EP2015012A2 - Procédé pour la séparation cryogénique d'air - Google Patents

Procédé pour la séparation cryogénique d'air Download PDF

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Publication number
EP2015012A2
EP2015012A2 EP08012052A EP08012052A EP2015012A2 EP 2015012 A2 EP2015012 A2 EP 2015012A2 EP 08012052 A EP08012052 A EP 08012052A EP 08012052 A EP08012052 A EP 08012052A EP 2015012 A2 EP2015012 A2 EP 2015012A2
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EP
European Patent Office
Prior art keywords
pressure
compressor
column
air
feed air
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP08012052A
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German (de)
English (en)
Other versions
EP2015012A3 (fr
Inventor
Dietrich Rottmann
Florian Schliebitz
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Linde GmbH
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Linde GmbH
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Filing date
Publication date
Application filed by Linde GmbH filed Critical Linde GmbH
Publication of EP2015012A2 publication Critical patent/EP2015012A2/fr
Publication of EP2015012A3 publication Critical patent/EP2015012A3/fr
Withdrawn legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04406Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
    • F25J3/04412Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04048Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
    • F25J3/04054Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of air
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/04084Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04006Providing pressurised feed air or process streams within or from the air fractionation unit
    • F25J3/04078Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
    • F25J3/0409Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04296Claude expansion, i.e. expanded into the main or high pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04284Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
    • F25J3/0429Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
    • F25J3/04303Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/04Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
    • F25J3/04248Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
    • F25J3/04375Details relating to the work expansion, e.g. process parameter etc.
    • F25J3/04393Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00Processes characterised by the type or other details of the product stream
    • F25J2215/50Oxygen or special cases, e.g. isotope-mixtures or low purity O2
    • F25J2215/52Oxygen production with multiple purity O2
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2215/00Processes characterised by the type or other details of the product stream
    • F25J2215/50Oxygen or special cases, e.g. isotope-mixtures or low purity O2
    • F25J2215/54Oxygen production with multiple pressure O2

