EP1272534A2 - Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation - Google Patents

Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation

Info

Publication number
EP1272534A2
EP1272534A2 EP01940327A EP01940327A EP1272534A2 EP 1272534 A2 EP1272534 A2 EP 1272534A2 EP 01940327 A EP01940327 A EP 01940327A EP 01940327 A EP01940327 A EP 01940327A EP 1272534 A2 EP1272534 A2 EP 1272534A2
Authority
EP
European Patent Office
Prior art keywords
polyvinyl
crosslinking
polyvinyl butyral
polyvinyl butyrals
butyrals
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01940327A
Other languages
German (de)
English (en)
Inventor
Bernd Papenfuhs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuraray Europe GmbH
Original Assignee
Kuraray Specialities Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kuraray Specialities Europe GmbH filed Critical Kuraray Specialities Europe GmbH
Publication of EP1272534A2 publication Critical patent/EP1272534A2/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/14—Esterification
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids

Definitions

  • the present invention relates to new, high molecular weight, crosslinked polyvinyl butyrals, processes for their preparation and their use.
  • EP-A-0 211 818 proposed to crosslink polyvinyl butyrals by means of stable intermolecular diacetal linkages.
  • the crosslinking is carried out by aldehydes with at least two aldehyde groups.
  • the crosslinking agent is added before or during the acetalization of the polyvinyl alcohols with butyraldehyde.
  • the present invention was therefore based on the object of making available polyvinyl butyrals which have a higher mechanical strength than non-crosslinked products and which, moreover, can be produced reproducibly. Surprisingly, it was found that high molecular weight polyvinyl butyrals can be produced reproducibly by crosslinking with di- and / or polycarboxylic acids or their esters.
  • the present invention thus relates to high molecular weight, crosslinked polyvinyl butyrals obtainable by crosslinking a polyvinyl butyral with at least one di- and / or polycarboxylic acid or its derivatives, preferably its esters, as a crosslinking reagent.
  • Preferred crosslinking reagents are oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, maleic acid, fumaric acid, itaconic acid, phthalic acid, terephthalic acid and their esters.
  • crosslinking reagents are aliphatic diesters of the formula (I)
  • Diethyl and / or dimethyl oxalate are used in particular.
  • crosslinked polyvinyl butyrals thus have the following structural units:
  • the polyvinyl butyrals according to the invention are notable for a marked increase in mechanical strength compared to conventional products.
  • polyvinyl butyrals known to the person skilled in the art can be used as starting materials, ie the starting polyvinyl butyrals are in terms of Molecular weight in no way limited. However, polyvinyl butyrals with a molecular weight of at least 50,000 g / mol are preferably used.
  • the polyvinyl alcohol contents of the polyvinyl butyrals used as starting materials are preferably between 10 and 25% by weight, and particularly preferably between 16 and 23% by weight.
  • the polyvinyl acetate contents of the polyvinyl butyrals used as starting materials are preferably between 0 and 20% by weight.
  • the high molecular weight, crosslinked polyvinyl butyrals produced according to the invention contain plasticizers or plasticizer mixtures. All plasticizers known to the person skilled in the art can be used as plasticizers, in particular esters of polyvalent acids, polyhydric alcohols or oligoether glycols. Preferred plasticizers are e.g. Diesters of aliphatic diols and of aliphatic polyether diols or of polyether polyols, with aliphatic
  • Carboxylic acids preferably diesters of polyalkylene oxides, especially diesters of di-, tri- and tetraethylene glycol with aliphatic (C-6 to C ⁇ o) carboxylic acids, further diesters of aliphatic or aromatic (C 2 to C-i8) dicarboxylic acids with aliphatic (C to C ⁇ 2 ) alcohols, preferably dihexyl adipate and mixtures of the esters mentioned.
  • the plasticizer is used in the usual amounts known to those skilled in the art, the plasticizer content preferably being between 25 and 60 parts by weight based on 100 parts by weight of PVB.
  • the present application therefore also relates to a process for the preparation of the polyvinyl butyrals according to the invention, which is characterized in that the crosslinking reagent and, if appropriate, the plasticizer are added to the polyvinyl butyral, the mixture is optionally homogenized and thermally crosslinked at temperatures in the range from 80 to 280.degree becomes.
  • the crosslinking is catalyzed by adding alkaline or acidic additives.
  • alkaline and / or alkaline earth metal hydroxides, alkanoates, carboxylates, sulfates, chlorides, nitrates, phosphates or free organic and / or inorganic acids and amines, for example, can be used as alkaline or acid additives.
  • the crosslinking reagent can, for example, be added to the polyvinyl butyral dissolved in the plasticizer and the mixture can then be homogenized.
  • the concentration of the crosslinking reagent is preferably in the range from 0.01 to 10% by weight, particularly preferably in the range from 0.1 to 3% by weight and in particular in the range from 0.1 to 1% by weight, in each case based on polyvinyl butyral.
  • the thermal crosslinking can be carried out in all heatable units known to the person skilled in the art, e.g. Kneaders or autoclaves. However, the crosslinking is preferably carried out in the extruder, preferably at melt temperatures in the range from 80 to 280.degree.
  • the crosslinking reaction is favored by the alkalinity of the polymer, which is usually adjusted to stabilize the polyvinyl butyral.
  • the present application also relates to a molding composition containing the high molecular weight, crosslinked polyvinyl butyral according to the invention.
  • the polyvinyl butyral according to the invention can also be processed directly into a film with the aid of a slot die.
