ES2074426T3 - Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad. - Google Patents
Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad.Info
- Publication number
- ES2074426T3 ES2074426T3 ES88111492T ES88111492T ES2074426T3 ES 2074426 T3 ES2074426 T3 ES 2074426T3 ES 88111492 T ES88111492 T ES 88111492T ES 88111492 T ES88111492 T ES 88111492T ES 2074426 T3 ES2074426 T3 ES 2074426T3
- Authority
- ES
- Spain
- Prior art keywords
- cps
- organic solvent
- atoms
- carbon
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QURLONWWPWCPIC-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol;3,6-dichloro-2-methoxybenzoic acid Chemical compound NCCOCCO.COC1=C(Cl)C=CC(Cl)=C1C(O)=O QURLONWWPWCPIC-UHFFFAOYSA-N 0.000 title 1
- 239000002253 acid Substances 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- 230000008719 thickening Effects 0.000 title 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 3
- 239000003960 organic solvent Substances 0.000 abstract 3
- 239000004215 Carbon black (E152) Substances 0.000 abstract 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 239000000178 monomer Substances 0.000 abstract 2
- 229920000642 polymer Polymers 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- -1 CARBOXYL Chemical class 0.000 abstract 1
- 150000001298 alcohols Chemical class 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000011780 sodium chloride Substances 0.000 abstract 1
- 238000002834 transmittance Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/923—Ethylenic monomers containing at least one salt group
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
POLIMERO Y PROCESO DE POLIMERIZACION DE UN MONOMERO CARGADO CONTENIENDO AL MENOS UN 85% DE UN MONOMERO CARBOXILO NO SATURADO ALQUENO NUMERADO DE 3 A 5 ATOMOS DE CARBONO DE HASTA UN 15% DE COMONOMERO COPOLIMERIZABLE, EN PRESENCIA DE UN MEDIO DE MEZCLA DE REACCION CONTENIENDO UN DISOLVENTE ORGANICO Y UN HIDROCARBURO DISOLVENTE EN RAZON DE PESO RESPECTIVO DE 95/5 A 1/99, DICHO DISOLVENTE ORGANICO SE SELECCIONA DE ENTRE ACETONAS, ESTERES, ETERES Y ALCOHOLES TENIENDO PARAMETROS DE SOLUBILIDAD EN EL RANGO DE 8 A 15 Y DICHO HIDROCARBURO DISOLVENTE SE SELECCIONA DE ENTRE ALIFATICOS Y ALQUENOS CICLICOS ALIFATICOS CONTENIENDO DE 4 A 12 ATOMOS DE CARBONO Y AROMATICOS DISTINTOS DEL BENCENO DE 7 A 9 ATOMOS DE CARBONO. DICHO DISOLVENTE ORGANICO Y DICHO HIDROCARBURO DISOLVENTE SON PREFERIBLEMENTE LIQUIDOS A TEMPERATURA AMBIENTE. VISCOSIDAD DE 0,2% DE DE PESO DE POLIMERO ES SUPERIOR A 15.000 CPS, PREFERIBLEMENTE SUPERIOR A 20.000 CPS, Y SU CARACTERISTICA DE CLARIDAD ES AL MENOS DEL 80%, PREFERIBLEMENTEDEL 85% LA TRANSMITANCIA. VISCOSIDAD ESPESANTE DEL 1% CONTENIENDO UN 1% DE SAL DE CLORURO SODICO ES MAYOR DE 5.000 CPS, PREFERIBLEMENTE MAYOR DE 8.000 CPS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/157,685 US4996274A (en) | 1988-02-19 | 1988-02-19 | Polycarboxylic acids with higher thickening capacity and better clarity |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2074426T3 true ES2074426T3 (es) | 1995-09-16 |
Family
ID=22564825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88111492T Expired - Lifetime ES2074426T3 (es) | 1988-02-19 | 1988-07-16 | Acidos policarboxilicos con capacidad espesante mas elevada y mejor claridad. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4996274A (es) |
| EP (1) | EP0328725B1 (es) |
| JP (1) | JP3023110B2 (es) |
| KR (1) | KR970007242B1 (es) |
| CN (1) | CN1019499B (es) |
| AU (1) | AU612670B2 (es) |
| BR (1) | BR8803727A (es) |
| CA (1) | CA1336852C (es) |
| DE (1) | DE3853716T2 (es) |
| ES (1) | ES2074426T3 (es) |
| MX (1) | MX171770B (es) |
| PT (1) | PT88478B (es) |
| ZA (1) | ZA885408B (es) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0222312A (ja) * | 1988-05-26 | 1990-01-25 | Sumitomo Seika Chem Co Ltd | 架橋型カルボキシル基含有重合体の製造方法 |
