EP2867352A1 - Produit détergent ou nettoyant liquide hautement concentré - Google Patents

Produit détergent ou nettoyant liquide hautement concentré

Info

Publication number
EP2867352A1
EP2867352A1 EP13730592.6A EP13730592A EP2867352A1 EP 2867352 A1 EP2867352 A1 EP 2867352A1 EP 13730592 A EP13730592 A EP 13730592A EP 2867352 A1 EP2867352 A1 EP 2867352A1
Authority
EP
European Patent Office
Prior art keywords
cleaning agent
washing
water
anionic surfactant
liquid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP13730592.6A
Other languages
German (de)
English (en)
Other versions
EP2867352B1 (fr
Inventor
Frank Meier
Marwa AMRAOUI
Sabine SCHÜMANN
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Original Assignee
Henkel AG and Co KGaA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=48670581&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP2867352(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Henkel AG and Co KGaA filed Critical Henkel AG and Co KGaA
Priority to PL13730592T priority Critical patent/PL2867352T3/pl
Publication of EP2867352A1 publication Critical patent/EP2867352A1/fr
Application granted granted Critical
Publication of EP2867352B1 publication Critical patent/EP2867352B1/fr
Revoked legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/83—Mixtures of non-ionic with anionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043—Liquid or thixotropic (gel) compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention relates to a highly concentrated liquid washing or cleaning agent with anionic and nonionic surfactants.
  • an ultra-concentrated liquid washing or cleaning agent which (a) 25 to 60 wt .-% nonionic surfactant, (b) 5 to 30 wt .-% anionic surfactant, (c) 0.5 bis 18 wt .-% of a cold water dispersing aid and (d) contains up to 60 wt .-% water.
  • Detergents or cleaners are now available to the consumer in a variety of forms.
  • this offer includes, for example, liquids, gels or sachets (tablets or filled pouches).
  • portion packs containing liquid detergents or cleaning agents are becoming increasingly popular, fulfilling, on the one hand, the consumer's desire for simplified dosing and, on the other hand, more and more consumers prefering liquid detergents or cleaners. Again, it is desirable to use highly concentrated detergents or cleaning agents as possible.
  • Detergents > 35 wt% surfactant
  • a high-surfactant optimized surfactant system sometimes have deficiencies in detergency.
  • a liquid washing or cleaning agent comprising:
  • Olefin sulfonates sulfonated estolides, Ci 2 -i 8-alkanesulfonates and mixtures thereof,
  • nonionic surfactant selected from the group consisting of alkoxylated fatty alcohols, alkoxylated oxo alcohols, alkylpolyglycosides and mixtures thereof,
  • anionic surfactant of the sulfate type selected from the group consisting of fatty alcohol sulfates, fatty alcohol ether sulfates and mixtures thereof and
  • phase-stable detergent or cleaning agent can be obtained with good cleaning performance.
  • the washing or cleaning agent has a particularly good cleaning performance and good
  • the ratio of sulfonate-type anionic surfactant to nonionic surfactant be from 1.25: 1 to 1: 1.25. It is also preferred that the ratio of sulfonate anionic surfactant to sulfate type anionic surfactant is greater than 2: 1 and / or that the ratio of nonionic surfactant to sulfate type anionic surfactant be greater than 2: 1.
  • the washing or cleaning agent is packaged in a water-soluble wrapper.
  • Detergents are packaged in the water-soluble wrapper.
  • the water-soluble coating be polyvinyl alcohol or a
  • Water solubility in particular cold water solubility, on.
  • the liquid washing or cleaning agent contains various surfactants.
  • the liquid detergent or cleaning agent contains nonionic surfactant selected from the group consisting of alkoxylated fatty alcohols, alkoxylated oxo alcohols, alkyl polyglycosides, ethoxylated methyl esters of natural fatty acids and mixtures thereof.
  • the alkoxylated fatty alcohols used are preferably ethoxylated, in particular primary, alcohols having preferably 8 to 18 carbon atoms and on average 4 to 12 moles of ethylene oxide (EO) per mole of alcohol, in which the alcohol radical is linear.
  • EO ethylene oxide
  • alcohol ethoxylates having 12 to 18 carbon atoms for example coconut, palm, tallow or oleyl alcohol, and on average 5 to 8 EO per mole of alcohol are preferred.
