ES2043629T3 - Procedimiento para la conversion hidrogenadora de aceites pesados y residuales. - Google Patents

Procedimiento para la conversion hidrogenadora de aceites pesados y residuales.

Info

Publication number
ES2043629T3
ES2043629T3 ES87114725T ES87114725T ES2043629T3 ES 2043629 T3 ES2043629 T3 ES 2043629T3 ES 87114725 T ES87114725 T ES 87114725T ES 87114725 T ES87114725 T ES 87114725T ES 2043629 T3 ES2043629 T3 ES 2043629T3
Authority
ES
Spain
Prior art keywords
heavy
oils
catalyst
residual oils
particle size
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87114725T
Other languages
English (en)
Inventor
Klaus Kretschmar
Ludwig Dr Merz
Klaus Dr Niemann
Jose Guitian
Julio Dr Krasuk
Franzo Dr Marruffo
Klaus Kurzeja
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Veba Oel Technologie und Automatisierung GmbH
Petroleos de Venezuela SA
Original Assignee
Veba Oel Technologie und Automatisierung GmbH
Petroleos de Venezuela SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Veba Oel Technologie und Automatisierung GmbH, Petroleos de Venezuela SA filed Critical Veba Oel Technologie und Automatisierung GmbH
Application granted granted Critical
Publication of ES2043629T3 publication Critical patent/ES2043629T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M175/00—Working-up used lubricants to recover useful products ; Cleaning
    • C10M175/0025—Working-up used lubricants to recover useful products ; Cleaning by thermal processes
    • C10M175/0041—Working-up used lubricants to recover useful products ; Cleaning by thermal processes by hydrogenation processes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C1/00—Working-up tar
    • C10C1/20—Refining by chemical means inorganic or organic compounds
    • C10C1/205—Refining by chemical means inorganic or organic compounds refining in the presence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/24—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles
    • C10G47/26—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions with moving solid particles suspended in the oil, e.g. slurries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)
  • Lubricants (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCEDIMIENTO PARA LA CONVERSION POR HIDROGENACION DE ACEITES PESADOS Y RESIDUALES, ACEITES USADOS Y DE DESECHO, ARENAS CON ALQUITRAN Y SIMILARES, POR CONTACTO COM HIDROGENO, A UNA PRESION PARCIAL ENTRE 50 Y 300 BAR, UNA TEMPERATURA ENTRE 250 Y 500 GRADOS C, UNA CARGA DE 0,1 A 5 T POR M3 Y HORA, Y UNA RELACION GAS/LIQUIDO ENTRE 100 Y 10.000 NM3/T. EL OBJETIVO Y MISION TECNICA DE LA INVENCION SON OFRECER UN PROCEDIMIENTO PARA LA TRANSFORMACION DE ACEITES PESADOS Y RESIDUALES EN EL QUE SE EVITE UNA FORMACION EXCESIVA DE ESPUMA Y SE APROVECHE MEJOR EL ESPACIO DE LOS REACTORES DE HIDROGENACION. LA SOLUCION DEL PROBLEMA TECNICO RESIDE EN QUE DURANTE EL TRATAMIENTO DE HIDROGENACION SE AÑADE UN ADITIVO CON DOS INTERVALOS GRANULOMETRICOS DISTINTOS, DE MODO QUE UNA PARTE DEL ADITIVO CONSTITUYE UNA FRACCION DE GRANO FINO CON UN TAMAÑO DE GRANO DE 90 MICRAS O MENOS, Y OTRA PARTE CONSTITUYE UNA FRACCION DE GRANO GRUESO CON UN TAMAÑO DE GRANO DE 100 MICRAS HASTA1000 MICRAS.
ES87114725T 1986-10-08 1987-10-08 Procedimiento para la conversion hidrogenadora de aceites pesados y residuales. Expired - Lifetime ES2043629T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE19863634275 DE3634275A1 (de) 1986-10-08 1986-10-08 Verfahren zur hydrierenden konversion von schwer- und rueckstandsoelen

Publications (1)

Publication Number Publication Date
ES2043629T3 true ES2043629T3 (es) 1994-01-01

Family

ID=6311311

Family Applications (2)

Application Number Title Priority Date Filing Date
ES87114725T Expired - Lifetime ES2043629T3 (es) 1986-10-08 1987-10-08 Procedimiento para la conversion hidrogenadora de aceites pesados y residuales.
ES92112758T Expired - Lifetime ES2078610T3 (es) 1986-10-08 1987-10-08 Procedimiento para la conversion por hidrogenacion de aceites pesados y residuales.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES92112758T Expired - Lifetime ES2078610T3 (es) 1986-10-08 1987-10-08 Procedimiento para la conversion por hidrogenacion de aceites pesados y residuales.

