EP2257192A2 - Dispositif et procede de refroidissement ou surgelation par jets impactants de produits alimentaires - Google Patents
Dispositif et procede de refroidissement ou surgelation par jets impactants de produits alimentairesInfo
- Publication number
- EP2257192A2 EP2257192A2 EP09721880A EP09721880A EP2257192A2 EP 2257192 A2 EP2257192 A2 EP 2257192A2 EP 09721880 A EP09721880 A EP 09721880A EP 09721880 A EP09721880 A EP 09721880A EP 2257192 A2 EP2257192 A2 EP 2257192A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- plate
- pressure
- cooling
- fluid
- orifices
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 235000013305 food Nutrition 0.000 title claims abstract description 27
- 238000007710 freezing Methods 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 19
- 230000003116 impacting effect Effects 0.000 title claims abstract description 11
- 239000012530 fluid Substances 0.000 claims abstract description 60
- 238000001816 cooling Methods 0.000 claims abstract description 54
- 230000008014 freezing Effects 0.000 claims description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 8
- 238000007664 blowing Methods 0.000 claims description 8
- 239000003570 air Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001569 carbon dioxide Substances 0.000 claims description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000007789 gas Substances 0.000 description 7
- 238000010586 diagram Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 241000219793 Trifolium Species 0.000 description 1
- 235000015241 bacon Nutrition 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007257 malfunction Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 235000013550 pizza Nutrition 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D13/00—Stationary devices, e.g. cold-rooms
- F25D13/06—Stationary devices, e.g. cold-rooms with conveyors carrying articles to be cooled through the cooling space
- F25D13/067—Stationary devices, e.g. cold-rooms with conveyors carrying articles to be cooled through the cooling space with circulation of gaseous cooling fluid
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/80—Freezing; Subsequent thawing; Cooling
- A23B2/803—Materials being transported through or in the apparatus, with or without shaping, e.g. in the form of powders, granules or flakes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23B—PRESERVATION OF FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES; CHEMICAL RIPENING OF FRUIT OR VEGETABLES
- A23B2/00—Preservation of foods or foodstuffs, in general
- A23B2/80—Freezing; Subsequent thawing; Cooling
- A23B2/85—Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals
- A23B2/88—Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals with direct contact between the food and the chemical, e.g. liquid N2 at cryogenic temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D3/00—Devices using other cold materials; Devices using cold-storage bodies
- F25D3/10—Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air
- F25D3/11—Devices using other cold materials; Devices using cold-storage bodies using liquefied gases, e.g. liquid air with conveyors carrying articles to be cooled through the cooling space
Definitions
- the present invention relates to industrial devices and methods for cooling or freezing food products.
- the cooling of food products generally takes place through a convective exchange between a cold gas and the products.
- the use of cryogenic fluids and fans is already known to industrialists who wish to carry out freezing of food.
- a freezing or cooling technology is based on the fact that the products are cooled more rapidly if they are subjected to impacting jets of a cryogenic fluid. These impacting jets are created by overpressure above a perforated plate inducing an increase in the speed of the fluid at the holes of the plate. These devices are translated on an industrial scale by tunnels in which the overpressure above a perforated plate is generated by means for circulating the gas, for example a centrifugal fan, located above the carpet where the food products to cool.
- the presence of moisture in the enclosure where the cooling takes place leads to the formation of frost and snow deposits in the case where the temperature of the cold gas is less than 0 ° C. In cryogenic tunnels, the temperature can reach -130 0 C.
- the moisture comes from the products which are partially dehydrated and possibly by the presence of moist air mixing with the cold gas, especially in the case of open equipment as are the tunnels.
- EP-1 621 830 is envisaged a means of remedying the icing phenomenon by the use of mechanical vibrations using a vibrator mounted on the plate having the orifices.
- Other authors use heating systems to periodically defrost frosted surfaces.
- the present invention aims to provide a device and a method for cooling food products equipped with means for preventing clogging by frost formation at the orifices forming impacting jets without the use of mechanical vibration or heating.
