EP1485519A2 - Zusammensetzung und verfahren zur beschichtung von metallsubstraten - Google Patents

Zusammensetzung und verfahren zur beschichtung von metallsubstraten

Info

Publication number
EP1485519A2
EP1485519A2 EP03727594A EP03727594A EP1485519A2 EP 1485519 A2 EP1485519 A2 EP 1485519A2 EP 03727594 A EP03727594 A EP 03727594A EP 03727594 A EP03727594 A EP 03727594A EP 1485519 A2 EP1485519 A2 EP 1485519A2
Authority
EP
European Patent Office
Prior art keywords
weight
coating composition
composition according
film
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP03727594A
Other languages
English (en)
French (fr)
Other versions
EP1485519B1 (de
Inventor
Jean-Marie Poulet
Alain Chesneau
Georges Leger
Denis Begue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NOF Metal Coatings Europe SA
Original Assignee
Dacral SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Dacral SA filed Critical Dacral SA
Priority to EP20100159057 priority Critical patent/EP2208809B9/de
Publication of EP1485519A2 publication Critical patent/EP1485519A2/de
Application granted granted Critical
Publication of EP1485519B1 publication Critical patent/EP1485519B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/60—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using alkaline aqueous solutions with pH greater than 8
    • C23C22/66—Treatment of aluminium or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20—Use of solutions containing silanes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31678—Of metal

