ES2074434T3 - Poliuretanos termoplasticos con altas temperaturas de transicion de vidrio. - Google Patents
Poliuretanos termoplasticos con altas temperaturas de transicion de vidrio.Info
- Publication number
- ES2074434T3 ES2074434T3 ES88121022T ES88121022T ES2074434T3 ES 2074434 T3 ES2074434 T3 ES 2074434T3 ES 88121022 T ES88121022 T ES 88121022T ES 88121022 T ES88121022 T ES 88121022T ES 2074434 T3 ES2074434 T3 ES 2074434T3
- Authority
- ES
- Spain
- Prior art keywords
- high temperatures
- glass transition
- highlighted
- thermoplastic polyurethanes
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3212—Polyhydroxy compounds containing cycloaliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/6505—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6511—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen the low-molecular compounds being compounds of group C08G18/32 or polyamines of C08G18/38 compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Laminated Bodies (AREA)
- Joining Of Glass To Other Materials (AREA)
Abstract
ESTAN DISPUESTOS UNOS NUEVOS PLASTICOS DE POLIURETANO DE MODULO SOMETIDO A ALTA FLEXION EN DONDE UN POLIISOCIANATO Y UNA COMBINACION PARTICULAR DE PROLONGADORES INCLUYEN UN DIOL CICLOALCANO QUE SON REACCIONADOS OPCIONALMENTE EN PRESENCIA DE UNA MENOR PROPORCION DE POLIOL DE ALTO PESO MOLECULAR. LOS POLIMEROS TIENEN UNA RESISTENCIA DESTACADA A ALTAS TEMPERATURAS POR LO QUE EXTENDEN SUS UTILIDADES A EXPRESIONES DE USO FINAL A MAYOR TEMPERATURA QUE SON EXPUESTOS ANTES DE LOS MATERIALES TECNICOS. CIERTOS MIEMBROS DE ESTOS NUEVOS POLIMEROS ESTAN TAMBIEN INTEGRADOS POR UNA CLARIDAD OPTICA DESTACADA POR LO QUE PROVEE UNA COMBINACION DE PROPIEDADES QUE NO ESTAN DISPONIBLES EN UN POLIURETANO.L ESTOS POLIMEROS SON FACILMENTE FABRICADOS FUNDIDOS NO SIN MANTENER SUS PROPIEDADES INHERENTES A ALTA TEMPERATURA.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/134,262 US4822827A (en) | 1987-12-17 | 1987-12-17 | Thermoplastic polyurethanes with high glass transition temperatures |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2074434T3 true ES2074434T3 (es) | 1995-09-16 |
Family
ID=22462529
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES88121022T Expired - Lifetime ES2074434T3 (es) | 1987-12-17 | 1988-12-15 | Poliuretanos termoplasticos con altas temperaturas de transicion de vidrio. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4822827A (es) |
| EP (1) | EP0320946B1 (es) |
| JP (1) | JPH01259023A (es) |
| KR (1) | KR910008319B1 (es) |
| AT (1) | ATE124968T1 (es) |
| AU (1) | AU616707B2 (es) |
| BR (1) | BR8806715A (es) |
| CA (1) | CA1334607C (es) |
| DE (1) | DE3854150T2 (es) |
| DK (1) | DK700188A (es) |
| ES (1) | ES2074434T3 (es) |
| FI (1) | FI885822L (es) |
| MX (1) | MX166817B (es) |
| NO (1) | NO885596L (es) |
| NZ (1) | NZ227265A (es) |
| PT (1) | PT89217B (es) |
Families Citing this family (48)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2607435B1 (fr) * | 1986-11-27 | 1989-04-07 | Vernhet Louis | Procede de realisation d'un produit a film protecteur transferable et produit obtenu pour la protection de documents ou autres elements |
| IT1222099B (it) * | 1987-07-23 | 1990-08-31 | Montedison Spa | Poliesteri del 4,4' diidrossibicicloesile |
| US4786656A (en) * | 1988-02-22 | 1988-11-22 | Ethyl Corporation | Polyhydroxyalkane/aromatic diamine chain extenders |
| EP0358406A3 (en) * | 1988-09-05 | 1991-01-30 | Sanyo Chemical Industries, Ltd. | Use of a polyol as a structural component of a polyurethane resin and method of forming an article |
| AU5949390A (en) * | 1989-06-27 | 1991-01-17 | Dow Chemical Company, The | Melt polymerization process for making polyurethanes |
| KR910011978A (ko) * | 1989-12-22 | 1991-08-07 | 리챠드 지.워터만 | 열가소성 폴리우레탄 및 이의 제조방법 |
| DE4019799A1 (de) * | 1990-06-21 | 1992-01-02 | Bayer Ag | Thermoplastische zusammensetzungen aus polyurethanen und partiell vernetzten alkylacrylatcopolymeren |
| US5089571A (en) * | 1990-12-04 | 1992-02-18 | The Dow Chemical Company | Regenerated, high molecular weight, thermoplastic resins and process for regenerating thermoplastic resins |