  • Processes for the production of polyvinyl butyral films are well known to the person skilled in the art.
  • Films from the inventive High molecular weight, crosslinked polyvinyl butyrals can also contain other conventional additives, such as, for example, oxidation stabilizers, UV stabilizers, dyes, pigments and non-stick agents.
  • the present application therefore also relates to a film comprising the high molecular weight, crosslinked polyvinyl butyral according to the invention.
  • the films are characterized by increased tear strength, which is particularly advantageous for the production of safety laminated glass, the main area of application for the films.
  • Another object of the present invention is thus the use of the films according to the invention for the production of safety laminated glasses.
  • the PVB is acetylated with an excess of acetic anhydride in pyridine. After the reaction, the excess acetic anhydride is hydrolyzed with water and the resulting sodium hydroxide solution is titrated potentiometrically. The PVOH content is calculated based on the consumption of sodium hydroxide solution.
  • the PVB is dissolved in a benzyl alcohol / ethanol mixture.
  • the acetyl groups are saponified with an excess of alcoholic potassium hydroxide solution.
  • the excess potassium hydroxide solution is titrated back with hydrochloric acid.
  • Polyvinyl acetate content is calculated based on the consumption of hydrochloric acid.
  • the molecular weights of the polyvinyl butyrals contained in the molding compositions are determined by means of gel permeation chromatography (GPC) in glacial acetic acid using RI detectors.
  • the detectors are calibrated using PVB calibration standards, the absolute values of which are determined by means of static light scattering.
  • the PVB is dissolved in ethanol and titrated with 0.01 molar hydrochloric acid until the color changes from green to violet.
  • a mixture of methylene blue and neutral red is used as an indicator.
  • the alkali titer is calculated based on the consumption of hydrochloric acid.
  • the films are air-conditioned for 24 hours at 23 ° C and a relative humidity of 50%.
  • the tensile strength is measured using a tensile and compressive strength testing machine (manufacturer: Cadis GbR, type: BRP 201) in accordance with DIN 53455.
  • the films are air-conditioned at 23 ° C and a relative humidity of 50% for 24 hours.
  • the films are measured with a melt index tester (manufacturer: Göttfert, type: MP-D) at 190 ° C with a load of 2.16 kg using a 2 mm nozzle in accordance with ISO 1133.
  • the moisture of the PVB film is measured on laminated safety glass using an infrared photometer (manufacturer: Pier-Electronic GmbH, Wallau).
  • the measuring device is calibrated beforehand with appropriate calibration standards.
  • the test specimens for the pummel test are produced as follows: The foils are air-conditioned at a climate of 23 ° C / 30% relative air humidity for 24 hours. Laying is carried out on 2 mm float glass in F / F and Sn / Sn orientation of the film to the glass surface. The glass is washed with demineralized water before filling.
  • the laminated glass panes are produced by pressing the composites in the pre-composite furnace with calender rolls at temperatures between 40 and 100 ° C, followed by pressing the composites in an autoclave at a pressure of 12 bar and a temperature of 140 ° C for 30 minutes.
  • Test specimens with a size of 10 x 30 cm are cut from the laminated safety glasses produced in this way to carry out the pummel test.
  • the test specimens are tempered for 4 hours at -18 ° C.
  • the test specimens are then placed on a support inclined at 45 ° and with an automatic
  • the extrusion is carried out on a twin-screw extruder with counter-rotating screws (manufacturer: Haake), equipped with a melt pump and a slot die, at a melt temperature of 190 ° C.
  • Comparative Example 3 Mixing and extrusion are carried out analogously to Comparative Example 1. However, 374.5 g of the polyvinyl butyral from Comparative Example 1 are used. Instead of the plasticizer (3G7) used in Comparative Example 1, 125.5 g of dihexyl adipate (DHA) are used.
  • 3G7 plasticizer
  • DHA dihexyl adipate
  • Extrusion The extrusion takes place on a twin-screw extruder with co-rotating screws (manufacturer: Leistritz), equipped with a melt pump and a slot die, at a melt temperature of 200 ° C.
  • Example 4a Mixing and extrusion are carried out analogously to Comparative Example 4.
  • 6.74 g of diethyl oxalate are additionally dissolved in the plasticizer as crosslinking reagent.
  • Example 4b Mixing and extrusion is carried out analogously to Comparative Example 4.
  • 5.3 g of dimethyl oxalate are additionally dissolved in the plasticizer as crosslinking reagent.
  • Example 4c Mixing is carried out analogously to example 4b and extrusion analogously
  • the extrusion is carried out on a twin-screw extruder with co-rotating screws (manufacturer: Leistritz), equipped with a melt pump and a slot die, at a melt temperature of 200 ° C.
  • polyvinyl butyral can be thermally crosslinked with derivatives of dicarboxylic acids.
  • the increase in the molecular weight due to the action of the crosslinking reagents can be recognized from the increase in the molecular weights Mw and Mn and from the decrease in the melt index values.
  • the crosslinking reaction is promoted by the increasing alkali titer of the polyvinyl butyral used (cf. Comparative Example 4, Examples 4b and 4c) and by the increasing concentration of the crosslinker (cf. Comparative Example 4, Examples 4c and 4d).
  • the crosslinking reaction improves the mechanical properties of films made from the molding compositions, recognizable by the increase in tear strength.
  • the glass adhesion of the films remains essentially unaffected by the crosslinking reaction, recognizable by the Pummel values, which is an important prerequisite for the use of the films in laminated safety glass.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