Definitions

  • the invention relates to a method by cryogenic separation of air, in particular for the production of gaseous pressure oxygen.
  • the distillation column system of the invention may be designed as a two-column system (for example as a classic Linde double column system), or as a three-column or multi-column system.
  • other devices may be provided to recover other air components, particularly noble gases, such as argon or krypton-xenon recovery.
  • the invention relates to a process in which at least one gaseous pressure product is recovered by withdrawing a liquid product stream from the nitrogen-oxygen separation distillation column system, raising it to an elevated pressure in the liquid state, and evaporating it under this increased pressure by indirect heat exchange or (at supercritical pressure) is pseudo-evaporated.
  • Such internal compression methods are known, for example DE 830805 .
  • EP 1139046 A1 EP 1146301 A1 .
  • EP 1150082 A1 EP 1213552 A1 .
  • EP 1357342 A1 or DE 10238282 A1
  • the invention has for its object to make such a method and a corresponding device economically particularly favorable.
  • the drive of the cold compressor through the first expansion machine is particularly energetically particularly favorable.
  • the feed air has a pressure potential which would create more refrigeration in the expansion machine (s) than can be used in the process.
  • the excess energy is used in the invention for driving the cold compressor, which brings the second partial flow of the feed air to a particularly high pressure.
  • the method has a second expansion machine, in which a third partial flow of the feed air is expanded to perform work.
  • the outlet pressure of the second expansion machine is, for example, approximately at the level of the low-pressure column or the high-pressure column. Depending on the relaxed air is introduced into the low pressure column or in the high pressure column.
  • atmospheric air is compressed in a main air compressor to a first pressure of for example 5 to 7.5 bar, preferably 5.5 to 6 bar and then cleaned in a cleaning device (not shown).
  • the purified feed air 1 is divided at about the first pressure on four partial streams 2, 3, 4, 5.
  • the first partial stream 2 is supplied to the warm end of a main heat exchanger 6, cooled there to a first intermediate temperature, removed again via line 7 and working in a first expansion machine 8 to a pressure of, for example, 1.3 to 1.8 bar, preferably 1.3 relaxed to 1.6 bar.
  • the work-performing relaxed first partial stream is introduced via lines 9 and 10 in the low-pressure column 12 of a distillation column system, which also has a high-pressure column 11 and a main capacitor 13.
  • the second partial stream 3 of the feed air is recompressed in a first secondary compressor 14 to a second pressure of for example 29 to 60 bar, preferably 35 to 50 bar and flows after cooling in an aftercooler 15 via line 16 also to the warm end of the main heat exchanger 6.
  • a second intermediate temperature the second partial flow is withdrawn via line 17 and fed to a second after-compressor 18, which is designed as a cold compressor and is mechanically coupled to the first expansion machine 8.
  • the outlet pressure of the cold compressor 18 (“third pressure") is for example 40 to 85 bar, preferably 45 to 70 bar.
  • Via line 19 the high-pressure air at a third intermediate temperature, which is higher than the first intermediate temperature, introduced into the main heat exchanger 6 and flows through this to the cold end.
  • the third substream 19 under the third pressure is cooled in the main heat exchanger and condensed or pseudo-condensed (at supercritical pressure).
  • the cold high-pressure air 20 is expanded in a throttle valve 21 to approximately the operating pressure of the high-pressure column 11, which is for example 5 to 7.5 bar, preferably 5.5 to 6 bar, and introduced into the high-pressure column. At least a portion of the introduced liquid air is removed again via line 22, cooled in a subcooling countercurrent 23 and fed via line 24 and throttle valve 25 in the low pressure column 12.
  • the third partial flow 4 of the feed air is recompressed in a third after-compressor 26 with aftercooler 27 to a fourth pressure of for example 7.5 to 11 bar, preferably 8 to 9 bar and fed via line 28 to the main heat exchanger 6.
  • a fourth intermediate temperature of the cooled third partial stream 29 is fed to a second expansion machine 30 and there labor to a pressure of, for example, 1.3 to 1.8 bar, preferably 1.3 to 1.6 bar relaxed.
