949T1/de not_active IP Right Cessation
2001
- 2001-02-20 ZA ZA200101410A patent/ZA200101410B/en unknown

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0018868A1 *

Also Published As

Publication number	Publication date
ZA200101410B (en)	2002-02-20
AU6080699A (en)	2000-04-17
EP1115833B1 (de)	2004-12-15
WO2000018868A1 (en)	2000-04-06
CA2345644A1 (en)	2000-04-06
DE69922672T2 (de)	2005-12-22
DE69922672D1 (de)	2005-01-20
ATE284949T1 (de)	2005-01-15
ES2230892T3 (es)	2005-05-01
BR9913923A (pt)	2001-06-19
TR200100847T2 (tr)	2002-02-21
CN1354784A (zh)	2002-06-19

Legal Events

Date	Code	Title	Description
2001-06-01	PUAI	Public reference made under article 153(3) epc to a published international application that has entered the european phase	Free format text: ORIGINAL CODE: 0009012
2001-07-18	17P	Request for examination filed	Effective date: 20010215
2001-07-18	AK	Designated contracting states	Kind code of ref document: A1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE
2001-07-18	AX	Request for extension of the european patent	Free format text: AL;LT;LV;MK;RO;SI
2003-09-03	17Q	First examination report despatched	Effective date: 20030721
2004-06-25	GRAP	Despatch of communication of intention to grant a patent	Free format text: ORIGINAL CODE: EPIDOSNIGR1
2004-10-01	GRAS	Grant fee paid	Free format text: ORIGINAL CODE: EPIDOSNIGR3
2004-10-29	GRAA	(expected) grant	Free format text: ORIGINAL CODE: 0009210
2004-12-15	AK	Designated contracting states	Kind code of ref document: B1 Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE
2004-12-15	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 Ref country code: LI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 Ref country code: CH Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20041215
2004-12-15	REG	Reference to a national code	Ref country code: GB Ref legal event code: FG4D Ref country code: CH Ref legal event code: EP
2005-01-12	REG	Reference to a national code	Ref country code: IE Ref legal event code: FG4D
2005-01-20	REF	Corresponds to:	Ref document number: 69922672 Country of ref document: DE Date of ref document: 20050120 Kind code of ref document: P
2005-03-15	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20050315 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20050315 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20050315
2005-05-01	REG	Reference to a national code	Ref country code: ES Ref legal event code: FG2A Ref document number: 2230892 Country of ref document: ES Kind code of ref document: T3
2005-06-01	NLV1	Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
2005-06-30	REG	Reference to a national code	Ref country code: CH Ref legal event code: PL
2005-09-08	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050908 Ref country code: CY Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20050908
2005-09-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: MC Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050930 Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050930
2005-10-21	ET	Fr: translation filed
2005-10-21	PLBE	No opposition filed within time limit	Free format text: ORIGINAL CODE: 0009261
2005-10-21	STAA	Information on the status of an ep patent application or granted ep patent	Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT
2005-12-07	26N	No opposition filed	Effective date: 20050916
2006-06-14	REG	Reference to a national code	Ref country code: IE Ref legal event code: MM4A
2006-10-18	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: BE Payment date: 20061018 Year of fee payment: 8
2007-09-26	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: ES Payment date: 20070926 Year of fee payment: 9
2008-01-02	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: PT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050515
2008-01-02	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: GB Payment date: 20070926 Year of fee payment: 9
2008-01-31	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: IT Payment date: 20070925 Year of fee payment: 9 Ref country code: DE Payment date: 20071031 Year of fee payment: 9
2008-03-31	BERE	Be: lapsed	Owner name: UNILEVER N.V. Effective date*: 20070930
2008-04-30	PGFP	Annual fee paid to national office [announced via postgrant information from national office to epo]	Ref country code: FR Payment date: 20070917 Year of fee payment: 9
2008-08-29	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: BE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20070930
2009-05-27	GBPC	Gb: european patent ceased through non-payment of renewal fee	Effective date: 20080908
2009-07-03	REG	Reference to a national code	Ref country code: FR Ref legal event code: ST Effective date: 20090529
2009-08-31	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080908 Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20090401
2009-10-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080930
2009-11-26	REG	Reference to a national code	Ref country code: ES Ref legal event code: FD2A Effective date: 20080909
2009-11-30	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080908
2010-01-29	PG25	Lapsed in a contracting state [announced via postgrant information from national office to epo]	Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20080909

Publication	Publication Date	Title
US5006273A (en)	1991-04-09	Concentrated aqueous liquid detergents containing viscosity reducing polymers
CA2187520C (en)	2001-07-24	Detergent composition
US5776883A (en)	1998-07-07	Structured liquid detergent compositions containing nonionic structuring polymers providing enhanced shear thinning behavior
EP1115833B1 (de)	2004-12-15	Tensidzusammensetzung
US5633223A (en)	1997-05-27	Heavy duty liquid compositions comprising structuring solids of defined dimension and morphology
AU773807B2 (en)	2004-06-10	Structured surfactant systems
AU639243B2 (en)	1993-07-22	Liquid detergent composition
US5205957A (en)	1993-04-27	Structured aqueous liquid detergents containing functional polymers
EP0301882B1 (de)	1992-01-15	Flüssige Reinigungsmittelzusammensetzungen
EP0499623B1 (de)	1996-03-27	Waschmittelzusammensetzungen
EP0362916B1 (de)	1995-04-19	Flüssige Waschmittelzusammensetzungen
AU628381B2 (en)	1992-09-17	Liquid detergents
AU651797B2 (en)	1994-08-04	Liquid detergents
WO1991006622A1 (en)	1991-05-16	Detergent compositions
AU667660B2 (en)	1996-04-04	Liquid detergents
US5573701A (en)	1996-11-12	Liquid detergent composition
CA2022902A1 (en)	1991-02-16	Heavy duty washing process
AU647039B2 (en)	1994-03-17	Liquid detergents