ES2052687T5 - Catalizador de deshidrogenacion. - Google Patents

Catalizador de deshidrogenacion.

Info

Publication number
ES2052687T5
ES2052687T5 ES88201357T ES88201357T ES2052687T5 ES 2052687 T5 ES2052687 T5 ES 2052687T5 ES 88201357 T ES88201357 T ES 88201357T ES 88201357 T ES88201357 T ES 88201357T ES 2052687 T5 ES2052687 T5 ES 2052687T5
Authority
ES
Spain
Prior art keywords
dehydrogenation catalyst
larger
quantities
alkenylaromatics
alkylaromatics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES88201357T
Other languages
English (en)
Other versions
ES2052687T3 (es
Inventor
Fred Allen Sherrod
Ray Allen Smith
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22089136&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2052687(T5) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of ES2052687T3 publication Critical patent/ES2052687T3/es
Application granted granted Critical
Publication of ES2052687T5 publication Critical patent/ES2052687T5/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8872—Alkali or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN CATALIZADOR DE DESHIDROGENACION MEJORADO, UTIL PARA TRANSFORMAR ALQUILAROMATICOS EN ALQUENILAROMATICOS, POR EJEMPLO, ETILBENCENO EN ESTIRENO, QUE CONTIENE CANTIDADES INFERIORES DE HIERRO Y CANTIDADES MAYORES DE CERIO Y POTASIO QUE LAS CONOCIDAS DE LA TECNICA.
ES88201357T 1987-07-01 1988-06-30 Catalizador de deshidrogenacion. Expired - Lifetime ES2052687T5 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/069,464 US4758543A (en) 1987-07-01 1987-07-01 Dehydrogenation catalyst

Publications (2)

Publication Number Publication Date
ES2052687T3 ES2052687T3 (es) 1994-07-16
ES2052687T5 true ES2052687T5 (es) 1998-04-16

Family

ID=22089136

Family Applications (1)

Application Number Title Priority Date Filing Date
ES88201357T Expired - Lifetime ES2052687T5 (es) 1987-07-01 1988-06-30 Catalizador de deshidrogenacion.

Country Status (8)

