EP3067444A3 - Abscheidung von dekorativen palladium-eisen-legierungsbeschichtungen auf metallischen substanzen - Google Patents

Abscheidung von dekorativen palladium-eisen-legierungsbeschichtungen auf metallischen substanzen Download PDF

Info

Publication number
EP3067444A3
EP3067444A3 EP16156476.0A EP16156476A EP3067444A3 EP 3067444 A3 EP3067444 A3 EP 3067444A3 EP 16156476 A EP16156476 A EP 16156476A EP 3067444 A3 EP3067444 A3 EP 3067444A3
Authority
EP
European Patent Office
Prior art keywords
palladium
bath
free
decorative
separation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP16156476.0A
Other languages
English (en)
French (fr)
Other versions
EP3067444A2 (de
EP3067444B1 (de
Inventor
Claudia GARHÖFER-ONDREICSKA
Christian GARHÖFER
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ing W Garhofer GmbH
Ing W Garhofer Ges Mbh
Original Assignee
Ing W Garhofer GmbH
Ing W Garhofer Ges Mbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ing W Garhofer GmbH, Ing W Garhofer Ges Mbh filed Critical Ing W Garhofer GmbH
Publication of EP3067444A2 publication Critical patent/EP3067444A2/de
Publication of EP3067444A3 publication Critical patent/EP3067444A3/de
Application granted granted Critical
Publication of EP3067444B1 publication Critical patent/EP3067444B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/56—Electroplating: Baths therefor from solutions of alloys
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/56—Electroplating: Baths therefor from solutions of alloys
    • C25D3/567—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/20—Electroplating: Baths therefor from solutions of iron
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00—Electroplating: Baths therefor
    • C25D3/02—Electroplating: Baths therefor from solutions
    • C25D3/50—Electroplating: Baths therefor from solutions of platinum group metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/10—Electroplating with more than one layer of the same or of different metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/60—Electroplating characterised by the structure or texture of the layers
    • C25D5/605—Surface topography of the layers, e.g. rough, dendritic or nodular layers
    • C25D5/611—Smooth layers
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00—Electroplating characterised by the article coated
    • C25D7/005—Jewels; Clockworks; Coins
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
    • C25D5/34—Pretreatment of metallic surfaces to be electroplated

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electroplating And Plating Baths Therefor (AREA)

Abstract

Die Erfindung betrifft ein Elektrolytbad für das kathodische Abscheiden von binären Legierungen und/oder Schichtfolgen unter Bildung von weißen, korrosionsbeständigen, rissfreien und (hoch)glänzenden Überzügen auf zumindest an ihrer Oberfläche metallischen bzw. elektrisch leitfähigen oder leitfähig beschichteten Objekten, welches Bad als Legierungsmetalle aus zumindest einer Palladiumverbindung, insbesondere einem Palladiumsalz, als Primärmetall und zumindest einer Eisenverbindung, insbesondere einem Eisensalz als Sekundärmetall besteht.
Die Erfindung ist dadurch gekennzeichnet, dass es - zur Abscheidung einer Pd/Fe-Legierung mit einem Gehalt von 5-15 Gew-% Fe - als wässerige, alkalisch reagierende Lösung, insbesondere mit einem pH-Wert von 7,5 bis 9, vorliegt und außer den Metall-Verbindungen, als wesentliche weitere Komponente zumindest ein Netzmittel, insbesondere aus der Gruppe der amphoteren Tenside, und zusätzlich mindestens einen der in galvanischen Palladiumbädern in üblicher Weise enthaltenen Glanzzusatz sowie Leitsalze, insbesondere pH-Stabilisatoren und insbesondere Spannungsverminderer enthält, wobei das Elektrolytbad frei von Ammoniak und Ammoniumverbindungen ist.
EP16156476.0A 2015-03-09 2016-02-19 Abscheidung von dekorativen palladium-eisen-legierungsbeschichtungen auf metallischen substanzen Active EP3067444B1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ATA50188/2015A AT516876B1 (de) 2015-03-09 2015-03-09 Abscheidung von dekorativen Palladium-Eisen-Legierungsbeschichtungen auf metallischen Substanzen

Publications (3)

Publication Number Publication Date
EP3067444A2 EP3067444A2 (de) 2016-09-14
EP3067444A3 true EP3067444A3 (de) 2016-12-07
EP3067444B1 EP3067444B1 (de) 2019-03-27

Family

ID=60153001

Family Applications (1)

Application Number Title Priority Date Filing Date
EP16156476.0A Active EP3067444B1 (de) 2015-03-09 2016-02-19 Abscheidung von dekorativen palladium-eisen-legierungsbeschichtungen auf metallischen substanzen