  • the preferred ethoxylated alcohols include, for example, C 12-14 alcohols with 4 EO or 7 EO, C 9 .
  • the degrees of ethoxylation given represent statistical means which, for a particular product, may be an integer or a fractional number. preferred
  • Alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • NRE narrow rank ethoxylates
  • fatty alcohols containing more than 12 EO can also be used. Examples include tallow fatty alcohol with 14 EO, 25 EO, 30 EO or 40 EO.
  • Alkoxylated fatty alcohols which contain EO and PO groups together in the molecule can also be used according to the invention.
  • Oxo alcohols are primary, partially branched higher alcohols, which are obtained in the oxo synthesis.
  • oxo-aldehydes or their primary aldokondensations may be converted by catalytic hydrogenation in the corresponding oxo alcohols.
  • the alkoxylated, preferably ethoxylated, oxo alcohols have a degree of alkoxylation between 5 and 12.
  • the indicated degrees of alkoxylation represent statistical averages, which may be an integer or a fractional number for a particular product.
  • Preferred oxo alcohol ethoxylates have a narrow homolog distribution (narrow rank ethoxylates, NRE).
  • a C is preferably 3 _i 5 oxo-alcohol with 7 EO, a C 3 _i 5 oxo-alcohol with 8 EO or a mixture of these two oxo alcohols in the liquid washing or cleaning agent used.
  • nonionic surfactants alkyl glycosides of the general formula RO (G) x can be used in which R is a primary straight-chain or methyl branched, especially in the 2-position methyl-branched aliphatic radical having 8 to 22, preferably 12 to 18 carbon atoms and G the symbol is that which represents a glycose unit having 5 or 6 C atoms, preferably glucose.
  • the degree of oligomerization x which indicates the distribution of monoglycosides and oligoglycosides, is any number between 1 and 10, preferably x is 1, 2 to 1, 4.
  • Further suitable nonionic surfactants are ethoxylated methyl esters of natural fatty acids, such as coconut, palm kernel or olive oil fatty acids, preferably having 8 to 18 EO units.
  • liquid detergent or cleaning agent contains only alkoxylated fatty alcohols as nonionic surfactants.
  • the total amount of nonionic surfactant in the liquid washing or cleaning agent is up to 25% by weight and preferably 16 to 20% by weight, based on the total liquid detergent or cleaning agent.
  • the liquid washing or cleaning agent further contains anionic surfactant of the sulfonate type. This is selected from the group consisting of C 9 _i 3 -alkylbenzenesulfonates, olefinsulfonates, sulfonated estolides, and mixtures thereof.
  • surfactants of the sulfonate type preferably C 9 _i 3 -alkylbenzenesulfonates are used.
  • Suitable sulfonated estolides which can be used as the sulfonate-type surfactant include compounds of the following formula
  • n is an integer of 1 to 30, one of X or Y is S0 3 -Z and the other is hydrogen, wherein X and Y are present in each repeating unit, A and A 2 are linear or branched, saturated or unsaturated, substituted or unsubstituted C 8 -C 2 2-alkylene units, a is independently 0, 1, or 2 in each repeat unit, R is a linear or branched, saturated or unsaturated, substituted or unsubstituted CC 2 4 -alkyl moiety, W is a monovalent or divalent metal cation, an ammonium cation, a substituted ammonium cation, hydrogen, a And Z is hydrogen, a monovalent or divalent metal cation, an ammonium cation or a substituted ammonium cation.
  • the amount of anionic surfactant of the sulfonate type is 18 to 35 wt .-%, preferably 20 to 30 wt .-%, each based on the total washing or cleaning agent.
  • the washing or cleaning agent contains 2 to 15 wt .-%, .-%, preferably 5 to 12% by weight, each based on the total washing or cleaning agent, anionic surfactant of the sulfate type selected from the group consisting of Fatty alcohol sulfates, fatty alcohol ether sulfates and mixtures thereof
  • the salts of the Schwefelklandester Ci are preferably 2 -C 8 fatty alcohols, for example coconut fatty alcohol, tallow fatty alcohol, lauryl, myristyl, cetyl or stearyl alcohol.
  • the Ci 2 -Ci 6 alkyl sulfates and Ci 2 -Ci 5 alkyl sulfates and Ci4-Ci 5 alkyl sulfates are preferred.
  • the fatty alcohol ether sulfates used are, for example, the sulfuric acid monoesters of straight-chain or branched C 7 ethoxylated with from 1 to 6 mol of ethylene oxide.
