EP1225215A3 - Verwendung von Übergangsmetallkomplexen mit Oxim-Liganden als Bleichkatalysatoren - Google Patents

Verwendung von Übergangsmetallkomplexen mit Oxim-Liganden als Bleichkatalysatoren Download PDF

Info

Publication number
EP1225215A3
EP1225215A3 EP02001237A EP02001237A EP1225215A3 EP 1225215 A3 EP1225215 A3 EP 1225215A3 EP 02001237 A EP02001237 A EP 02001237A EP 02001237 A EP02001237 A EP 02001237A EP 1225215 A3 EP1225215 A3 EP 1225215A3
Authority
EP
European Patent Office
Prior art keywords
oder
alkenyl
aryl
alkyl
ligand
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02001237A
Other languages
English (en)
French (fr)
Other versions
EP1225215B1 (de
EP1225215A2 (de
Inventor
Gerd Dr. Reinhardt
Michael Dr. Seebach
Nicole Reichardt
Laszlo I. Prof.-Dr. Simandi
Tatiana M. Simandi
Gabor Besenyei
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
clariant Produkte Deutschland GmbH
Original Assignee
Clariant GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant GmbH filed Critical Clariant GmbH
Publication of EP1225215A2 publication Critical patent/EP1225215A2/de
Publication of EP1225215A3 publication Critical patent/EP1225215A3/de
Application granted granted Critical
Publication of EP1225215B1 publication Critical patent/EP1225215B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Übergangsmetallkomplexe der Formel (1) M(L)nXm wobei
M
ein Metallatom aus der Gruppe Mn, Fe, Co, Ni, Mo, W,
L
einen Ligand der allgemeinen Formel R1R2C=N-O(H)z
R1
C1-C22-Alkyl, C2-C22-Alkenyl oder C5-C24-Aryl,
R2
H, C1-C22-Alkyl, C2-C22-Alkenyl, C5-C24-Aryl oder
Figure 80000001
mit z = 0 oder 1,
X
einen Neutral- oder Anionligand aus der Gruppe Pyridine, Imidazoline, Methylimidazole, Picoline, Lutidine, Chlorid, Bromid, Nitrat, Perchlorat, Citrat, Hexafluorophosphat oder Anionen organischer Säuren mit C1-C22 Kohlenstoffatomen, n eine Zahl von 2 bis 4 und m eine Zahl von 0 bis 4 bedeuten, werden als Bleichkatalysator eingesetzt.
EP02001237A 2001-01-19 2002-01-17 Verwendung von Übergangsmetallkomplexen mit Oxim-Liganden als Bleichkatalysatoren Expired - Lifetime EP1225215B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10102248 2001-01-19
DE10102248A DE10102248A1 (de) 2001-01-19 2001-01-19 Verwendung von Übergangsmetallkomplexen mit Oxim-Liganden als Bleichkatalysatoren

Publications (3)

Publication Number Publication Date
EP1225215A2 EP1225215A2 (de) 2002-07-24
EP1225215A3 true EP1225215A3 (de) 2003-05-07
EP1225215B1 EP1225215B1 (de) 2005-09-07

Family

ID=7671042

Family Applications (1)

Application Number Title Priority Date Filing Date
EP02001237A Expired - Lifetime EP1225215B1 (de) 2001-01-19 2002-01-17 Verwendung von Übergangsmetallkomplexen mit Oxim-Liganden als Bleichkatalysatoren

Country Status (5)