  • the working expanded third partial stream 31 is fed together with the first partial flow 9 via line 10 of the low-pressure column 12.
  • the second expansion machine 30 is mechanically coupled to the third post-compressor 26 and drives it. Both expansion machines are preferably designed as a turboexpander and relax to about the pressure of the low-pressure column (injection turbines).
  • the fourth partial stream 5 of the feed air flows through the main heat exchanger 6 at approximately the first pressure and is fed in gaseous form to the sump of the high-pressure column 11 via line 32.
  • Liquid raw oxygen 33 is cooled in the subcooling countercurrent 23 and fed via line 34 and throttle valve 35 into the low pressure column 12.
  • a portion of the top gas of the high pressure column 11 is withdrawn via line 36, heated in the main heat exchanger 6 to about ambient temperature and finally withdrawn at 37 as gaseous medium pressure nitrogen product.
  • the rest of the overhead gas is condensed in the main condenser 13.
  • the liquid nitrogen 38 thus obtained is fed to a first part 39 via the subcooling countercurrent 23, a line 40 and a throttle valve 41 as reflux to the top of the low pressure column 12.
  • a second part serves as reflux in the high pressure column 11.
  • a third part 42 is brought in a nitrogen pump 43 in the liquid state to an elevated pressure of for example 10 to 50 bar, preferably 10 to 15 bar, passed via line 44 to the main heat exchanger 6 and there vaporized or pseudo-evaporated under this increased pressure by indirect heat exchange with feed air and warmed to about ambient temperature. He leaves the plant via line 45 as gaseous pressure nitrogen product.
  • liquid oxygen 46 is withdrawn, brought in an oxygen pump 47 in the liquid state to an elevated pressure of for example 10 to 50 bar, preferably 12 to 40 bar, passed via line 48 to the main heat exchanger 6 and there under this increased pressure indirect heat exchange with feed air evaporated or pseudo-evaporated and warmed to about ambient temperature. He leaves the plant via line 49 as gaseous pressure oxygen product.
  • gaseous nitrogen 50 is withdrawn and warmed in the supercooling countercurrent 23 and in the main heat exchanger 6.
  • the warm pressureless nitrogen 51 can be used as a product, discarded and / or used in the system as a regeneration gas in the cleaning device, not shown, and / or as a dry gas in an evaporative cooler for cooling of cooling water.
  • FIG. 2 is different from this FIG. 1 in that the discharge pressure of the second expansion machine 130 is higher, namely at the level of the operating pressure of the high-pressure column 11. Consequently, the work-performing relaxed third partial stream 131 is here combined with the cold fourth partial stream and fed via line 132 of the high-pressure column 11.
  • liquid products are obtained by withdrawing a portion 136 of the liquid oxygen from the bottom of the low-pressure column 12 as liquid oxygen product (LOX) and a portion of the liquid nitrogen 142a, 142b produced in the main condenser 13 as liquid nitrogen product (LIN).
  • LOX liquid oxygen product
  • LIN liquid nitrogen product
  • Return liquid 139-140-141 for the low-pressure column 12 is taken from the high-pressure column 11 here at an intermediate point.
  • the procedure of FIG. 3 differs from FIG. 1 in that the first, the second and the third partial flow are first jointly recompressed (203) in a fourth after-compressor 214 with aftercooler 215 to an intermediate pressure.
  • the boosters 214 and 14 can be formed by different stages of the same machine.
  • second pressure first expansion machine 8
  • intermediate pressure intermediate pressure
  • the liquid product removal takes place analogously to FIG. 2 from the bottom of the low-pressure column 12 (LOX with a purity of 99.5% via lines 146a, 146b and / or LIN via lines 142a, 142b).
  • Return liquid 139-140 -141 for the low-pressure column 12 is taken from the high-pressure column 11 here at an intermediate point.
  • the inner-to-be-compressed liquid oxygen 46 is withdrawn at a lower purity of about 95% from an intermediate point of the low-pressure column 12.
  • a second, purer oxygen product 346, 348, 349 can be recovered by internal compression (second oxygen pump 347). Because of the pure oxygen production, the air pressure must be slightly higher than in the above-described embodiments. It is for example 6 to 7.5 bar, preferably 6 to 7 bar.
  • FIG. 4 combines the airflow of the FIG. 2 with the product removal of the FIG. 3 ,

