EP2015012A2 - Procédé pour la séparation cryogénique d'air - Google Patents
Procédé pour la séparation cryogénique d'air Download PDFInfo
- Publication number
- EP2015012A2 EP2015012A2 EP08012052A EP08012052A EP2015012A2 EP 2015012 A2 EP2015012 A2 EP 2015012A2 EP 08012052 A EP08012052 A EP 08012052A EP 08012052 A EP08012052 A EP 08012052A EP 2015012 A2 EP2015012 A2 EP 2015012A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- pressure
- compressor
- column
- air
- feed air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000000926 separation method Methods 0.000 title claims description 6
- 239000000047 product Substances 0.000 claims abstract description 13
- 238000004821 distillation Methods 0.000 claims abstract description 10
- 239000012263 liquid product Substances 0.000 claims abstract description 8
- 238000004140 cleaning Methods 0.000 claims abstract description 6
- 238000001704 evaporation Methods 0.000 claims abstract description 6
- 239000007788 liquid Substances 0.000 claims description 13
- 238000007906 compression Methods 0.000 claims description 4
- 230000006835 compression Effects 0.000 claims description 3
- 230000008020 evaporation Effects 0.000 claims 2
- 230000008016 vaporization Effects 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000007789 gas Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- DOTMOQHOJINYBL-UHFFFAOYSA-N molecular nitrogen;molecular oxygen Chemical compound N#N.O=O DOTMOQHOJINYBL-UHFFFAOYSA-N 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 206010016352 Feeling of relaxation Diseases 0.000 description 1
- 241000883306 Huso huso Species 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- PDEXVOWZLSWEJB-UHFFFAOYSA-N krypton xenon Chemical compound [Kr].[Xe] PDEXVOWZLSWEJB-UHFFFAOYSA-N 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 150000002835 noble gases Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04048—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams
- F25J3/04054—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of cold gaseous streams, e.g. intermediate or oxygen enriched (waste) streams of air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/04084—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of nitrogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04303—Lachmann expansion, i.e. expanded into oxygen producing or low pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04393—Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/50—Oxygen or special cases, e.g. isotope-mixtures or low purity O2
- F25J2215/52—Oxygen production with multiple purity O2
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2215/00—Processes characterised by the type or other details of the product stream
- F25J2215/50—Oxygen or special cases, e.g. isotope-mixtures or low purity O2
- F25J2215/54—Oxygen production with multiple pressure O2
Definitions
- the invention relates to a method by cryogenic separation of air, in particular for the production of gaseous pressure oxygen.
- the distillation column system of the invention may be designed as a two-column system (for example as a classic Linde double column system), or as a three-column or multi-column system.
- other devices may be provided to recover other air components, particularly noble gases, such as argon or krypton-xenon recovery.
- the invention relates to a process in which at least one gaseous pressure product is recovered by withdrawing a liquid product stream from the nitrogen-oxygen separation distillation column system, raising it to an elevated pressure in the liquid state, and evaporating it under this increased pressure by indirect heat exchange or (at supercritical pressure) is pseudo-evaporated.
- Such internal compression methods are known, for example DE 830805 .
- EP 1139046 A1 EP 1146301 A1 .
- EP 1150082 A1 EP 1213552 A1 .
- EP 1357342 A1 or DE 10238282 A1
- the invention has for its object to make such a method and a corresponding device economically particularly favorable.
- the drive of the cold compressor through the first expansion machine is particularly energetically particularly favorable.
- the feed air has a pressure potential which would create more refrigeration in the expansion machine (s) than can be used in the process.
- the excess energy is used in the invention for driving the cold compressor, which brings the second partial flow of the feed air to a particularly high pressure.
- the method has a second expansion machine, in which a third partial flow of the feed air is expanded to perform work.
- the outlet pressure of the second expansion machine is, for example, approximately at the level of the low-pressure column or the high-pressure column. Depending on the relaxed air is introduced into the low pressure column or in the high pressure column.
- atmospheric air is compressed in a main air compressor to a first pressure of for example 5 to 7.5 bar, preferably 5.5 to 6 bar and then cleaned in a cleaning device (not shown).
- the purified feed air 1 is divided at about the first pressure on four partial streams 2, 3, 4, 5.
- the first partial stream 2 is supplied to the warm end of a main heat exchanger 6, cooled there to a first intermediate temperature, removed again via line 7 and working in a first expansion machine 8 to a pressure of, for example, 1.3 to 1.8 bar, preferably 1.3 relaxed to 1.6 bar.
- the work-performing relaxed first partial stream is introduced via lines 9 and 10 in the low-pressure column 12 of a distillation column system, which also has a high-pressure column 11 and a main capacitor 13.