| AU6788890A (en) * | 1989-12-29 | 1991-07-04 | B.F. Goodrich Company, The | Oxidation resistant polymeric thickeners and method relating thereto |
| US5034488A (en) * | 1990-01-11 | 1991-07-23 | Gaf Chemicals Corporation | Slurry polymerization of crosslinked maleic anhydride-alkyl vinyl ether copolymers in a solvent system comprising a carboxylic acid ester and a saturated hydrocarbon |
| JPH07500357A (ja) * | 1990-03-29 | 1995-01-12 | アイエスピー インヴェストメンツ インコーポレイテッド | 義歯接着剤に有用な無水マレイン酸及びアクリル酸のコポリマー |
| GB9114095D0 (en) * | 1991-06-29 | 1991-08-14 | Allstate Limited | Improvements in water-soluble polymers |
| JPH059235A (ja) * | 1991-07-04 | 1993-01-19 | Daicel Chem Ind Ltd | 無水マレイン酸−アルキルビニルエ−テル共重合体の製造方法 |
| DE4213283A1 (de) | 1992-04-23 | 1993-10-28 | Basf Ag | Verwendung von Copolymerisaten aus Carbonsäuren und langkettigen Verbindungen mit isolierten C-C-Mehrfachverbindungen als Verdickungs- oder Dispergiermittel |
| DE4213971A1 (de) | 1992-04-29 | 1993-11-04 | Basf Ag | Copolymerisate aus carbonsaeuren und quartaeren ammoniumverbindungen und ihre verwendung als verdickungs- oder dispergiermittel |
| US5338345A (en) * | 1993-05-05 | 1994-08-16 | Eastman Kodak Company | Water-based water repellent coating compositions |
| US5342911A (en) * | 1993-08-25 | 1994-08-30 | 3V Inc. | Crosslinked polyacrylic acids having low solvent residue, a process for the preparation thereof and the use thereof as thickening agents |
| IT1270968B (it) * | 1993-08-25 | 1997-05-26 | Sigma Prod Chim | Acidi poliacrilici reticolati a basso tenore di solventi, procedimento per la loro produzione e loro uso come agenti addensanti |
| DE4330767A1 (de) * | 1993-09-10 | 1995-03-16 | Hoechst Ag | Polymermischungen mit Wasser |
| US5422233A (en) * | 1994-05-17 | 1995-06-06 | Polaroid Corporation | Photographic processing compositions including hydrophobically modified thickening agent |
| DE19546698A1 (de) * | 1995-12-14 | 1997-06-19 | Basf Ag | Copolymerisate aus Carbonsäuren und mehrfach olefinisch ungesättigten Carbonsäurederivaten und ihre Verwendung als Verdickungs- oder Dispergiermittel |
| US5804624A (en) * | 1997-04-30 | 1998-09-08 | Wang; Jianming | Water-based silicone resin compositions |
| US5997764A (en) * | 1997-12-04 | 1999-12-07 | The B.F. Goodrich Company | Thickened bleach compositions |
| US6297337B1 (en) | 1999-05-19 | 2001-10-02 | Pmd Holdings Corp. | Bioadhesive polymer compositions |
| AU2002319689B2 (en) | 2001-07-25 | 2006-06-08 | The Sherwin-Williams Company | Water-based water repellent coating compositions |
| JP3940009B2 (ja) | 2002-03-18 | 2007-07-04 | 住友精化株式会社 | カルボキシル基含有水溶性重合体の製造方法 |
| GB2393908A (en) * | 2002-10-12 | 2004-04-14 | Reckitt Benckiser Inc | Thickened, abrasive containing, liquid disinfectant |
| JP4759236B2 (ja) * | 2004-07-28 | 2011-08-31 | 住友精化株式会社 | カルボキシル基含有水溶性重合体の製造方法 |
| JP2005097630A (ja) * | 2004-12-07 | 2005-04-14 | Nippon Junyaku Kk | 水溶性架橋共重合体粉末の製造方法 |
| DE102005019398A1 (de) * | 2005-04-25 | 2006-10-26 | Basf Ag | Verfahren zur Herstellung von Fällungspolymeren durch Sprühpolymerisation |
| US8309667B2 (en) | 2005-11-14 | 2012-11-13 | Sumitomo Seika Chemicals Co., Ltd. | Water-soluble copolymer having alkyl-modified carboxyl groups |
| EP1953176B1 (en) | 2005-11-21 | 2011-07-06 | Sumitomo Seika Chemicals Co., Ltd. | Water-soluble copolymer having alkyl-modified carboxyl group |
| CA2643608A1 (en) | 2006-03-31 | 2007-10-11 | Basf Se | Process for preparing acrylate copolymers |
| US7842779B2 (en) * | 2006-05-12 | 2010-11-30 | Sumitomo Seika Chemicals Co., Ltd. | Process for producing granular carboxylated-polymer particle and granular carboxylated-polymer particle |
| BRPI0812513B1 (pt) * | 2007-06-19 | 2019-01-15 | Sumitomo Seika Chemicals Co., Ltd. | método para a produção de partícula granulada de polímero contendo grupo carboxila |
| JP4998727B2 (ja) * | 2007-09-27 | 2012-08-15 | 日本純薬株式会社 | 増粘用不飽和カルボン酸系重合体粉末の製造方法 |
| BRPI0922802B1 (pt) * | 2008-11-21 | 2019-09-17 | Hercules Incorporated | Copolímero de ácido carboxílico reticulado |
