ES2046185T3 - Catalizador de oligomerizacion y procedimiento de oligomerizacion. - Google Patents

Catalizador de oligomerizacion y procedimiento de oligomerizacion.

Info

Publication number
ES2046185T3
ES2046185T3 ES198787110563T ES87110563T ES2046185T3 ES 2046185 T3 ES2046185 T3 ES 2046185T3 ES 198787110563 T ES198787110563 T ES 198787110563T ES 87110563 T ES87110563 T ES 87110563T ES 2046185 T3 ES2046185 T3 ES 2046185T3
Authority
ES
Spain
Prior art keywords
metal
catalyst
group
transitional
oligomerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES198787110563T
Other languages
English (en)
Inventor
Rex Eugene Murray
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Corp
Original Assignee
Union Carbide Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Corp filed Critical Union Carbide Corp
Application granted granted Critical
Publication of ES2046185T3 publication Critical patent/ES2046185T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B01J31/2252—Sulfonate ligands
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/16—Copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/847—Nickel
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/06—Halogens; Compounds thereof
    • C07C2527/08—Halides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/025—Sulfonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

UN PROCESO DE OLIGOMERIZACION O COOLIGOMERIZACION QUE COMPRENDE PASAR ETILENO O UNA MEZCLA DE ETILENO Y PROPILENO EN CONTACTO CON UN CATALIZADOR, EN LA FASE LIQUIDA, COMPRENDIENDO DICHO CATALIZADOR EL PRODUCTO DE REACCION DE (I) UN COMPUESTO DE METAL DE TRANSICION DONDE EL METAL DE TRANSICION SE SELECCIONA DEL GRUPO QUE COMPRENDE EL NIQUEL, CROMO, COBALTO, HIERRO Y COBRE Y MEZCLAS DE LOS MISMOS; (II) EN EL CASO DE QUE (A) EL METAL DE TRANSICION NO ESTA EN EL ESTADO DE OXIDACION DE O O (B) EL COMPUESTO DE METAL DE TRANSICION NO TIENE UN HIDRURO O UN GRUPO ALQUILO, ALQUENILO, ALQUINILO O HIDRURO O UN GRUPO ALQUILO, ALQUENILO, ALQUINILO O ARILO UNIDO AL METAL DE TANSICION, UN ACTIVADOR CATALIZADOR CONSISTENTE EN UN COMPUESTO CAPAZ DE TRANSFERIR UN HIDRURO O UN GRUPO ALQUILO, ALQUENILO, ALQUINILO O ARILO DESDE SI MISMO AL COMPLEJO METAL DE TRANSICION/LIGANDO FORMADO POR LA REACCION DEL COMPUESTO DEL METAL DE TRANSICION CON ELLIGANDO Y UNIENDO EL GRUPO AL METAL DE TRANSICION, ESTANDO DICHO ACTIVADOR PRESENTE EN CANTIDAD SUFICIENTE PARA ACTIVAR EL CATALIZADOR; Y (III) AL MENOS UN LIGANDO DE SULFONATO ORGANOFOSFORADO CUYA COMPOSICION SE DETALLA.
ES198787110563T 1986-07-21 1987-07-21 Catalizador de oligomerizacion y procedimiento de oligomerizacion. Expired - Lifetime ES2046185T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/887,183 US4689437A (en) 1986-07-21 1986-07-21 Oligomerization to alpha-olefins

Publications (1)

Publication Number Publication Date
ES2046185T3 true ES2046185T3 (es) 1994-02-01

Family

ID=25390621

Family Applications (1)

Application Number Title Priority Date Filing Date
ES198787110563T Expired - Lifetime ES2046185T3 (es) 1986-07-21 1987-07-21 Catalizador de oligomerizacion y procedimiento de oligomerizacion.

Country Status (18)

Country Link
US (1) US4689437A (es)
EP (1) EP0254277B1 (es)
JP (5) JPH0764759B2 (es)
KR (1) KR920003609B1 (es)
CN (2) CN1011694B (es)
AR (1) AR243858A1 (es)
AT (1) ATE86957T1 (es)
AU (1) AU597397B2 (es)
BR (1) BR8703795A (es)
CA (1) CA1329608C (es)
DE (1) DE3784800T2 (es)
ES (1) ES2046185T3 (es)
FI (1) FI88802C (es)
GR (1) GR3008105T3 (es)
MY (1) MY101763A (es)
NO (1) NO173600C (es)
NZ (1) NZ221148A (es)
ZA (1) ZA875353B (es)

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CN105478167B (zh) * 2014-10-13 2017-11-07 中国石油化工股份有限公司 一种乙烯齐聚催化剂组合物及乙烯齐聚方法
CN105562100B (zh) * 2014-10-13 2018-04-10 中国石油化工股份有限公司 一种乙烯四聚催化剂组合物及乙烯四聚方法
CN108484668A (zh) * 2018-04-25 2018-09-04 中山大学 具有磺酰基官能团的有机膦化合物及其制备方法和应用
CN110935489B (zh) * 2019-05-31 2021-10-26 东华大学 通过氢键作用的负载型过渡金属催化剂体系及其制备方法
CN110760336A (zh) * 2019-09-17 2020-02-07 中国科学院青岛生物能源与过程研究所 一种合成气直接制备高品质航油的方法
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JP5647887B2 (ja) 2010-12-24 2015-01-07 株式会社スマートセンシング 多重構造液晶光学素子及びその製造方法

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JPH0764759B2 (ja) 1995-07-12
ZA875353B (en) 1988-04-27
JP2948181B2 (ja) 1999-09-13
EP0254277B1 (en) 1993-03-17
AU7594987A (en) 1988-01-28
KR920003609B1 (ko) 1992-05-04
BR8703795A (pt) 1988-03-29
JPH07165821A (ja) 1995-06-27
NO173600C (no) 1994-01-05
FI873199L (fi) 1988-01-22
NO173600B (no) 1993-09-27
DE3784800T2 (de) 1993-08-19
JP2930921B2 (ja) 1999-08-09
JPH10195090A (ja) 1998-07-28
FI88802B (fi) 1993-03-31
EP0254277A2 (en) 1988-01-27
FI88802C (fi) 1993-07-12
JPS63113006A (ja) 1988-05-18
NO873048L (no) 1987-01-22
DE3784800D1 (de) 1993-04-22
GR3008105T3 (es) 1993-09-30
JP2915302B2 (ja) 1999-07-05
MY101763A (en) 1992-01-17
JPH10195089A (ja) 1998-07-28
CN87105841A (zh) 1988-03-09
CN1011694B (zh) 1991-02-20
US4689437A (en) 1987-08-25
FI873199A0 (fi) 1987-07-21
NZ221148A (en) 1989-04-26
AU597397B2 (en) 1990-05-31
AR243858A1 (es) 1993-09-30
JPH10195000A (ja) 1998-07-28
CN1051312A (zh) 1991-05-15
KR880001705A (ko) 1988-04-26
JP2920126B2 (ja) 1999-07-19
EP0254277A3 (en) 1988-12-28
CA1329608C (en) 1994-05-17
CN1022989C (zh) 1993-12-08
ATE86957T1 (de) 1993-04-15
NO873048D0 (no) 1987-07-21

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