EP2004295A2 - Zusammensetzung zur feuerbekämpfung und formulierungen aus dieser zusammensetzung - Google Patents

Zusammensetzung zur feuerbekämpfung und formulierungen aus dieser zusammensetzung

Info

Publication number: EP2004295A2
Authority: EP; European Patent Office
Prior art keywords: compound; composition; fighting fire; water; grams
Prior art date: 2006-04-13
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Granted

Application number

EP07788949A

Other languages

English (en)

French (fr)

Other versions

EP2004295B1 (de

Inventor

Marc Lanciaux

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

BIO CREATION

Original Assignee

BIO CREATION

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

2006-04-13

Filing date

2007-04-13

Publication date

2008-12-24

2007-04-13 Application filed by BIO CREATION filed Critical BIO CREATION

2007-04-13 Priority to PL07788949T priority Critical patent/PL2004295T3/pl

2008-12-24 Publication of EP2004295A2 publication Critical patent/EP2004295A2/de

2011-03-23 Application granted granted Critical

2011-03-23 Publication of EP2004295B1 publication Critical patent/EP2004295B1/de

Status Not-in-force legal-status Critical Current

2027-04-13 Anticipated expiration legal-status Critical

Links

239000000203 mixture Substances 0.000 title claims abstract description 55
238000009472 formulation Methods 0.000 title claims abstract description 8
150000001875 compounds Chemical class 0.000 claims abstract description 52
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
239000000843 powder Substances 0.000 claims abstract description 23
230000008719 thickening Effects 0.000 claims abstract description 8
238000006243 chemical reaction Methods 0.000 claims abstract description 5
239000003795 chemical substances by application Substances 0.000 claims abstract description 5
235000013311 vegetables Nutrition 0.000 claims abstract description 4
FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 15
229920002472 Starch Polymers 0.000 claims description 11
235000019698 starch Nutrition 0.000 claims description 11
239000011780 sodium chloride Substances 0.000 claims description 8
239000004927 clay Substances 0.000 claims description 7
235000013312 flour Nutrition 0.000 claims description 6
239000003349 gelling agent Substances 0.000 claims description 6
229920001592 potato starch Polymers 0.000 claims description 5
244000303965 Cyamopsis psoralioides Species 0.000 claims description 4
QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 claims description 3
102000002322 Egg Proteins Human genes 0.000 claims description 3
108010000912 Egg Proteins Proteins 0.000 claims description 3
235000010443 alginic acid Nutrition 0.000 claims description 3
229920000615 alginic acid Polymers 0.000 claims description 3
235000014103 egg white Nutrition 0.000 claims description 3
210000000969 egg white Anatomy 0.000 claims description 3
229910052500 inorganic mineral Inorganic materials 0.000 claims description 3
238000004519 manufacturing process Methods 0.000 claims description 3
239000011707 mineral Substances 0.000 claims description 3
230000001737 promoting effect Effects 0.000 claims description 3
240000008886 Ceratonia siliqua Species 0.000 claims description 2
235000013912 Ceratonia siliqua Nutrition 0.000 claims description 2
241000196324 Embryophyta Species 0.000 claims description 2
229920000881 Modified starch Polymers 0.000 claims description 2
229910019142 PO4 Inorganic materials 0.000 claims description 2
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 claims description 2
235000019426 modified starch Nutrition 0.000 claims description 2
235000021317 phosphate Nutrition 0.000 claims description 2
150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 2
108090000623 proteins and genes Proteins 0.000 claims description 2
102000004169 proteins and genes Human genes 0.000 claims description 2
239000008187 granular material Substances 0.000 claims 1
230000008020 evaporation Effects 0.000 description 13
238000001704 evaporation Methods 0.000 description 13
239000000654 additive Substances 0.000 description 9
239000000499 gel Substances 0.000 description 8
238000005507 spraying Methods 0.000 description 6
239000008107 starch Substances 0.000 description 6
239000002245 particle Substances 0.000 description 5
235000013339 cereals Nutrition 0.000 description 4