- the second partial stream 3 of the feed air is recompressed in a first secondary compressor 14 to a second pressure of for example 29 to 60 bar, preferably 35 to 50 bar and flows after cooling in an aftercooler 15 via line 16 also to the warm end of the main heat exchanger 6.
- a second intermediate temperature the second partial flow is withdrawn via line 17 and fed to a second after-compressor 18, which is designed as a cold compressor and is mechanically coupled to the first expansion machine 8.
- the outlet pressure of the cold compressor 18 (“third pressure") is for example 40 to 85 bar, preferably 45 to 70 bar.
- Via line 19 the high-pressure air at a third intermediate temperature, which is higher than the first intermediate temperature, introduced into the main heat exchanger 6 and flows through this to the cold end.
- the third substream 19 under the third pressure is cooled in the main heat exchanger and condensed or pseudo-condensed (at supercritical pressure).
- the cold high-pressure air 20 is expanded in a throttle valve 21 to approximately the operating pressure of the high-pressure column 11, which is for example 5 to 7.5 bar, preferably 5.5 to 6 bar, and introduced into the high-pressure column. At least a portion of the introduced liquid air is removed again via line 22, cooled in a subcooling countercurrent 23 and fed via line 24 and throttle valve 25 in the low pressure column 12.
- the third partial flow 4 of the feed air is recompressed in a third after-compressor 26 with aftercooler 27 to a fourth pressure of for example 7.5 to 11 bar, preferably 8 to 9 bar and fed via line 28 to the main heat exchanger 6.
- a fourth intermediate temperature of the cooled third partial stream 29 is fed to a second expansion machine 30 and there labor to a pressure of, for example, 1.3 to 1.8 bar, preferably 1.3 to 1.6 bar relaxed.
- the working expanded third partial stream 31 is fed together with the first partial flow 9 via line 10 of the low-pressure column 12.
- the second expansion machine 30 is mechanically coupled to the third post-compressor 26 and drives it. Both expansion machines are preferably designed as a turboexpander and relax to about the pressure of the low-pressure column (injection turbines).
- the fourth partial stream 5 of the feed air flows through the main heat exchanger 6 at approximately the first pressure and is fed in gaseous form to the sump of the high-pressure column 11 via line 32.
- Liquid raw oxygen 33 is cooled in the subcooling countercurrent 23 and fed via line 34 and throttle valve 35 into the low pressure column 12.
- a portion of the top gas of the high pressure column 11 is withdrawn via line 36, heated in the main heat exchanger 6 to about ambient temperature and finally withdrawn at 37 as gaseous medium pressure nitrogen product.
- the rest of the overhead gas is condensed in the main condenser 13.
- the liquid nitrogen 38 thus obtained is fed to a first part 39 via the subcooling countercurrent 23, a line 40 and a throttle valve 41 as reflux to the top of the low pressure column 12.
- a second part serves as reflux in the high pressure column 11.
- a third part 42 is brought in a nitrogen pump 43 in the liquid state to an elevated pressure of for example 10 to 50 bar, preferably 10 to 15 bar, passed via line 44 to the main heat exchanger 6 and there vaporized or pseudo-evaporated under this increased pressure by indirect heat exchange with feed air and warmed to about ambient temperature. He leaves the plant via line 45 as gaseous pressure nitrogen product.
- liquid oxygen 46 is withdrawn, brought in an oxygen pump 47 in the liquid state to an elevated pressure of for example 10 to 50 bar, preferably 12 to 40 bar, passed via line 48 to the main heat exchanger 6 and there under this increased pressure indirect heat exchange with feed air evaporated or pseudo-evaporated and warmed to about ambient temperature. He leaves the plant via line 49 as gaseous pressure oxygen product.
- gaseous nitrogen 50 is withdrawn and warmed in the supercooling countercurrent 23 and in the main heat exchanger 6.
- the warm pressureless nitrogen 51 can be used as a product, discarded and / or used in the system as a regeneration gas in the cleaning device, not shown, and / or as a dry gas in an evaporative cooler for cooling of cooling water.
- FIG. 2 is different from this FIG. 1 in that the discharge pressure of the second expansion machine 130 is higher, namely at the level of the operating pressure of the high-pressure column 11. Consequently, the work-performing relaxed third partial stream 131 is here combined with the cold fourth partial stream and fed via line 132 of the high-pressure column 11.
- liquid products are obtained by withdrawing a portion 136 of the liquid oxygen from the bottom of the low-pressure column 12 as liquid oxygen product (LOX) and a portion of the liquid nitrogen 142a, 142b produced in the main condenser 13 as liquid nitrogen product (LIN).
- LOX liquid oxygen product
- LIN liquid nitrogen product
- Return liquid 139-140-141 for the low-pressure column 12 is taken from the high-pressure column 11 here at an intermediate point.