Country Link
US (1) US6746996B2 (de)
EP (1) EP1225215B1 (de)
JP (1) JP2002302698A (de)
DE (2) DE10102248A1 (de)
ES (1) ES2249498T3 (de)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10226522A1 (de) * 2002-06-14 2003-12-24 Degussa Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen mehrzähnigen Liganden als Bleichkatalysator und Bleichmittelzusammensetzung
DE10227775A1 (de) * 2002-06-21 2004-02-19 Degussa Ag Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen mehrzähnigen Liganden als Bleichkatalysator und Bleichmittelzusammensetzungen
DE10227774A1 (de) * 2002-06-21 2004-01-08 Degussa Ag Verwendung von Übergangsmetallkomplexen mit stickstoffhaltigen mehrzähnigen Liganden als Bleichkatalysator und Bleichmittelzusammensetzung
DE10304131A1 (de) 2003-02-03 2004-08-05 Clariant Gmbh Verwendung von Übergangsmetallkomplexen als Bleichkatalysatoren
US8262850B2 (en) 2003-09-23 2012-09-11 International Paper Company Chemical activation and refining of southern pine kraft fibers
DE10345273A1 (de) 2003-09-30 2005-04-21 Clariant Gmbh Verwendung von Übergangsmetallkomplexen mit Lactamliganden als Bleichkatalysatoren
NZ562593A (en) 2005-05-02 2011-05-27 Int Paper Co Ligno cellulosic materials and the products made therefrom, using an oxidizing agent with a transition metal catalyst
EP2103735A1 (de) * 2008-03-18 2009-09-23 Unilever PLC Katalytische Substratbleichung
US9512563B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Surface treated modified cellulose from chemical kraft fiber and methods of making and using same
US9512237B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Method for inhibiting the growth of microbes with a modified cellulose fiber
MX382645B (es) 2009-05-28 2025-03-13 Gp Cellulose Gmbh Celulosa modificada a partir de fibra kraft química y métodos para elaborarla y su uso.
US9511167B2 (en) 2009-05-28 2016-12-06 Gp Cellulose Gmbh Modified cellulose from chemical kraft fiber and methods of making and using the same
KR20140032937A (ko) * 2010-10-01 2014-03-17 우베 고산 가부시키가이샤 탄화수소 화합물의 산화 촉매, 및 그것을 이용한 탄화수소 화합물의 산화물의 제조 방법 및 제조 장치
WO2014100283A1 (en) 2012-12-19 2014-06-26 University Of Southern California Photoactivated molecules for light-induced modulation of the activity of electrically excitable cells and methods of using same
MX364379B (es) 2013-03-14 2019-04-24 Gp Cellulose Gmbh Un metodo para preparar una fibra kraft altamente funcional y de baja viscosidad, usando una secuencia de blanqueamiento acido, y una fibra hecha por el proceso.
CN105143547B (zh) 2013-03-15 2018-05-01 Gp 纤维素股份有限公司 具有增高羧基含量的低粘度牛皮纸纤维及其制造和使用方法
DE102013010150A1 (de) * 2013-06-15 2014-12-18 Clariant International Ltd. Bleichkatalysatorgranulate
DE102013019269A1 (de) * 2013-11-15 2015-06-03 Weylchem Switzerland Ag Geschirrspülmittel sowie dessen Verwendung
US10232043B2 (en) 2015-08-19 2019-03-19 California Institute Of Technology Photoactivated molecules for light-induced modulation of the activity of electrically excitable cells and methods of using the same
WO2018093697A1 (en) 2016-11-16 2018-05-24 Gp Cellulose Gmbh Modified cellulose from chemical fiber and methods of making and using the same
CN119121674A (zh) 2017-03-21 2024-12-13 国际纸业公司 气味控制纸浆组合物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3982892A (en) * 1974-07-12 1976-09-28 Colgate-Palmolive Company Activated peroxy bleach composition
US4100203A (en) * 1977-02-18 1978-07-11 Ici Americas Inc. Oxidative coupling of alkylphenols or 1-naphthols catalyzed by metal complexes of an oxime of a keto or aldehyde compound
SU806686A1 (ru) * 1979-03-29 1981-02-23 Ордена Трудового Красного Знамениинститут Химии Ah Молдавской Ccp Трехлигандные диоксимины никел /11/и СпОСОб иХ пОлучЕНи
JPH01240831A (ja) * 1988-03-23 1989-09-26 Tanaka Kikinzoku Kogyo Kk 圧力インジケータ
JPH09132797A (ja) * 1995-11-07 1997-05-20 Mitsui Toatsu Chem Inc 黴汚れ洗浄剤組成物