Country Link
US (1) US4758543A (es)
EP (1) EP0297685B2 (es)
JP (1) JP2604426B2 (es)
AU (1) AU606174B2 (es)
BR (1) BR8803250A (es)
CA (1) CA1329584C (es)
DE (1) DE3876155T3 (es)
ES (1) ES2052687T5 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE116572T1 (de) * 1989-10-31 1995-01-15 Dow Chemical Co Trägerkatalysator, verfahren zu seiner herstellung und seine verwendung für die dehydrierung von kohlenwasserstoffen.
US5262198A (en) * 1991-04-08 1993-11-16 Aluminum Company Of America Method of producing a carbon coated ceramic membrane and associated product
US5376613A (en) * 1993-05-04 1994-12-27 The Dow Chemical Company Dehydrogenation catalyst and process for preparing same
DE4324905A1 (de) * 1993-07-24 1995-01-26 Basf Ag Dehydrierungskatalysator und dessen Verwendung
CA2207560A1 (en) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Large particle dehydrogenation catalyst and process
DE19535416A1 (de) * 1995-09-23 1997-03-27 Basf Ag Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen
US6037305A (en) * 1997-03-03 2000-03-14 Rhodia Chimie Use of Ce/Zr mixed oxide phase for the manufacture of styrene by dehydrogenation of ethylbenzene
IT1293531B1 (it) 1997-08-01 1999-03-01 Sud Chemie Mt S R L Ex Monteca Catalizzatori per la deidrogenazione dell'etilbenzene a stirene
US6756339B1 (en) 1998-04-01 2004-06-29 Sud-Chemie Inc. Dehydrogenation catalysts
US6242379B1 (en) 1998-04-01 2001-06-05 United Catalysts Inc. Dehydrogenation catalysts
KR100584961B1 (ko) * 1999-11-10 2006-05-29 에스케이 주식회사 배연탈질용 선택적 환원 촉매의 코팅방법 및 이의방법으로 제조된 지지체
EG22595A (en) * 1999-12-17 2003-04-30 Dow Chemical Co Dehydrogenation of an alkyl aromatic compound and catalyst regeneration in a fluidized bed reactor
US20020183573A1 (en) * 2002-05-17 2002-12-05 Cocco Raymond A Dehydrogenation of an alkyl aromatic compound and catalyst regeneration in a fluidized bed reactor
US7244868B2 (en) 2002-06-25 2007-07-17 Shell Oil Company Process for the dehydrogenation of an unsaturated hydrocarbon
WO2004060839A1 (en) * 2002-12-19 2004-07-22 Dow Global Technologies Inc. Dehydrogenation of alkyl aromatic compound over a rare earth catalyst
US7282619B2 (en) 2003-10-14 2007-10-16 Shell Oil Company Method of operating a dehydrogenation reactor system
US7297402B2 (en) * 2004-04-15 2007-11-20 Shell Oil Company Shaped particle having an asymmetrical cross sectional geometry
US20060020152A1 (en) * 2004-07-22 2006-01-26 Theobald Eugene H Method for the low temperature selective oxidation of hydrogen contained in a hydrocarbon stream
AU2005307854A1 (en) * 2004-11-18 2006-05-26 Shell Internationale Research Maatschappij B.V. Dehydrogenation process
JP2009508860A (ja) * 2005-09-16 2009-03-05 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 芳香族生成物を作製する方法
JP5096751B2 (ja) 2007-01-26 2012-12-12 クラリアント触媒株式会社 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法
US20090246523A1 (en) * 2008-03-28 2009-10-01 Shizhong Jason Zhao Small Diameter Calcium Aluminate Based Catalyst Supports by Extrusion and Pelletizing
CN102046568A (zh) * 2008-04-09 2011-05-04 国际壳牌研究有限公司 改进脱氢工艺的方法
KR20110057184A (ko) 2008-09-22 2011-05-31 각코호진 와세다다이가쿠 산화환원능력이 높은 알킬 방향족 화합물의 탈수소 촉매 및 그 제조 방법 및 그것을 사용한 탈수소화 방법
EP2353712A4 (en) 2008-11-07 2012-08-01 Sued Chemie Catalysts Jp Inc DEHYDRATION CATALYST FOR ALKYLAROMATIC COMPOUNDS WITH HIGH PERFORMANCE IN THE PRESENCE OF HIGH-CONCENTRATED CO2, METHOD OF PREPARATION THEREOF AND DEHYDRATION METHOD THEREWITH
CN103539627B (zh) * 2012-07-12 2015-09-09 中国石油化工股份有限公司 制造苯乙烯的方法
RU2016148232A (ru) 2014-05-09 2018-06-09 Басф Се Улучшенный катализатор дегидрирования углеводородов
US10315970B2 (en) 2014-05-09 2019-06-11 Basf Se Catalyst for dehydrogenating hydrocarbons

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2036410A (en) * 1929-08-20 1936-04-07 Du Pont Process of making styrene
US1985844A (en) * 1930-08-16 1934-12-25 Ig Farbenindustrie Ag Process for the manufacture of aromatic hydrocarbons containing unsaturated side chains
US2408140A (en) * 1944-09-18 1946-09-24 Shell Dev Dehydrogenation catalyst
US2414585A (en) * 1945-06-26 1947-01-21 Shell Dev Catalytic dehydrogenation
US2866790A (en) * 1957-02-18 1958-12-30 Phillips Petroleum Co Catalyst and dehydrogenation process
NL256686A (es) * 1959-10-28
US3223743A (en) * 1961-12-29 1965-12-14 Monsanto Chemicals Dehydrogenation of ethylbenzene
US3360579A (en) * 1965-05-21 1967-12-26 Shell Oil Co Catalytic dehydrogenation of alkylaromatics
US3364277A (en) * 1965-05-21 1968-01-16 Shell Oil Co Dehydrogenating olefins to diolefins in the presence of a yellow iron oxide catalyst
US3904552A (en) * 1973-03-08 1975-09-09 Girdler Chemical Dehyrogenation catalyst
US4098723A (en) * 1977-01-27 1978-07-04 Shell Oil Company Catalyst for dehydrogenation
IN148558B (es) * 1977-04-14 1981-04-04 Shell Int Research
US4467046A (en) * 1982-01-07 1984-08-21 Smith James L Dehydrogenation catalyst
JPS58177148A (ja) * 1982-04-13 1983-10-17 Mitsubishi Petrochem Co Ltd スチレン製造用触媒
JPS6190741A (ja) * 1984-10-11 1986-05-08 Nissan Gaadoraa Shokubai Kk 脱水素用触媒

