ES2058079T3 - Composicion de resina epoxidicas avanzadas y cationicas. - Google Patents

Composicion de resina epoxidicas avanzadas y cationicas.

Info

Publication number
ES2058079T3
ES2058079T3 ES87110375T ES87110375T ES2058079T3 ES 2058079 T3 ES2058079 T3 ES 2058079T3 ES 87110375 T ES87110375 T ES 87110375T ES 87110375 T ES87110375 T ES 87110375T ES 2058079 T3 ES2058079 T3 ES 2058079T3
Authority
ES
Spain
Prior art keywords
diglicidilic
cationic
epoxy
weight
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87110375T
Other languages
English (en)
Inventor
Kenneth W Anderson
Richard A Hickner
Nancy A Rao
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/887,849 external-priority patent/US4698141A/en
Priority claimed from US07/069,459 external-priority patent/US4868230A/en
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Application granted granted Critical
Publication of ES2058079T3 publication Critical patent/ES2058079T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/02—Polycondensates containing more than one epoxy group per molecule
    • C08G59/04—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof
    • C08G59/06—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols
    • C08G59/066—Polycondensates containing more than one epoxy group per molecule of polyhydroxy compounds with epihalohydrins or precursors thereof of polyhydric phenols with chain extension or advancing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/14—Polycondensates modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22—Di-epoxy compounds
    • C08G59/226—Mixtures of di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443—Polyepoxides
    • C09D5/4434—Polyepoxides characterised by the nature of the epoxy binder

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Molecular Biology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Epoxy Resins (AREA)
  • Paints Or Removers (AREA)

Abstract

SE PREPARA UNA RESINA CATIONICA EPOXI AVANZADA QUE TIENE UNA DENSIDAD DE CARGA COMPRENDIDA ENTRE 0,2 Y 0,6 MILIEQUIVALENTES DE CARGA CATIONICA POR GRAMO DE RESINA, HACIENDO REACCIONAR EN PRERSENCIA DE UN CATALIZADOR ADECUADO (A) UNA COMPOSICION QUE COMPRENDE (1) AL MENOS UN ETERDIGLICIDILICO DE UN POLIOL Y (2) AL MENOS UN ETER DIGLICIDILICO DE UN FENOLDIHIDRICO CON (B) AL MENOS UN FENOL DIHIDRICO Y OPCIONALMENTE (C) UN AGENTE MONOFUNCIONAL TERMINADOR DE CADENA. LOS COMPONENTES (A-1) Y (A-2) SE EMPLEAN EN CANTIDADES TALES QUE ENTRE 10 Y 75% EN PESO DE LOS ETERES DIGLICIDILICOS DEL COMPONENTE (A) ESTAN CONSTITUIDOS POR EL COMPONENTE (A-1) Y ENTRE EL 25 Y 90% EN PESO DE TALES ETERES DIGLICIDILICOS ESTAN CONSTITUIDOS POR EL COMPONENTE (A-2). LOS COMPONENTES (A) Y (B) SE EMPLEAN EN CANTIDADES TALES QUE LA RESINA EPOXI RESULTANTE TIENE UN EQUIVALENTE MEDIO EN PESO EPOXIDO ENTRE 350 Y 10000. LOS GRUPOS OXIVANO TERMINALES DE LA RESINA EPOXI AVANZADA FORMADA SE CONVIERTEN EN GRUPOS CATIONICOSHACIENDO REACCIONAR CON UN COMPUESTO NUCLEOFILO Y AÑADIENDO UN ACIDO ORGANICO Y AGUA AL MENOS EN UN PUNTO DE LA REACCION. TAMBIEN SE REFIERE LA INVENCION A LA PREPARACION DE ESTAS RESINAS CATIONICAS EPOXI AVANZADAS Y A SU EMPLEO EN LA PREPARACION DE RECUBRIMIENTOS ADECUADOS PARA ELECTRODEPOSICION.
ES87110375T 1986-07-18 1987-07-17 Composicion de resina epoxidicas avanzadas y cationicas. Expired - Lifetime ES2058079T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/887,849 US4698141A (en) 1986-07-18 1986-07-18 Cationic, advanced epoxy resin compositions
US07/069,459 US4868230A (en) 1987-07-02 1987-07-02 Cationic, advanced epoxy resins from (1) diglycidyl ethers of phenols (2) diglycidyl ethers of alkane diols and (3) a dihydric phenol

Publications (1)

Publication Number Publication Date
ES2058079T3 true ES2058079T3 (es) 1994-11-01

Family

ID=26750087

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87110375T Expired - Lifetime ES2058079T3 (es) 1986-07-18 1987-07-17 Composicion de resina epoxidicas avanzadas y cationicas.

