ES2054837T3 - Interpolimero compuesto multicapas que comprende una distribucion bimodal de particulas, su procedimiento de preparacion y su aplicacion al refuerzo de matrices termoplasticas. - Google Patents
Interpolimero compuesto multicapas que comprende una distribucion bimodal de particulas, su procedimiento de preparacion y su aplicacion al refuerzo de matrices termoplasticas.Info
- Publication number
- ES2054837T3 ES2054837T3 ES88400190T ES88400190T ES2054837T3 ES 2054837 T3 ES2054837 T3 ES 2054837T3 ES 88400190 T ES88400190 T ES 88400190T ES 88400190 T ES88400190 T ES 88400190T ES 2054837 T3 ES2054837 T3 ES 2054837T3
- Authority
- ES
- Spain
- Prior art keywords
- parts
- particles
- monomer
- reinforcement
- application
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002245 particle Substances 0.000 title abstract 2
- 230000002902 bimodal effect Effects 0.000 title 1
- 239000002131 composite material Substances 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 230000002787 reinforcement Effects 0.000 title 1
- 229920001169 thermoplastic Polymers 0.000 title 1
- 239000004416 thermosoftening plastic Substances 0.000 title 1
- 239000000178 monomer Substances 0.000 abstract 5
- -1 aralkyl acrylate Chemical compound 0.000 abstract 2
- 238000004132 cross linking Methods 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 150000001993 dienes Chemical class 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012035 limiting reagent Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S525/902—Core-shell
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
ESTA MATERIA INTERPOLIMERA MULTICAPAS COMPRENDE UN ESTADO INTERNO, ELASTOMERO, POLIMERIZADO A PARTIR DE (A) 50-99,9 PARTES DE AL MENOS UNO DE ENTRE DIENOS CONJUGADOS Y ACRILATO DE ALQUILO Y DE ARALQUILO; (B) 0-49,9 PARTES DE AL MENOS UN MONOMERO COPOLIMERIZABLE, (C) 0,05-8 PARTES DE AL MENOSUN MONOMERO DE RETICULACION; Y (D) 0,05-6 PARTES DE AL MENOS UN MONOMERO DE INJERTO; Y UN ESTADO EXTERNO NO ELASTOMERO, POLIMEROZADO A PARTIR DE (A) 50-99,9 PARTES EN PESO DE AL MENOS UNO DE ENTRE: METACRILATO DE ALQUILO, HIDROCARBUROS VINILAROMATICOS Y NITRATOS Y NITRILOS INSATURADOS; (B) 0,1-50 PARTES DE AL MENOS UN MONOMERO COPOLIMERIZABLE; Y (C) 0-5 PARTES DE AL MENOS UN AGENTE LIMITADOR DE CADENA, DANDOSE LAS PARTES EN PESO, DICHO POLIMERO PUEDE COMPRENDER UN ESTADO DE NUCLEO NO ELASTOMERO O BIEN ELASTOMERO SIN MONOMEROS DE INJERTO Y DE RETICULACION. SE MEZCLA EN LAS CANTIDADES DADAS, DOS POBLACIONES DE PARTICULAS DE DIAMETRO MEDIO RESPECTIVAMENTE, 40-150 NM Y ALREDEDOR DE 160-500 NM. SE MEJORA ASI LA RESISENCIA AL CHOQUE DE LAS MATRICES RESULTANTES.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8701169A FR2610328B1 (fr) | 1987-01-30 | 1987-01-30 | Matiere interpolymere renforcatrice de matrices thermoplastiques rigides, preparation de cette matiere interpolymere et compositions renforcees correspondantes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2054837T3 true ES2054837T3 (es) | 1994-08-16 |
Family
ID=9347454
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88400190T Expired - Lifetime ES2054837T3 (es) | 1987-01-30 | 1988-01-28 | Interpolimero compuesto multicapas que comprende una distribucion bimodal de particulas, su procedimiento de preparacion y su aplicacion al refuerzo de matrices termoplasticas. |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US4897449A (es) |
| EP (1) | EP0279724B1 (es) |
| JP (1) | JPS63270715A (es) |
| KR (1) | KR950010231B1 (es) |
| AT (1) | ATE88729T1 (es) |
| BR (1) | BR8800413A (es) |
| CA (1) | CA1310864C (es) |
| DE (1) | DE3880528T2 (es) |
| ES (1) | ES2054837T3 (es) |
| FR (1) | FR2610328B1 (es) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3907019A1 (de) * | 1989-03-04 | 1990-09-06 | Roehm Gmbh | Thermoplastisch verarbeitbare loesungsmittelbestaendige kunststoffmischungen |
| US5047474A (en) * | 1989-08-03 | 1991-09-10 | Rohm And Haas Company | Polymeric modifier compositions |
| ATE120773T1 (de) * | 1989-12-21 | 1995-04-15 | Atochem Elf Sa | Verfahren zur herstellung einer gegossenen platte aus thermoplastischem harz. |
| JP3396240B2 (ja) * | 1992-05-25 | 2003-04-14 | 住友化学工業株式会社 | メタアクリル樹脂組成物 |
