ES2013588T3 - Purificacion de glioxilatos de alquilo. - Google Patents

Purificacion de glioxilatos de alquilo.

Info

Publication number
ES2013588T3
ES2013588T3 ES89870115T ES89870115T ES2013588T3 ES 2013588 T3 ES2013588 T3 ES 2013588T3 ES 89870115 T ES89870115 T ES 89870115T ES 89870115 T ES89870115 T ES 89870115T ES 2013588 T3 ES2013588 T3 ES 2013588T3
Authority
ES
Spain
Prior art keywords
glioxylates
purification
alkyl
glycolic acid
oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89870115T
Other languages
English (en)
Other versions
ES2013588A4 (es
Inventor
Dario Ricardo Cova
John Michael Thorman
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of ES2013588A4 publication Critical patent/ES2013588A4/es
Application granted granted Critical
Publication of ES2013588T3 publication Critical patent/ES2013588T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D1/00—Evaporating
    • B01D1/22—Evaporating by bringing a thin layer of the liquid into contact with a heated surface
    • B01D1/222—In rotating vessels; vessels with movable parts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/14—Fractional distillation or use of a fractionation or rectification column
    • B01D3/143—Fractional distillation or use of a fractionation or rectification column by two or more of a fractionation, separation or rectification step
    • B01D3/146—Multiple effect distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
    • B01D3/34—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping with one or more auxiliary substances
    • B01D3/36—Azeotropic distillation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D5/00—Condensation of vapours; Recovering volatile solvents by condensation
    • B01D5/0078—Condensation of vapours; Recovering volatile solvents by condensation characterised by auxiliary systems or arrangements
    • B01D5/0093—Removing and treatment of non condensable gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/20—Power plant
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S203/00—Distillation: processes, separatory
    • Y10S203/90—Particular type of heating

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)

Abstract

SE DESCRIBE UN PROCESO MEJORADO PARA LA FABRICACION DE ACIDO GLIOXILICO, OBTENIDO POR OXIDACION DE ACIDO GLICOLICO. SE EMPLEAN PARA PROCESAR ESTERES ALQUILICOS DE ESTOS ACIDOS. SE OBTIENE UNA EFICACIA MEJORADA POR RECUPERACION DE CORRIENTES RICAS EN GLICOLATO PROCEDENTES DE UNA O MAS OPERACIONES DE DESTILACION Y, DESPUES DE TRATAMIENTO PARA ELIMINAR EL SUBPRODUCTO ACIDO ACETICO, LAS CORRIENTES SE RECICLAN A LA REACCION DE OXIDACION.
ES89870115T 1988-07-25 1989-07-24 Purificacion de glioxilatos de alquilo. Expired - Lifetime ES2013588T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/224,045 US4867849A (en) 1988-07-25 1988-07-25 Purification of alkyl glyoxylate

Publications (2)

Publication Number Publication Date
ES2013588A4 ES2013588A4 (es) 1990-05-16
ES2013588T3 true ES2013588T3 (es) 1994-08-01

Family

ID=22839075

Family Applications (1)

Application Number Title Priority Date Filing Date
ES89870115T Expired - Lifetime ES2013588T3 (es) 1988-07-25 1989-07-24 Purificacion de glioxilatos de alquilo.

Country Status (7)

Country Link
US (1) US4867849A (es)
EP (1) EP0353215B1 (es)
JP (1) JPH0745435B2 (es)
AT (1) ATE107272T1 (es)
CA (1) CA1324103C (es)
DE (1) DE68916123T2 (es)
ES (1) ES2013588T3 (es)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT392638B (de) * 1989-06-05 1991-05-10 Chemie Linz Gmbh Verfahren zur kontinuierlichen herstellung einer konzentrierten waessrigen loesung von glyoxylsaeure
US5217582A (en) * 1990-06-20 1993-06-08 E. I. Du Pont De Nemours And Company Process for the isolation of alkyl glyoxylate
JP3150909B2 (ja) * 1996-09-05 2001-03-26 株式会社日本触媒 グリオキシル酸エステル類の精製方法
US6286335B1 (en) * 1999-09-03 2001-09-11 Air Products And Chemicals, Inc. Processes for multicomponent separation
NL1013682C2 (nl) * 1999-11-26 2001-05-30 Purac Biochem Bv Werkwijze en inrichting voor het zuiveren van een waterige oplossing van melkzuur.
US9114328B2 (en) 2012-05-16 2015-08-25 Eastman Chemical Company Reactive distillation of a carboxylic acid and a glycol
US9040748B2 (en) 2012-06-08 2015-05-26 Eastman Chemical Company Hydrocarboxylation of aqueous formaldehyde using a dehydrating recycle stream to decrease water concentration
DE102013222343A1 (de) 2013-11-04 2015-05-07 Matthias Enzenhofer Vorrichtung und Verfahren für den Kontakt einer Gasphase mit einem flüssigen Medium

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1627091A (en) * 1923-03-05 1927-05-03 Boehringer Sohn Ingelheim Making keto and aldo aliphatic carboxylic acids
US3476656A (en) * 1968-06-07 1969-11-04 Universal Oil Prod Co Fractional distillation and recovery of styrene containing sulfur with subsequent bottoms separation
FR2383911A1 (fr) * 1977-03-17 1978-10-13 Hoechst France Procede permettant d'augmenter les rendements en hemiacetal-esters de l'acide glyoxylique au cours de leur obtention ou leurs taux de recuperation dans les milieux les contenant
US4144226A (en) * 1977-08-22 1979-03-13 Monsanto Company Polymeric acetal carboxylates
US4234739A (en) * 1978-12-05 1980-11-18 Stauffer Chemical Company Method for preparing glyoxylic acids and derivatives thereof
DE2904775C2 (de) * 1979-02-08 1985-03-21 Hoechst Ag, 6230 Frankfurt Verfahren zur Herstellung von Glyoxylsäureestern
JPS57176929A (en) * 1981-04-24 1982-10-30 Nippon Synthetic Chem Ind Co Ltd:The Preparation of glyoxylic ester
DE3323372A1 (de) * 1983-06-29 1985-01-10 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung eines glyoxylsaeureesters
US4502923A (en) * 1983-10-06 1985-03-05 Monsanto Company Production of high purity alkyl glyoxylate by plural stage distillation
JPS61109221A (ja) * 1984-10-31 1986-05-27 田中貴金属工業株式会社 孔あき型クラツドボタン接点の製造方法
DE3446528A1 (de) * 1984-12-20 1986-06-26 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von glyoxylsaeurehemiacetalestern
DE3602274A1 (de) * 1986-01-25 1987-07-30 Hoechst Ag Halbacetale von glyoxylsaeureestern sowie verfahren zur isolierung von glyoxylsaeureestern

Also Published As

Publication number Publication date
ES2013588A4 (es) 1990-05-16
JPH0273040A (ja) 1990-03-13
DE68916123D1 (de) 1994-07-21
US4867849A (en) 1989-09-19
EP0353215A2 (en) 1990-01-31
DE68916123T2 (de) 1994-12-01
JPH0745435B2 (ja) 1995-05-17
ATE107272T1 (de) 1994-07-15
EP0353215B1 (en) 1994-06-15
CA1324103C (en) 1993-11-09
EP0353215A3 (en) 1990-08-08

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