230000000694 effects Effects 0.000 description 4
230000000717 retained effect Effects 0.000 description 4
238000003763 carbonization Methods 0.000 description 3
238000002485 combustion reaction Methods 0.000 description 3
239000006260 foam Substances 0.000 description 3
239000004088 foaming agent Substances 0.000 description 3
230000008961 swelling Effects 0.000 description 3
108010010803 Gelatin Proteins 0.000 description 2
230000004888 barrier function Effects 0.000 description 2
230000008859 change Effects 0.000 description 2
239000000975 dye Substances 0.000 description 2
238000005187 foaming Methods 0.000 description 2
239000008273 gelatin Substances 0.000 description 2
229920000159 gelatin Polymers 0.000 description 2
235000019322 gelatine Nutrition 0.000 description 2
235000011852 gelatine desserts Nutrition 0.000 description 2
239000010410 layer Substances 0.000 description 2
239000007788 liquid Substances 0.000 description 2
230000002265 prevention Effects 0.000 description 2
239000013535 sea water Substances 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000000725 suspension Substances 0.000 description 2
231100000331 toxic Toxicity 0.000 description 2
230000002588 toxic effect Effects 0.000 description 2
239000002023 wood Substances 0.000 description 2
229920000945 Amylopectin Polymers 0.000 description 1
229920000856 Amylose Polymers 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
229940123973 Oxygen scavenger Drugs 0.000 description 1
244000061456 Solanum tuberosum Species 0.000 description 1
235000002595 Solanum tuberosum Nutrition 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
235000019826 ammonium polyphosphate Nutrition 0.000 description 1
229920001276 ammonium polyphosphate Polymers 0.000 description 1
238000013459 approach Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
230000008033 biological extinction Effects 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
239000011248 coating agent Substances 0.000 description 1
238000000576 coating method Methods 0.000 description 1
230000003247 decreasing effect Effects 0.000 description 1
230000003111 delayed effect Effects 0.000 description 1
238000005538 encapsulation Methods 0.000 description 1
239000000686 essence Substances 0.000 description 1
239000010696 ester oil Substances 0.000 description 1
238000004079 fireproofing Methods 0.000 description 1
239000012530 fluid Substances 0.000 description 1
239000003517 fume Substances 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000001879 gelation Methods 0.000 description 1
238000005469 granulation Methods 0.000 description 1
230000003179 granulation Effects 0.000 description 1
230000000670 limiting effect Effects 0.000 description 1
239000007791 liquid phase Substances 0.000 description 1
230000007774 longterm Effects 0.000 description 1
230000008018 melting Effects 0.000 description 1
238000002844 melting Methods 0.000 description 1
239000003921 oil Substances 0.000 description 1
230000008520 organization Effects 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
229920000642 polymer Polymers 0.000 description 1
235000012015 potatoes Nutrition 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
230000005855 radiation Effects 0.000 description 1
238000011084 recovery Methods 0.000 description 1
230000002829 reductive effect Effects 0.000 description 1
238000009938 salting Methods 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
GTSHREYGKSITGK-UHFFFAOYSA-N sodium ferrocyanide Chemical compound [Na+].[Na+].[Na+].[Na+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] GTSHREYGKSITGK-UHFFFAOYSA-N 0.000 description 1
235000012247 sodium ferrocyanide Nutrition 0.000 description 1
239000000264 sodium ferrocyanide Substances 0.000 description 1
239000002689 soil Substances 0.000 description 1
239000010902 straw Substances 0.000 description 1
239000000126 substance Substances 0.000 description 1
235000000346 sugar Nutrition 0.000 description 1
150000008163 sugars Chemical class 0.000 description 1
230000002195 synergetic effect Effects 0.000 description 1
231100000419 toxicity Toxicity 0.000 description 1
230000001988 toxicity Effects 0.000 description 1
230000009466 transformation Effects 0.000 description 1
239000012808 vapor phase Substances 0.000 description 1
230000000007 visual effect Effects 0.000 description 1