Definitions

  • the subject of the present invention is a coating composition for a metal substrate based on an aqueous solution of sodium and / or potassium and / or lithium silicate.
  • the present invention also relates to the methods of applying this composition to said metallic substrate and to the various uses of this coating composition.
  • the coating composition is intended to be applied to a steel substrate having a free exterior surface constituted by a metallic layer of zinc or of zinc-based alloy.
  • said metal layer may have been deposited on said steel substrate by electrolytic means or by hot immersion.
  • electro-galvanized sheets steel substrate coated with a layer of zinc applied electrolytically
  • hot-dip galvanized sheets steel substrate coated with a layer of zinc applied by immersion said sheet in a bath of molten zinc
  • GALFAN steel substrate coated with a layer of zinc alloy (95% by weight) and aluminum (5% by weight) applied by immersion in a bath of zinc and aluminum alloy in the same proportions in fusion
  • GALVALUME ® steel substrate coated with a layer of aluminum alloy (55% by weight) and zinc (45% by weight) applied by immersion in a bath of aluminum alloy and zinc in the same molten proportions
  • the metal surface treatment is subject to multiple constraints that are technical, economic and environmental.
  • the production of sheet metal coils in steelmakers is carried out by very rapid processes, the line speed of which can range from a few m / min up to 250 m / min.
  • surface treatment technologies must accommodate these line speed constraints.
  • Anti-corrosion treatment technologies usually use chromium-based products (hexavalent or trivalent) which are applied in one or more coats. However, these products are harmful to the environment and need to be replaced by treatment products with no impact on the environment. In addition, manufacturers are now seeking to implement a technology that meets minimum specifications and is capable of being functionalized in order to meet higher levels of requirements and increase the added value of surface treatment.
  • the functionalization of the treatments relates in particular to the following fields: surface properties such as the hydrophobic or hydrophilic nature of the surface, the anti-fingerprint character of the surface or even the modification of the alkalinity free of the surface, - the processing properties such as the flexibility and the lubrication of the coating for bending or stamping operations, but also the electrical conductivity for assembly by welding.
  • the subject of the present invention is a composition which satisfies the requirements and constraints mentioned above.
  • the coating composition according to the present invention is characterized in that it comprises (% by weight):
  • the coating composition is intended to be applied to a metal substrate.
  • the wet film thus obtained is then dried and gives rise to a dry coating film.
  • the coating composition preferably contains 5 to 30% by weight of sodium and / or potassium and / or lithium silicate (s), more preferably 5 to 20% by weight of sodium and / or potassium silicate (s). potassium and or lithium, even more preferably 8 to 15% by weight of sodium silicate (s) and / or potassium and / or lithium.
  • this coating composition can be prepared in the form of a concentrate in which the percentage of sodium and / or potassium and / or lithium silicate (s) can reach up to approximately 40% by weight, or alternatively in the form powder in which the percentage of sodium and / or potassium and / or lithium silicate (s) can reach up to approximately 80% by weight.
  • sodium silicate can be used in said composition in the form of an aqueous solution of sodium silicate of the following composition by weight: - SiO 2 20 to 40% by weight
  • This sodium silicate solution can also contain a small proportion of Na 2 C0 3 of the order of 0.1% by weight relative to the weight of the silicate solution.
  • the potassium silicate can be used in said composition in the form of an aqueous solution of potassium silicate of the following composition by weight:
  • the lithium silicate can be used in said composition in the form of an aqueous solution of lithium silicate of the following composition by weight: - SiO 2 15 to 40% by weight
  • a subject of the present invention is also the dry coating film capable of being obtained from the application process (described below) of the coating composition on a metal substrate.
  • This dry coating film is characterized in that it comprises at least 40% by weight of dry matter of sodium and / or potassium silicate (s) and / or lithium, preferably between 60% and 99.9% by weight relative to the total weight of dry coating film.
  • tensioning agent means an additive whose function is to lower and control the energy of the liquid surface of the composition (or surface tension).
  • Surface energy is the energy necessary to bring the molecules from inside the liquid of the composition to its surface. The lower the surface energy of the composition, the greater the wettability of the surface of the metal substrate. Wettability is the faculty for said substrate to receive a liquid allowing it to spread over the largest possible surface.
  • the surface energy of the composition is preferably adjusted so as to obtain good wettability of the surface to be coated under conditions of high line speed before the product is frozen when entering the drying zone.
  • the coating composition contains between 0.01 to 1% by weight of a tensioning agent, preferably about 0.1% by weight of a tensioning agent.
  • a coating composition is thus advantageously obtained having a surface tension value of between 20 and 50 Dynes.cm “1 (20mN.rrf 1 and 50mN.m “ 1 ), preferably between 22 and 45 Dynes.cm "
  • the tensioning agent can be added separately or on the occasion of the incorporation of another constituent containing such an agent, for example a dispersion or an emulsion of a polymer.
  • tensioning agent By way of example of tensioning agent, mention will be made of the copolymers of polypropylene glycol and of polyethylene glycol (such as Pluronic PE).
  • silicone-based resins such as
  • BYK348 ® manufactured by BYK
  • acetylene glycols such as Dynol604 ® , manufactured by Air Products
