ES2045478T3 - Procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metiltio-butirico. - Google Patents

Procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metiltio-butirico.

Info

Publication number
ES2045478T3
ES2045478T3 ES89400157T ES89400157T ES2045478T3 ES 2045478 T3 ES2045478 T3 ES 2045478T3 ES 89400157 T ES89400157 T ES 89400157T ES 89400157 T ES89400157 T ES 89400157T ES 2045478 T3 ES2045478 T3 ES 2045478T3
Authority
ES
Spain
Prior art keywords
hydroxy
methyltio
procedure
organic phase
aqueous solutions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES89400157T
Other languages
English (en)
Inventor
Hernandez Javier Azagra
Moreno Luis Ruiz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
DESARROLLO TECHNICO IND SOC DE
Original Assignee
DESARROLLO TECHNICO IND SOC DE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by DESARROLLO TECHNICO IND SOC DE filed Critical DESARROLLO TECHNICO IND SOC DE
Application granted granted Critical
Publication of ES2045478T3 publication Critical patent/ES2045478T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C323/00—Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

SE DESCRIBE UN PROCEDIMIENTO QUE CONSISTE EN ENUTRALIZAR CON HIDROXIDO DE AMONIO LA MEZCLA REACCIONAL QUE PROVIENE DE LA HIDROLISIS POR ACIDO SULFURICO DEL 2 - HIDROXI - 4 - METILTIO - BUTIRONITRILO, DE MANERA QUE SE OBTENGA UNA FASE ACUOSA Y UNA FASE ORGANICA, QUE UNA VEZ SEPARADAS, SON SOMETIDAS A EVAPORACION PARA SEPARAR EL SULFATO DE AMONIO FORMADO. EN EL CASO DE LA FASE ACIOSA, ESTE SULFATO ES RETIRADO COMO SUBPRODUCTO Y, EN EL CASO DE LA FASE ORGANICA, ES PUESTO EN CIRCULACION HASTA EL RECIPIENTE DE NEUTRALIZACION. EL ACIDO 2 HIDROXI - 4 - METILTIO - BUTIRICO OBTENIDO A PARTIR DE LA FASE ORGANICA ES ENSEGUIDA DILUIDO CON AGUA Y EVENTUALMENTE ESTABILIZADO CON ACIDO SULFURICO. EL PRODUCTO OBTENIDO ES UTIL COMO SUPLEMENTO ALIMENTARIO EN EL REGIMEN DE LOS ANIMALES.
ES89400157T 1988-02-22 1989-01-19 Procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metiltio-butirico. Expired - Lifetime ES2045478T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
ES8800496A ES2005784A6 (es) 1988-02-22 1988-02-22 Un procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metil-tiobutirico.

Publications (1)

Publication Number Publication Date
ES2045478T3 true ES2045478T3 (es) 1994-01-16

Family

ID=8254970

Family Applications (2)

Application Number Title Priority Date Filing Date
ES8800496A Expired ES2005784A6 (es) 1988-02-22 1988-02-22 Un procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metil-tiobutirico.
ES89400157T Expired - Lifetime ES2045478T3 (es) 1988-02-22 1989-01-19 Procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metiltio-butirico.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES8800496A Expired ES2005784A6 (es) 1988-02-22 1988-02-22 Un procedimiento para preparar soluciones acuosas de acido 2-hidroxi-4-metil-tiobutirico.

Country Status (12)

Country Link
US (1) US4912257A (es)
EP (1) EP0330527B1 (es)
AT (1) ATE80871T1 (es)
CA (1) CA1308419C (es)
DE (1) DE68902934T2 (es)
DK (1) DK175368B1 (es)
ES (2) ES2005784A6 (es)
GR (1) GR3005881T3 (es)
HK (1) HK17793A (es)
IE (1) IE63393B1 (es)
PT (1) PT89776B (es)
SG (1) SG125692G (es)

Families Citing this family (30)