Classifications

- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/005—Dispersions; Emulsions
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0007—Solid extinguishing substances
- A62D1/0014—Powders; Granules

Definitions

the present invention relates to a fire-fighting composition and formulations of this composition.
the first is that of spraying by the mechanical means used: high-speed lance, plane, helicopter etc.
the second is evaporation from supports that have been wet but not yet attacked by fire.
the heat emanating from the hearth generally not far away, the sun, the wind provoke a strong evaporation which limits the spread of the fire.
the third is the evaporation during the projection on the hearth. This is the stage where the projection is directly effective by absorbing a lot energy during the change of liquid / vapor phase but with a very high emission of hot vapors or even toxic fumes.
water additives including so-called retardant additives and dyes to determine areas already treated.
Such additives are intended to improve the wettability by modifying the surface tension, to limit the evaporation, to increase the viscosity.
additives may be accompanied by oxygen scavengers, foaming agents. These additives do little to alter the losses by runoff and it has been found that the evaporation, delayed initially, can develop abruptly with sudden steam releases.
the foaming agents must also be used in small amounts so that the protective layer is not strong in the long term because the gas contained in the bubbles, expanding with heat, destructure the foam. As for the amount of water resulting after destructuring, it is necessarily very limited in the case of a foam.
Gelling agents are not very compatible with saline water such as seawater, which is also a disadvantage.
the mode of application is also important because the water additive as used does not allow the use of the projection under medium pressure, that is to say in the range 30 to 200 bar, the yields being considered as insufficient. In fact, fine spraying increases evaporation in the aerial phase. Or 1 the medium pressure conduit to improve the accuracy of application, limits the amount of water used and increases the current and power coating, always provided that they can be away from home, which is currently difficult for the reasons given above before.
the present invention aims to overcome these drawbacks and in particular avoids any impact on the natural environment, increases the extinguishing capacity even after evaporation and contains the ability to flame back the home, ballast the incandescent particles in post combustion, gives a visual contrast on the treated areas without adding dyes, allows a vertical grip, promotes the application capacity.
composition according to the present invention can also be formulated in different ways depending on the applications either for spraying, in particular at medium pressure or for the production of barriers.
the composition according to the invention comprises at least:
a third compound comprising at least one agent promoting the Maillard reaction of the at least first and / or second compounds, and - water.
the first compound in the form of a powder, is more particularly chosen from: guar flour, carob flour, modified starches, alginates.
This first compound must be free of oils and / or essences.
This first thickening compound is intended to maintain, in the composition, the insoluble particles in suspension to obtain a homogeneity of the medium.
the amount of the first compound is adapted according to the size of the particles to be kept in suspension, thus able to avoid settling.
the second compound in the form of a powder, is more particularly chosen from native starches and more particularly from native starches rich in phosphates and more particularly among potato starches.
the native starch consists of at least two polymers: amylose and amylopectin, and the structure is in the form of grains with grain sizes of a few microns to a few tens of microns. The organization of the network in crystalline form renders the native starch insoluble.
the interest is to retain native starch which has large grains, which is the case of native starch potatoes, potato starch.
the dimensions in the high range help to limit the evaporation during the different stages by decreasing the surface area for the same quantity and also increases the projection distance by increasing the kinetic energy.
Native starch has especially the ability to be soluble in a fluid temperature from 65 ° C, hot water or steam for example. In addition, this starch simultaneously becomes thickening and swelling under these conditions.
the third compound comprises at least one agent promoting the Maillard reaction of the at least first and second compounds: this third compound is sodium chloride.