- the invention proposes a device for cooling food products by impacting jets consisting of a tunnel comprising
- a movable carpet at least one plate, located opposite (above or below said movable belt), and provided with through orifices, according to one of the preferred embodiments at least two plates, a top plate; and a lower plate, located parallel to each other on either side of said moving belt, at least one, preferably both, being provided with through holes,
- At least one means for blowing a cold fluid comprising
- a zone under pressure P2 between the plate (s) and the moving belt the pressure P1 being greater than the pressure P2, characterized in that it comprises means for varying the pressure in the pressure zone P1 and / or means for cooling and maintaining the temperature of the plate or plates to a temperature below about -80 ° C., preferably below -80 ° C.
- the cold fluid can be cold air obtained by mechanical cold or a cryogenic fluid.
- the cold fluid is a cryogenic fluid selected from the group comprising in particular nitrogen, carbon dioxide, oxygen, or air and mixtures thereof.
- the cooling device according to the invention is preferably a freezing device for food products. Freezing is a means of freezing foods very fast. Freezing is, for the purpose of the present invention, a very rapid freezing of food. This technique is preferably used on an industrial scale when the food is flat or small, such as chopped steaks, pizzas or bacon. Indeed, the exchange surface of such foods is large, with a small thickness, which promotes rapid freezing.
- the plate (s) with (or) through orifices are advantageously made of food grade stainless steel. These plates are tiltable and removable to facilitate cleaning after operation.
- the through orifices of the plate may be of varied shape and in particular in the form of cylinders, rounds, slots, clovers or cones with chamfered or rounded edges.
- the plates can be flat or 1 V shaped or corrugated.
- the fluid blowing means is a centrifugal fan driven by a motor.
- the means for varying the pressure in the pressure zone P1 and / or the means for cooling and maintaining the temperature of the plate or plates at a temperature below -80 0 C can prevent clogging of the plate orifices by frost formation without making the system more energy-intensive.
- this device is characterized in that the means for cooling and maintaining the temperature of the plate or plates at a temperature below -80 ° C. are chosen from the group comprising a circuit heat exchanger attached to the plate, a plate acting as an exchanger (also called plate-exchanger), a cold fluid bath on the top of the plate (s) and combinations thereof.
- the inventors have found that by lowering the temperature of the plate to a temperature below -80 ° C, the ice crystals do not adhere to the edges of the orifices, thereby preventing their clogging.
- These cooling means are economical. Indeed, when the cooling of the plates is effected by means of an exchanger, and according to a preferred embodiment of the invention, the cryogenic fluid flowing through the exchanger is taken from the supply circuit of the equipment. cooling.
- the cryogenic fluid contributes directly or indirectly to the cooling of the fluid that is in contact with the products.
- the exchanger attached to the plate may be a tube attached to one or both sides of the plate in which circulates a cold fluid.
- the exchangers preferably have a shape that allows them to pass as close to a maximum number of orifices, and thus promote the cooling of the plate around a maximum of orifices.
- the exchanger attached to the plate has one or more passes necessary for cooling a maximum of through holes.
- Another embodiment is to use a good heat-conducting material which would constitute the plate or would contact the plate so as to cool the edge of the orifices. This material would be cooled locally by a cooling circuit.
- this exchanger attached to the plate has a shape and a connection to the plate such that the heat exchange is favored.
- the cooling of the plate is best performed at the through holes and for a maximum of orifices.
- the heat exchanger plate may be formed by a double plate baffled or not, for a better distribution of the cold fluid.
- baffles makes it possible to prevent the fluid from taking preferential paths, and thus promotes the cooling of a maximum number of orifices.
- the plate is provided with sufficiently high edges, of tubular orifices and means for regulating the level of the bath.
- a device can prevent any overflow of the cold fluid through the through holes and on the edges of the plate.
- the device can be designed in such a way that the fluid which is stirred within the pressurized zone P1 is cooled at the single contact of the cold plate.