  • anionic and nonionic mixtures such as Dapro W95 HS ® , marketed by Elementis
  • ammonium quaternaries such as Cycloquart ® , manufactured by Clariant
  • modified polyethoxylated alcohols such as Triton DF16 ® , manufactured by Union Carbide
  • the tensioning agent can be added to the composition according to the present invention in the form of an aqueous solution, a dispersion or an emulsion in water, with or without co-solvent.
  • the water used in the coating composition according to the present invention undergoes a deionization process beforehand so that the conductivity of this water is approximately less than 20 ⁇ S / cm.
  • the pH of the coating composition may be an alkaline pH, preferably between 11 and 13, more preferably between 11 and 12.
  • the coating composition can also contain a polymer whose function is to lower the glass transition temperature of the dry coating film.
  • composition When said composition is applied to a substrate and then undergoes a drying operation, the presence of said polymer confers elasticity and flexibility properties on the dry coating film thus obtained. Said polymer then makes it possible to reduce or eliminate the appearance of cracks in the dry coating film, during subsequent mechanical deformation of the metal substrate.
  • said polymer in particular may be mentioned acrylic polymers or copolymers such as Polysol M-19 ® (manufactured by SHOWA Highpolymer Co. Ltd.) or Rhodopas D-20 40 ® (manufactured by
  • Rhodia polyurethanes, alkyds, epoxy esters, as well as their compatible mixtures.
  • said polymer can be added to the composition according to the present invention in the form of a dispersion or an emulsion in water or an aqueous solution, in a proportion which allows advantageously reaching up to 60% by weight of the dry coating film.
  • the coating composition may also contain an additive making it possible to increase the hydrophobicity of the dry coating film, in a proportion which advantageously makes it possible to reach up to 50% by weight of the film. dry coating, preferably up to 25% by weight of the dry coating film.
  • This additive is advantageously a silane, preferably chosen from di- or trimethoxysilanes, or functionalized di- or triethoxysilanes, as well as their mixtures.
  • the organic functionality can be of vinyl, amino or oxyran (epoxy) type.
  • the silane is chosen from silanes with epoxy functionality such as beta (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 4 (trimethoxysilyl) butane-1,2 epoxide or gamma-glycidoxypropyltrimethoxysilane.
  • epoxy functionality such as beta (3,4-epoxycyclohexyl) ethyltrimethoxysilane, 4 (trimethoxysilyl) butane-1,2 epoxide or gamma-glycidoxypropyltrimethoxysilane.
  • the silane can also act as a binder, a stabilizer for the coating composition and make it possible to increase the corrosion resistance of the dry coating film.
  • These silanes can be used independently or in combination in prehydrolyzed form or not.
  • silane can also be combined with the addition of Titanate or Zirconate to reinforce the crosslinking of the binder system depending on the characteristics required of the coating.
  • the increase in the hydrophobicity of the dry coating film can be observed visually, in particular during cyclic corrosion tests (DIN 50017KTW), by the formation of droplets of condensed water vapor (coming from the electrolyte) less spread out than in the case of a coating whose binder is only composed of silicate. It is assumed that the introduction of silane into the coating composition leads to a reduction in the permeability and / or the porosity of the dry film coating the electrolyte, thus giving it its hydrophobic character.
  • the hydrophobic nature of the dry coating film by the introduction of silane into the coating composition makes it possible to apply a smaller dry film thickness for the same result of corrosion resistance.
  • the coating composition may also contain an additive making it possible to reduce the free surface alkalinity of the dry coating film, in a proportion which advantageously makes it possible to reach up to 25% by weight dry coating film.
  • This additive is preferably a cerium (Ce) salt, a lanthanum salt (La), a molybdenum salt (Mo), molybdic acid, paratoluene sulfonic acid, as well as their salts, or else a polyol such than glycerol, as well as their mixtures.
  • the coating composition may also contain an additive making it possible to increase the anticorrosion properties of the dry coating film, in a proportion which advantageously makes it possible to reach up to 25% by weight of the film. dry coating.
  • This additive is preferably a mineral binder such as a titanate or a zirconate, as well as their mixtures.
  • the coating composition can also contain a lubricating agent.
  • a lubricating agent By way of example of a lubricating agent, mention will be made in particular of synthetic organic polymers such as polytetrafluoroethylene, polyethylene, polyethylene glycol or natural organic polymers such as Camauba wax or paraffins, as well as their mixtures.
  • the lubricant is added to the coating composition in a proportion which advantageously makes it possible to reach up to 15% by weight of the dry coating film, preferably between 1, 5 and 15% by weight of the dry coating film, more preferably between 3 and 15% by weight of the dry film of coating, even more preferably between 5 and 15% by weight of the dry coating film.
  • the lubricant may require a stabilizer in order to avoid phase separation in the coating composition.
  • stabilizer By way of example of stabilizer, mention may be made in particular of organophilic clays (natural or synthetic), silica derivatives, cellulose derivatives, xanthan gum or associative thickeners of polyurethane or acrylic type, as well as their mixtures.
  • organophilic clays natural or synthetic
  • silica derivatives silica derivatives
  • cellulose derivatives cellulose derivatives
  • xanthan gum associative thickeners of polyurethane or acrylic type
  • the stabilizer is added to the coating composition according to the present invention in a proportion which makes it possible to reach between approximately 0.1 and 5% by weight of the dry coating film.
