EP4716708A1 - Catalyseurs et polymérisations pour polyoléfines améliorées - Google Patents
Catalyseurs et polymérisations pour polyoléfines amélioréesInfo
- Publication number
- EP4716708A1 EP4716708A1 EP24732117.7A EP24732117A EP4716708A1 EP 4716708 A1 EP4716708 A1 EP 4716708A1 EP 24732117 A EP24732117 A EP 24732117A EP 4716708 A1 EP4716708 A1 EP 4716708A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- catalyst
- polyethylene copolymer
- melt index
- polyethylene
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2420/00—Metallocene catalysts
- C08F2420/09—Cyclic bridge, i.e. Cp or analog where the bridging unit linking the two Cps or analogs is part of a cyclic group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
La présente divulgation concerne des polymères de polyéthylène et des films fabriqués à partir de ceux-ci. Dans certains modes de réalisation, un copolymère de polyéthylène comprend 90 % en poids ou plus d'unités éthylène et un reste d'unités comonomères C3-C20. Le copolymère de polyéthylène a une distribution de composition bimodale, une densité allant de 0,914 g/cm3 à 0,925 g/cm3, un indice de fusion de 0,1 g/10 min à 1 g/10 min, un indice de fusion sous charge élevée (HLMI) de 21 g/10 min à 70 g/10 min, un rapport d'indice de fusion (MIR) de 40 à 65, et une distribution de poids moléculaire (MWD) de 4 à 7.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US202363503845P | 2023-05-23 | 2023-05-23 | |
| PCT/US2024/029297 WO2024242936A1 (fr) | 2023-05-23 | 2024-05-14 | Catalyseurs et polymérisations pour polyoléfines améliorées |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP4716708A1 true EP4716708A1 (fr) | 2026-04-01 |
Family
ID=91465283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP24732117.7A Pending EP4716708A1 (fr) | 2023-05-23 | 2024-05-14 | Catalyseurs et polymérisations pour polyoléfines améliorées |
Country Status (3)
| Country | Link |
|---|---|
| EP (1) | EP4716708A1 (fr) |
| CN (1) | CN121420002A (fr) |
| WO (1) | WO2024242936A1 (fr) |
Family Cites Families (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US5008204A (en) | 1988-02-02 | 1991-04-16 | Exxon Chemical Patents Inc. | Method for determining the compositional distribution of a crystalline copolymer |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5382630A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
| US5041584A (en) | 1988-12-02 | 1991-08-20 | Texas Alkyls, Inc. | Modified methylaluminoxane |
| AU660043B2 (en) | 1991-07-18 | 1995-06-08 | Exxon Chemical Patents Inc. | Heat sealed article |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| JP3077940B2 (ja) | 1993-04-26 | 2000-08-21 | エクソン・ケミカル・パテンツ・インク | 流動層重合法のための安定な操作条件を決定する方法 |
| US5462999A (en) | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| US6255426B1 (en) | 1997-04-01 | 2001-07-03 | Exxon Chemical Patents, Inc. | Easy processing linear low density polyethylene |
| US6147173A (en) | 1998-11-13 | 2000-11-14 | Univation Technologies, Llc | Nitrogen-containing group 13 anionic complexes for olefin polymerization |
| US6479424B1 (en) | 1998-12-14 | 2002-11-12 | Bp Corporation North America Inc. | Fluxional catalysts and related ligands containing bulky substituents |
| US6936675B2 (en) | 2001-07-19 | 2005-08-30 | Univation Technologies, Llc | High tear films from hafnocene catalyzed polyethylenes |
| US7235607B2 (en) * | 2002-09-05 | 2007-06-26 | Exxonmobil Chemical Patents Inc. | Shrink film |
| US7319125B2 (en) | 2002-09-20 | 2008-01-15 | Exxonmobil Chemical Patents Inc. | Supercritical polymerization process and polymers produced therefrom |
| WO2004046214A2 (fr) | 2002-10-15 | 2004-06-03 | Exxonmobil Chemical Patents Inc. | Systeme catalyseur multiple pour la polymerisation d'olefines et polymeres ainsi produits |
| US6989344B2 (en) | 2002-12-27 | 2006-01-24 | Univation Technologies, Llc | Supported chromium oxide catalyst for the production of broad molecular weight polyethylene |
| US6841630B2 (en) | 2002-12-31 | 2005-01-11 | Univation Technologies, Llc | Processes for transitioning between chrome-based and mixed polymerization catalysts |
| US6833417B2 (en) | 2002-12-31 | 2004-12-21 | Univation Technologies, Llc | Processes for transitioning between chrome-based and mixed polymerization catalysts |
| BRPI0409019B1 (pt) | 2003-03-28 | 2014-09-02 | Univation Tech Llc | Processo para produzir polietileno com catalisadores baseados em cromo |