Sodium chloride promotes the transformation of sugars and carbonization.
Sodium chloride is added or at least partly naturally present if the water used is seawater.
the rapid carbonization at least at the surface, even if the composition contains water, has many consequences, in particular :
the carbonized layer limits the rate of evaporation of the water
sodium chloride has natural fireproofing qualities that are also used.
This third compound also contributes, by a synergistic effect, to increase the water retention capacity of the at least first and second compounds.
the composition according to the invention may be improved by the addition of certain other compounds.
the composition is supplemented with a fourth compound, which is soluble in water and film-forming.
This fourth compound is a natural film-forming agent.
This fourth compound consists of a protein powder, for example egg white powder or alginates with a thermo-gelation range of about 65 ° C.
This fourth compound thus provides some encapsulation and binds the grains of the second compound during swelling under the effect of heat, leading to the production of a foam generated by the steam at the beginning of the thermal exposure.
the composition includes a fifth compound which is a ballast compound, which is insoluble and dissolvable.
This fifth compound is chosen from mineral powders and more particularly clay powders, especially white clay powders.
This fifth compound is optional and is of interest only in the case of fire-generating fireplaces, for example forest fires.
the clay powders are the least mechanically aggressive. If these powders are white clay powders, the zones treated with the composition according to the invention are visually identifiable. The ballast avoids the propagation by the sparks from the combustion of parts of the support.
a composition is thus obtained, the respective amounts of a particular embodiment of which can be specified, amounts given for 1 liter for medium-pressure spraying, 30 to 120 bar. It is noted that this spraying is possible since there is no foaming agent, also avoiding any cavitation or defusing pumps.
composition can be used both in direct attack of the home, in prevention or by delaying.
the first compound retained is guar flour at a rate of 3 to 14 grams.
the second compound selected is potato starch at a rate of 20 to 30 grams.
the third compound retained is sodium chloride in a proportion of 10 to 14 grams.
the fourth compound retained is egg white powder at 0.2 to 2 grams.
the fifth compound retained is clay powder at 5 to 40 grams.
composition according to the invention carbonizes and swells to a thickness of several millimeters, eight to nine millimeters to further specify the thicknesses achieved. This composition is scraped after removing the exposure of the support to the flame to reveal the wood support intact, free of any trace of carbonization.
composition can be used to attack a fire directly on the fire to ensure its extinction but also prevention or delay.
This composition can be formulated in liquid form as indicated and be applied by spraying using known means of firefighting.
composition can also be formulated in solid form, more particularly in gel form.
composition according to the invention makes it possible to produce gel ribbons, gel balls or even gel blocks.
an armature may be added to provide better mechanical performance, in particular for making web rolls and for easy handling.
One side may also be coated with a reflector, better still light in color, on the one hand to limit evaporation and on the other hand to reflect the heat.
Such tape can be unwound and placed as a retarder to limit the spread of a fire. As soon as the fire approaches and the temperature rises, the composition reacts as in the case of the liquid composition and forms a total barrier to propagation.
the gel balls can be projected at long distances mechanically, with great precision, by any suitable means.
Another formulation may be a granulation of this gel and a distribution by means such as road salting machines thus ensuring the formation of cords. It is noted that this formulation is of great interest for fire-fighters who, with such products, avoid the spread of fire.
thermo-liquefaction properties such as gelatin of animal origin.
gelatin with a bloom degree of 200 to 200 is used.
composition according to the present invention whatever its formulation, leads to extremely high performances.
the composition according to the invention comprises from 44 to 150 grams of dry matter per liter of composition.
aqueous composition according to the present invention For 1150 kg of aqueous composition according to the present invention, it would be 20 m3 of water or 20 000 kg of water.
the load to be transported is therefore extremely reduced, as is the volume.