| DE4226750A1 (de) * | 1992-08-13 | 1994-02-17 | Basf Ag | Thermoplastische Formmasse mit Matteffekt |
| JPH11502540A (ja) † | 1995-02-01 | 1999-03-02 | バイエル・アントバーペン・エヌ・ベー | 改善された着色性を有する重合体配合物 |
| DE19527579A1 (de) * | 1995-07-28 | 1997-01-30 | Basf Ag | Transparente spannungsrißbeständige Formmassen mit einem verbesserten Zähigkeits-Steifigkeits-Verhältnis |
| TW476772B (en) * | 1996-04-30 | 2002-02-21 | Kureha Chemical Ind Co Ltd | Acrylic copolymer, process for producing same and vinyl chloride resin composition containing same |
| US6072002A (en) * | 1997-10-21 | 2000-06-06 | Bayer Corporation | Weatherable resinous composition |
| JP3376283B2 (ja) | 1998-07-14 | 2003-02-10 | 三菱レイヨン株式会社 | アクリルゴム系衝撃強度改質剤およびこれを用いた硬質塩化ビニル系樹脂組成物 |
| GB9919304D0 (en) | 1999-08-17 | 1999-10-20 | Ici Plc | Acrylic composition |
| TW572912B (en) * | 2000-10-25 | 2004-01-21 | Rohm & Haas | Processes for preparing impact modifier powders |
| TWI231305B (en) * | 2000-10-25 | 2005-04-21 | Rohm & Haas | High rubber impact modifier powders |
| KR100428637B1 (ko) * | 2000-12-13 | 2004-04-30 | 주식회사 엘지화학 | 아크릴계 충격보강제의 제조방법 |
| KR100463347B1 (ko) * | 2001-12-17 | 2004-12-23 | 주식회사 엘지화학 | 스티렌-아크릴계 공중합체 수지의 연속 제조방법 |
| KR101335319B1 (ko) | 2005-10-28 | 2013-12-03 | 아르끄마 프랑스 | 충격 보강제 크기의 바이모달 분포를 갖는 충격 보강된 아크릴 |
| KR101338539B1 (ko) * | 2011-01-27 | 2013-12-06 | 주식회사 엘지화학 | 딥 성형용 카르본산 변성 니트릴계 공중합체 라텍스, 이를 포함하는 딥 성형용 라텍스 조성물 및 이로부터 제조된 성형품 |
| AU2015210804B2 (en) | 2014-01-31 | 2018-09-20 | Kimberly-Clark Worldwide, Inc. | Thin nanocomposite film for use in an absorbent article |
| BR112016017524B1 (pt) * | 2014-01-31 | 2021-11-30 | Kimberly-Clark Worldwide, Inc | Película nanocomposta rígida para uso em um artigo absorvente |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US150032A (en) * | 1874-04-21 | Improvement in flue-caps | ||
| FR2092389A5 (es) * | 1970-04-13 | 1972-01-21 | Rohm & Haas | |
| US4145380A (en) * | 1970-07-17 | 1979-03-20 | Rohm And Haas Company | Vinyl halide polymer impact modifiers |
| US3668274A (en) * | 1970-09-10 | 1972-06-06 | Rohm & Haas | Acrylic modifiers for polycarbonamides |
| FR2159822A5 (en) * | 1971-11-10 | 1973-06-22 | Tarrerias Georges | Colour tinting of cutlery - to improve suppleness of blades |
| JPS5845446B2 (ja) * | 1975-03-06 | 1983-10-11 | ジェイエスアール株式会社 | ネツカソセイジユシノセイゾウホウホウ |
| JPS5928576B2 (ja) * | 1980-07-14 | 1984-07-13 | 東レ株式会社 | 耐衝撃性熱可塑性樹脂の製造方法 |
| US4419492A (en) * | 1981-08-06 | 1983-12-06 | Monsanto Company | Process for preparing ABS polymeric polyblends |
| JPS59122513A (ja) * | 1982-12-28 | 1984-07-16 | Mitsubishi Rayon Co Ltd | 多層構造重合体の製造方法 |
| JPS6038418A (ja) * | 1983-08-12 | 1985-02-28 | Mitsubishi Rayon Co Ltd | 耐衝撃性改質剤 |
| JPS6090209A (ja) * | 1983-10-24 | 1985-05-21 | Asahi Chem Ind Co Ltd | 後架橋性のない多層構造アクリル樹脂組成物 |
-
1987
- 1987-01-30 FR FR8701169A patent/FR2610328B1/fr not_active Expired
-
1988
- 1988-01-28 ES ES88400190T patent/ES2054837T3/es not_active Expired - Lifetime
- 1988-01-28 EP EP88400190A patent/EP0279724B1/fr not_active Revoked
- 1988-01-28 DE DE88400190T patent/DE3880528T2/de not_active Revoked
- 1988-01-28 AT AT88400190T patent/ATE88729T1/de not_active IP Right Cessation
- 1988-01-29 BR BR8800413A patent/BR8800413A/pt not_active IP Right Cessation
- 1988-01-29 CA CA000557700A patent/CA1310864C/fr not_active Expired - Lifetime
- 1988-01-29 JP JP63019438A patent/JPS63270715A/ja active Pending
- 1988-01-29 US US07/150,021 patent/US4897449A/en not_active Expired - Lifetime
- 1988-01-30 KR KR1019880000846A patent/KR950010231B1/ko not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| FR2610328B1 (fr) | 1989-08-25 |
| ATE88729T1 (de) | 1993-05-15 |
| FR2610328A1 (fr) | 1988-08-05 |
| KR880009052A (ko) | 1988-09-14 |
| DE3880528T2 (de) | 1993-10-14 |
| US4897449A (en) | 1990-01-30 |
| EP0279724B1 (fr) | 1993-04-28 |
| DE3880528D1 (de) | 1993-06-03 |
| BR8800413A (pt) | 1988-09-20 |
| EP0279724A2 (fr) | 1988-08-24 |
| KR950010231B1 (ko) | 1995-09-12 |
| CA1310864C (fr) | 1992-12-01 |
| JPS63270715A (ja) | 1988-11-08 |
| EP0279724A3 (en) | 1988-09-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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