  • 2 rAlkohole such as 2-methyl-branched C 9 _ ii alcohols having an average of 3.5 moles of ethylene oxide (EO) or Ci 2 _i 8 -Fettalkohole with 1 to 4 EO used.
  • the washing or cleaning agent contains a fatty acid and / or a fatty acid soap.
  • Suitable are saturated and unsaturated fatty acids, such as lauric acid, myristic acid, palmitic acid, stearic acid, (hydrogenated) erucic acid and behenic acid, and in particular natural fatty acids, for example coconut, palm kernel, olive oil or tallow fatty acids, and soaps or soap mixtures derived from these fatty acids.
  • the amount of fatty acid and / or a fatty acid soap in the entire washing or cleaning agent is 0.5 to 20 wt .-% and preferably 2 to 15 wt .-%.
  • the anionic surfactants and the fatty acid soaps may be in the form of their sodium, potassium or ammonium salts.
  • the anionic surfactants are in the form of their sodium salts or ammonium salts.
  • the ammonium salts may be the salts of organic bases.
  • the amine used for the neutralization is preferably choline, triethylamine, monoethanolamine,
  • Diethanolamine, triethanolamine, methylethylamine or a mixture thereof, with monoethanolamine is preferred.
  • the total amount of nonionic surfactant, sulfonate type anionic surfactant, sulfate type anionic surfactant and fatty acid (soap) in the liquid detergent or cleaner is at least 35 wt .-%, preferably 40 to 75 wt .-%, and most preferably 50 to 60 wt .-%, each based on the total liquid detergent or cleaning agent.
  • the liquid washing or cleaning agent may further contain an organic solvent, which preferably comprises 1, 2-propanediol, glycerol and / or ethanol.
  • the liquid washing or cleaning agent may contain water, wherein the content of water is less than 25 wt .-%, and more preferably less than 15 wt .-%, each based on the total liquid detergent or cleaning agent.
  • the liquid washing or cleaning agent may contain other ingredients which enhance the performance and / or aesthetics of the laundry or cleaning product Cleaner further improve.
  • the washing or cleaning agent preferably additionally contains one or more substances from the group of builders, bleaches, bleach catalysts, bleach activators, enzymes, electrolytes, pH adjusters, perfumes, perfume carriers, fluorescers, dyes, hydrotopes, foam inhibitors, silicone oils , Inlet preventer, anti-crease agents, color transfer inhibitors, antimicrobial agents, germicides, fungicides, antioxidants, preservatives,
  • Corrosion inhibitors antistatic agents, bittering agents, ironing aids, repellents and impregnating agents, skincare active ingredients, swelling and anti-slip agents, softening components and UV absorbers.
  • the liquid washing or cleaning agent can be filled into a water-soluble casing and thus be part of a water-soluble packaging. Is this liquid washing or
  • Detergent packaged in a water-soluble wrapper it is preferred that the content of water is less than 10 wt .-%, based on the total liquid detergent or cleaning agent
  • the water-soluble envelope forms a closed structure, which has in its interior one or more chambers for receiving one or more washing or cleaning agents.
  • the water-soluble packaging may be dimensionally stable or deformable.
  • the water-soluble packaging may be formed as a dimensionally stable container, for example in the form of a capsule, box, box or container.
  • a non-dimensionally stable container for example as a bag.
  • water-soluble packaging can be largely adapted to the conditions of use.
  • various forms such as hoses, pillows, cylinders, bottles or discs in question.
  • a water-soluble packaging contains, in addition to the liquid washing or cleaning agent, a water-soluble coating.
  • the water-soluble coating is preferably formed by a water-soluble film material.
  • Such water-soluble packages can be obtained either by vertical methods
  • VFFS Form hypoxialversiegelns
  • thermoforming process thermoforming process
  • the thermoforming process generally includes forming a first layer of water-soluble film material to form protuberances for receiving one
  • a composition therein filling the composition into the protrusions, covering the bulges filled with the composition with a second layer of a water-soluble film material and sealing the first and second layers together at least about