Country Status (8)

Country Link
US (1) US4851107A (es)
EP (2) EP0516187B1 (es)
JP (1) JPH0696710B2 (es)
AT (1) ATE128174T1 (es)
CA (1) CA1302332C (es)
DE (3) DE3634275A1 (es)
ES (2) ES2043629T3 (es)
NO (1) NO171219C (es)

Families Citing this family (48)

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US5166118A (en) * 1986-10-08 1992-11-24 Veba Oel Technologie Gmbh Catalyst for the hydrogenation of hydrocarbon material
DE3737370C1 (de) * 1987-11-04 1989-05-18 Veba Oel Entwicklungs Gmbh Verfahren zur hydrierenden Konversion von Schwer- und Rueckstandsoelen,Alt- und Abfalloelen in Mischung mit Klaerschlaemmen
DE3806365C1 (es) * 1988-02-27 1989-07-20 Veba Oel Entwicklungs-Gesellschaft Mbh, 4650 Gelsenkirchen, De
DE3912807A1 (de) * 1989-04-19 1990-11-08 Gfk Kohleverfluessigung Gmbh Katalysator bzw. additiv zur hydrierenden behandlung von schweren erdoelen bzw. schweren erdoelfraktionen sowie verfahren zur gewinnung des katalysators
US5755955A (en) * 1995-12-21 1998-05-26 Petro-Canada Hydrocracking of heavy hydrocarbon oils with conversion facilitated by control of polar aromatics
US5721186A (en) * 1996-09-06 1998-02-24 The United States Of America As Represented By The United States Department Of Energy Method for producing catalysis from coal
US5922191A (en) * 1996-10-04 1999-07-13 Intevep, S.A. Foam control using a fluidized bed of particles
US5922190A (en) * 1996-10-04 1999-07-13 Intevep, S.A. Process for suppressing foam formation in a bubble column reactor
DE19742266A1 (de) * 1997-09-25 1999-05-06 Ludger Dr Steinmann Aufwertung von Chemie- und Energierohstoffen durch Reaktion mit geringwertigen Rohstoffen
US8506794B2 (en) 2003-12-19 2013-08-13 Shell Oil Company Systems, methods, and catalysts for producing a crude product
US7745369B2 (en) 2003-12-19 2010-06-29 Shell Oil Company Method and catalyst for producing a crude product with minimal hydrogen uptake
US20100098602A1 (en) * 2003-12-19 2010-04-22 Opinder Kishan Bhan Systems, methods, and catalysts for producing a crude product
EP2650346A1 (en) 2004-04-28 2013-10-16 Headwaters Heavy Oil, LLC Ebullated bed hydroprocessing method for treating heavy hydrocarbons
US10941353B2 (en) 2004-04-28 2021-03-09 Hydrocarbon Technology & Innovation, Llc Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock
RU2385346C2 (ru) * 2004-04-28 2010-03-27 Хедуотерс Хэви Ойл, Ллс Способ обработки с использованием водорода и система для обогащения тяжелой нефти с использованием коллоидного или молекулярного катализатора
EP1753845B1 (en) * 2004-04-28 2018-01-03 Headwaters Heavy Oil, LLC Fixed bed hydroprocessing methods and systems and methods for upgrading an existing fixed bed system
US7422904B2 (en) * 2005-02-04 2008-09-09 Exxonmobil Chemical Patents Inc. Method of operating a fixed bed reactor under predetermined hydraulic conditions
CN101166808B (zh) 2005-04-11 2013-03-27 国际壳牌研究有限公司 生产具有降低mcr含量的原油产品的方法和催化剂
US20060234876A1 (en) * 2005-04-11 2006-10-19 Bhan Opinder K Systems, methods, and catalysts for producing a crude product
RU2007141712A (ru) 2005-04-11 2009-05-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) Способ получения полупродукта с пониженным содержанием азота и катализатор для его осуществления
US20080083650A1 (en) 2006-10-06 2008-04-10 Bhan Opinder K Methods for producing a crude product
WO2008043785A1 (en) * 2006-10-10 2008-04-17 Bioecon International Holding N.V. Two-stage process for the conversion of tar sand to liquid fuels and specialty chemicals
US8034232B2 (en) * 2007-10-31 2011-10-11 Headwaters Technology Innovation, Llc Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
US9688934B2 (en) 2007-11-23 2017-06-27 Bixby Energy Systems, Inc. Process for and processor of natural gas and activated carbon together with blower
US8142645B2 (en) * 2008-01-03 2012-03-27 Headwaters Technology Innovation, Llc Process for increasing the mono-aromatic content of polynuclear-aromatic-containing feedstocks