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MY109603A (en) * 1992-05-21 1997-03-31 Daicel Chem Process for producing 2-hydroxy-4-methylthiobutanoic acid
US5498790A (en) * 1993-06-09 1996-03-12 Novus International, Inc. Regeneration of sulfuric acid from sulfate by-products of 2-hydroxy-4-(methylthio)butyric acid manufacture
WO1996001809A1 (de) * 1994-07-11 1996-01-25 Degussa Aktiengesellschaft Verfahren zur gewinnung von 2-hydroxy-4-methylthiobuttersäure (mha), mha und dessen verwendung
DE4428608C1 (de) * 1994-08-12 1996-02-29 Degussa Verfahren zur Gewinnung von 2-Hydroxy-4-methylthiobuttersäure (MHA)
FR2733231B1 (fr) * 1995-04-24 1997-07-04 Rhone Poulenc Nutrition Animal Procede de condensation de l'acide cyanhydrique avec un aldehyde
US5583243A (en) * 1995-05-19 1996-12-10 Zinpro Corporation Salts of alpha-hydroxy aliphatic carboxylic acids and uses thereof
JPH11508876A (ja) 1995-06-07 1999-08-03 ノーバス インターナショナル インコーポレイテッド ２−ヒドロキシ−４−メチルチオブタン酸又はその塩を製造するための連続加水分解法
US5856567A (en) 1995-06-07 1999-01-05 Novus International, Inc. Continuous hydrolysis process for preparing 2-hydroxy-4-methylthiobutanioc acid or salts thereof
DE19548538C2 (de) * 1995-12-23 1997-12-18 Degussa Verfahren zur Gewinnung von 2-Hydroxy-4-methylthiobuttersäure (MHA)
JP3804210B2 (ja) * 1997-03-04 2006-08-02 住友化学株式会社 ２−ヒドロキシ−４−メチルチオブタン酸の製造方法
DE19754562A1 (de) * 1997-12-09 1999-06-10 Degussa Verfahren zur Rückgewinnung von Schwefelsäure aus schwefelhaltigen Nebenprodukten eines Prozesses zur Herstellung von 2-Hydroxy-4-methylthiobuttersäure (MHA)
FR2780969B1 (fr) * 1998-07-10 2000-08-18 Rhone Poulenc Nutrition Animal Procede de separation de l'acide hydroxymethylthiobutyrique
FR2780968B1 (fr) * 1998-07-10 2000-08-18 Rhone Poulenc Nutrition Animal Procede de preparation de l'acide hydroxymethylthiobutyrique
AU2324000A (en) * 1999-02-03 2000-08-25 Sumitomo Chemical Company, Limited Process for producing 2-hydroxy-4-methyl-thiobutanoic acid
WO2001010776A1 (en) 1999-08-05 2001-02-15 Novus International, Inc. Reductive combustion of ammonium salts of sulfuric acid
US6649794B2 (en) * 2000-02-18 2003-11-18 Sumitomo Chemical Company, Limited Method for producing 2-Hydroxy-4-Methylthiobutanoic Acid
WO2005091739A2 (en) * 2004-02-26 2005-10-06 Tasker Products Ip Holdings Corp. Antimicrobial composition for pre-harvest and post-harvest treatment of plants and animals
JP4696496B2 (ja) * 2004-08-18 2011-06-08 住友化学株式会社 ２−ヒドロキシ−４−メチルチオ酪酸の製造方法
DE102004041250A1 (de) * 2004-08-26 2006-03-02 Degussa Ag Herstellung von 2-Hydroxy-4-Methylthiobuttersäure
JP4948002B2 (ja) * 2006-03-10 2012-06-06 住友化学株式会社 ２−ヒドロキシ−４−メチルチオブタン酸の製造方法および製造装置
JP4896548B2 (ja) * 2006-03-10 2012-03-14 住友化学株式会社 ２−ヒドロキシ−４−メチルチオブタン酸の製造方法および製造装置
WO2012113665A1 (de) 2011-02-23 2012-08-30 Evonik Degussa Gmbh Lagerstabiles 2-hydroxy-4-(methylthio)buttersäurenitril
WO2012113664A1 (de) * 2011-02-23 2012-08-30 Evonik Degussa Gmbh Verfahren zur herstellung von 2-hydroxy-4-(methylthio)buttersäurenitril aus 3-(methylthio)propanal und cyanwasserstoff
CN103420883A (zh) * 2013-08-28 2013-12-04 重庆紫光化工股份有限公司 利用粗氢氰酸气体制备2-羟基-4-甲硫基丁腈的方法
CN103641754B (zh) * 2013-11-19 2016-08-24 宁夏紫光天化蛋氨酸有限责任公司 药用d,l-2-羟基-4-甲硫基丁酸金属螯合物的制备方法
CN104262216A (zh) * 2014-10-15 2015-01-07 重庆紫光化工股份有限公司 一种2-羟基-4-甲硫基丁酸的制备方法
CN105130861A (zh) * 2015-07-28 2015-12-09 重庆紫光国际化工有限责任公司 氰醇水解法合成蛋氨酸羟基类似物的分离纯化方法
FR3064006B1 (fr) * 2017-03-16 2019-03-29 Adisseo France S.A.S. Procede de fabrication de l'acide-2-hydroxy-4-methylthio-butyrique
CN111116437B (zh) 2018-11-01 2021-02-05 山东新和成氨基酸有限公司 制备2-羟基-4-甲硫基丁酸及其中间体的方法和装置
CN109232336A (zh) * 2018-11-09 2019-01-18 禄丰天宝磷化工有限公司 一种清洁环保的蛋氨酸羟基类似物生产方法

