ES2044894T3 - Poliuretanos solubles o dispersables en agua, un procedimiento para su fabricacion y su utilizacion para el recubrimiento de substratos discrecionales. - Google Patents
Poliuretanos solubles o dispersables en agua, un procedimiento para su fabricacion y su utilizacion para el recubrimiento de substratos discrecionales.Info
- Publication number
- ES2044894T3 ES2044894T3 ES87117280T ES87117280T ES2044894T3 ES 2044894 T3 ES2044894 T3 ES 2044894T3 ES 87117280 T ES87117280 T ES 87117280T ES 87117280 T ES87117280 T ES 87117280T ES 2044894 T3 ES2044894 T3 ES 2044894T3
- Authority
- ES
- Spain
- Prior art keywords
- polyurethanes
- water
- present
- ethylene oxide
- oxide units
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002635 polyurethane Polymers 0.000 title abstract 6
- 239000004814 polyurethane Substances 0.000 title abstract 6
- 239000011248 coating agent Substances 0.000 title abstract 2
- 238000000576 coating method Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000000758 substrate Substances 0.000 title abstract 2
- XLYOFNOQVPJJNP-PWCQTSIFSA-N Tritiated water Chemical compound [3H]O[3H] XLYOFNOQVPJJNP-PWCQTSIFSA-N 0.000 title 1
- 238000004519 manufacturing process Methods 0.000 title 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 3
- 150000007942 carboxylates Chemical group 0.000 abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
- C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
- C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/50—Polyethers having heteroatoms other than oxygen
- C08G18/5021—Polyethers having heteroatoms other than oxygen having nitrogen
- C08G18/5036—Polyethers having heteroatoms other than oxygen having nitrogen containing -N-C=O groups
- C08G18/5042—Polyethers having heteroatoms other than oxygen having nitrogen containing -N-C=O groups containing ureum groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/7806—Nitrogen containing -N-C=0 groups
- C08G18/7818—Nitrogen containing -N-C=0 groups containing ureum or ureum derivative groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Paints Or Removers (AREA)
Abstract
POLIURETANOS DISPERSABLES Y SOLUBLES EN AGUA QUE PRESENTAN DE 0,5 A 30% EN PESO DE UNIDADES DE OXIDO DE ETILENO CON CADENAS POLIETER ORDENADAS LATERALMENTE O AL FINAL Y DE 0,1 A 120 MILIEQUIVALENTES POR 100 GRAMOS DE SUSTANCIA SOLIDA, GRUPOS CARBOXILATO EN FORMA DE UNIDADES ESTRUCTURALES DE LA FORMULA GENERAL (I), DONDE R ES UN RESTO ALQUILO CON 1 A 4 ATOMOS DE CARBONO; UN PROCEDIMIENTO PARA OBTENCION DE POLIURETANO POR TRANSFORMACION DEL MATERIAL DE PARTIDA RESIDUAL EN LA OBTENCION DE POLIURETANOS SOLUBLES O DISPERSABLES EN AGUA BAJO APLICACION DE COMPONENTES DE CONSTRUCCION QUE PRESENTAN UNIDADES DE OXIDO DE ETILENO Y DE ACIDOS DIHIDROXIMONOCARBOXILICOS DE LA FORMULA (II), Y LA TRANSFORMACION SE CONSIGUE AL MENOS EN LA FASE FINAL EN PRESENCIA DE UN DISOLVENTE MISCIBLE CON AGUA Y A CONTINUACION DE LA TRANSFORMACION LOS GRUPOS CARBOXILO FORMADOS SE PASAN A CARBOXILATO AL MENOS PARCIALMENTE POR