Country Status (12)

Country Link
EP (1) EP0253405B1 (es)
JP (1) JPH0647611B2 (es)
KR (1) KR910000857B1 (es)
CN (1) CN1016430B (es)
AU (1) AU599681B2 (es)
BR (1) BR8707397A (es)
DE (1) DE3786959T2 (es)
DK (1) DK376287A (es)
ES (1) ES2058079T3 (es)
MY (1) MY101761A (es)
NO (1) NO872998L (es)
WO (1) WO1988000600A1 (es)

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4727119A (en) * 1986-09-15 1988-02-23 The Dow Chemical Company Halogenated epoxy resins
US4867854A (en) * 1986-09-24 1989-09-19 The Dow Chemical Company Controlled film build epoxy coatings applied by cathodic electrodeposition
CA1336029C (en) * 1987-11-06 1995-06-20 Michiharu Kitabatake Coating resin composition containing an epoxy-polyamine resin
JPH0751693B2 (ja) * 1987-11-06 1995-06-05 関西ペイント株式会社 被覆用樹脂組成物
US5212262A (en) * 1987-12-03 1993-05-18 The Dow Chemical Company Epoxy resin advanced with diphenol/diglycidyl ether adducts
US4835225A (en) * 1988-01-13 1989-05-30 The Dow Chemical Company Modified advanced epoxy resins
US5147905A (en) * 1991-05-01 1992-09-15 The Dow Chemical Company Advanced and unadvanced compositions, nucleophilic derivatives thereof and curable and coating compositions thereof
MY106546A (en) * 1990-05-15 1995-06-30 Dow Chemical Co Advanced and unadvanced compositions, nucleophilic derivatives thereof curable and coating compositions thereof
US5244998A (en) * 1990-05-15 1993-09-14 The Dow Chemical Company Advanced and unadvanced compositions, nucleophilic derivatives thereof and curable coating compositions thereof
NZ244069A (en) * 1991-08-26 1995-04-27 Dow Chemical Co Flexibilized epoxy resin comprising a residue of at least one polyaromatic hydroxy compound and at least one polyglycidyl ether of such compounds and a polybutylene glycol derivative; electrodeposition coatings
EP0666885B1 (en) * 1992-10-21 2003-02-05 Air Products And Chemicals, Inc. Novel ionic emulsion polymers and their preparation
EP0864594A1 (de) * 1997-03-06 1998-09-16 Ciba SC Holding AG Alpha-Glykolgruppen enthaltende Glycidylverbindungen
US5962093A (en) * 1997-10-22 1999-10-05 The Dow Chemical Company Thermally stable polyetheramines
JP2000290584A (ja) * 1999-02-05 2000-10-17 Kansai Paint Co Ltd 被覆用樹脂組成物
US7892396B2 (en) 2006-06-07 2011-02-22 Zephyros, Inc. Toughened activatable material for sealing, baffling or reinforcing and method of forming same
JP5567767B2 (ja) * 2007-05-18 2014-08-06 関西ペイント株式会社 カチオン電着塗料組成物
US8729196B2 (en) 2007-09-11 2014-05-20 Kansai Paint Co., Ltd. Cationic electrodeposition paint compositions
JP5637722B2 (ja) * 2009-04-24 2014-12-10 関西ペイント株式会社 カチオン電着塗料組成物
JP5634145B2 (ja) * 2009-07-31 2014-12-03 関西ペイント株式会社 カチオン電着塗料組成物
EP2621990B1 (en) 2010-09-30 2016-02-24 Blue Cube IP LLC Thermosettable compositions and thermosets therefrom
JP2013539804A (ja) * 2010-09-30 2013-10-28 ダウ グローバル テクノロジーズ エルエルシー アドバンストエポキシ樹脂組成物
JP2014501793A (ja) 2010-09-30 2014-01-23 ダウ グローバル テクノロジーズ エルエルシー エポキシ樹脂組成物
WO2012044442A1 (en) 2010-09-30 2012-04-05 Dow Global Technologies Llc Process for preparing epoxy resins
JP5795804B2 (ja) 2010-09-30 2015-10-14 ダウ グローバル テクノロジーズ エルエルシー コーティング組成物
CN103140532B (zh) 2010-09-30 2016-05-04 蓝立方知识产权有限责任公司 环氧树脂加合物及其热固性材料
CN104685012B (zh) * 2012-10-02 2016-12-14 关西涂料株式会社 阳离子电沉积涂料组合物
CN114149774A (zh) * 2021-09-06 2022-03-08 常熟市石油固井工具有限公司 一种耐高温高强度树脂胶水
CN117050476B (zh) * 2023-10-11 2024-03-26 山东万亿体育健康服务有限公司 一种高强度双酚a型环氧树脂及其制备方法