  • the water-soluble coating is preferably formed from a water-soluble film material selected from the group comprising polymers and polymer blends.
  • the wrapper may be formed of one or two or more layers of the water-soluble film material.
  • the water-soluble film material of the first layer and the further layers, if present, may be the same or different.
  • the water-soluble coating be polyvinyl alcohol or a
  • Suitable water soluble films for the production of the water-soluble envelope preferably based on polyvinyl alcohol or a polyvinyl alcohol copolymer, whose molecular weight in the range of 10,000 to 1, 000,000 gmol ", preferably from 20,000 to 500,000 gmol", particularly preferably 30,000 to 100,000 gmol "1 and in particular of 40,000 to 80,000 gmol "1 lies.
  • polyvinyl alcohol is usually carried out by hydrolysis of polyvinyl acetate, since the direct synthesis route is not possible.
  • polyvinyl alcohol copolymers which are prepared from correspondingly polyvinyl acetate copolymers.
  • its degree of hydrolysis is preferably 70 to 100 mol%, preferably 80 to 90 mol%, particularly preferably 81 to 89 mol% and in particular 82 to 88 mol%.
  • a polymer selected from the group consisting of (meth) acrylic acid-containing (co) polymers, polyacrylamides, oxazoline polymers, polystyrenesulfonates, polyurethanes, polyesters, polyethers, polylactic acids or mixtures of the above can additionally be selected from a polyvinyl alcohol-containing film material suitable for producing the water-soluble coating Be added polymers.
  • a preferred additional polymer is polylactic acids.
  • Preferred polyvinyl alcohol copolymers include, in addition to vinyl alcohol, dicarboxylic acids as further monomers.
  • Suitable dicarboxylic acids are itaconic acid, malonic acid, succinic acid and mixtures thereof, with itaconic acid being preferred.
  • polyvinyl alcohol copolymers include, in addition to vinyl alcohol, an ethylenically unsaturated carboxylic acid, its salt or its esters.
  • Such polyvinyl alcohol copolymers particularly preferably contain, in addition to vinyl alcohol, acrylic acid, methacrylic acid, acrylates, methacrylates or mixtures thereof.
  • the film material contains further additives.
  • the film material may contain, for example, plasticizers such as dipropylene glycol, ethylene glycol, diethylene glycol, propylene glycol, glycerol, sorbitol, mannitol or mixtures thereof.
  • Other additives include, for example, release aids, fillers, crosslinking agents, surfactants, antioxidants, UV absorbers, antiblocking agents, detackifying agents, or mixtures thereof.
  • water-soluble packaging according to the invention are films marketed by MonoSol LLC, for example under the designation M8630, M8310, C8400 or M8900.
  • Other suitable films include films named Solublon® PT, Solublon® GA, Solublon® KC or Solublon® KL from Aicello Chemical Europe GmbH or the films VF-HP from Kuraray.
  • the water-soluble packaging has a chamber for receiving the highly concentrated liquid washing or cleaning agent.
  • the water-soluble packaging has two chambers.
  • the first chamber contains the above-described highly concentrated liquid detergent or cleaning agent and the second chamber may contain a solid or a liquid detergent or cleaning agent.
  • the water-soluble packaging in yet another preferred embodiment has three chambers, these chambers can each contain a liquid washing or cleaning agent. But it is also possible that a chamber containing a solid detergent or detergent and two chambers containing a liquid detergent or cleaning agent. It is also possible that a solid washing or cleaning agent is contained in two chambers and a liquid detergent or cleaning agent in a chamber.
  • At least one chamber contains the above-described liquid detergent or cleaning agent according to the invention.
  • the liquid detergents or cleaning agents contained in the other chambers of a water-soluble packaging may have the same composition.
  • the liquid detergents or cleaners in a water-soluble packaging with at least two chambers preferably have compositions which differ at least in the content of an ingredient.
  • Packaging is equal to the full dose needed for a wash of 4.5 kg of laundry.
  • 20 to 25 g of liquid washing or cleaning agent are packaged in a water-soluble wrapper.