MEDIO DE AMONIACO, ASI COMO LA APLICACION DE SOLUCIONES O DISPERSIONES ACUOSAS DE TALES POLIURETANOS COMO MEDIO DE RECUBRIMIENTO DE CUALQUIER SUSTRATO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863641494 DE3641494A1 (de) | 1986-12-04 | 1986-12-04 | In wasser loesliche oder dispergierbare poylurethane, ein verfahren zu ihrer herstellung und ihre verwendung zur beschichtung beliebiger substrate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2044894T3 true ES2044894T3 (es) | 1994-01-16 |
| ES2044894T5 ES2044894T5 (es) | 1997-03-01 |
Family
ID=6315491
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES87117280T Expired - Lifetime ES2044894T5 (es) | 1986-12-04 | 1987-11-24 | Procedimiento para la preparacion de poliuretanos solubles o dispersables en agua y su uso para el recubrimiento de cualquier substrato. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4764553A (es) |
| EP (1) | EP0269972B2 (es) |
| JP (1) | JP2678448B2 (es) |
| AT (1) | ATE85352T1 (es) |
| CA (1) | CA1334231C (es) |
| DE (2) | DE3641494A1 (es) |
| ES (1) | ES2044894T5 (es) |
Families Citing this family (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1213441B (it) * | 1986-12-30 | 1989-12-20 | Ausimont Spa | Dispersioni acquose di poliuretani e fluorurati e loro impiego per spalmature tessili. |
| US4794147A (en) * | 1987-07-24 | 1988-12-27 | Basf Corporation, Inmont Division | Novel non-ionic polyurethane resins having polyether backbones in water-dilutable basecoats |
| DE3728140A1 (de) * | 1987-08-22 | 1989-03-02 | Bayer Ag | Waessrige loesungen oder dispersionen von polyisocyanat-polyadditionsprodukten, ein verfahren zur herstellung der waessrigen loesungen oder dispersionen sowie ihre verwendung als klebstoff |
| GB2209758B (en) * | 1987-09-14 | 1990-12-12 | Ici America Inc | Aqueous dispersions |
| US4904522A (en) * | 1988-07-26 | 1990-02-27 | Mobay Corporation | Process for the production of fiberglass mats |
| DE3828157A1 (de) * | 1988-08-19 | 1990-02-22 | Hoechst Ag | Verwendung von polyurethanharzen fuer waessrige fuellerzusammensetzungen |
| DE3839940A1 (de) * | 1988-11-26 | 1990-05-31 | Stockhausen Chem Fab Gmbh | Waessrige polyurethan- bzw. polyurethanharnstoff-dispersionen und verfahren zum beflocken elastomerer formkoerper unter verwendung dieser dispersionen |
| US4956438A (en) * | 1989-02-08 | 1990-09-11 | The Dow Chemical Company | Bulk polyurethane ionomers |
| JPH02302929A (ja) * | 1989-05-17 | 1990-12-14 | Fuji Photo Film Co Ltd | 磁気記録媒体 |
| DE3922493A1 (de) * | 1989-07-08 | 1991-01-17 | Bayer Ag | Verfahren zur herstellung von waessrigen dispersionen von polyurethanen und ihre verwendung als beschichtungsmittel fuer beliebige substrate |
| DE4003422A1 (de) * | 1990-02-06 | 1991-08-08 | Basf Ag | Waessrige polyurethanzubereitungen |
| US5137967A (en) * | 1990-07-06 | 1992-08-11 | Reichhold Chemicals, Inc. | Hydrazine extended aqueous polyurethane |
| ES2052303T3 (es) * | 1990-07-30 | 1994-07-01 | Miles Inc | Dispersiones acuosas de poliuretano de dos componentes. |