La présente invention concerne des polyvinyl butyrals réticulés de masse moléculaire élevée, pouvant être obtenus par réticulation d'un polyvinyl butyral avec au moins un acide dicarboxylique et/ou polycarboxylique ou avec leurs dérivés, en tant que réactif de réticulation. Cette invention concerne également un procédé permettant leur préparation ainsi que leur utilisation.
EP01940327A 2000-04-13 2001-04-12 Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation Withdrawn EP1272534A2 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10018517 2000-04-13
DE10018517A DE10018517A1 (de) 2000-04-13 2000-04-13 Hochmolekulare, vernetzte Polyvinylbutyrale, Verfahren zu deren Herstellung sowie deren Verwendung
PCT/EP2001/004259 WO2001079305A2 (fr) 2000-04-13 2001-04-12 Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation

Publications (1)

Publication Number Publication Date
EP1272534A2 true EP1272534A2 (fr) 2003-01-08

Family

ID=7638737

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01940327A Withdrawn EP1272534A2 (fr) 2000-04-13 2001-04-12 Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation

Country Status (11)

Country Link
US (1) US6835784B2 (fr)
EP (1) EP1272534A2 (fr)
JP (1) JP2003531226A (fr)
KR (1) KR20020091196A (fr)
CN (1) CN1464884A (fr)
CZ (1) CZ20023398A3 (fr)
DE (1) DE10018517A1 (fr)
MX (1) MXPA02010036A (fr)
RU (1) RU2261255C2 (fr)
TW (1) TWI236485B (fr)
WO (1) WO2001079305A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2784736C1 (ru) * 2022-05-26 2022-11-29 Общество с ограниченной ответственностью "Научно-исследовательский центр "Современные полимерные материалы" Термопластичная эластомерная композиция с демпфирующими свойствами и способ ее применения