Country Status (2)

Country Link
EP (1) EP3067444B1 (de)
AT (1) AT516876B1 (de)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT522158B1 (de) * 2019-05-03 2020-09-15 Iwg Ing W Garhoefer Ges M B H Beschichtungssystem zum Aufbringen durch galvanische Abscheidung auf einen Rohling
US10612149B1 (en) 2019-09-05 2020-04-07 Chow Sang Sang Jewellery Company Limited Platinum electrodeposition bath and uses thereof
AT523922B1 (de) * 2020-09-08 2022-01-15 Iwg Ing W Garhoefer Ges M B H Elektrolytbad für Palladium-Ruthenium-Beschichtungen

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2741347A1 (de) * 1976-09-17 1978-03-23 Parker Ste Continentale Bad und verfahren zur elektrolytischen abscheidung von legierungen auf der basis von palladium
JP2001181887A (ja) * 1999-12-24 2001-07-03 Bikutoria:Kk パラジウム／鉄合金メッキ液及びパラジウム合金メッキ基材
EP1396559A1 (de) * 1999-10-27 2004-03-10 Kojima Chemicals Co., Ltd Palladium-platierungslösung
EP2192210A1 (de) * 2008-11-21 2010-06-02 Umicore Galvanotechnik GmbH Edelmetallhaltige Schichtfolge für dekorative Artikel

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2657925A1 (de) 1976-12-21 1978-06-22 Siemens Ag Ammoniakfreies, waessriges bad zur galvanischen abscheidung von palladium bzw. palladiumlegierungen
DE2906783A1 (de) * 1979-02-22 1980-10-16 Degussa Verfahren zur vorbehandlung von leichtmetallen vor dem galvanisieren
DE19512888A1 (de) * 1995-04-06 1996-10-10 Vacuumschmelze Gmbh Verfahren zur elektrolytischen Beschichtung von Seltene Erden enthaltenden Dauermagneten mit minimaler Oberflächenschädigung
JPH1046384A (ja) 1996-05-10 1998-02-17 Lucent Technol Inc パラジウム合金メッキ浴
US6251249B1 (en) * 1996-09-20 2001-06-26 Atofina Chemicals, Inc. Precious metal deposition composition and process
JP3601005B2 (ja) 1999-10-27 2004-12-15 小島化学薬品株式会社 パラジウムめっき液
JP4811880B2 (ja) * 2006-01-06 2011-11-09 エントン インコーポレイテッド 艶消し金属層を堆積するための電解液および工程
ATE555235T1 (de) * 2008-05-07 2012-05-15 Umicore Galvanotechnik Gmbh Pd- und pd-ni-elektrolytbäder
DE102009055828A1 (de) * 2008-12-19 2010-07-01 Merck Patent Gmbh Verfahren zur Herstellung metallbeschichteter Partikel

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2741347A1 (de) * 1976-09-17 1978-03-23 Parker Ste Continentale Bad und verfahren zur elektrolytischen abscheidung von legierungen auf der basis von palladium
EP1396559A1 (de) * 1999-10-27 2004-03-10 Kojima Chemicals Co., Ltd Palladium-platierungslösung
JP2001181887A (ja) * 1999-12-24 2001-07-03 Bikutoria:Kk パラジウム／鉄合金メッキ液及びパラジウム合金メッキ基材
EP2192210A1 (de) * 2008-11-21 2010-06-02 Umicore Galvanotechnik GmbH Edelmetallhaltige Schichtfolge für dekorative Artikel

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HERNANDEZ S C ET AL: "Electrodeposition of iron-palladium thin films", ELECTROCHIMICA ACTA, ELSEVIER SCIENCE PUBLISHERS, BARKING, GB, vol. 53, no. 18, 20 July 2008 (2008-07-20), pages 5621 - 5627, XP022655646, ISSN: 0013-4686, [retrieved on 20080318], DOI: 10.1016/J.ELECTACTA.2008.03.001 *

Also Published As

Publication number Publication date
EP3067444A2 (de) 2016-09-14
AT516876B1 (de) 2016-11-15
AT516876A1 (de) 2016-09-15
EP3067444B1 (de) 2019-03-27