| US5236994A (en) * | 1991-03-28 | 1993-08-17 | Miles Inc. | Process for sealing and/or priming concrete with aqueous polyisocyanate dispersions and the concrete obtained by this process |
| DE4113160A1 (de) * | 1991-04-23 | 1992-10-29 | Bayer Ag | Polyisocyanatgemische, ein verfahren zu ihrer herstellung und ihre verwendung |
| DE4125454A1 (de) * | 1991-08-01 | 1993-02-04 | Bayer Ag | Beschichtungsmittel und ihre verwendung zur erzeugung wasserdampfdurchlaessiger beschichtungen |
| US5358997A (en) * | 1992-05-07 | 1994-10-25 | Miles Inc. | Reactive aqueous polyurea dispersions prepared by an emulsion polymerization process |
| DE4222530A1 (de) * | 1992-07-09 | 1994-01-13 | Hoechst Ag | Polyurethan-Dispersionen |
| DE4226243A1 (de) † | 1992-08-08 | 1994-02-10 | Herberts Gmbh | Wasserverdünnbares Überzugsmittel auf Polyol- und Polyisocyanatbasis, Verfahren zu dessen Herstellung und seine Verwendung |
| US5380787A (en) * | 1992-08-24 | 1995-01-10 | Padico Co., Ltd. | Paint resembling stained glass |
| US5608000A (en) * | 1993-09-24 | 1997-03-04 | H. B. Fuller Licensing & Financing, Inc. | Aqueous polyurethane dispersion adhesive compositions with improved heat resistance |
| US5610232A (en) * | 1993-09-24 | 1997-03-11 | H.B. Fuller Licensing & Financing, Inc. | Aqueous non-gelling, anionic polyurethane dispersions and process for their manufacture |
| US5703158A (en) * | 1993-09-24 | 1997-12-30 | H.B. Fuller Licensing & Financing, Inc. | Aqueous anionic poly (urethane/urea) dispersions |
| JP3042950B2 (ja) * | 1993-09-28 | 2000-05-22 | 大日精化工業株式会社 | ポリウレタンゲル微粒子及びその製造方法 |
| JP3197130B2 (ja) * | 1993-12-27 | 2001-08-13 | 第一工業製薬株式会社 | 熱架橋性ポリウレタンエマルジョン組成物 |
| ATE183562T1 (de) * | 1994-05-03 | 1999-09-15 | Basf Ag | Verwendung von hydrophil modifizierten polyisocyanaten im textilbereich |
| AT401524B (de) | 1994-07-27 | 1996-09-25 | Vianova Kunstharz Ag | Verfahren zur herstellung von wasserverdünnbaren urethanharzen und deren verwendung |
| US5872182A (en) * | 1994-09-09 | 1999-02-16 | H. B. Fuller Licensing & Financing, Inc. | Water-based polyurethanes for footwear |
| DE4433667C1 (de) * | 1994-09-21 | 1996-04-11 | Degussa | Polyoxymethylen mit verbesserter Stabilität gegen Zink- und/oder Kupferionen sowie Verfahren zu seiner Herstellung und Weiterverarbeitung zu Formteilen |
| DE19523103A1 (de) * | 1995-06-26 | 1997-01-02 | Bayer Ag | Wäßrige Bindemittelkombination mit langer Verarbeitungszeit, ein Verfahren zu ihrer Herstellung und ihre Verwendung |
| US5708073A (en) * | 1996-05-23 | 1998-01-13 | Bayer Corporation | Non-aqueous, base-degradable polyurethane |
| US5714561A (en) * | 1996-09-23 | 1998-02-03 | Uniroyal Chemical Company, Inc. | Water-dispersable polyurethanes |
| US5885662A (en) † | 1997-01-31 | 1999-03-23 | Atoma International, Inc. | Decorative automotive interior trim articles with integral light stable polyurethane elastomer covering and process for making the same |
| JPH11131045A (ja) * | 1997-10-28 | 1999-05-18 | Nippon Polyurethane Ind Co Ltd | ラミネート用接着剤 |