  • Liquid detergents or cleaners were prepared by conventional and known methods and procedures. Table 1 below shows the compositions of a washing or cleaning agent E1 according to the invention and a washing or cleaning agent V1 not according to the invention.
  • the efficiency of washing or cleaning agents E1 and V1 was determined as the sum of the remission units at different spots (53 fat-containing spots and 18 enzyme-sensitive spots).
  • a household washing machine (Miele W 1734) was loaded with 3.5 kg accompanying laundry as well as correspondingly contaminated cloth rags.
  • Detergent E1 was added and it was washed at 40 ° C. After hanging drying and mangling of the cloth rags their remission was determined spectrophotometrically (Minolta CR200-1). The stain removal was evaluated by the Y value. It was found that the values obtained were almost identical in the case of enzyme-sensitive stains, while the detergent or cleaning agent E1 on stains containing fat showed a better degree of efficiency than the washing or cleaning agent V1 not according to the invention.
  • Detergent V1 or 20 g of the detergent or cleaning agent E1 was added and it was washed at 20 ° C, 40 ° C or 60 ° C. After hanging drying and mangling of the cloth rags their remission was determined spectrophotometrically (Minolta CR200-1). The rating of
  • Stain removal was via the Y value.
  • a third washing test the graying-inhibiting performance of the washing or cleaning agents E1 and V1 was determined.
  • a household washing machine (Miele W 1734) was loaded with 2.5 kg of white accompanying laundry, various test fabrics, five SBL 2004 wipes with standardized dirt load (32 g of dirt ballast).
  • either 39 g of the washing or cleaning agent V1, 25 g of the washing or cleaning agent E1 or 25 g of the washing or cleaning agent E1 were added and it was washed at 40 ° C. After hanging Drying and mangling of the cloth rags their whiteness was determined spectrophotometrically (Minolta CR200-1). The stain removal was evaluated by the Y value.
  • Table 4 shows these measurements versus the baseline test fabric.
  • the cotton fabrics were eight different commercially available cotton fabrics.
  • the fabrics of polyester were five different commercially available polyester fabrics.
  • the used fabrics comprised four commercial ones
  • Everyday textiles such as kitchen towel, toweling, barley grain towel and white T-shirts.
  • V1 (39g) -10.50 -4.05 -13.70 -9.41
  • Detergent E1 is higher than in the washing or cleaning agent V1 not according to the invention.
  • Detergent E1 or 20 g of the detergent or cleaning agent E1 was added and it was washed at 40 ° C. After hanging drying and mangling of the cloth rags their remission was determined spectrophotometrically (Minolta CR200-1). The stain removal was evaluated by the Y value.
  • a film of the type M 8630 (ex Monosol) with a thickness of 76 ⁇ for forming a bulge was drawn by means of vacuum in a trough. Subsequently, the bulge was filled with 25 g of the liquid detergent or cleaning agent E1. After covering the agent filled bulges with a second layer of M 8630 film, the first and second layers were sealed together. The sealing temperature was 150 ° C and the sealing time 1, 1 seconds.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un produit détergent ou nettoyant liquide hautement concentré contenant, rapporté à chaque fois au poids total du produit détergent ou nettoyant : a) de 18 à 35 % en poids d'un agent tensio-actif anionique de type sulfonate choisi dans le groupe constitué par des alkylbenzènesulfonates en C9-13, des oléfinesulfonates, des estolides sulfonés, des alcanesulfonates en C12-18 et des mélanges de ces composés; b) de 15 à 25 % en poids d'un agent tensio-actif non ionique choisi dans le groupe constitué par des alcools gras alcoxylés, des oxoalcools alcoxylés, des alkylpolyglycosides et des mélanges de ces composés; c) de 2 à 15 % en poids d'un agent tensio-actif anionique de type sulfate choisi dans le groupe constitué par des sulfates d'alcools gras, des sulfates d'éthers d'alcools gras et des mélanges de ces composés; et d) de 0,5 à 20 % en poids d'un acide gras et/ou d'un savon d'acide gras.
EP13730592.6A 2012-06-27 2013-06-24 Produit détergent ou nettoyant liquide hautement concentré Revoked EP2867352B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL13730592T PL2867352T3 (pl) 2012-06-27 2013-06-24 Wysoce stężony, ciekły środek piorący lub czyszczący