Similar Documents

Publication Publication Date Title
DE102008050135B4 (de) Verfahren zur Abscheidung von Platin-Rhodiumschichten mit verbesserter Helligkeit
EP2116634B1 (de) Modifizierter Kupfer-Zinn-Elektrolyt und Verfahren zur Abscheidung von Bronzeschichten
AT514818B1 (de) Abscheidung von Cu, Sn, Zn-Beschichtungen auf metallischen Substraten
EP2192210B1 (de) Edelmetallhaltige Schichtfolge für dekorative Artikel
CN103757672B (zh) 一种锌锡合金电镀方法
PH12019500424A1 (en) Method for electrodepositing zinc and zinc alloy coatings from an alkaline coating bath with reduced depletion of organic bath additives
CN105442000B (zh) 一种碱性锌铁合金电镀液、制备方法及电镀工艺
EP3067444B1 (de) Abscheidung von dekorativen palladium-eisen-legierungsbeschichtungen auf metallischen substanzen
AT514427B1 (de) Elektrolytbad sowie damit erhältliche Objekte bzw. Artikel
AT523922B1 (de) Elektrolytbad für Palladium-Ruthenium-Beschichtungen
DE1771241A1 (de) Plattierte Gegenstaende
DE102020133188B4 (de) Verwendung eines Silber-Bismut-Elektrolyt zur Abscheidung von Hartsilberschichten
DE102014019753A1 (de) Borsaurefreies Nickel-Bad
DE102014118614A1 (de) Borsäurefreies Nickel-Bad
CN107735846B (zh) 铝合金带材制成的插接器
JP3277816B2 (ja) 三元系亜鉛合金電気めっき方法
DE102014100862B4 (de) Elektrolytisches Bad
RU2616314C1 (ru) Способ нанесения гальванических покрытий сплавом олово-цинк
DE704713C (de) Verfahren zur Herstellung einer reinweissen, hochglaenzenden und korrosionssicheren Verzinkung
DE102014118593A1 (de) Nickel-Wolfram-Legierung
DE1107044B (de) Baeder zur Herstellung hochglaenzender galvanischer Metallueberzuege
CN113430591A (zh) 一种铝合金的表面处理工艺
DE1149961B (de) Verfahren zur Herstellung von galvanischen Metallueberzuegen
WO1995027812A1 (de) Beschichtung von metalloberflächen mit kupfer oder kupferlegierungen
DE102016102319A1 (de) Verfahren zur Beschichtung eines Kontaktelements mit einer Kupfer-Nickel-Legierung

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

AX Request for extension of the european patent

Extension state: BA ME

RIC1 Information provided on ipc code assigned before grant

Ipc: C25D 5/34 20060101ALN20161102BHEP

Ipc: C25D 7/00 20060101AFI20161102BHEP

Ipc: C25D 3/56 20060101ALI20161102BHEP

Ipc: C25D 5/10 20060101ALI20161102BHEP

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: REQUEST FOR EXAMINATION WAS MADE

17P Request for examination filed

Effective date: 20170601

RBV Designated contracting states (corrected)

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

TPAC Observations filed by third parties

Free format text: ORIGINAL CODE: EPIDOSNTIPA

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: EXAMINATION IS IN PROGRESS

17Q First examination report despatched

Effective date: 20170824

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

RIC1 Information provided on ipc code assigned before grant

Ipc: C25D 7/00 20060101AFI20181129BHEP

Ipc: C25D 5/34 20060101ALN20181129BHEP

Ipc: C25D 5/10 20060101ALI20181129BHEP

Ipc: C25D 3/56 20060101ALI20181129BHEP

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: GRANT OF PATENT IS INTENDED

RIC1 Information provided on ipc code assigned before grant

Ipc: C25D 7/00 20060101AFI20181211BHEP

Ipc: C25D 3/56 20060101ALI20181211BHEP

Ipc: C25D 5/34 20060101ALN20181211BHEP

Ipc: C25D 5/10 20060101ALI20181211BHEP

INTG Intention to grant announced

Effective date: 20190103

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE PATENT HAS BEEN GRANTED

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: AT

Ref legal event code: REF

Ref document number: 1113201

Country of ref document: AT

Kind code of ref document: T

Effective date: 20190415

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

Free format text: LANGUAGE OF EP DOCUMENT: GERMAN

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 502016003871

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: SE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: NO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190627

REG Reference to a national code

Ref country code: NL

Ref legal event code: MP

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: LV

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190628

Ref country code: HR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190627

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: IT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: AL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190727

Ref country code: ES

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: SM

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190727

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 502016003871

Country of ref document: DE

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

26N No opposition filed

Effective date: 20200103

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 502016003871

Country of ref document: DE

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20200219

REG Reference to a national code

Ref country code: BE

Ref legal event code: MM

Effective date: 20200229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200219

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200901

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200219

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200219

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20200229

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 1113201

Country of ref document: AT

Kind code of ref document: T

Effective date: 20210219

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20210219

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20190327