| DE19750186A1 (de) * | 1997-11-13 | 1999-05-20 | Bayer Ag | Hydrophilierungsmittel, ein Verfahren zu dessen Herstellung sowie dessen Verwendung als Dispergator für wäßrige Polyurethan-Dispersionen |
| FR2772781B1 (fr) * | 1997-12-24 | 2000-02-04 | Ato Findley Sa | Adhesif polyurethane a haute resistance au cisaillement, bande formee a partir dudit adhesif et article le contenant |
| US5968494A (en) * | 1998-02-24 | 1999-10-19 | National Starch And Chemical Investment Holding Corporation | Polyurethanes with carboxylate functionality for hair fixative applications |
| DE19807908A1 (de) * | 1998-02-25 | 1999-08-26 | Basf Ag | Kosmetisches Mittel |
| DE19852621A1 (de) * | 1998-11-14 | 2000-05-18 | Hansa Textilchemie Gmbh | Permanentes Mittel zum Ausrüsten von Fasern oder aus Faser bestehenden Produkten |
| DE19857530C2 (de) | 1998-12-14 | 2001-11-15 | Bayer Ag | Schlichtezusammensetzung für Glasfasern |
| US6239209B1 (en) | 1999-02-23 | 2001-05-29 | Reichhold, Inc. | Air curable water-borne urethane-acrylic hybrids |
| DE19914882A1 (de) * | 1999-04-01 | 2000-10-05 | Bayer Ag | Selbstvernetzende Polyurethan-, Polyurethan-Polyharnstoff- bzw. Polyharnstoff-Dispersionen für Schlichten |
| US6635706B1 (en) | 1999-06-23 | 2003-10-21 | Reichhold, Inc. | Urethane-acrylic hybrid polymer dispersion |
| KR100746464B1 (ko) | 1999-12-23 | 2007-08-03 | 아크조 노벨 엔.브이. | 부가 중합체 및 폴리우레탄을 포함하는 수성 코팅 조성물 |
| DE10056183A1 (de) * | 2000-11-13 | 2002-05-29 | Basf Ag | Hochverzweigte Polymere zur Antiknitterausrüstung von cellulosehaltigen Textilien |
| GB0128221D0 (en) * | 2001-11-24 | 2002-01-16 | Avecia Ltd | Aqueous urethane dispersants |
| CA2495953C (en) * | 2002-09-18 | 2011-11-22 | Valspar Sourcing, Inc. | Self-crosslinkable waterborne coating composition |
| EP1565506A1 (en) * | 2002-11-04 | 2005-08-24 | INVISTA Technologies S.à.r.l. | Articles comprising aqueous dispersions using poly(urea/urethanes) |
| DE10315175A1 (de) * | 2003-04-03 | 2004-10-14 | Degussa Construction Chemicals Gmbh | Elektrosterisch stabilisierte wässrige Polyurethan-Harze, Verfahren zu ihrer Herstellung und deren Verwendung |
| GB0311121D0 (en) * | 2003-05-15 | 2003-06-18 | Avecia Ltd | Polyurethane dispersants |
| KR101358658B1 (ko) | 2005-06-07 | 2014-02-06 | 루브리졸 어드밴스드 머티어리얼스, 인코포레이티드 | 반응성 이중 결합을 함유하는 폴리우레탄 기재 안료 분산제 |
| US8487051B2 (en) * | 2005-06-07 | 2013-07-16 | Lubrizol Advanced Materials, Inc. | Polyurethane based pigment dispersants which contain reactive double bonds |
| DE102005043173A1 (de) * | 2005-09-09 | 2007-03-15 | Basf Ag | Polyurethandispersion, enthaltend Alkanolamine |
| EP1963392B2 (en) | 2005-12-15 | 2012-08-01 | Akzo Nobel Coatings International BV | Multilayer coating system |
| DE102007054002A1 (de) * | 2007-11-13 | 2009-05-14 | Bayer Materialscience Ag | Nicht-ionisch hydrophilierte Bindemittel-Dispersionen |
| JP5574709B2 (ja) * | 2007-12-06 | 2014-08-20 | 三井化学株式会社 | 親水性樹脂およびフィルム |
| ES2708202T3 (es) * | 2015-06-25 | 2019-04-09 | Covestro Deutschland Ag | Dispersiones de poliuretano desprovistas de urea |
