EP1433552B1 - Verfahren zur Herstellung eines Leichtmetall-Verbundgussteils sowie Leichtmetall-Verbundbussteil - Google Patents
Verfahren zur Herstellung eines Leichtmetall-Verbundgussteils sowie Leichtmetall-Verbundbussteil Download PDFInfo
- Publication number
- EP1433552B1 EP1433552B1 EP20030025165 EP03025165A EP1433552B1 EP 1433552 B1 EP1433552 B1 EP 1433552B1 EP 20030025165 EP20030025165 EP 20030025165 EP 03025165 A EP03025165 A EP 03025165A EP 1433552 B1 EP1433552 B1 EP 1433552B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- light
- alloy
- intermediate layer
- metal alloy
- casting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000005266 casting Methods 0.000 title claims description 39
- 238000000034 method Methods 0.000 title claims description 17
- 239000002905 metal composite material Substances 0.000 title description 12
- 238000004519 manufacturing process Methods 0.000 title description 5
- 229910001092 metal group alloy Inorganic materials 0.000 claims description 30
- 239000011248 coating agent Substances 0.000 claims description 26
- 238000000576 coating method Methods 0.000 claims description 26
- 239000002131 composite material Substances 0.000 claims description 18
- 229910000838 Al alloy Inorganic materials 0.000 claims description 14
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 13
- 239000000956 alloy Substances 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 12
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 11
- 229910052749 magnesium Inorganic materials 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 239000010949 copper Substances 0.000 claims description 5
- 238000010285 flame spraying Methods 0.000 claims description 5
- 238000007750 plasma spraying Methods 0.000 claims description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 238000005058 metal casting Methods 0.000 claims 8
- 229910000789 Aluminium-silicon alloy Inorganic materials 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 1
- 230000035515 penetration Effects 0.000 claims 1
- 238000011161 development Methods 0.000 description 5
- 230000018109 developmental process Effects 0.000 description 5
- 239000011856 silicon-based particle Substances 0.000 description 4
- 238000002485 combustion reaction Methods 0.000 description 3
- 238000001000 micrograph Methods 0.000 description 3
- 229910001366 Hypereutectic aluminum Inorganic materials 0.000 description 2
- 238000005422 blasting Methods 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 229910001234 light alloy Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D19/00—Casting in, on, or around objects which form part of the product
- B22D19/0081—Casting in, on, or around objects which form part of the product pretreatment of the insert, e.g. for enhancing the bonding between insert and surrounding cast metal
Definitions
- the invention relates according to the preamble of claim 1, a method for producing a light metal composite casting. Furthermore, the invention relates to a light metal composite casting according to the preamble of claim 6.
- Out DE-A-197 46 167 a light metal component of magnesium die-casting is known in which in a growing area a threaded bush made of hardened aluminum during casting of the light metal component is partially enclosed by this. Out DE-A-197 46 167 It is known to coat the inserts in order to increase the adhesion between the insert and the casting material.
- the materials are light alloys, for example based on aluminum or magnesium, a temperature-related reaction occurs on the surface of the starting part during the casting process; The result is a bonding layer, which consists of a combination of the two materials.
- Such aluminum- or magnesium-based materials form a tie layer containing a high proportion of brittle magnesium phases, for example Al12Mg17; These phases disadvantageously cause a low mechanical strength of the connecting layer.
- one of the cast materials is a hypereutectic aluminum alloy, such as AlSi17Cu4Mg
- a hypereutectic aluminum alloy such as AlSi17Cu4Mg
- the invention has for its object to provide a method for producing a light metal composite casting mentioned above, which advantageously allows a compound of an initial part, which is formed essentially of a first light metal alloy, with a second light metal alloy by casting.
- an insulating, ductile intermediate layer should be formed, which on the one hand sufficient Strength and a sufficient line limit has to compensate for stresses between the two composite materials by plastic deformation and on the other a crack initiation, for example, on sharp aluminum particles of an aluminum alloy and crack propagation through brittle phases of a magnesium alloy by a separation of the Si particles from the magnesium phases prevented.
- a light metal composite casting comprising a first light metal alloy, in particular an aluminum alloy, as well as a second light metal alloy connected thereto, in particular a magnesium alloy, is to be provided, which has such an intermediate layer in the connection region between the light metal alloys.
- the output part is provided with a coating which during the casting process at high temperature and high pressure between the first and second light metal alloy in the composite casting forms a ductile, plastically deformable intermediate layer.