- the procedure of FIG. 3 differs from FIG. 1 in that the first, the second and the third partial flow are first jointly recompressed (203) in a fourth after-compressor 214 with aftercooler 215 to an intermediate pressure.
- the boosters 214 and 14 can be formed by different stages of the same machine.
- second pressure first expansion machine 8
- intermediate pressure intermediate pressure
- the liquid product removal takes place analogously to FIG. 2 from the bottom of the low-pressure column 12 (LOX with a purity of 99.5% via lines 146a, 146b and / or LIN via lines 142a, 142b).
- Return liquid 139-140 -141 for the low-pressure column 12 is taken from the high-pressure column 11 here at an intermediate point.
- the inner-to-be-compressed liquid oxygen 46 is withdrawn at a lower purity of about 95% from an intermediate point of the low-pressure column 12.
- a second, purer oxygen product 346, 348, 349 can be recovered by internal compression (second oxygen pump 347). Because of the pure oxygen production, the air pressure must be slightly higher than in the above-described embodiments. It is for example 6 to 7.5 bar, preferably 6 to 7 bar.
- FIG. 4 combines the airflow of the FIG. 2 with the product removal of the FIG. 3 ,
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007031765A DE102007031765A1 (de) | 2007-07-07 | 2007-07-07 | Verfahren zur Tieftemperaturzerlegung von Luft |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2015012A2 true EP2015012A2 (fr) | 2009-01-14 |
| EP2015012A3 EP2015012A3 (fr) | 2012-08-22 |
Family
ID=39828943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP08012052A Withdrawn EP2015012A3 (fr) | 2007-07-07 | 2008-07-03 | Procédé pour la séparation cryogénique d'air |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US20090064714A1 (fr) |
| EP (1) | EP2015012A3 (fr) |
| DE (1) | DE102007031765A1 (fr) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2458311A1 (fr) | 2010-11-25 | 2012-05-30 | Linde Aktiengesellschaft | Procédé et dispositif de production d'un produit d'impression gazeux par décomposition à basse température d'air |
| DE102010052544A1 (de) | 2010-11-25 | 2012-05-31 | Linde Ag | Verfahren zur Gewinnung eines gasförmigen Druckprodukts durch Tieftemperaturzerlegung von Luft |
| EP2520886A1 (fr) | 2011-05-05 | 2012-11-07 | Linde AG | Procédé et dispositif de production d'un produit comprimé à oxygène gazeux par décomposition à basse température d'air |
| EP2568242A1 (fr) | 2011-09-08 | 2013-03-13 | Linde Aktiengesellschaft | Procédé et dispositif destinés à la production d'acier |
| EP2600090A1 (fr) | 2011-12-01 | 2013-06-05 | Linde Aktiengesellschaft | Procédé et dispositif destinés à la production d'oxygène sous pression par décomposition à basse température de l'air |
| DE102011121314A1 (de) | 2011-12-16 | 2013-06-20 | Linde Aktiengesellschaft | Verfahren zur Erzeugung eines gasförmigen Sauerstoff-Druckprodukts durch Tieftemperaturzerlegung von Luft |
| DE102012017488A1 (de) | 2012-09-04 | 2014-03-06 | Linde Aktiengesellschaft | Verfahren zur Erstellung einer Luftzerlegungsanlage, Luftzerlegungsanlage und zugehöriges Betriebsverfahren |
| EP2784420A1 (fr) | 2013-03-26 | 2014-10-01 | Linde Aktiengesellschaft | Procédé de séparation de l'air et installation de séparation de l'air |
| WO2014154339A2 (fr) | 2013-03-26 | 2014-10-02 | Linde Aktiengesellschaft | Procédé de séparation d'air et installation de séparation d'air |
| EP2801777A1 (fr) | 2013-05-08 | 2014-11-12 | Linde Aktiengesellschaft | Installation de décomposition de l'air dotée d'un entraînement de compresseur principal |
| FR3010778A1 (fr) * | 2013-09-17 | 2015-03-20 | Air Liquide | Procede et appareil de production d'oxygene gazeux par distillation cryogenique de l'air |
| EP2963370A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procede et dispositif cryogeniques de separation d'air |
| EP2963371A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procede et dispositif de production d'un produit de gaz sous pression par decomposition a basse temperature d'air |
| EP2963369A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procede et dispositif cryogeniques de separation d'air |
| EP2963367A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procédé et dispositif cryogéniques de séparation d'air avec consommation d'énergie variable |
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|---|---|---|---|---|