  • the coating composition can also be added with an anti-foaming agent chosen in a manner compatible with the other constituents of the coating composition and the optimum amount of which is determined according to conventional experiments of routine known to those skilled in the art.
  • said composition may be essentially devoid of organic solvent.
  • organic solvents have been found, in practice, not very compatible with sodium and / or potassium and / or lithium silicates, main constituents of the coating composition.
  • the present invention also relates to a method of coating a metal substrate which comprises applying the coating composition previously described on the surface of said substrate.
  • the application of the coating composition previously described is carried out during an operation which consists in depositing a wet film of said composition, of appropriate thin thickness, followed by a drying operation of said metallic substrate thus coated, giving rise to a dry film for coating said substrate.
  • the wet film thickness of the coating composition deposited on the metal substrate is between 0.3 and 39 ⁇ m, preferably between 0.3 and 30 ⁇ m and the wet film is applied at a rate of 0.6 to 40 g / m 2 , preferably from 0.6 to 24 g / m 2 .
  • the process which is the subject of the present invention can be carried out online, after the step of metallic coating of zinc or zinc-based alloy on the steel substrate, or on a take-up line such as on a pre-lacquering line (“ coil-coating ”).
  • the operation of depositing the wet film of the coating composition on the metal substrate can advantageously be carried out by spraying, by spraying followed by a wringing operation, by soaking followed by a spinning operation or by means of a coating system composed of at least one roller.
  • the wringing operation makes it possible to control the thickness of the wet film deposited on the metal substrate.
  • This spinning operation can advantageously be carried out using a set of drain rollers.
  • the drying operation of the metal substrate coated with the wet film is carried out by heating the metal substrate or the wet wire so as to bring the latter to a temperature between room temperature and 240 ° C.
  • the heating operation can be carried out directly by induction, or indirectly by convection or by infrared. Convection heating generally requires a longer drying time than induction or infrared heating.
  • This drying operation is advantageously carried out by heating the metal substrate or the wet film so as to bring the latter preferably to a temperature of at least about 35 ° C. for a period of at least 2 seconds if heating by means of convection and for a maximum of 10 seconds, preferably 5 seconds, more preferably 1 to 2 seconds, if using induction or infrared heating.
  • the drying operation is carried out in order to obtain a thickness of dry coating film of between 0.05 and 0.80 ⁇ m, preferably between 0.05 and 0.60 ⁇ m and so as to obtain a weight of dry coating film layer of between 0.1 g / m 2 and 1.3 g / m 2 , preferably between 0.2 g / m 2 and 1.2 g / m 2 , perhaps more preferably between 0.2 at 0.5 g / m 2 .
  • the operations of depositing the wet film and drying are carried out between the operations of metallic coating based on zinc or of zinc alloy of the steel substrate and of final winding.
  • the present invention also relates to the various uses of the coating composition which is the subject of the present invention.
  • the coating composition can be used as an anti-corrosion protective layer of metal sheets when it is applied to said sheets.
  • said composition can be used as an anti-corrosion protective layer of metal sheets intended to be temporarily stored.
  • the coating composition can be used as a lubricating layer when it additionally contains a lubricating agent and when it is applied to metal sheets with a view to their shaping, in particular for folding, bending and stamping of said metal sheets.
  • the coating composition can be used as an anti-fingerprint agent. In practice, it has been observed that metal sheets coated with the coating composition object of the present invention can be handled as they are, without fingerprints remaining subsequently printed on said metal sheets.
  • the coating composition can be applied to pieces of metal substrate intended to be welded.
  • said substrates thus coated retain their weldability and the welding operations can be carried out directly.
  • the coating composition may require the addition of conductive pigments such as iron phosphide, ammonium silicate, nickel, tungsten, zinc (pure or ally) and carbon, and mixtures thereof.
  • conductive pigments such as iron phosphide, ammonium silicate, nickel, tungsten, zinc (pure or ally) and carbon, and mixtures thereof.
  • the tensioning agent Copolymer of polypropylene glycol and polyethylene glycol with 10% polyethylene glycol in the molecule (Pluronic PE 3100 ® manufactured by BASF).
  • Example 5 Surface energy of the coating composition as a function of the tensioning agent.
  • composition according to the present invention corresponding to the following composition (% expressed by weight of dry matter relative to the dry coating film obtained):
  • the test consists in subjecting the sample of metallic substrate to friction over a length of approximately 50 mm (see FIG. 1).
  • the samples are in a format of 50 mm x 200 mm and are processed on both sides.
  • a lateral force (FL) is imposed on the sample and it is subjected to a constant speed traction of 20 mm / min.
  • the tensile force Fj is measured after a friction distance of 50 mm.
  • the weights of the coating dry film layer deposited on the samples of metal substrate are between 1 and 1.2 g / m 2 .
  • the measurements reported in the table below were obtained for a lateral force FL of 500 daN.
  • the reference sample is an electrogalvanized sheet (7.5 ⁇ m on each side) on which a layer of ANTICORRIT 4107 S® oil (manufacturer FUCHS) has been applied at a height of 2.5 g / m 2 on each side .
  • This oil is widely used in the automotive industry as a lubricant for sheet metal used in stamping.
  • Example 7 Results of a formulation comprising a silane
  • composition comprising the silane is more effective against corrosion than the composition without silane.
  • introduction of silane therefore makes it possible to reduce the layer weights while maintaining the same anti-corrosion properties.