- the object is achieved according to the features of claim 6, wherein a ductile, plastically deformable intermediate layer between the first and second light metal alloy is formed.
- the first light metal alloy is an aluminum alloy, the second Alloy alloy a magnesium alloy and the coating an aluminum-silicon alloy.
- the aluminum alloy is preferably the alloy AlSi17Cu4Mg with the designation A390 and the magnesium alloy is the alloy MgAl6Sr2 with the designation AJ62 or alloys which are similar in each case at least in the relevant properties.
- the coating is applied by means of a flame spraying method, in particular by flame spraying with powder or wire, arc spraying with powder or wire or plasma spraying.
- the coating has a thickness of about 10 to 500 .mu.m, in particular from about 100 to 140 .mu.m.
- An at least on the outside porous structure of the coating has proven to be very favorable, which is compressed during the casting process and with which the second light metal alloy combines to form an intermediate layer between the first and second light metal alloys.
- the second light metal alloy at a temperature of about 600 to 800 ° C, in particular at about 680 ° C to 720 ° C and under a pressure of about 500 to 1200 bar, in particular about 850 to 900 bar, connected to the first light alloy in the casting process.
- the intermediate layer is formed by an alloy with the elements aluminum (Al), magnesium (Mg), silicon (Si), copper (Cu) and strontium (Sr).
- the intermediate layer of the light metal composite casting has a thickness of about 5 to 350 .mu.m, in particular from about 70 to 120 .mu.m, a hardness of at most 400 HV, in particular from about 250 to 350 HV, a ductility of at least 0.05 %, in particular of at least 0.1%, a tensile strength R m of at least 10 MPa, in particular of at least 20 Mpa, and a yield strength R p0.2 of at least 5 MPa, in particular of at least 10 MPa.
- an initial part made of an aluminum alloy such as AlSi17Cu4Mg with the designation A390, is produced by casting by means of gravity die casting.
- This output part which may well be in several parts and optionally provided on the outside with an example waffle-like structure pattern is surface-treated in a subsequent operation.
- a mechanical blasting treatment is carried out with a blasting medium such as corundum.
- a blasting medium such as corundum.
- other or further, for example, chemical surface treatments are performed.
- the output part is provided with a coating, in the present case an alloy of AlSi12 type is used and by means of a flame spraying method, in particular by flame spraying with powder or wire, arcing with powder or wire or plasma spraying is applied.
- the coating is primarily mechanically connected to the output part due to micro-region connections and at least on the outside has a porous structure;
- the coating has a thickness of about 10 to 500 .mu.m, in particular from about 100 to 140 .mu.m.
- the coated starting part is preheated to a temperature of about 400 to 550 ° C, in particular to about 480 ° C, to avoid cracks and to ensure a better connection of the subsequently applied magnesium casting.
- connection of the coated starting part takes place in a casting tool, in which the output part is inserted, wherein between the tool and the output part one or more mold spaces are formed, in which a molten casting material is introduced.
- the output part can be held in places on the tool wall adjacent and / or medium resolvable core elements.
- the coated starting part with a molten magnesium alloy such as MgAl6Sr2 with the designation AJ62, in the casting process at a temperature of about 600 to 800 ° C, especially at about 680 ° C to 720 ° C and under a pressure of about 500 up to 1200 bar, in particular about 850 to 900 bar connected, wherein the molten magnesium alloy combines very beneficial with the porous coating and the coating at the same time under the high pressure to about 70 to 90%, in particular to about 80% of their original thickness is compressed. Temperature and pressure caused a cohesive connection between the magnesium alloy and the coated output part.
- a molten magnesium alloy such as MgAl6Sr2 with the designation AJ62
- Fig. 2 shows a micrograph of a composite aluminum casting 200 from the hypereutectic aluminum alloy AlSi17Cu4Mg A390 and the magnesium alloy MgAl6Sr2 with the name AJ62 with intermediate layer. It can be seen how the molten magnesium alloy 206 has penetrated into the porous coating (212) and under pressure, the intermediate layer 204 has been formed. The intermediate layer 204 is compressed with respect to the original porous coating, with the magnesium alloy 206 and the intermediate layer 204 being adhesively bonded to one another. The transition from the intermediate layer 204 to the aluminum alloy 202 of the Output parts is much less fluent, which shows the more form-fitting nature of this connection.