| US8726691B2 (en) * | 2009-01-30 | 2014-05-20 | Praxair Technology, Inc. | Air separation apparatus and method |
| FR2943408A1 (fr) * | 2009-03-17 | 2010-09-24 | Air Liquide | Procede et installation de separation d'air par distillation cryogenique |
| US20150114037A1 (en) * | 2013-10-25 | 2015-04-30 | Neil M. Prosser | Air separation method and apparatus |
| EP2980514A1 (fr) * | 2014-07-31 | 2016-02-03 | Linde Aktiengesellschaft | Procédé de séparation cryogénique de l'air et installation de séparation d'air |
| CN110553465B (zh) * | 2019-09-29 | 2024-04-12 | 杭州中泰深冷技术股份有限公司 | 一种pdh分离系统联产燃料电池车用氢气装置及工艺 |
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| EP2458311A1 (fr) | 2010-11-25 | 2012-05-30 | Linde Aktiengesellschaft | Procédé et dispositif de production d'un produit d'impression gazeux par décomposition à basse température d'air |
| DE102010052545A1 (de) | 2010-11-25 | 2012-05-31 | Linde Aktiengesellschaft | Verfahren und Vorrichtung zur Gewinnung eines gasförmigen Druckprodukts durch Tieftemperaturzerlegung von Luft |
| DE102010052544A1 (de) | 2010-11-25 | 2012-05-31 | Linde Ag | Verfahren zur Gewinnung eines gasförmigen Druckprodukts durch Tieftemperaturzerlegung von Luft |
| EP2466236A1 (fr) | 2010-11-25 | 2012-06-20 | Linde Aktiengesellschaft | Procédé de production d'un produit d'impression gazeux par décomposition à basse température de l'air |
| EP2520886A1 (fr) | 2011-05-05 | 2012-11-07 | Linde AG | Procédé et dispositif de production d'un produit comprimé à oxygène gazeux par décomposition à basse température d'air |
| EP2568242A1 (fr) | 2011-09-08 | 2013-03-13 | Linde Aktiengesellschaft | Procédé et dispositif destinés à la production d'acier |
| DE102011112909A1 (de) | 2011-09-08 | 2013-03-14 | Linde Aktiengesellschaft | Verfahren und Vorrichtung zur Gewinnung von Stahl |
| EP2600090A1 (fr) | 2011-12-01 | 2013-06-05 | Linde Aktiengesellschaft | Procédé et dispositif destinés à la production d'oxygène sous pression par décomposition à basse température de l'air |
| DE102011121314A1 (de) | 2011-12-16 | 2013-06-20 | Linde Aktiengesellschaft | Verfahren zur Erzeugung eines gasförmigen Sauerstoff-Druckprodukts durch Tieftemperaturzerlegung von Luft |
| DE102012017488A1 (de) | 2012-09-04 | 2014-03-06 | Linde Aktiengesellschaft | Verfahren zur Erstellung einer Luftzerlegungsanlage, Luftzerlegungsanlage und zugehöriges Betriebsverfahren |
| EP2784420A1 (fr) | 2013-03-26 | 2014-10-01 | Linde Aktiengesellschaft | Procédé de séparation de l'air et installation de séparation de l'air |
| WO2014154339A2 (fr) | 2013-03-26 | 2014-10-02 | Linde Aktiengesellschaft | Procédé de séparation d'air et installation de séparation d'air |
| EP2801777A1 (fr) | 2013-05-08 | 2014-11-12 | Linde Aktiengesellschaft | Installation de décomposition de l'air dotée d'un entraînement de compresseur principal |
| FR3010778A1 (fr) * | 2013-09-17 | 2015-03-20 | Air Liquide | Procede et appareil de production d'oxygene gazeux par distillation cryogenique de l'air |
| WO2015040306A3 (fr) * | 2013-09-17 | 2015-06-11 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procédé et appareil de production d'oxygène gazeux par distillation cryogénique de l'air |
| US9976803B2 (en) | 2013-09-17 | 2018-05-22 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitattion Des Procedes Georges Claude | Process and apparatus for producing gaseous oxygen by cryogenic distillation of air |
| EP2963370A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procede et dispositif cryogeniques de separation d'air |
| EP2963371A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procede et dispositif de production d'un produit de gaz sous pression par decomposition a basse temperature d'air |
| EP2963369A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procede et dispositif cryogeniques de separation d'air |
| EP2963367A1 (fr) | 2014-07-05 | 2016-01-06 | Linde Aktiengesellschaft | Procédé et dispositif cryogéniques de séparation d'air avec consommation d'énergie variable |
| WO2016005031A1 (fr) | 2014-07-05 | 2016-01-14 | Linde Aktiengesellschaft | Procédé et dispositif de fractionnement de l'air à basse température à consommation d'énergie variable |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2015012A3 (fr) | 2012-08-22 |
| DE102007031765A1 (de) | 2009-01-08 |
| US20090064714A1 (en) | 2009-03-12 |
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