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE201210211028 DE102012211028A1 (de) 2012-06-27 2012-06-27 Hochkonzentriertes flüssiges Wasch- oder Reinigungsmittel
PCT/EP2013/063146 WO2014001260A1 (fr) 2012-06-27 2013-06-24 Produit détergent ou nettoyant liquide hautement concentré

Publications (2)

Publication Number Publication Date
EP2867352A1 true EP2867352A1 (fr) 2015-05-06
EP2867352B1 EP2867352B1 (fr) 2017-11-01

Family

ID=48670581

Family Applications (1)

Application Number Title Priority Date Filing Date
EP13730592.6A Revoked EP2867352B1 (fr) 2012-06-27 2013-06-24 Produit détergent ou nettoyant liquide hautement concentré

Country Status (7)

Country Link
US (1) US9150821B2 (fr)
EP (1) EP2867352B1 (fr)
DE (1) DE102012211028A1 (fr)
ES (1) ES2655025T3 (fr)
HU (1) HUE035741T2 (fr)
PL (1) PL2867352T3 (fr)
WO (1) WO2014001260A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3101100B1 (fr) 2015-06-05 2018-02-07 The Procter and Gamble Company Composition détergente liquide concentrée pour le lavage du linge
EP3101107B1 (fr) 2015-06-05 2019-04-24 The Procter and Gamble Company Composition de detergent liquide compacte pour blanchisserie
EP3101102B2 (fr) 2015-06-05 2023-12-13 The Procter & Gamble Company Composition de detergent liquide compacte pour blanchisserie
EP3101106B1 (fr) * 2015-06-05 2019-04-24 The Procter and Gamble Company Composition de detergent liquide compacte pour blanchisserie
ES2694703T3 (es) * 2015-07-30 2018-12-26 The Procter & Gamble Company Artículo de dosis unitaria soluble en agua
CN111065268B (zh) * 2017-08-25 2022-01-25 联合利华知识产权控股有限公司 抗微生物组合物
DE102017215016A1 (de) 2017-08-28 2019-02-28 Henkel Ag & Co. Kgaa Strukturiertes Wasch- oder Reinigungsmittel mit Fließgrenze
EP3623458A1 (fr) * 2018-09-11 2020-03-18 The Procter & Gamble Company Article de dose unitaire soluble dans l'eau
EP3892707A1 (fr) 2020-04-06 2021-10-13 Dalli-Werke GmbH & Co. KG Composition de détergent liquide, kit et système de dosage
DE102020212100A1 (de) * 2020-09-25 2022-03-31 Henkel Ag & Co. Kgaa Konzentrierte fließfähige Waschmittelzubereitung mit verbesserten Eigenschaften
US20220298453A1 (en) * 2021-03-18 2022-09-22 Henkel IP & Holding GmbH Liquid Laundry Detergent Compositions Containing Soil Release Polymers
CN114653213A (zh) * 2021-12-25 2022-06-24 华能酒泉发电有限公司 一种去除超滤膜油脂、有机物的清洗剂制备方法及其应用
CN115386435A (zh) * 2022-09-06 2022-11-25 湖北雅绿镓新材料科技有限公司 一种多彩型深海晶盐抑菌去污留香洗衣凝珠及其制备方法