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10018517A1 (de) 2000-04-13 2001-10-18 Clariant Gmbh Hochmolekulare, vernetzte Polyvinylbutyrale, Verfahren zu deren Herstellung sowie deren Verwendung
JP4158434B2 (ja) * 2001-07-05 2008-10-01 株式会社ブリヂストン 異方性導電フィルム
DE10140597A1 (de) 2001-08-18 2003-03-06 Kuraray Specialities Europe Teilvernetzter Polyvinylalkohol
DE10319198A1 (de) 2002-07-04 2004-01-15 Kuraray Specialities Europe Gmbh Vernetzte Polyvinylacetale
US20040147675A1 (en) * 2002-11-27 2004-07-29 Hofmann George H Thermoplastic elastomers from crosslinked polyvinylbutyral
EP1437369A1 (fr) * 2003-01-07 2004-07-14 Clariant GmbH Alcool polyvinylique partiellement réticulé
WO2005019278A1 (fr) * 2003-08-19 2005-03-03 Kuraray Specialities Europe Gmbh Polyacetal de vinyle a couleur stable, son procede de production et son utilisation
JP4339745B2 (ja) * 2003-08-22 2009-10-07 積水化学工業株式会社 合わせガラス及び合わせガラス用中間膜
US7125607B2 (en) * 2004-03-16 2006-10-24 Solutia Incorporated Polymer sheets and methods of controlling adhesion of polymer sheets to glass
DE102004030411A1 (de) * 2004-06-23 2006-01-19 Kuraray Specialities Europe Gmbh Solarmodul als Verbundsicherheitsglas
EP1798245A1 (fr) * 2005-12-13 2007-06-20 Kuraray Europe GmbH Modifiant de polymères à base d' alcools vinyliques acetalisés avec des anydride d'acids carboxyliques et leur réticulation photochimique
JP5036405B2 (ja) * 2007-05-29 2012-09-26 株式会社クラレ 組成物および粉体塗料
DE102008001507A1 (de) * 2008-04-30 2009-11-05 Kuraray Europe Gmbh Photovoltaikmodule enthaltend plastifizierte Zwischenschicht-Folien mit hohem Alkalititer
DE102008001512A1 (de) * 2008-04-30 2009-11-05 Kuraray Europe Gmbh Dünnschicht-Solarmodul als Verbundsicherheitsglas
DE102008001505A1 (de) * 2008-04-30 2009-11-05 Kuraray Europe Gmbh Photovoltaikmodule enthaltend plastifizierte Zwischenschicht-Folien mit niedrigem Polyvinylacetatgehalt
EA024472B1 (ru) 2010-09-21 2016-09-30 Сэн-Гобэн Гласс Франс Остекление, способ его изготовления и применение указанного остекления
CN101955623B (zh) * 2010-09-29 2011-12-21 广州市奥吉斯新材料有限公司 一种用苯甲酸改性的聚乙烯醇缩丁醛及其制备方法与应用
CN101967249B (zh) * 2010-09-29 2011-12-21 广州市奥吉斯新材料有限公司 一种增韧聚苯乙烯及其制备方法与应用
CN102174238A (zh) * 2011-03-04 2011-09-07 浙江德斯泰塑胶有限公司 一种制备高强度pvb片材的配方
KR20140039190A (ko) 2011-04-15 2014-04-01 쌩-고벵 글래스 프랑스 발광 입자를 함유하는 필름의 제조 방법
US9922621B2 (en) 2011-08-29 2018-03-20 Sekisui Chemical Co., Ltd. Device for generating a display image on a composite glass pane
CN104844739A (zh) * 2015-05-15 2015-08-19 亿帆鑫富药业股份有限公司 可交联pvb及其生产方法、利用该可交联pvb生产可交联pvb胶片的方法
US10293517B2 (en) * 2015-08-30 2019-05-21 Kuraray Europe Gmbh Process for extrusion of plasticized PVB film with reduced plate-out of adhesion control agent residues
CN109207085B (zh) * 2018-06-29 2021-05-07 洛阳祺诺塑胶有限公司 一种高撕裂强度的聚乙烯醇缩丁醛胶片及其生产制造方法
CN110655336B (zh) * 2019-10-28 2022-05-27 怀德创建有限公司 Pvb膜和夹层玻璃