US8679322B2 (en) 2009-11-24 2014-03-25 Intevep, S.A. Hydroconversion process for heavy and extra heavy oils and residuals
US9168506B2 (en) 2010-01-21 2015-10-27 Intevep, S.A. Additive for hydroconversion process and method for making and using same
US9039890B2 (en) 2010-06-30 2015-05-26 Chevron U.S.A. Inc. Two-stage, close-coupled, dual-catalytic heavy oil hydroconversion process
US9334452B2 (en) 2010-06-30 2016-05-10 Chevron U.S.A. Inc. Two-stage, close-coupled, dual-catalytic heavy oil hydroconversion process
US20120157726A1 (en) * 2010-12-15 2012-06-21 Air Liquide Large Industries U.S. Lp Process For The Production Of Cellulose Based Biofuels
CN103228355A (zh) 2010-12-20 2013-07-31 雪佛龙美国公司 加氢加工催化剂及其制备方法
WO2012170167A1 (en) * 2011-06-10 2012-12-13 4Crgroup, Llc Two-stage, close-coupled, dual-catalytic heavy oil hydroconversion process
US9790440B2 (en) 2011-09-23 2017-10-17 Headwaters Technology Innovation Group, Inc. Methods for increasing catalyst concentration in heavy oil and/or coal resid hydrocracker
WO2013126364A2 (en) 2012-02-21 2013-08-29 4CRGroup LLC Two-zone, close-coupled, dual-catalytic heavy oil hydroconversion process utilizing improved hydrotreating
WO2013126362A2 (en) 2012-02-21 2013-08-29 4CRGroup LLC Two-zone, close-coupled, heavy oil hydroconversion process utilizing an ebullating bed first zone
US9644157B2 (en) 2012-07-30 2017-05-09 Headwaters Heavy Oil, Llc Methods and systems for upgrading heavy oil using catalytic hydrocracking and thermal coking
US8999145B2 (en) * 2012-10-15 2015-04-07 Uop Llc Slurry hydrocracking process
JP6231653B2 (ja) * 2013-03-14 2017-11-15 ベーペー オイローパー エスエー 重質炭化水素の水素化転化のための微粉及び粗粒添加剤の導入方法
EP3104968B1 (en) * 2014-02-12 2019-04-24 BP Europa SE Process for hydrocracking heavy oil and oil residue
US11414607B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor with increased production rate of converted products
US11414608B2 (en) 2015-09-22 2022-08-16 Hydrocarbon Technology & Innovation, Llc Upgraded ebullated bed reactor used with opportunity feedstocks
US11421164B2 (en) 2016-06-08 2022-08-23 Hydrocarbon Technology & Innovation, Llc Dual catalyst system for ebullated bed upgrading to produce improved quality vacuum residue product
US11732203B2 (en) 2017-03-02 2023-08-22 Hydrocarbon Technology & Innovation, Llc Ebullated bed reactor upgraded to produce sediment that causes less equipment fouling
MX2018002577A (es) 2017-03-02 2018-11-09 Hydrocarbon Tech & Innovation Llc Reactor de lecho en ebullicion mejorado con menos sedimento de ensuciamiento.
CA3057131C (en) 2018-10-17 2024-04-23 Hydrocarbon Technology And Innovation, Llc Upgraded ebullated bed reactor with no recycle buildup of asphaltenes in vacuum bottoms
FI128237B (en) * 2018-12-21 2020-01-15 Neste Oyj METHOD FOR UPGRADING GAME OILS
CN114425273B (zh) * 2020-10-10 2022-11-18 中国石油化工股份有限公司 碳二加氢反应器的控制方法及应用
US12497569B2 (en) 2022-05-26 2025-12-16 Hydrocarbon Technology & Innovation, Llc Method and system for mixing catalyst precursor into heavy oil using a high boiling hydrocarbon diluent

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CA1094492A (en) * 1977-10-24 1981-01-27 Ramaswami Ranganathan Hydrocracking of heavy oils using iron coal catalyst
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Also Published As

Publication number Publication date
EP0516187A2 (de) 1992-12-02
ATE128174T1 (de) 1995-10-15
US4851107A (en) 1989-07-25
NO171219C (no) 1993-02-10
NO874205D0 (no) 1987-10-07
DE3634275A1 (de) 1988-04-28
ES2078610T3 (es) 1995-12-16
NO874205L (no) 1988-04-11
DE3751534D1 (de) 1995-10-26
DE3787434D1 (de) 1993-10-21
CA1302332C (en) 1992-06-02
JPH0696710B2 (ja) 1994-11-30
EP0263522A3 (en) 1989-04-12
JPS63146989A (ja) 1988-06-18
EP0263522B1 (de) 1993-09-15
EP0263522A2 (de) 1988-04-13
NO171219B (no) 1992-11-02
EP0516187B1 (de) 1995-09-20
EP0516187A3 (en) 1992-12-09

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