Family Cites Families (56)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3234158A (en) 1962-08-30 1966-02-08 Borden Co Floor polish
DE1193019B (de) * 1963-06-20 1965-05-20 Reinluft G M B H Verfahren zur Adsorption von Schwefeloxyden sowie gleichzeitig von einer oder mehreren reduzierenden Schwefelverbindungen aus industriellen Gasen, insbesondere Abgasen
AT330930B (de) 1973-04-13 1976-07-26 Henkel & Cie Gmbh Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen
JPS582436B2 (ja) * 1978-10-09 1983-01-17 株式会社日立製作所 メモリの駆動方法
DE3413571A1 (de) 1984-04-11 1985-10-24 Hoechst Ag, 6230 Frankfurt Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
DE3417649A1 (de) * 1984-05-12 1985-11-14 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von kristallinen natriumsilikaten
GB8415909D0 (en) 1984-06-21 1984-07-25 Procter & Gamble Ltd Peracid compounds
FR2597473B1 (fr) * 1986-01-30 1988-08-12 Roquette Freres Procede d'oxydation de di-, tri-, oligo- et polysaccharides en acides polyhydroxycarboxyliques, catalyseur mis en oeuvre et produits ainsi obtenus.
US5002691A (en) * 1986-11-06 1991-03-26 The Clorox Company Oxidant detergent containing stable bleach activator granules
US5087385A (en) * 1986-11-06 1992-02-11 The Clorox Company Acyloxynitrogen peracid precursors
GB8629837D0 (en) 1986-12-13 1987-01-21 Interox Chemicals Ltd Bleach activation
DE3719467A1 (de) 1987-06-11 1988-12-29 Hoechst Ag Organisch substituierte ammoniumsilikate und verfahren zu ihrer herstellung
US4915863A (en) 1987-08-14 1990-04-10 Kao Corporation Bleaching composition
GB8908416D0 (en) 1989-04-13 1989-06-01 Unilever Plc Bleach activation
US5318733A (en) 1989-08-09 1994-06-07 Henkel Kommanditgesellschaft Auf Aktien Production of compacted granules for detergents
CA2025073C (en) 1989-10-25 1995-07-18 Gunther Schimmel Process for producing sodium silicates
CA2024966C (en) 1989-10-25 1995-07-18 Gunther Schimmel Process for producing sodium silicates
YU221490A (sh) 1989-12-02 1993-10-20 Henkel Kg. Postupak za hidrotermalnu izradu kristalnog natrijum disilikata
DE4000705A1 (de) 1990-01-12 1991-07-18 Hoechst Ag Verfahren zur herstellung von kristallinen natriumsilikaten
GB9003741D0 (en) 1990-02-19 1990-04-18 Unilever Plc Bleach activation
DE69125310T2 (de) 1990-05-21 1997-07-03 Unilever Nv Bleichmittelaktivierung
US5075041A (en) * 1990-06-28 1991-12-24 Shell Oil Company Process for the preparation of secondary alcohol sulfate-containing surfactant compositions
DE4041752A1 (de) 1990-12-24 1992-06-25 Henkel Kgaa Enzymzubereitung fuer wasch- und reinigungsmittel
DE4107230C2 (de) 1991-03-07 1995-04-06 Hoechst Ag Verfahren zur Herstellung von Natriumsilikaten
IT1245063B (it) 1991-04-12 1994-09-13 Ferruzzi Ricerca & Tec Procedimento per l'ossidazione di carboidrati
EP0544490A1 (de) 1991-11-26 1993-06-02 Unilever Plc Bleich- und Reinigungsmittelzusammensetzungen
CA2085642A1 (en) 1991-12-20 1993-06-21 Ronald Hage Bleach activation
DE4142711A1 (de) 1991-12-21 1993-06-24 Hoechst Ag Verfahren zur herstellung von kristallinen natriumdisilikaten
DE4221381C1 (de) 1992-07-02 1994-02-10 Stockhausen Chem Fab Gmbh Pfropf-Copolymerisate von ungesättigten Monomeren und Zuckern, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4203923A1 (de) 1992-02-11 1993-08-12 Henkel Kgaa Verfahren zur herstellung von polycarboxylaten auf polysaccharid-basis