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE423916A (fr) * 1937-05-03
US3434915A (en) * 1965-11-17 1969-03-25 Du Pont Glass laminate
DE2527083A1 (de) * 1974-07-03 1976-01-22 Xerox Corp Neue druckmatrizen, verfahren zu ihrer herstellung und ihre verwendung zum drucken
SU827503A1 (ru) * 1979-07-02 1981-05-07 Предприятие П/Я В-2913 Пленочна композици дл промежуточногоСлО бЕзОСКОлОчНыХ СТЕКОл
DE3228076A1 (de) 1982-07-28 1984-02-02 Hoechst Ag, 6230 Frankfurt Verfahren zur herstelltung eines polyvinylbutyral-formkoerpers
CA1276744C (fr) 1985-07-02 1990-11-20 George Etienne Cartier Polyvinylbutyral reticule
US4847324A (en) 1988-04-25 1989-07-11 Hydromer, Inc. Hydrophilic polyvinylbutyral alloys
US5176947A (en) * 1990-12-07 1993-01-05 International Business Machines Corporation Electroerosion printing plates
FR2720683B1 (fr) * 1994-06-02 1996-07-05 Saint Gobain Vitrage Film intercalaire résistant au feu et son utilisation dans un verre feuilleté.
DE10018517A1 (de) 2000-04-13 2001-10-18 Clariant Gmbh Hochmolekulare, vernetzte Polyvinylbutyrale, Verfahren zu deren Herstellung sowie deren Verwendung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0179305A2 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2784736C1 (ru) * 2022-05-26 2022-11-29 Общество с ограниченной ответственностью "Научно-исследовательский центр "Современные полимерные материалы" Термопластичная эластомерная композиция с демпфирующими свойствами и способ ее применения

Also Published As

Publication number Publication date
TWI236485B (en) 2005-07-21
WO2001079305A2 (fr) 2001-10-25
MXPA02010036A (es) 2004-08-19
KR20020091196A (ko) 2002-12-05
DE10018517A1 (de) 2001-10-18
US20030166788A1 (en) 2003-09-04
CZ20023398A3 (cs) 2003-02-12
WO2001079305A3 (fr) 2002-02-14
CN1464884A (zh) 2003-12-31
RU2261255C2 (ru) 2005-09-27
US6835784B2 (en) 2004-12-28
JP2003531226A (ja) 2003-10-21

Similar Documents

Publication Publication Date Title
WO2001079305A2 (fr) Polyvinyl butyrals reticules de masse moleculaire elevee, leur procede de preparation et leur utilisation
EP1432742B1 (fr) Procede de production de butyrals de polyvinyle reticules a haut poids moleculaire
EP1355980A1 (fr) Poly(butyrals de vinyle) renfermant un plastifiant, leur procede de production et leur utilisation, notamment dans la production de films utilises dans des verres de securite feuilletes
EP1042121B1 (fr) Feuille plastifiee constituee d'alcools polyvinyliques partiellement acetalises
EP2548732B1 (fr) Feuilles en (iso)acétate de polyvinyle contenant un adoucissant
EP2336199B1 (fr) Poly-acétate de vinyle ayant une fluidité supérieure et feuille contenant du plastifiant ainsi fabriquée
EP2498989B1 (fr) Vitrifications composites dotées de feuilles contenant du plastifiant et ayant un faible fluage
WO2005037877A1 (fr) Compositions contenant du polyvinylacetal, films et verre feuillete et procede pour les produire
EP0617078A1 (fr) Polyvinylbutyrals plastifiées ayant des proprietés de réduction d'adhérence améliorées vis-à-vis de verre silicate, procédé de leur fabrication et utilisation
US4243572A (en) Alkyl alkylaryl adipate plasticizers for polyvinyl butyral
EP1390415B1 (fr) Butyrals de polyvinyle reticules a poids moleculaire eleve et procede de production et d'utilisation desdits butyrals
WO1990011324A1 (fr) Matiere de moulage pour la fabrication de films destines a des vitres de securite en verre feuillete
EP1646676B1 (fr) Film destine a un vitrage composite de securite et ayant une faible auto-adherence et une bonne adherence sur le verre
JPH11287797A (ja) ポリビニルアセタール樹脂の相溶性評価方法及び合わせガラス用中間膜組成物
WO2006114085A1 (fr) Polyvinylacetales plastifies, leur fabrication et leur utilisation

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20020918

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

17Q First examination report despatched

Effective date: 20060927

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: KURARAY EUROPE GMBH

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 20101102