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4048179A (en) * 1974-12-12 1977-09-13 Ciba-Geigy Corporation Process for preparing water-dilutable, heat-curing coating compositions
IT1027884B (it) * 1974-12-20 1978-12-20 Sir Soc Italiana Resine Spa Procedimento per la preparazione di poliespossidi
DE2829236A1 (de) * 1977-07-06 1979-01-25 Ciba Geigy Ag Lineare, glycidyl- und hydroxylgruppenhaltige polyaetherharze
US4182831A (en) * 1977-12-07 1980-01-08 Celanese Polymer Specialties Company Cationic epoxide resinous composition
JPS5638358A (en) * 1979-09-07 1981-04-13 Dainippon Ink & Chem Inc Curable composition for covering
US4315044A (en) * 1980-11-05 1982-02-09 Celanese Corporation Stable aqueous epoxy dispersions
US4339369A (en) * 1981-04-23 1982-07-13 Celanese Corporation Cationic epoxide-amine reaction products
US4419467A (en) * 1981-09-14 1983-12-06 Ppg Industries, Inc. Process for the preparation of cationic resins, aqueous, dispersions, thereof, and electrodeposition using the aqueous dispersions
US4608313A (en) * 1982-06-10 1986-08-26 The Dow Chemical Company Advanced epoxy resins crosslinked with polyisocyanates
EP0111547B1 (en) * 1982-06-10 1988-11-17 The Dow Chemical Company Advanced epoxy resins and coating compositions containing the advanced epoxy resins
JPS59501017A (ja) * 1982-06-10 1984-06-07 ザ・ダウ・ケミカル・カンパニ− エポキシ樹脂含有被覆組成物
US4610769A (en) * 1983-05-16 1986-09-09 Ppg Industries, Inc. Method of electrodeposition employing low temperature aminoplast curable cationic electrodepositable coating compositions
US4552814A (en) * 1984-05-21 1985-11-12 The Dow Chemical Company Advanced epoxy resins having improved impact resistance when cured
US4612156A (en) * 1985-02-26 1986-09-16 The Dow Chemical Company Solventless process for producing resinous materials
US4608405A (en) * 1985-05-06 1986-08-26 Celanese Corporation Aqueous based epoxy resin curing agents

Also Published As

Publication number Publication date
NO872998D0 (no) 1987-07-17
NO872998L (no) 1988-01-19
EP0253405B1 (en) 1993-08-11
EP0253405A2 (en) 1988-01-20
CN87104910A (zh) 1988-05-04
WO1988000600A1 (en) 1988-01-28
KR880001760A (ko) 1988-04-26
DE3786959D1 (de) 1993-09-16
CN1016430B (zh) 1992-04-29
AU599681B2 (en) 1990-07-26
DK376287D0 (da) 1987-07-17
DK376287A (da) 1988-01-19
JPS6392637A (ja) 1988-04-23
MY101761A (en) 1992-01-17
KR910000857B1 (ko) 1991-02-11
BR8707397A (pt) 1988-09-13
JPH0647611B2 (ja) 1994-06-22
AU7575787A (en) 1988-01-21
EP0253405A3 (en) 1988-07-27
DE3786959T2 (de) 1994-02-03

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