| JP5544706B2 (ja) * | 2008-12-02 | 2014-07-09 | 東亞合成株式会社 | 不飽和カルボン酸系架橋重合体およびこの重合体の製造方法 |
| EP2463311B1 (en) | 2009-08-04 | 2014-03-19 | Sumitomo Seika Chemicals CO. LTD. | Method for manufacturing a carboxyl-containing water-soluble polymer |
| US20110218295A1 (en) * | 2010-03-02 | 2011-09-08 | Basf Se | Anionic associative rheology modifiers |
| US20130196890A1 (en) | 2012-01-30 | 2013-08-01 | Reckitt Benckiser Llc | Stable, viscous, peroxide containing lavatory treatment compositions |
| US9707162B2 (en) | 2012-11-30 | 2017-07-18 | Reckitt & Colman (Overseas) Limited | Microbicidal personal care compositions comprising metal ions |
| EP2907828A1 (de) | 2014-02-14 | 2015-08-19 | Basf Se | Verfahren zur Herstellung von kationogen-ampholytischen VP/VI-Copolymeren |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2798053A (en) * | 1952-09-03 | 1957-07-02 | Goodrich Co B F | Carboxylic polymers |
| NL230828A (es) * | 1957-08-27 | |||
| CH606154A5 (es) * | 1974-07-02 | 1978-11-15 | Goodrich Co B F | |
| US3940351A (en) * | 1974-07-02 | 1976-02-24 | The B. F. Goodrich Company | Polymerization of carboxylic acid monomers and alkyl acrylate esters in chlorofluoroethane |
| US4062817A (en) * | 1977-04-04 | 1977-12-13 | The B.F. Goodrich Company | Water absorbent polymers comprising unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, and another acrylic ester containing alkyl group 2-8 carbon atoms |
| US4066583A (en) * | 1977-05-16 | 1978-01-03 | The B. F. Goodrich Company | Flexible water absorbent polymer compositions comprising (a) unsaturated carboxylic acid, acrylic ester containing alkyl group 10-30 carbon atoms, additional monomer plus (b) aliphatic diol |
| US4267103A (en) * | 1978-12-07 | 1981-05-12 | The B. F. Goodrich Company | Solvent polymerization of carboxyl containing monomers |
| DE2927132A1 (de) * | 1979-07-05 | 1981-01-08 | Bayer Ag | Verfahren zur herstellung vernetzter acrylsaeurepolymerisate |
| CA1321435C (en) * | 1986-12-15 | 1993-08-17 | Chao-Jen Chung | Non-aqueous polymeric dispersion compositions having improved metal adhesion |
-
1988
- 1988-02-19 US US07/157,685 patent/US4996274A/en not_active Expired - Lifetime
- 1988-07-16 EP EP88111492A patent/EP0328725B1/en not_active Expired - Lifetime
- 1988-07-16 ES ES88111492T patent/ES2074426T3/es not_active Expired - Lifetime
- 1988-07-16 DE DE3853716T patent/DE3853716T2/de not_active Expired - Lifetime
- 1988-07-21 AU AU19279/88A patent/AU612670B2/en not_active Expired - Fee Related
- 1988-07-25 JP JP63183764A patent/JP3023110B2/ja not_active Expired - Lifetime
- 1988-07-25 ZA ZA885408A patent/ZA885408B/xx unknown
- 1988-07-26 MX MX012411A patent/MX171770B/es unknown
- 1988-07-27 BR BR8803727A patent/BR8803727A/pt unknown
- 1988-07-29 CA CA000573500A patent/CA1336852C/en not_active Expired - Lifetime
- 1988-08-10 KR KR1019880010199A patent/KR970007242B1/ko not_active Expired - Fee Related
- 1988-09-09 CN CN88106609A patent/CN1019499B/zh not_active Expired
- 1988-09-09 PT PT88478A patent/PT88478B/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| KR890013092A (ko) | 1989-09-21 |
| CN1019499B (zh) | 1992-12-16 |
| BR8803727A (pt) | 1989-07-25 |
| JP3023110B2 (ja) | 2000-03-21 |
| DE3853716D1 (de) | 1995-06-08 |
| EP0328725A3 (en) | 1990-06-27 |
| AU612670B2 (en) | 1991-07-18 |
| DE3853716T2 (de) | 1995-09-07 |
| EP0328725B1 (en) | 1995-05-03 |
| CA1336852C (en) | 1995-08-29 |
| CN1035299A (zh) | 1989-09-06 |
| PT88478B (pt) | 1994-04-29 |
| JPH01217017A (ja) | 1989-08-30 |
| ZA885408B (en) | 1989-07-26 |
| MX171770B (es) | 1993-11-15 |
| PT88478A (pt) | 1989-10-04 |
| EP0328725A2 (en) | 1989-08-23 |
| US4996274A (en) | 1991-02-26 |
| AU1927988A (en) | 1989-08-24 |
| KR970007242B1 (ko) | 1997-05-07 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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