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • General Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Separation By Low-Temperature Treatments (AREA)
EP08012052A 2007-07-07 2008-07-03 Procédé pour la séparation cryogénique d'air Withdrawn EP2015012A3 (fr)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102007031765A DE102007031765A1 (de) 2007-07-07 2007-07-07 Verfahren zur Tieftemperaturzerlegung von Luft

Publications (2)

Publication Number Publication Date
EP2015012A2 true EP2015012A2 (fr) 2009-01-14
EP2015012A3 EP2015012A3 (fr) 2012-08-22

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EP08012052A Withdrawn EP2015012A3 (fr) 2007-07-07 2008-07-03 Procédé pour la séparation cryogénique d'air

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US (1) US20090064714A1 (fr)
EP (1) EP2015012A3 (fr)
DE (1) DE102007031765A1 (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2458311A1 (fr) 2010-11-25 2012-05-30 Linde Aktiengesellschaft Procédé et dispositif de production d'un produit d'impression gazeux par décomposition à basse température d'air
DE102010052544A1 (de) 2010-11-25 2012-05-31 Linde Ag Verfahren zur Gewinnung eines gasförmigen Druckprodukts durch Tieftemperaturzerlegung von Luft
EP2520886A1 (fr) 2011-05-05 2012-11-07 Linde AG Procédé et dispositif de production d'un produit comprimé à oxygène gazeux par décomposition à basse température d'air
EP2568242A1 (fr) 2011-09-08 2013-03-13 Linde Aktiengesellschaft Procédé et dispositif destinés à la production d'acier
EP2600090A1 (fr) 2011-12-01 2013-06-05 Linde Aktiengesellschaft Procédé et dispositif destinés à la production d'oxygène sous pression par décomposition à basse température de l'air
DE102011121314A1 (de) 2011-12-16 2013-06-20 Linde Aktiengesellschaft Verfahren zur Erzeugung eines gasförmigen Sauerstoff-Druckprodukts durch Tieftemperaturzerlegung von Luft
DE102012017488A1 (de) 2012-09-04 2014-03-06 Linde Aktiengesellschaft Verfahren zur Erstellung einer Luftzerlegungsanlage, Luftzerlegungsanlage und zugehöriges Betriebsverfahren
EP2784420A1 (fr) 2013-03-26 2014-10-01 Linde Aktiengesellschaft Procédé de séparation de l'air et installation de séparation de l'air
WO2014154339A2 (fr) 2013-03-26 2014-10-02 Linde Aktiengesellschaft Procédé de séparation d'air et installation de séparation d'air
EP2801777A1 (fr) 2013-05-08 2014-11-12 Linde Aktiengesellschaft Installation de décomposition de l'air dotée d'un entraînement de compresseur principal
FR3010778A1 (fr) * 2013-09-17 2015-03-20 Air Liquide Procede et appareil de production d'oxygene gazeux par distillation cryogenique de l'air
EP2963370A1 (fr) 2014-07-05 2016-01-06 Linde Aktiengesellschaft Procede et dispositif cryogeniques de separation d'air
EP2963371A1 (fr) 2014-07-05 2016-01-06 Linde Aktiengesellschaft Procede et dispositif de production d'un produit de gaz sous pression par decomposition a basse temperature d'air
EP2963369A1 (fr) 2014-07-05 2016-01-06 Linde Aktiengesellschaft Procede et dispositif cryogeniques de separation d'air
EP2963367A1 (fr) 2014-07-05 2016-01-06 Linde Aktiengesellschaft Procédé et dispositif cryogéniques de séparation d'air avec consommation d'énergie variable

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8726691B2 (en) * 2009-01-30 2014-05-20 Praxair Technology, Inc. Air separation apparatus and method
FR2943408A1 (fr) * 2009-03-17 2010-09-24 Air Liquide Procede et installation de separation d'air par distillation cryogenique
US20150114037A1 (en) * 2013-10-25 2015-04-30 Neil M. Prosser Air separation method and apparatus
EP2980514A1 (fr) * 2014-07-31 2016-02-03 Linde Aktiengesellschaft Procédé de séparation cryogénique de l'air et installation de séparation d'air
CN110553465B (zh) * 2019-09-29 2024-04-12 杭州中泰深冷技术股份有限公司 一种pdh分离系统联产燃料电池车用氢气装置及工艺

Citations (49)

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DE830805C (de) 1944-11-19 1952-02-07 Linde Eismasch Ag Verfahren zur Gas-, insbesondere zur Luftzerlegung
DE901542C (de) 1952-01-10 1954-01-11 Linde Eismasch Ag Verfahren zur Zerlegung von Luft durch Verfluessigung und Rektifikation
US2712738A (en) 1952-01-10 1955-07-12 Linde S Eismaschinen Ag Method for fractionating air by liquefaction and rectification
DE952908C (de) 1953-10-11 1956-11-22 Linde Eismasch Ag Verfahren zur Zerlegung von Luft
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EP2963370A1 (fr) 2014-07-05 2016-01-06 Linde Aktiengesellschaft Procede et dispositif cryogeniques de separation d'air
EP2963371A1 (fr) 2014-07-05 2016-01-06 Linde Aktiengesellschaft Procede et dispositif de production d'un produit de gaz sous pression par decomposition a basse temperature d'air
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WO2016005031A1 (fr) 2014-07-05 2016-01-14 Linde Aktiengesellschaft Procédé et dispositif de fractionnement de l'air à basse température à consommation d'énergie variable

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