DE4216774A1 (de) 1992-05-21 1993-11-25 Henkel Kgaa Verfahren zur kontinuierlichen Herstellung eines granularen Wasch und/oder Reinigungsmittels
AU682314B2 (en) 1992-07-17 1997-10-02 Genencor International, Inc. High alkaline serine proteases
KR100294361B1 (ko) 1992-07-23 2001-09-17 피아 스타르 돌연변이체알파-아밀라제,세정제,접시세척제,및액화제
DE4300772C2 (de) 1993-01-14 1997-03-27 Stockhausen Chem Fab Gmbh Wasserlösliche, biologisch abbaubare Copolymere auf Basis von ungesättigten Mono- und Dicarbonsäuren, Verfahren zu ihrer Herstellung und ihre Verwendung
DE4303320C2 (de) 1993-02-05 1995-12-21 Degussa Waschmittelzusammensetzung mit verbessertem Schmutztragevermögen, Verfahren zu dessen Herstellung und Verwendung eines geeigneten Polycarboxylats hierfür
HU219675B (hu) 1993-02-11 2001-06-28 Genencor International Inc. Oxidatívan stabil alfa-amiláz
DE4310506A1 (de) 1993-03-31 1994-10-06 Cognis Bio Umwelt Enzymzubereitung für Wasch- und Reinigungsmittel
DK39093D0 (da) 1993-04-01 1993-04-01 Novo Nordisk As Enzym
ES2121174T3 (es) 1993-06-19 1998-11-16 Ciba Geigy Ag Inhibicion de la reabsorcion de colorantes migrantes en el licor de lavado.
DK100893D0 (da) 1993-09-09 1993-09-09 Novo Nordisk As Enzym
WO1995007331A1 (en) 1993-09-09 1995-03-16 The Procter & Gamble Company Liquid detergents with n-alkoxy or n-aryloxy polyhydroxy fatty acid amide surfactants
US5512699A (en) 1994-01-25 1996-04-30 The Procter & Gamble Company Poly polyhydroxy fatty acid amides
WO1995019955A1 (en) 1994-01-25 1995-07-27 The Procter & Gamble Company Gemini polyether fatty acid amides and their use in detergent compositions
US5534197A (en) 1994-01-25 1996-07-09 The Procter & Gamble Company Gemini polyhydroxy fatty acid amides
DE4405511A1 (de) 1994-02-22 1995-08-24 Henkel Kgaa Waschmittel mit amorphen silikatischen Buildersubstanzen
DE4416438A1 (de) 1994-05-10 1995-11-16 Basf Ag Ein- oder mehrkernige Metall-Komplexe und ihre Verwendung als Bleich- und Oxidationskatalysatoren
DE4417734A1 (de) 1994-05-20 1995-11-23 Degussa Polycarboxylate
DE4443177A1 (de) 1994-12-05 1996-06-13 Henkel Kgaa Aktivatormischungen für anorganische Perverbindungen
JPH10513213A (ja) 1995-02-02 1998-12-15 ザ、プロクター、エンド、ギャンブル、カンパニー コバルト触媒を含む自動皿洗い組成物
EP0807160B1 (de) 1995-02-02 2001-11-21 The Procter & Gamble Company Verfahren zur entfernung von teeflecken in geschirrspülern mit zusammensetzungen enthaltend kobalt (iii)- katalysator
AU711960B2 (en) 1995-02-02 1999-10-28 Procter & Gamble Company, The Automatic dishwashing compositions comprising cobalt chelated catalysts
WO1996034092A2 (en) 1995-04-28 1996-10-31 Genencor International, Inc. Detergents comprising cellulases
US6313081B1 (en) 1995-04-28 2001-11-06 Henkel Kommanditgesellschaft Auf Aktien (Kgaa) Detergents comprising cellulases
DE19529904A1 (de) 1995-08-15 1997-02-20 Henkel Kgaa Reinigungsmittel mit Aktivatorkomplexen für Persauerstoffverbindungen
DE69727711T2 (de) 1996-11-29 2004-07-15 The Clorox Co., Oakland N-alkyl-ammonium-acetonitril-salze, methoden dazu und zusammensetzungen die diese enthalten
DE19704143A1 (de) * 1997-02-04 1998-08-06 Basf Ag Aktivatoren für anorganische Perverbindungen