- the fluid arrives in the pressure zone P1 at an ambient temperature T1 and cools at a temperature T2 during its passage through the through orifices of the plate, which is at a temperature T3 of less than -80 ° C. C, T2 being between T1 and T3.
- the means for cooling the fluid can be the cooling means of the plate.
- the means for cooling and maintaining the plate at a temperature below -80 ° C have the advantage that they are easy to implement, especially on existing cooling devices and inexpensive because it is sufficient for humans of the trade to interchange conventional perforated plates with perforated plates with heat exchangers.
- the device is characterized in that the means for varying the pressure are selected from the group comprising frequency converters, and pressurized reservoir balloons.
- the variation of the pressure in the pressure zone P1 can be caused, according to a particular embodiment of the invention, by the variation of the blowing flow rate of the centrifugal fan. If the blower flow rate of the centrifugal fan increases, the pressure in the pressure zone P1 increases. In this case, to obtain a variation of the pressure in the pressure zone P1, the speed of the motor driving the centrifugal fan is varied in controlled proportions.
- Another way of generating a variation of the pressure in the pressure zone P1 is to intermittently supply an additional quantity of pressurized fluid to the pressure zone P1.
- This fluid can come from a pressure tank connected to the pressure zone P1 by means of releasing the pressure of the reservoir which are for example valves, or valves. The opening and closing of these release means are controlled so as to generate the desired pressure variation in the pressure zone P1.
- the present invention also proposes a method of cooling by impacting jets of food products in which
- the fluid is forced to pass through orifices of a plate and to impact the food product to be cooled, characterized in that the temperature of the plate is maintained at a temperature below about -80 ° C., preferably below - 90 0 C and more preferably still less than -100 0 C and / or that the pressure P1 of said fluid is varied as a function of time.
- the cold fluid is a cryogenic fluid selected from the group comprising in particular nitrogen, carbon dioxide, oxygen, air and mixtures thereof.
- the cooling method of the invention is a freezing process.
- the variation of the pressure P1 is preferably short and of low amplitude, which has the advantage of being inexpensive in energy and of not requiring any major modification in the cooling device.
- the pressure variation is a square-wave sequence whose amplitude is a pressure difference ⁇ P between a normal operating value and a chosen setpoint value lower or higher than the normal value, said pressure difference ⁇ P being between 10 and 1000 Pa, in particular between 200 and 800 Pa and preferably between 400 and 600 Pa, and whose duration during which the variation of the pressure is applied ⁇ t is between 1 and 60s, in particular between 2 and 30s and preferably between 5 and 15s.
- the method of the invention is preferably implemented with the device described above. This pressure variation can be achieved by varying the flow rate of the cold fluid into the zone P1 of the device.
- This pressure variation can thus be induced by the brief and sudden release of pressure from a pressurized flask connected to the pressure zone P1.
- This release of pressure occurs when opening a release means such as a valve, or a valve.
- the opening and closing of this pressure release means can be automated.
- the method according to the invention has the advantageous characteristic of being able to be applied to existing cooling or freezing devices.
- FIG. 1 is a sectional view of a cooling tunnel
- FIG. 2 is a picture of the underside of a lower plate after operation of the cooling device according to example 1
- FIG. 3 is a diagram of a cooling device. Part 4 of the plate used in Example 2
- Figure 4 is a picture of the top of the bottom plate after operation of the device according to Example 2
- Figure 5 is an operating chart diagram used in Example 3.
- FIG. 6 is a photo of the top of the top plate after operation according to example 3
- FIGS. 7a, 7b, 8, 9a and 9b are diagrams of cooling means of the plate according to particular embodiments of the invention. 'invention.
- FIG. 1 is a cross-sectional view of an impact jet cooling device according to the prior art.
- This device consists of a tunnel 1 within which is disposed a movable belt 2 which allows to move food to freeze or cool, which are arranged on it, from one end to the other of said tunnel 1.
- a movable belt 2 which allows to move food to freeze or cool, which are arranged on it, from one end to the other of said tunnel 1.
- plates 3 Parallel and on both sides of said moving belt, plates 3 are present. These plates 3 have through holes 4 allowing the passage of a fluid.