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DK131638A (fr) 1969-06-07
EP0019315B1 (fr) * 1979-05-16 1983-05-25 Procter & Gamble European Technical Center Compositions détergentes liquides contenant un acide gras très concentré
DE4028850A1 (de) * 1990-09-11 1992-03-12 Johannes Kiehl Kg Fluessigwaschmittel-hochkonzentrate, verfahren zu ihrer herstellung und ihre verwendung
US6060441A (en) 1997-04-10 2000-05-09 Henkel Corporation Cleaning compositions having enhanced enzyme activity
ES2266150T3 (es) * 2001-05-22 2007-03-01 THE PROCTER & GAMBLE COMPANY Composiciones embolsadas.
EP1516917B1 (fr) * 2003-09-22 2006-07-26 The Procter & Gamble Company Composition détergente sous forme de dose unitaire liquide
ES2479392T3 (es) 2007-11-09 2014-07-24 The Procter & Gamble Company Composiciones limpiadoras con polialquileniminas solubles en agua anfifílicas que tienen un bloque interno de poli(óxido de etileno) y un bloque externo de óxido de polipropileno
GB0810881D0 (en) 2008-06-16 2008-07-23 Unilever Plc Improvements relating to fabric cleaning
US7985725B2 (en) 2008-08-14 2011-07-26 Melaleuca, Inc. Ultra concentrated liquid laundry detergent
CA2767172A1 (fr) 2009-07-10 2011-01-13 The Procter & Gamble Company Compositions contenant des particules delivrant un agent benefique
WO2011075556A1 (fr) 2009-12-18 2011-06-23 The Procter & Gamble Company Composition comprenant des produits encapsulés, et procédé de fabrication desdits produits encapsulés
MX364609B (es) 2010-01-29 2019-05-02 Monosol Llc Pelicula soluble en agua mejorada que tiene una mezcla de polimeros de pvoh, y envases realizados a partir de la misma.
US20110268778A1 (en) 2010-04-28 2011-11-03 Jiten Odhavji Dihora Delivery particles
US9186642B2 (en) 2010-04-28 2015-11-17 The Procter & Gamble Company Delivery particle
MX350545B (es) 2010-07-20 2017-09-08 The Procter & Gamble Company * Partículas de suministro con pluralidad de núcleos.
US20120028874A1 (en) 2010-07-20 2012-02-02 Susana Fernandez Prieto Particles
DE102012204270A1 (de) * 2012-03-19 2013-09-19 Henkel Ag & Co. Kgaa Flüssiges Waschmittel mit erhöhter Reinigungsleistung

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2014001260A1 *

Also Published As

Publication number Publication date
PL2867352T3 (pl) 2018-04-30
WO2014001260A1 (fr) 2014-01-03
EP2867352B1 (fr) 2017-11-01
HUE035741T2 (hu) 2018-05-28
US20150105313A1 (en) 2015-04-16
DE102012211028A1 (de) 2014-01-02
US9150821B2 (en) 2015-10-06
ES2655025T3 (es) 2018-02-16