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  • Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Laminated Bodies (AREA)
  • Internal Circuitry In Semiconductor Integrated Circuit Devices (AREA)
  • Liquid Crystal (AREA)
EP20030727594 2002-03-18 2003-03-18 Zusammensetzung und verfahren zur beschichtung von metallsubstraten Expired - Lifetime EP1485519B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP20100159057 EP2208809B9 (de) 2002-03-18 2003-03-18 Zusammensetzung zur Beschichtung eines metallischen Substrates

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0203353 2002-03-18
FR0203353A FR2837218B1 (fr) 2002-03-18 2002-03-18 Composition de revetement de substrat metallique
PCT/FR2003/000863 WO2003078683A2 (fr) 2002-03-18 2003-03-18 Composition et procede de revêtement de substrat métallique

Related Child Applications (2)

Application Number Title Priority Date Filing Date
EP20100159057 Division EP2208809B9 (de) 2002-03-18 2003-03-18 Zusammensetzung zur Beschichtung eines metallischen Substrates
EP10159057.8 Division-Into 2010-04-02

Publications (2)

Publication Number Publication Date
EP1485519A2 true EP1485519A2 (de) 2004-12-15
EP1485519B1 EP1485519B1 (de) 2010-05-19

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EP20100159057 Expired - Lifetime EP2208809B9 (de) 2002-03-18 2003-03-18 Zusammensetzung zur Beschichtung eines metallischen Substrates
EP20030727594 Expired - Lifetime EP1485519B1 (de) 2002-03-18 2003-03-18 Zusammensetzung und verfahren zur beschichtung von metallsubstraten

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EP20100159057 Expired - Lifetime EP2208809B9 (de) 2002-03-18 2003-03-18 Zusammensetzung zur Beschichtung eines metallischen Substrates

Country Status (11)

Country Link
US (1) US7232479B2 (de)
EP (2) EP2208809B9 (de)
AT (1) ATE468424T1 (de)
AU (1) AU2003233381A1 (de)
BR (1) BR0308562A (de)
CA (1) CA2479060C (de)
DE (1) DE60332605D1 (de)
ES (2) ES2343244T3 (de)
FR (1) FR2837218B1 (de)
MX (1) MXPA04009082A (de)
WO (1) WO2003078683A2 (de)

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Publication number Publication date
FR2837218B1 (fr) 2005-02-18
BR0308562A (pt) 2005-01-04
CA2479060A1 (fr) 2003-09-25
WO2003078683A9 (fr) 2004-07-15
CA2479060C (fr) 2011-05-24
AU2003233381A8 (en) 2003-09-29
WO2003078683A2 (fr) 2003-09-25
US7232479B2 (en) 2007-06-19
AU2003233381A1 (en) 2003-09-29
ES2423317T3 (es) 2013-09-19
EP2208809B9 (de) 2014-11-12
EP1485519B1 (de) 2010-05-19
MXPA04009082A (es) 2004-12-06
ES2343244T3 (es) 2010-07-27
WO2003078683A3 (fr) 2004-06-03
DE60332605D1 (de) 2010-07-01
US20060086281A1 (en) 2006-04-27
EP2208809B1 (de) 2013-06-12
FR2837218A1 (fr) 2003-09-19
ATE468424T1 (de) 2010-06-15
EP2208809A1 (de) 2010-07-21

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