Landscapes

Chemical & Material Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Business, Economics & Management (AREA)
Emergency Management (AREA)
Dispersion Chemistry (AREA)
Fire-Extinguishing Compositions (AREA)
Fireproofing Substances (AREA)
Compositions Of Macromolecular Compounds (AREA)
Paints Or Removers (AREA)
Medicinal Preparation (AREA)

EP07788949A 2006-04-13 2007-04-13 Zusammensetzung zur feuerbekämpfung und formulierungen aus dieser zusammensetzung Not-in-force EP2004295B1 (de)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
PL07788949T PL2004295T3 (pl)	2006-04-13	2007-04-13	Kompozycja do walki z ogniem i formulacja tej kompozycji

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
FR0603275A FR2899818B1 (fr)	2006-04-13	2006-04-13	Solution aqueuse a forte teneur en matieres seches pour la lutte contre des incendies
PCT/FR2007/051113 WO2007122342A2 (fr)	2006-04-13	2007-04-13	Composition pour lutter contre le feu et formulations de ladite composition

Publications (2)

Publication Number	Publication Date
EP2004295A2 true EP2004295A2 (de)	2008-12-24
EP2004295B1 EP2004295B1 (de)	2011-03-23

Family

ID=36437024

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
EP07788949A Not-in-force EP2004295B1 (de)	2006-04-13	2007-04-13	Zusammensetzung zur feuerbekämpfung und formulierungen aus dieser zusammensetzung

Country Status (17)

Country	Link
US (1)	US7922928B2 (de)
EP (1)	EP2004295B1 (de)
JP (1)	JP2009533118A (de)
AR (1)	AR060452A1 (de)
AT (1)	ATE502682T1 (de)
AU (1)	AU2007242620A1 (de)
BR (1)	BRPI0709509A2 (de)
CA (1)	CA2649236A1 (de)
DE (1)	DE602007013374D1 (de)
DK (1)	DK2004295T3 (de)
ES (1)	ES2363257T3 (de)
FR (1)	FR2899818B1 (de)
PL (1)	PL2004295T3 (de)
PT (1)	PT2004295E (de)
RU (1)	RU2438741C2 (de)
WO (1)	WO2007122342A2 (de)
ZA (1)	ZA200809640B (de)

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* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US8192653B2 (en)	2009-09-30	2012-06-05	EarthCleanCorporation	Fire suppression biodegradable suspension forming compositions
US8961838B2 (en)	2010-04-05	2015-02-24	Earthclean Corporation	Non-aqueous fire suppressing liquid concentrate
WO2013025954A2 (en) *	2011-08-16	2013-02-21	Sinclair Dan Dwight	Fire, dust and erosion suppression product and method
DE102013112063A1 (de) *	2013-11-01	2015-05-07	Viktor Bauf	Brandschutz- oder brandhemmende Zusammensetzung und deren Verwendung
DE102013112062A1 (de) *	2013-11-01	2015-05-07	Viktor Bauf	Brandmindernde oder brandlöschende Zusammensetzung und deren Verwendung
RU2605056C1 (ru) *	2015-06-29	2016-12-20	Федеральное Государственное Бюджетное Образовательное Учреждение Высшего Образования "Ивановская Пожарно-Спасательная Академия Государственной Противопожарной Службы Министерства Российской Федерации По Делам Гражданской Обороны, Чрезвычайным Ситуациям И Ликвидации Последствий Стихийных Бедствий" (Ф	Огнетушащий порошок многоцелевого назначения
CA3120661A1 (en) *	2018-11-21	2020-05-28	Firerein Inc.	Fire suppressing pellets
CN109701198A (zh) *	2019-01-10	2019-05-03	北京理工大学	一种即配型可自然降解海藻酸钠水凝胶灭火剂及其使用方法
KR20240046085A (ko) *	2022-09-30	2024-04-08	주식회사 엘지화학	조성물