Also Published As

Publication number Publication date
ES2052687T3 (es) 1994-07-16
BR8803250A (pt) 1989-01-31
EP0297685B2 (en) 1998-02-25
DE3876155D1 (de) 1993-01-07
EP0297685B1 (en) 1992-11-25
DE3876155T2 (de) 1993-04-01
CA1329584C (en) 1994-05-17
JP2604426B2 (ja) 1997-04-30
US4758543A (en) 1988-07-19
EP0297685A1 (en) 1989-01-04
DE3876155T3 (de) 1998-04-30
AU1852588A (en) 1989-01-05
JPS6445320A (en) 1989-02-17
AU606174B2 (en) 1991-01-31

Similar Documents

Publication Publication Date Title
ES2052687T3 (es) Catalizador de deshidrogenacion.
ES2044151T3 (es) Reacciones cataliticas usando zeolitas.
ES2184888T3 (es) Empleo de catalizadores de estaño, asi como mezclas reticulables que contienen estos catalizadores.
DE3665301D1 (en) Dehydrogenation of alkylaromatics
MX167426B (es) Procedimiento para la oxideshidrogenacion de etano en etileno
KR890009824A (ko) 시클로헥세논 탈 수소 방법
ES479066A1 (es) Un procedimiento para preparar 6a,10a-cis-hexahidrodibenzo( b,d-piran-9-onas.
BR9306798A (pt) Processo para a produção de aromátios a partir de butadieno
IT1152297B (it) Procedimento per l'isomerizzazione di ossido di stirene od omologhi a beta-fenilaldeidi
ES2119283T3 (es) Proceso para producir 2-metil-1,4-naftoquinona.
ES468218A1 (es) Perfeccionamientos en o relacionados con compuestos organi- cos.
KR890005016A (ko) 폴리방향족 물질의 트랜스 알킬화 방법
ES2191137T3 (es) Procedimiento para la deshidrogenacion de 1,4-butano-diol para dar gama-butirolactona.
ES2136785T3 (es) Un procedimiento para producir alcohol alfa-feniletilico.
ES2089739T3 (es) Reduccion del contenido en benceno en las gasolinas por un procedimiento de isomerizacion.
YU48387B (sh) Postupak za regenerisanje upotrebljenog katalizatora za alkilovanje
BR0016603A (pt) Processo para a produção de olefinas
ES2052083T3 (es) Craqueo catalitico.
BR9813345A (pt) Processo para preparar uma quinonadiimina
BR8506294A (pt) Processo para a separacao de t-butilestireno de um efluente de uma zona de desidrogenacao por oxidacao contendo t-butiletilbenzeno e t-butilestireno
DE3887859D1 (de) Zersetzung von Dihydroperoxyd zu Resorcin.
ES2182353T3 (es) Fabricacion y purificacion de 3-(4-hidroxifenil)-1,1,3-trimetilindan-5-ol.
Gani et al. Intramolecular free-radical functionalisation of the methyl group of 5′-deoxyadenosine
KR920006269A (ko) 2급-부틸벤젠의 제조방법
NO922360L (no) Fremgangsmaate for dehydrogenering av en c2-c10-paraffin til et alkenprodukt

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 297685

Country of ref document: ES