| TW202003731A (zh) * | 2018-06-01 | 2020-01-16 | 日商第一工業製藥股份有限公司 | 塗膜劑 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1495745C3 (de) * | 1963-09-19 | 1978-06-01 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung wäßriger, emulgatorfreier Polyurethan-Latices |
| US3412054A (en) * | 1966-10-31 | 1968-11-19 | Union Carbide Corp | Water-dilutable polyurethanes |
| DE2314513C3 (de) * | 1973-03-23 | 1980-08-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von wäßrigen Polyurethandispersionen |
| DE2314512C3 (de) * | 1973-03-23 | 1980-10-09 | Bayer Ag, 5090 Leverkusen | Thermoplastische, nichtionische, in Wasser despergierbare im wesentlichen lineare Polyurethanelastomere |
| DE2551094A1 (de) * | 1975-11-14 | 1977-05-26 | Bayer Ag | Verfahren zur herstellung von in wasser dispergierbaren polyurethanen |
| DE2651506C2 (de) * | 1976-11-11 | 1986-04-30 | Bayer Ag, 5090 Leverkusen | Verfahren zur Herstellung von in Wasser dispergierbaren Polyurethanen |
| DE2730514A1 (de) * | 1977-07-06 | 1979-01-18 | Bayer Ag | Verfahren zur herstellung von in wasser loeslichen polyurethanen |
| US4277380A (en) * | 1979-03-29 | 1981-07-07 | Textron, Inc. | Water-dispersible urethane polymers and aqueous polymer dispersions |
| DE2930410A1 (de) * | 1979-07-26 | 1981-02-12 | Bayer Ag | Verfahren zur herstellung von stabilen waessrigen dispersionen von oligo- oder polyurethanen, sowie ihre verwendung als beschichtungsmittel fuer flexible oder nicht- flexible substrate |
| US4408008A (en) * | 1981-07-24 | 1983-10-04 | Mobay Chemical Corporation | Stable, colloidal, aqueous dispersions of cross-linked urea-urethane polymers and their method of production |
| US4501852A (en) * | 1983-06-20 | 1985-02-26 | Mobay Chemical Corporation | Stable, aqueous dispersions of polyurethane-ureas |
| US4701480A (en) * | 1985-09-23 | 1987-10-20 | Mobay Corporation | Stable, aqueous dispersions of polyurethane-ureas |
-
1986
- 1986-12-04 DE DE19863641494 patent/DE3641494A1/de not_active Withdrawn
-
1987
- 1987-11-24 ES ES87117280T patent/ES2044894T5/es not_active Expired - Lifetime
- 1987-11-24 EP EP87117280A patent/EP0269972B2/de not_active Expired - Lifetime
- 1987-11-24 DE DE8787117280T patent/DE3784030D1/de not_active Expired - Fee Related
- 1987-11-24 AT AT87117280T patent/ATE85352T1/de not_active IP Right Cessation
- 1987-11-25 CA CA000552714A patent/CA1334231C/en not_active Expired - Fee Related
- 1987-12-01 US US07/127,340 patent/US4764553A/en not_active Expired - Lifetime
- 1987-12-03 JP JP62304702A patent/JP2678448B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0269972A3 (en) | 1989-06-07 |
| CA1334231C (en) | 1995-01-31 |
| EP0269972B2 (de) | 1996-11-27 |
| ATE85352T1 (de) | 1993-02-15 |
| JPS63145317A (ja) | 1988-06-17 |
| DE3641494A1 (de) | 1988-06-09 |
| DE3784030D1 (de) | 1993-03-18 |
| JP2678448B2 (ja) | 1997-11-17 |
| US4764553A (en) | 1988-08-16 |
| ES2044894T5 (es) | 1997-03-01 |
| EP0269972B1 (de) | 1993-02-03 |
| EP0269972A2 (de) | 1988-06-08 |
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