- Two zones can be distinguished.
- the first, 5, called pressure zone P1 is delimited by the walls of the tunnel 1, the top of the upper plate 3a, the underside of the lower plate 3b and the separating elements of the pressure zones 6.
- the second zone, 7 is called pressure zone P2 and is delimited by the walls of the tunnel 1, the underside of the upper plate 3a, the top of the lower plate 3b and the separating elements 6.
- a centrifugal fan 8 In the upper part of the tunnel 1 and within the pressurized zone P1 5 is placed a centrifugal fan 8. Its role is to perform the blowing of the fluid within the pressure zone P1 5.
- the centrifugal fan is driven by a motor 9 positioned with preferably out of tunnel 1.
- a cold fluid inlet 10 is provided in the pressure zone P15.
- the cold fluid which is supplied by the cold fluid inlet 10
- the blowing means centrifugal fan 8 and motor 9
- This blowing generates a pressure P1 in the pressure zone P1 5 which will force the cold fluid through the through holes 4 of the plates 3 with a relatively high speed.
- the fluid is in the form of impacting jets that will impact the food placed on the moving carpet 2.
- the cold fluid that has impacted the food on the moving carpet escapes through the pressure zone P2 7 which is open to the outside. It is understood that P1 is greater than P2 during operation of the device and P1 is equal to P2 when the device is not running. If the tunnel 1 is in a room under atmospheric pressure, then P2 is also the atmospheric pressure.
- the invention proposes to add to the known device for cooling food, means for preventing such clogging.
- FIG. 3 shows a diagram of an exchanger 1 1 attached to a plate 3 in order to maintain the temperature, at the through orifices 4, of less than -80 ° C.
- This exchanger 11 is provided with a cold fluid inlet 12 and a cold fluid outlet 13. In order to optimize the heat exchange, the exchanger 11 performs several passes 14.
- FIG. 7a and 7b show other patterns of exchanger devices reported to a plate.
- the cold fluid is circulated near the through holes 4 of the plate 3 in a cold fluid circuit 15.
- FIG. 8 shows another embodiment of the cooling and holding means of the plate at a temperature below -80.degree. C.
- the cold fluid can not pass through the through holes 4.
- FIGS. 9a and 9b A third embodiment of the means for cooling and maintaining the plate at a temperature below -80 ° C. is illustrated in FIGS. 9a and 9b. These figures are diagrams of an exchanger internal to the plate. This exchanger may be formed by a double plate secured to the through openings 4. A space between the two plates 15 allows the flow of cold fluid which enters through a feed end 12 and exits through a fluid extraction end cold 13.
- Example 1 (comparative): Test of the freezing device without anti-clogging means according to the invention:
- a device as described in FIG. 1 is used in which there is: a moving mat,
- the steam generator is started for about 4 hours from the start of operation.
- the temperature of the tunnel is maintained at -80 ° C.
- the pressure in the pressure zone P1 is measured by means of a manometer or pressure sensor placed at the pressure zone P1 of the lower plate, and variations in the pressure curve indicating a partial blockage of the orifices.
- Example 1 The device of Example 1 is used, which has been modified by fixing an exchanger under the lower plate allowing it to be maintained at a temperature of the order of -100 ° C. to a few centimeters of the exchanger tube during the operation.
- This exchanger which is represented in FIG. 3, consists of two copper tubes of 14 mm diameter, pinned on two times 5 holes, and which are welded on two copper plates, themselves fixed under the lower perforated plate. . Thermal paste ensures better contact.
- the exchanger is traversed by liquid nitrogen at -187 ° C approximately for cooling the plate.
- the orifices cooled by the exchanger are the orifices of the rows 4 and 5 and lines 2 to 6 indexed in FIGS. 3 and 4.
- the steam generator is turned on for the duration of the operation, ie 4 hours.
- the pressure P1 is maintained at 550 Pa and the tunnel temperature at -60 ° C.