Similar Documents

Publication Publication Date Title
EP2867352B1 (fr) Produit détergent ou nettoyant liquide hautement concentré
EP3024917B1 (fr) Détergent contenant de l'oxyde d'amine
EP2850169B1 (fr) Détergent liquide à faible teneur en eau, contenant des tensioactifs obtenus à partir de matières premières renouvelables
EP2828368B1 (fr) Composition détergente liquide ayant une puissance de nettoyage augmentée
DE102013218614A1 (de) Waschmittel enthaltend Ethercarboxylate
WO2015091110A2 (fr) Détergent contenant du méthylestersulfonate (mes) et du méthylesteréthoxylate (mee)
EP2809759B1 (fr) Détergent liquide pauvre en eau à pouvoir dégraissant renforcé
EP2875107B1 (fr) Détergent liquide stable à capacité antiredéposition
DE102011085639A1 (de) Strukturiertes Wasch- oder Reinigungsmittel mit Fließgrenze
EP3250668B1 (fr) Lessive liquide acide à faible teneur en eau, contenant de l'acide hydroxycarboxylique, un tensioactif neutre et une -amylase
DE102013217373A1 (de) Waschmittel enthaltend Alkylglykolether
DE102014205928A1 (de) Wasch- oder Reinigungsmittel mit anionischem Tensid, Fettalkoholalkoxylat, Fettsäureester und Alkylenglykolmonoether
EP3087169A1 (fr) Détergent contenant un carboxylate d'alkyle
DE102013218225A1 (de) Waschmittel enthaltend Alkylpyrrolidon
EP2875106B1 (fr) Composition détergente liquide stable à capacité antiredéposition
DE102016206647A1 (de) Flüssigwaschmittel
DE102013212647A1 (de) Tensidmischung für Waschmittel
DE102015214056A1 (de) Waschkraftverstärkende Hydroxyaminoxide
WO2014206810A1 (fr) Détergent ou produit de nettoyage contenant de l'ester alkylique de saccharose
DE102014204826A1 (de) Waschmittel enthaltend Esterquats

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20140306

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

DAX Request for extension of the european patent (deleted)
TPAC Observations filed by third parties

Free format text: ORIGINAL CODE: EPIDOSNTIPA

17Q First examination report despatched

Effective date: 20160211

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

INTG Intention to grant announced

Effective date: 20170621

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

Ref country code: AT

Ref legal event code: REF

Ref document number: 942031

Country of ref document: AT

Kind code of ref document: T

Effective date: 20171115

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502013008720

Country of ref document: DE

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2655025

Country of ref document: ES

Kind code of ref document: T3

Effective date: 20180216

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20171101

REG Reference to a national code

Ref country code: LT

Ref legal event code: MG4D

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180201

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

REG Reference to a national code

Ref country code: HU

Ref legal event code: AG4A

Ref document number: E035741

Country of ref document: HU

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180301

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180202

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20180201

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 6

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 502013008720

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

26 Opposition filed

Opponent name: DALLI-WERKE GMBH CO. KG

Effective date: 20180727

Opponent name: THE PROCTER GAMBLE COMPANY

Effective date: 20180801

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20180630

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180624

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180630

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180630

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180624

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180630

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 942031

Country of ref document: AT

Kind code of ref document: T

Effective date: 20180624

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20180801

RDAF Communication despatched that patent is revoked

Free format text: ORIGINAL CODE: EPIDOSNREV1

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180624

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20171101

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20171101

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20210622

Year of fee payment: 9

Ref country code: DE

Payment date: 20210618

Year of fee payment: 9

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20210826

Year of fee payment: 9

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: THE PROCTER & GAMBLE COMPANY

Effective date: 20180801

REG Reference to a national code

Ref country code: DE

Ref legal event code: R103

Ref document number: 502013008720

Country of ref document: DE

Ref country code: DE

Ref legal event code: R064

Ref document number: 502013008720

Country of ref document: DE

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

RDAG Patent revoked

Free format text: ORIGINAL CODE: 0009271

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: PATENT REVOKED

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: FI

Ref legal event code: MGE

27W Patent revoked

Effective date: 20220609

GBPR Gb: patent revoked under art. 102 of the ep convention designating the uk as contracting state

Effective date: 20220609

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20220627

Year of fee payment: 10

Ref country code: HU

Payment date: 20220617

Year of fee payment: 10

Ref country code: GB

Payment date: 20220627

Year of fee payment: 10

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PL

Payment date: 20220620

Year of fee payment: 10

REG Reference to a national code

Ref country code: AT

Ref legal event code: MA03

Ref document number: 942031

Country of ref document: AT

Kind code of ref document: T

Effective date: 20220609