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3982892A (en) * 1974-07-12 1976-09-28 Colgate-Palmolive Company Activated peroxy bleach composition
US4100203A (en) * 1977-02-18 1978-07-11 Ici Americas Inc. Oxidative coupling of alkylphenols or 1-naphthols catalyzed by metal complexes of an oxime of a keto or aldehyde compound
SU806686A1 (ru) * 1979-03-29 1981-02-23 Ордена Трудового Красного Знамениинститут Химии Ah Молдавской Ccp Трехлигандные диоксимины никел /11/и СпОСОб иХ пОлучЕНи
JPH01240831A (ja) * 1988-03-23 1989-09-26 Tanaka Kikinzoku Kogyo Kk 圧力インジケータ
JPH09132797A (ja) * 1995-11-07 1997-05-20 Mitsui Toatsu Chem Inc 黴汚れ洗浄剤組成物

Non-Patent Citations (13)

* Cited by examiner, † Cited by third party
Title
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 1 March 1976 (1976-03-01), XP002231642, retrieved from STN Database accession no. 84:58329 *
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 17 April 1978 (1978-04-17), XP002231638, retrieved from STN Database accession no. 1978:114519 *
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 17 July 1980 (1980-07-17), XP002231639, retrieved from STN Database accession no. 1980:418308 *
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 26 December 1983 (1983-12-26), XP002231640, retrieved from STN Database accession no. 1983:624092 *
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 30 July 1973 (1973-07-30), XP002231641, retrieved from STN Database accession no. 1973-426668 *
DATABASE CAPLUS [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; 4 January 1965 (1965-01-04), XP002231637, retrieved from STN Database accession no. 1964:423017 *
DATABASE WPI Section Ch Week 198035, Derwent World Patents Index; Class A60, AN 1980-61726C, XP002231644 *
DATABASE WPI Section Ch Week 198147, Derwent World Patents Index; Class A60, AN 1981-86783D, XP002231643 *
DATABASE WPI Section Ch Week 199730, Derwent World Patents Index; Class D22, AN 1997-328640, XP002231645 *
HOLLEMANN, WIBERG: "Lehrbuch der anorganischen Chemie", 1971, WALTER DE GRUYTER & CO, BERLIN, XP002231636 *
PANG, STYNES: "Kinetics", INORG.CHEM., vol. 16, no. 3, 1977, pages 590 - 594, XP001145938 *
PATENT ABSTRACTS OF JAPAN vol. 013, no. 572 (P - 978) 18 December 1989 (1989-12-18) *
SCHRAUZER, LEE: "Cobaloximes", J.AM.CHEM.SOC., vol. 92, no. 6, 1970, pages 1551 - 1557, XP001145939 *

Also Published As

Publication number Publication date
EP1225215B1 (de) 2005-09-07
JP2002302698A (ja) 2002-10-18
US20020165110A1 (en) 2002-11-07
US6746996B2 (en) 2004-06-08
DE50204137D1 (de) 2005-10-13
ES2249498T3 (es) 2006-04-01
DE10102248A1 (de) 2002-07-25
EP1225215A2 (de) 2002-07-24