- Example 3 Test of the freezing device with the variation of pressure as an anti-clogging means
- Example 1 The device of Example 1 is used and the pressure is varied over time according to the sequence shown in FIG. 5.
- the variation applied is in the form of slots whose amplitude ⁇ P enters a normal value of the pressure.
- PN and a high value of the pressure PH is 500Pa.
- the duration during which the zone under pressure P1 is subjected to the pressure PH is ⁇ t which corresponds to 10s.
- the time between two slots is 5 minutes in Figure 5.
- PN equal to 550 Pa and PH equal to 1330 Pa.
- the tunnel temperature is maintained at -60 ° C.
- the steam generator is operated for the duration of the test, ie 4 hours. After 4 hours of operation, we photograph the top plate seen from above ( Figure 6) and it is observed that snow has accumulated significantly on the plate but all the orifices remained free.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Zoology (AREA)
- Food Science & Technology (AREA)
- Wood Science & Technology (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Freezing, Cooling And Drying Of Foods (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0851590A FR2928520B1 (fr) | 2008-03-12 | 2008-03-12 | Dispositif et procede de refroidissement ou surgelation par jets impactants de produits alimentaires |
| PCT/FR2009/050384 WO2009115754A2 (fr) | 2008-03-12 | 2009-03-10 | Dispositif et procede de refroidissement ou surgelation par jets impactants de produits alimentaires |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP2257192A2 true EP2257192A2 (fr) | 2010-12-08 |
Family
ID=39769492
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP09721880A Withdrawn EP2257192A2 (fr) | 2008-03-12 | 2009-03-10 | Dispositif et procede de refroidissement ou surgelation par jets impactants de produits alimentaires |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20110011097A1 (fr) |
| EP (1) | EP2257192A2 (fr) |
| FR (1) | FR2928520B1 (fr) |
| WO (1) | WO2009115754A2 (fr) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2972608B1 (fr) * | 2011-03-18 | 2015-02-06 | Air Liquide | Equipement de croutage cryogenique de produits alimentaires |
| CN105744842A (zh) | 2013-11-26 | 2016-07-06 | 洲际大品牌有限责任公司 | 用于控制咀嚼型胶基糖的温度的系统和方法 |
| US20180058744A1 (en) * | 2016-09-01 | 2018-03-01 | Michael D. Newman | Method and apparatus for impingement freezing of irregularly shaped products |
| US20180103661A1 (en) * | 2016-10-17 | 2018-04-19 | Michael D. Newman | Apparatus and method for freezer gas control |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9303212D0 (en) * | 1993-02-17 | 1993-03-31 | Air Prod & Chem | Method and apparatus for freezing |
| FR2773393A1 (fr) * | 1998-01-08 | 1999-07-02 | Roger Dew | Tunnel de surgelation de produits alimentaires a film d'entrainement interrompu |
| US6263680B1 (en) * | 2000-01-18 | 2001-07-24 | The Boc Group, Inc. | Modular apparatus for cooling and freezing of food product on a moving substrate |
| DE10148777B4 (de) * | 2001-10-02 | 2019-01-24 | Air Liquide Deutschland Gmbh | Verfahren und Vorrichtung zum Kühlen einer Masse einer Substanz |
-
2008
- 2008-03-12 FR FR0851590A patent/FR2928520B1/fr not_active Expired - Fee Related
-
2009
- 2009-03-10 WO PCT/FR2009/050384 patent/WO2009115754A2/fr not_active Ceased
- 2009-03-10 US US12/922,022 patent/US20110011097A1/en not_active Abandoned
- 2009-03-10 EP EP09721880A patent/EP2257192A2/fr not_active Withdrawn
Non-Patent Citations (1)
| Title |
|---|
| None * |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2928520B1 (fr) | 2014-09-26 |
| WO2009115754A3 (fr) | 2009-11-12 |
| FR2928520A1 (fr) | 2009-09-18 |
| WO2009115754A2 (fr) | 2009-09-24 |
| US20110011097A1 (en) | 2011-01-20 |
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Legal Events
| Date | Code | Title | Description |
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