- an insulating, ductile intermediate layer is formed which, on the one hand, has sufficient strength and a sufficient distance limit to compensate for stresses between the two composite materials by plastic deformation and, on the other hand, initiation of cracking, for example, on the sharp-edged silicon particles 208 of the aluminum alloy 202 and crack propagation by brittle phases of the magnesium alloy 206 prevented by a separation of the Si particles 208 of the magnesium phases.
- connection method according to the invention is particularly suitable for the production of the crankcase of internal combustion engines, in the light metal composite casting is therefore a crankcase for an internal combustion engine.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10259700 | 2002-12-18 | ||
| DE2002159700 DE10259700A1 (de) | 2002-12-18 | 2002-12-18 | Verfahren zur Herstellung eines Leichtmetall-Verbundgussteil sowie Leichtmetall-Verbundgussteil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1433552A1 EP1433552A1 (de) | 2004-06-30 |
| EP1433552B1 true EP1433552B1 (de) | 2009-05-06 |
Family
ID=32403998
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP20030025165 Expired - Lifetime EP1433552B1 (de) | 2002-12-18 | 2003-11-04 | Verfahren zur Herstellung eines Leichtmetall-Verbundgussteils sowie Leichtmetall-Verbundbussteil |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP1433552B1 (es) |
| DE (2) | DE10259700A1 (es) |
| ES (1) | ES2322700T3 (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102009013625A1 (de) | 2009-03-11 | 2010-09-16 | Elgan-Diamantwerkzeuge Gmbh & Co. Kg | Verfahren zur Feinbearbeitung von Bohrungen, Bearbeitungswerkzeug und Bearbeitungsmaschine hierfür sowie Werkstück |
| CN103372641A (zh) * | 2012-04-28 | 2013-10-30 | 宇宙钢丝绳有限公司 | 一种钢丝绳绳头浇铸方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB689224A (en) * | 1950-04-03 | 1953-03-25 | Aluminium Lab Ltd | Process for the production of light-metal castings having metallic inserts |
| GB747137A (en) * | 1953-03-06 | 1956-03-28 | Metallgesellschaft Ag | Method of producing compound castings between a metal or alloy and magnesium or magnesium alloys |
| NL97314C (es) * | 1955-09-29 | |||
| JPS4946215B1 (es) * | 1970-04-02 | 1974-12-09 | ||
| CH682307A5 (es) * | 1991-02-05 | 1993-08-31 | Alusuisse Lonza Services Ag | |
| JP3078411B2 (ja) * | 1992-11-12 | 2000-08-21 | 株式会社ユニシアジェックス | 複合アルミニウム部材の製造方法 |
| DE19745725A1 (de) * | 1997-06-24 | 1999-01-07 | Ks Aluminium Technologie Ag | Verfahren zum Herstellen eines Verbundgussteils |
| WO1998058755A1 (de) * | 1997-06-24 | 1998-12-30 | Ks Aluminium-Technologie Ag | Verfahren zum herstellen eines verbundgussteils |
| DE19733205B4 (de) * | 1997-08-01 | 2005-06-09 | Daimlerchrysler Ag | Beschichtung für eine Zylinderlauffläche einer Hubkolbenmaschine aus einer übereutektischen Aluminium/Siliziumlegierung, Spritzpulver zu deren Herstellung und deren Verwendung |
| US6443211B1 (en) * | 1999-08-31 | 2002-09-03 | Cummins Inc. | Mettallurgical bonding of inserts having multi-layered coatings within metal castings |
| DE10019793C1 (de) * | 2000-04-20 | 2001-08-30 | Federal Mogul Friedberg Gmbh | Zylinderlaufbuchse für Verbrennungskraftmaschinen und Herstellungsverfahren |
-
2002
- 2002-12-18 DE DE2002159700 patent/DE10259700A1/de not_active Ceased
-
2003
- 2003-11-04 ES ES03025165T patent/ES2322700T3/es not_active Expired - Lifetime
- 2003-11-04 EP EP20030025165 patent/EP1433552B1/de not_active Expired - Lifetime
- 2003-11-04 DE DE50311494T patent/DE50311494D1/de not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2322700T3 (es) | 2009-06-25 |
| EP1433552A1 (de) | 2004-06-30 |
| DE50311494D1 (de) | 2009-06-18 |
| DE10259700A1 (de) | 2004-07-15 |
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Inventor name: WAGENER, WOLFRAM Inventor name: WOLF, JOHANN Inventor name: DOERNENBURG, FRANK, DR. Inventor name: FENT, ANDREAS, DR. Inventor name: JOOSS, REINHARD |
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