Similar Documents

Publication Publication Date Title
Viciano‐Chumillas et al. Coordination Versatility of Pyrazole‐Based Ligands towards High‐Nuclearity Transition‐Metal and Rare‐Earth Clusters
Salignac et al. Reactivity of the Organometallic f ac-[(CO) 3ReI (H2O) 3]+ Aquaion. Kinetic and Thermodynamic Properties of H2O Substitution
Dei et al. Tetraoxolene radical stabilization by the interaction with transition-metal ions
Chen et al. Coordination Assemblies of Metallacyclic, Prismatic and Tubular Molecular Architectures Based on the Non‐rigid Ligands
DE10345273A1 (de) Verwendung von Übergangsmetallkomplexen mit Lactamliganden als Bleichkatalysatoren
Kadish et al. Electrochemical and NMR studies of six-coordinate oxidized. mu.-nitrido iron porphyrin dimers
Lal et al. Modeling the Oxygen-Evolving Complex of Photosystem II. Synthesis, Redox Properties, and Core Interconversion Studies of Dimanganese Complexes Having {MnIII2 (μ-O)(μ-OAc) 2} 2+,{MnIIIMnIV (μ-O) 2 (μ-OAc)} 2+, and {MnIV2 (μ-O) 2 (μ-OAc)} 3+ Cores with MeL as a Terminal Ligand: A New Asymmetric Mixed-Valence Core
Lee et al. Endo-and exocyclic supramolecular complexes of mixed-donor macrocycles via [1: 1] and [2: 2] cyclizations
Acharyya et al. Rhodium Assisted C− H Activation of Benzaldehyde Thiosemicarbazones and Their Oxidation via Activation of Molecular Oxygen
Goedken et al. Monocarbon monoxide complexes of iron (II): synthesis and X-ray structural characterization
Njogu et al. Coordination polymers and discrete complexes of Ag (I)-N-(pyridylmethylene) anilines: synthesis, crystal structures and photophysical properties
Mondal et al. Observation of T LIESST above Liquid Nitrogen Temperature and Disclosure of Hidden Hysteresis in Multiresponsive Hofmann-type Coordination Polymers
Zhang et al. Ferrocenyl functional coordination polymers based on mono-, bi-, and heterotrinuclear organometallic building blocks: syntheses, structures, and properties
Matalobos et al. A di-μ-phenoxo bridged zinc dimer with unfamiliar spatial arrangement
Maurya et al. Synthesis, magnetic, and spectral studies of some mono‐and binuclear dioxomolybdenum (vi) complexes with chelating hydrazones derived from acid hydrazides and furfural or thiophene‐2‐aldehyde
Wei et al. Heterobimetallic metal-complex assemblies constructed from the flexible arm-like ligand 1, 1′-bis [(3-pyridylamino) carbonyl] ferrocene: structural versatility in the solid state
Asokan et al. A novel polymer of a binuclear nickel (II) complex bridged by 1, 3-diaminopropane: structure and magnetism
Cai et al. Structural, UV− Visible, and Electrochemical Studies on 2, 3-Dicyano-5, 6-di-2-pyridylpyrazine,[(CN) 2Py2Pyz], Related Species and Its Complexes [(CN) 2Py2PyzMCl2](M= PtII, PdII)
Klein et al. Coordination Behaviour of 1-(4, 2': 6', 4"-terpyridin-4'-yl) ferrocene and 1-(3, 2': 6', 3"-terpyridin-4'-yl) ferrocene: Predictable and Unpredictable Assembly Algorithms
Tołoczko et al. Does the Structural Preorganization Contribute to the “Two-Way” Spin Crossover in 1, 1′-Di (tetrazol-1-ylo) methane-Based Fe (II) Coordination Polymer Containing Conformationally Labile Adiponitrile Coligand?
Ali et al. Synthetic, spectroscopic and X-ray crystallographic structural study of the monomeric [Cu (pysme)(sac)(MeOH)] and dimeric [Cu (6mptsc)(sac)] 2 complexes [pysme= anion of the pyridine-2-carboxaldehyde Schiff base of S-methyldithiocarbazate, 6mptsc= the anion of the 6-methyl-2-pyridinecarbaldehydethiosemicarbazone and sac= the saccharinate anion]
Trumm et al. One‐versus Two‐Electron Oxidation of Complexed Guanidino‐Functionalized Aromatic Compounds
Pannu et al. Aryl-Linked Salicylaldoxime-Based Copper (II) Helicates and “Boxes”: Synthesis, X-ray Analysis, and Anion Influence on Complex Structure
Kovalchukova et al. Coordination chemistry of polyoxo-carbocyclic compounds containing one or more neighboring oxo-groups
Delville-Desbois et al. 17-and 19-Electron Complexes [FeIII (η5-C5R5)(S2CNMe2) L] n+(n= 1, 0): Electronic Structure and Substitution and Redox Chemistry. Formation of [FeIV (η5-C5R5)(dtc) 2] and Characterization of both 17e and 19e States of a Transition-Metal Complex

