ES2064307T3 - Polimeros solubles, conductores de la electricidad, procedimiento para su obtencion y uso de los mismos. - Google Patents

Polimeros solubles, conductores de la electricidad, procedimiento para su obtencion y uso de los mismos.

Info

Publication number
ES2064307T3
ES2064307T3 ES87112128T ES87112128T ES2064307T3 ES 2064307 T3 ES2064307 T3 ES 2064307T3 ES 87112128 T ES87112128 T ES 87112128T ES 87112128 T ES87112128 T ES 87112128T ES 2064307 T3 ES2064307 T3 ES 2064307T3
Authority
ES
Spain
Prior art keywords
square
group
procedure
polymers
alcoxi
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES87112128T
Other languages
English (en)
Inventor
Michael Dr Feldhues
Thomas Dr Mecklenburg
Peter Dr Wegener
Gunther Dr Kampf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
Original Assignee
Hoechst AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DE19863628895 external-priority patent/DE3628895A1/de
Priority claimed from DE19873717669 external-priority patent/DE3717669A1/de
Application filed by Hoechst AG filed Critical Hoechst AG
Application granted granted Critical
Publication of ES2064307T3 publication Critical patent/ES2064307T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
    • C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
    • C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124—Intrinsically conductive polymers
    • H01B1/127—Intrinsically conductive polymers comprising five-membered aromatic rings in the main chain, e.g. polypyrroles, polythiophenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913—Rod, strand, filament or fiber
    • Y10T428/2933—Coated or with bond, impregnation or core
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Paints Or Removers (AREA)
  • Chemically Coating (AREA)
  • Silicon Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

EL INVENTO TRATA DE POLIMEROS CONDUCTORES ELECTRICOS INTRINSECOS, EN PARTICULAR OLIGOMEROS QUE EN LA FORMA OXIDANTE SON SOLUBLES COMPLETAMENTE EN MEDIOS SOLUBLES APROTICOS DIPOLARES EN LA TEMPERATURA AMBIENTE Y CONTIENEN UNIDADES DE ESTRUCTURAS QUE DESVIAN AL MENOS UN MONOMERO DE LA FORMULA (I); DONDE R1 REPRESENTA UN GRUPO ALCOXI C1 - C12 O O(CH2CH20)NCH3 CON N = 1 A 4 Y R (AL CUADRADO) UN ATOMO DE HIDROGENO, UN GRUPO ALQUIL VX C1 -C12, UN GRUPO ALCOXI C1 - C12 O - (CH2CH20)NCH3 CON N = 1 A 4 O R1 JUNTO CON R (AL CUADRADO) - O(CH2)M - CH2 O 0(CH2)M) - 0 - CON M = 1 A12. ADEMAS EL INVENTO CONSISTE EN UN PROCEDIMIENTO PARA LA FABRICACION DE ESTOS POLIMEROS POR POLIMERIZACION ELECTROQUIMICA DE AL MENOS UN MONOMERO DE ESTA FORMULA (1) EN PRESENCIA DE UNA SAL CONDUCTORA, CON LO QUE EL ANODO MUESTRA UNA SUPERFICIE ESPECIFICA DE AL MENOS 0,01 M (AL CUADRADO) /G Y EN ESPECIAL UNA ESTRUCTURA DE RED, ESPONJA, TEJIDO O FIELTRO, EL MEDIO SOLUBLE ELECTROLITICO ES APROSICO DIPOLAR Y EL SISTEMA ELECTROLITICO NO SE MUEVE O SOLO DEBILMENTE HACIA EL ANODO. LOS POLIMEROS SEGUN EL INVENTO SE INSTALAN BIEN ESPECIALMENTE PARA RECUBRIMIENTOS.
ES87112128T 1986-08-26 1987-08-21 Polimeros solubles, conductores de la electricidad, procedimiento para su obtencion y uso de los mismos. Expired - Lifetime ES2064307T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19863628895 DE3628895A1 (de) 1986-08-26 1986-08-26 Loesliche, elektrisch leitende polymere, verfahren zu ihrer herstellung und ihre verwendung
DE19873717669 DE3717669A1 (de) 1987-05-26 1987-05-26 Loesliche, elektrisch leitende oligomere, verfahren zu ihrer herstellung und ihre verwendung

Publications (1)

Publication Number Publication Date
ES2064307T3 true ES2064307T3 (es) 1995-02-01

Family

ID=25846862

Family Applications (1)

Application Number Title Priority Date Filing Date
ES87112128T Expired - Lifetime ES2064307T3 (es) 1986-08-26 1987-08-21 Polimeros solubles, conductores de la electricidad, procedimiento para su obtencion y uso de los mismos.