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GB836465A (en) *	1957-08-12	1960-06-01	Pyrene Co Ltd	Fire-extinguishing composition
FR1485729A (fr) *	1966-05-13	1967-06-23	Carbonisation Charbons Actifs	Procédé de mise en solution des colloïdes organiques hydrophiles
JPS5846968A (ja) *	1981-09-14	1983-03-18	株式会社初田製作所	消火用濃厚液
US4459213A (en) *	1982-12-30	1984-07-10	Secom Co., Ltd.	Fire-extinguisher composition
US4610311A (en) *	1983-02-15	1986-09-09	Sanitek Products, Inc.	Method for reducing the aerial drift of aqueous preparations
US4950410A (en) *	1988-12-30	1990-08-21	United American, Inc.	Fire extinguishing compositions and methods
DE4290321D2 (de) *	1991-02-05	1994-04-28	Juergen Buil	Feuerlösch- und Brandschutzmittel
FR2690627A1 (fr) *	1992-04-30	1993-11-05	Lafarge Nouveaux Materiaux	Compositions utiles à la prévention et/ou à la lutte contre le feu.
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US6780991B2 (en) *	2000-11-28	2004-08-24	Astaris Llc	Biopolymer thickened fire retardant compositions
WO2003049813A1 (en) *	2001-12-07	2003-06-19	3M Innovative Properties Company	Aqueous foaming composition
WO2006042064A2 (en) *	2004-10-11	2006-04-20	Hagquist James Alroy E	Composition inhibiting the expansion of fire, suppressing existing fire, and methods of manufacture and use thereof
DE102004056830A1 (de) *	2004-11-24	2006-06-08	Basf Ag	Brandlöschende und/oder brandhemmende Zusammensetzungen

2006
- 2006-04-13 FR FR0603275A patent/FR2899818B1/fr not_active Expired - Fee Related
2007
- 2007-04-13 CA CA002649236A patent/CA2649236A1/fr not_active Abandoned
- 2007-04-13 AR ARP070101585A patent/AR060452A1/es active IP Right Grant
- 2007-04-13 AT AT07788949T patent/ATE502682T1/de active
- 2007-04-13 ES ES07788949T patent/ES2363257T3/es active Active
- 2007-04-13 RU RU2008144354/05A patent/RU2438741C2/ru not_active IP Right Cessation
- 2007-04-13 DK DK07788949.1T patent/DK2004295T3/da active
- 2007-04-13 JP JP2009504797A patent/JP2009533118A/ja active Pending
- 2007-04-13 BR BRPI0709509-0A patent/BRPI0709509A2/pt not_active IP Right Cessation
- 2007-04-13 PL PL07788949T patent/PL2004295T3/pl unknown
- 2007-04-13 PT PT07788949T patent/PT2004295E/pt unknown
- 2007-04-13 DE DE602007013374T patent/DE602007013374D1/de active Active
- 2007-04-13 AU AU2007242620A patent/AU2007242620A1/en not_active Abandoned
- 2007-04-13 EP EP07788949A patent/EP2004295B1/de not_active Not-in-force
- 2007-04-13 WO PCT/FR2007/051113 patent/WO2007122342A2/fr not_active Ceased
2008
- 2008-10-13 US US12/250,417 patent/US7922928B2/en not_active Expired - Fee Related
- 2008-11-12 ZA ZA200809640A patent/ZA200809640B/xx unknown

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Title
See references of WO2007122342A2 *

Also Published As

Publication number	Publication date
ATE502682T1 (de)	2011-04-15
FR2899818B1 (fr)	2009-05-15
AU2007242620A1 (en)	2007-11-01
AR060452A1 (es)	2008-06-18
RU2438741C2 (ru)	2012-01-10
ZA200809640B (en)	2009-11-25
JP2009533118A (ja)	2009-09-17
ES2363257T3 (es)	2011-07-28
DK2004295T3 (da)	2011-07-18
RU2008144354A (ru)	2010-05-20
WO2007122342A3 (fr)	2008-09-12
PL2004295T3 (pl)	2011-08-31
FR2899818A1 (fr)	2007-10-19
DE602007013374D1 (de)	2011-05-05
EP2004295B1 (de)	2011-03-23
US20090146097A1 (en)	2009-06-11
BRPI0709509A2 (pt)	2011-07-19
WO2007122342A2 (fr)	2007-11-01
US7922928B2 (en)	2011-04-12
CA2649236A1 (fr)	2007-11-01
PT2004295E (pt)	2011-07-01

Legal Events

Date	Code	Title	Description
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