| KR20070039930A (ko) | 2004-07-08 | 2007-04-13 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 초임계 조건에서 중합체의 제조방법 |
| US7078467B1 (en) | 2005-06-14 | 2006-07-18 | Univation Technologies, Llc | Single catalyst low, medium and high density polyethylenes |
| US8129484B2 (en) | 2005-07-27 | 2012-03-06 | Univation Technologies, Llc | Blow molding polyethylene resins |
| US20070027276A1 (en) | 2005-07-27 | 2007-02-01 | Cann Kevin J | Blow molding polyethylene resins |
| BRPI0713012B1 (pt) | 2006-06-27 | 2018-05-08 | Univation Tech Llc | copolímero de etileno alfa-olefina, composição, artigo obtido através de moldagem rotativa e processo para a produção de um copolímero de etileno alfa-olefina |
| CN102239187B (zh) | 2008-11-11 | 2014-04-30 | 东曹精细化工株式会社 | 固体状聚甲基铝氧烷组合物及其制造方法 |
| EP2361268B1 (fr) | 2008-12-22 | 2012-11-07 | Univation Technologies, LLC | Systèmes et procédés de fabrication de polymères |
| JP5856561B2 (ja) | 2010-05-11 | 2016-02-10 | 東ソー・ファインケム株式会社 | 固体状担体−ポリメチルアルミノキサン複合体、その製造方法、オレフィン類の重合触媒及びポリオレフィン類の製造方法 |
| US9309340B2 (en) | 2011-03-30 | 2016-04-12 | Japan Polyethylene Corporation | Ethylene-based polymer, polyethylene-based resin composition and use thereof, catalyst component for olefin polymerization, olefin polymerization catalyst containing the component, and method for producing ethylene-based polymer by using the catalyst |
| US8658556B2 (en) | 2011-06-08 | 2014-02-25 | Exxonmobil Chemical Patents Inc. | Catalyst systems comprising multiple non-coordinating anion activators and methods for polymerization therewith |
| KR102009005B1 (ko) | 2012-03-28 | 2019-10-23 | 토소 화인켐 가부시키가이샤 | 작은 입자 직경을 갖는 고체상 폴리메틸알루미녹산 조성물의 제조방법 |
| US9266977B2 (en) | 2012-12-21 | 2016-02-23 | Exxonmobil Chemical Patents Inc. | Bridged metallocene compounds, catalyst systems and processes for polymerization therewith |
| CA2800056A1 (fr) * | 2012-12-24 | 2014-06-24 | Nova Chemicals Corporation | Compositions de melange de polyethylene |
| CA2871463A1 (fr) * | 2014-11-19 | 2016-05-19 | Nova Chemicals Corporation | Supports passives : catalyseur, procede et produit |
| MY191910A (en) * | 2016-12-05 | 2022-07-18 | Exxonmobil Chemical Patents Inc | Broad orthogonal distribution metallocene polyethylenes for films |
| EP3606931B1 (fr) | 2017-04-04 | 2025-08-27 | SABIC Global Technologies B.V. | Complexes métallocènes dihydrocarbyle-silyle-ponté-substitué cyclopentadiényle pour la polymérisation d'oléfines |
| KR102452018B1 (ko) | 2017-10-23 | 2022-10-07 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 촉매계 및 이를 이용한 중합 방법 |
| US11976140B2 (en) | 2018-11-01 | 2024-05-07 | Exxonmobil Chemical Patents Inc. | In-line trimming of dry catalyst feed |
| KR102530448B1 (ko) | 2019-03-13 | 2023-05-08 | 주식회사 엘지화학 | 전이 금속 화합물 및 이를 포함하는 촉매 조성물 |
| EP4017887A4 (fr) | 2019-08-22 | 2023-01-18 | ExxonMobil Chemical Patents Inc. | Homopolymères et copolymères de propylène isotactique produits avec des catalyseurs métallocènes symétriques en c1 |
| US11718635B2 (en) | 2019-12-16 | 2023-08-08 | Exxonmobil Chemical Patents Inc. | Iron bis(imino) aryl catalysts and methods thereof |
| US20230212330A1 (en) | 2020-06-16 | 2023-07-06 | Exxonmobil Chemical Patents Inc. | Metallocene Catalysts for Producing Vinyl-Terminated Polyalphaolefins and Methods Associated Therewith |
| WO2024170345A1 (fr) * | 2023-02-14 | 2024-08-22 | Borealis Ag | Mélange de polyéthylènes pour couche de film |
-
2024
- 2024-05-14 EP EP24732117.7A patent/EP4716708A1/fr active Pending
- 2024-05-14 CN CN202480043413.XA patent/CN121420002A/zh active Pending
- 2024-05-14 WO PCT/US2024/029297 patent/WO2024242936A1/fr not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN121420002A (zh) | 2026-01-27 |
| WO2024242936A1 (fr) | 2024-11-28 |
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Legal Events
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| STAA | Information on the status of an ep patent application or granted ep patent |
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| PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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| STAA | Information on the status of an ep patent application or granted ep patent |
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| 17P | Request for examination filed |
Effective date: 20251215 |
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| AK | Designated contracting states |
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