Country Status (13)

Country Link
US (1) US5093033A (es)
EP (1) EP0257573B1 (es)
JP (1) JP2540166B2 (es)
CN (1) CN1025037C (es)
AT (1) ATE112883T1 (es)
CA (1) CA1336220C (es)
DE (1) DE3750650D1 (es)
DK (1) DK172980B1 (es)
ES (1) ES2064307T3 (es)
FI (1) FI95918C (es)
IL (1) IL83627A (es)
NO (1) NO173738C (es)
PT (1) PT85579B (es)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5286414A (en) * 1987-05-26 1994-02-15 Hoechst Aktiengesellschaft Electroconductive coating composition, a process for the production thereof and the use thereof
JPS6411128A (en) * 1987-07-03 1989-01-13 Agency Ind Science Techn 3,4-dialkoxythiophene polymer film
DE3804520A1 (de) * 1988-02-13 1989-08-24 Hoechst Ag Elektrisch leitende polymere und ihre herstellung
DE3843412A1 (de) * 1988-04-22 1990-06-28 Bayer Ag Neue polythiophene, verfahren zu ihrer herstellung und ihre verwendung
FI890427A7 (fi) * 1989-01-27 1990-07-28 Neste Oy Bruk av en elledande polymerkomposit.
JPH02229186A (ja) * 1989-03-01 1990-09-11 Agency Of Ind Science & Technol チオフェン系化合物及びその製造方法
DE3925970A1 (de) * 1989-08-05 1991-02-07 Hoechst Ag Elektrisch leitfaehige polymere und ihre verwendung als orientierungsschicht in fluessigkristall-schalt- und -anzeigeelementen
DE3913857A1 (de) * 1989-04-27 1990-10-31 Agfa Gevaert Ag Fotografisches material mit einer antistatikschicht
FR2648140B1 (fr) * 1989-06-08 1991-05-03 Centre Nat Rech Scient Procede de preparation d'oligomeres d'heterocycles aromatiques par couplage oxydant d'oligomeres inferieurs
JPH0321276A (ja) * 1989-06-19 1991-01-30 Kyogyo Kumiai Aomori Sukii Seisakusho スキー用上面材及びその製造方法
DE3929690A1 (de) * 1989-09-07 1991-03-14 Hoechst Ag Elektrochemisches verfahren zur herstellung von elektrisch leitenden poly(alkoxythiophenen) unter zusatz von carbonsaeuren
US5185100A (en) * 1990-03-29 1993-02-09 Allied-Signal Inc Conductive polymers formed from conjugated backbone polymers doped with non-oxidizing protonic acids
DE4110263A1 (de) * 1991-03-28 1992-10-01 Hoechst Ag Waessrige dispersion aus intrinsisch elektrisch leitfaehigen polyalkoxythiophenen, verfahren zu ihrer herstellung und ihre verwendung
DE4203208A1 (de) * 1992-02-05 1993-08-12 Hoechst Ag Beschichtungsmittel fuer kunststoffolien
DE4219410A1 (de) * 1992-06-13 1993-12-16 Hoechst Ag Heißsiegelfähige, antistatisch beschichtete Folien und Folienlaminate, Verfahren zu deren Herstellung und deren Verwendung
US5532025A (en) * 1993-07-23 1996-07-02 Kinlen; Patrick J. Corrosion inhibiting compositions
US5571454A (en) * 1994-03-16 1996-11-05 National Science Council Soluble and processable doped electrically conductive polymer and polymer blend thereof
DE19627071A1 (de) 1996-07-05 1998-01-08 Bayer Ag Elektrolumineszierende Anordnungen
ATE212988T1 (de) * 1996-07-22 2002-02-15 Univ Montreal Saure selbstdotierte, hochleitfähige polythiophene
DE19841803A1 (de) 1998-09-12 2000-03-16 Bayer Ag Hilfsschichten für elektrolumineszierende Anordnungen
DE10024738A1 (de) * 2000-05-19 2001-11-29 Qvf Engineering Gmbh Glasbauteile mit einer ableitfähigen Beschichtung, ihre Verwendung und daraus hergestellte Apparate, Anlagen und Rohrleitungen
JP3963693B2 (ja) * 2001-10-15 2007-08-22 富士通株式会社 導電性有機化合物及び電子素子
EP1453877B1 (en) 2001-12-04 2007-03-28 Agfa-Gevaert Process for preparing an aqueous or non-aqueous solution or dispersion of a polythiophene or thiophene copolymer
US7105620B2 (en) 2001-12-20 2006-09-12 Agfa Gevaert 3,4-alkylenedioxy-thiophene copolymers
DE10206294A1 (de) * 2002-02-15 2003-08-28 Bayer Ag Transparente Polythiophenschichten hoher Leitfähigkeit
AU2002337064A1 (en) 2002-09-02 2004-03-19 Agfa-Gevaert New 3,4-alkylenedioxythiophenedioxide compounds and polymers comprising monomeric units thereof
TW200516094A (en) * 2003-09-25 2005-05-16 Showa Denko Kk Pi-Conjugated copolymer, production method thereof, and capacitor using the copolymer
DE10349029B4 (de) * 2003-11-07 2006-09-28 Polyic Gmbh & Co. Kg Verwendung von Poly(alkoxythiophen) als Funktionsschicht in elektrischen Bauelementen
AT500289A1 (de) * 2003-12-29 2005-11-15 Hueck Folien Gmbh Substrate mit elektrisch leitfähigen schichten für technische anwendungen
EP1721323A1 (en) * 2004-03-04 2006-11-15 NV Bekaert SA Metal element coated with a coating layer comprising an inherently conductive polymer
KR101269256B1 (ko) * 2004-09-24 2013-05-29 플렉스트로닉스, 인크 헤테로 원자를 갖는 위치 규칙적 폴리(3-치환 티오펜)를 포함하는 전기발광 소자
JP2010138222A (ja) * 2008-12-09 2010-06-24 Kuraray Co Ltd チオフェン骨格を有する新規重合体及びその用途
JP2012017398A (ja) * 2010-07-07 2012-01-26 Nagase Chemtex Corp 導電性樹脂組成物、印刷インキ、透明電極基板及び電磁波シールド材
WO2012021301A1 (en) * 2010-08-13 2012-02-16 Massachusetts Institute Of Technology Interconnection between conducting polymer materials
TWI555772B (zh) * 2011-10-21 2016-11-01 索爾維美國有限公司 經由氧化聚合之共軛聚合物之改良合成法及相關組合物
US9534306B2 (en) * 2012-01-23 2017-01-03 Macdermid Acumen, Inc. Electrolytic generation of manganese (III) ions in strong sulfuric acid
JP2014031433A (ja) * 2012-08-02 2014-02-20 Ritsumeikan π共役高分子、導電性高分子複合体、有機溶剤分散体、導電性塗料、薄膜及び帯電防止膜
JP6995308B2 (ja) * 2017-08-25 2022-01-14 国立大学法人千葉大学 黒色光沢塗料、黒色光沢塗膜及び黒色光沢塗料の製造方法
CN110218298B (zh) * 2019-06-10 2021-12-24 华东师范大学 一种可溶性噻吩共聚物及其制备方法和应用
JP2021095426A (ja) 2019-12-13 2021-06-24 富士フイルムビジネスイノベーション株式会社 金属光沢膜形成用組成物、金属光沢膜、及び物品
JP7665172B2 (ja) * 2020-07-20 2025-04-21 国立大学法人千葉大学 金属光沢を発現する膜及びその膜を生成する塗料