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA694610A (en) * 1964-09-22 J. Wineman Robert Preparation of salts of 2-hydroxy-4-alkylthiobutyric acid
CA694650A (en) * 1964-09-22 Mark Victor Preparation of 4-(alkylthio)-2-hydroxybutyric acids
GB722024A (en) * 1950-10-31 1955-01-19 Monsanto Chemicals Production of alpha-hydroxy-gamma-mercapto-carboxylic acids and salts thereof and compositions containing the same
US2745745A (en) * 1952-10-30 1956-05-15 Monsanto Chemicals Poultry feed
US2938053A (en) * 1955-12-29 1960-05-24 Monsanto Chemicals Amino acid analogues
CH385823A (de) * 1959-09-01 1964-12-31 Inventa Ag Verfahren zur Herstellung des Calciumsalzes der a-Oxy-y-methylthio-buttersäure
BE611435A (fr) * 1960-12-14 1962-06-12 Stamicarbon Procédé de préparation de sels métalliques d'acide alpha-hydroxy- gamma -méthylmercaptobutyrique
GB1353832A (en) * 1971-08-03 1974-05-22 Degussa Sulphonium compounds of alpha-hydroxy-gamma-alkyl-mercapto butyric acid
US3773927A (en) * 1971-12-20 1973-11-20 Du Pont Preparation of an aqueous slurry of ammonium chloride and methylmercapto-hydroxybutyric acid
US4353924A (en) * 1979-09-04 1982-10-12 Monsanto Company Animal feed supplement having reduced corrosion characteristics
US4524077A (en) * 1983-11-14 1985-06-18 Monsanto Company Liquid 2-hydroxy-4-methylthiobutyric acid and process for the preparation thereof
JPS60166661A (ja) * 1983-11-14 1985-08-29 ヌブス　インターナショナル，インコーポレイテッド ２−ヒドロキシ−４−メチルチオ酪酸の製造方法

Also Published As

Publication number Publication date
HK17793A (en) 1993-03-12
DK175368B1 (da) 2004-09-13
PT89776B (pt) 1994-03-31
CA1308419C (fr) 1992-10-06
IE63393B1 (en) 1995-04-19
IE890547L (en) 1989-08-22
US4912257A (en) 1990-03-27
EP0330527A1 (fr) 1989-08-30
DE68902934T2 (de) 1993-04-08
ES2005784A6 (es) 1989-03-16
SG125692G (en) 1993-02-19
DK78889D0 (da) 1989-02-21
ATE80871T1 (de) 1992-10-15
PT89776A (pt) 1989-10-04
DK78889A (da) 1989-08-22
DE68902934D1 (de) 1992-10-29
EP0330527B1 (fr) 1992-09-23
GR3005881T3 (es) 1993-06-07

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