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

RIC1 Information provided on ipc code assigned before grant

Ipc: 7D 06L 3/02 B

Ipc: 7D 21C 9/10 B

Ipc: 7C 11D 3/39 A

AK Designated contracting states

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

17P Request for examination filed

Effective date: 20031107

AKX Designation fees paid

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

17Q First examination report despatched

Effective date: 20040907

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RBV Designated contracting states (corrected)

Designated state(s): BE CH DE ES FR GB IT LI

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE CH DE ES FR GB IT LI

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REF Corresponds to:

Ref document number: 50204137

Country of ref document: DE

Date of ref document: 20051013

Kind code of ref document: P

GBT Gb: translation of ep patent filed (gb section 77(6)(a)/1977)

Effective date: 20051111

REG Reference to a national code

Ref country code: CH

Ref legal event code: PFA

Owner name: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH

Free format text: CLARIANT GMBH#BRUENINGSTRASSE 50#65929 FRANKFURT AM MAIN (DE) -TRANSFER TO- CLARIANT PRODUKTE (DEUTSCHLAND) GMBH#BRUENINGSTRASSE 50#65929 FRANKFURT AM MAIN (DE)

RAP2 Party data changed (patent owner data changed or rights of a patent transferred)

Owner name: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2249498

Country of ref document: ES

Kind code of ref document: T3

ET Fr: translation filed
PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20060608

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: CH

Payment date: 20061213

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20061220

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20070105

Year of fee payment: 6

REG Reference to a national code

Ref country code: FR

Ref legal event code: CD

BECN Be: change of holder's name

Owner name: *CLARIANT PRODUKTE DEUTSCHLAND G.M.B.H.

Effective date: 20050907

BERE Be: lapsed

Owner name: *CLARIANT PRODUKTE DEUTSCHLAND G.M.B.H.

Effective date: 20080131

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080131

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080131

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20080118

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20080118

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20120116

Year of fee payment: 11

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20111221

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20130930

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20130117

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20140122

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20140121

Year of fee payment: 13

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 50204137

Country of ref document: DE

Representative=s name: ACKERMANN, JOACHIM KARL WILHELM, DIPL.-CHEM. D, DE

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 50204137

Country of ref document: DE

Representative=s name: ACKERMANN, JOACHIM KARL WILHELM, DIPL.-CHEM. D, DE

Effective date: 20140902

Ref country code: DE

Ref legal event code: R081

Ref document number: 50204137

Country of ref document: DE

Owner name: WEYLCHEM WIESBADEN GMBH, DE

Free format text: FORMER OWNER: CLARIANT PRODUKTE (DEUTSCHLAND) GMBH, 65929 FRANKFURT, DE

Effective date: 20140902

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 50204137

Country of ref document: DE

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20150117

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150117

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150801