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Publication number Priority date Publication date Assignee Title
US4599194A (en) * 1984-06-18 1986-07-08 Allied Corporation Simultaneous polymerization, doping and solubilization of heterocyclic polymers, solutions and cast articles
JPS6144921A (ja) * 1984-08-10 1986-03-04 Agency Of Ind Science & Technol 有機半導体材料の製造方法
EP0203438A1 (en) * 1985-05-31 1986-12-03 Corporation Allied Solution processible forms of neutral and electrically conductive poly(substituted heterocycles)

Also Published As

Publication number Publication date
FI95918C (fi) 1996-04-10
DK442887D0 (da) 1987-08-25
NO173738C (no) 1994-01-26
NO173738B (no) 1993-10-18
PT85579B (pt) 1990-05-31
PT85579A (en) 1987-09-01
IL83627A0 (en) 1988-01-31
FI873653A0 (fi) 1987-08-24
NO873580L (no) 1988-02-29
US5093033A (en) 1992-03-03
EP0257573B1 (de) 1994-10-12
ATE112883T1 (de) 1994-10-15
CA1336220C (en) 1995-07-04
EP0257573A1 (de) 1988-03-02
DE3750650D1 (de) 1994-11-17
AU7739087A (en) 1988-03-03
JPS6366221A (ja) 1988-03-24
FI95918B (fi) 1995-12-29
IL83627A (en) 1991-12-15
FI873653A7 (fi) 1988-02-27
CN1025037C (zh) 1994-06-15
CN87105806A (zh) 1988-05-04
AU603128B2 (en) 1990-11-08
DK442887A (da) 1988-02-27
JP2540166B2 (ja) 1996-10-02
DK172980B1 (da) 1999-11-01
NO873580D0 (no) 1987-08-25

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