| EP0500259A3 (en) * | 1991-02-20 | 1993-01-07 | The Dow Chemical Company | Thermally processable blends of high modulus polyurethanes and impact modifiers |
| AU1999192A (en) * | 1991-05-24 | 1992-12-30 | Dow Chemical Company, The | Thermally processable blends of high modulus polyurethanes and mass polymerized abs resins |
| US5319039A (en) * | 1992-04-30 | 1994-06-07 | The Dow Chemical Company | Thermally processable blends of aromatic polyesters and high modulus polyurethanes |
| SG45373A1 (en) * | 1992-06-26 | 1998-01-16 | Minnesota Mining & Mfg | Polyurethane/polyurea elastomers |
| US5266669A (en) * | 1992-10-26 | 1993-11-30 | Becton, Dickinson And Company | Softening non-swelling polyurethane |
| US5352754A (en) * | 1992-10-26 | 1994-10-04 | Becton, Dickinson And Company | High impact polyurethane |
| WO1994015985A1 (en) * | 1992-12-31 | 1994-07-21 | The Dow Chemical Company | Thermoplastic polyurethanes and a process for their preparation |
| US5599874A (en) * | 1993-08-25 | 1997-02-04 | Caterpillar Inc. | Thermoplastic polyurethane elastomer based on a hydroxyl terminated polyol, an aromatic chain extender and 1,5 naphthalene diisocyanate |
| US5648412A (en) * | 1995-01-30 | 1997-07-15 | The Dow Chemical Company | Blow-moldable rigid thermoplastic polyurethane resins |
| US5562794A (en) * | 1995-03-08 | 1996-10-08 | Basf Corporation | Low solvent, thermoplastic polyurethane containing solvent cement |
| IL127593A (en) * | 1995-11-29 | 2001-05-20 | Paltough Ltd | Extruded plastic |
| US5627254A (en) * | 1996-05-03 | 1997-05-06 | The Dow Chemical Company | Rigid thermoplastic plyurethane comprising units of butane diol and a polyethylene glycol |
| US5714562A (en) * | 1996-06-12 | 1998-02-03 | Bayer Corporation | Light stable elastomers having good dynamic properties |
| US6043313A (en) * | 1997-09-04 | 2000-03-28 | Eastman Chemical Company | Thermoplastic polyurethane additives for improved polymer matrix composites and methods of making and using therefor |
| EP1178063A1 (en) * | 2000-08-01 | 2002-02-06 | Huntsman International Llc | Process for preparing a polyurethane material |
| DE10112366B4 (de) * | 2001-03-15 | 2006-06-08 | Bayer Materialscience Ag | Aliphatische thermoplastische Polyurethane und ihre Verwendung |
| US7501182B2 (en) * | 2001-08-27 | 2009-03-10 | Kurabe Industrial Co., Ltd. | Light transmitting material, structure connecting light transmitting material and optical device, and method for manufacturing light transmitting material |
| FR2858623B1 (fr) * | 2003-08-08 | 2006-01-13 | Rhodia Polyamide Intermediates | Mousses polyurethannes, procede de fabrication et utilisation de ces mousses |
| US7593687B2 (en) * | 2003-10-07 | 2009-09-22 | Immersion Entertainment, Llc | System and method for providing event spectators with audio/video signals pertaining to remote events |
| KR200365063Y1 (ko) * | 2004-07-21 | 2004-10-15 | 안병옥 | 내장물이 내장된 발향 액세서리 |
| US11008418B2 (en) | 2004-09-01 | 2021-05-18 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US11149107B2 (en) | 2004-09-01 | 2021-10-19 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US11248083B2 (en) | 2004-09-01 | 2022-02-15 | Ppg Industries Ohio, Inc. | Aircraft windows |
| US11591436B2 (en) | 2004-09-01 | 2023-02-28 | Ppg Industries Ohio, Inc. | Polyurethane article and methods of making the same |
| US20090280329A1 (en) | 2004-09-01 | 2009-11-12 | Ppg Industries Ohio, Inc. | Polyurethanes, Articles and Coatings Prepared Therefrom and Methods of Making the Same |
| US9464169B2 (en) | 2004-09-01 | 2016-10-11 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| EP1657267A1 (en) * | 2004-11-10 | 2006-05-17 | INSA (Institut National des Sciences Appliqées) | Two-part polyisocyanate/polyol composition and its use for making casted products, in particular ophthalmic lenses |
| DE102006021734A1 (de) * | 2006-05-09 | 2007-11-15 | Bayer Materialscience Ag | Aliphatische, sinterfähige, thermoplastische Polyurethanformmassen mit verbessertem Ausblühverhalten |
| US20160024340A1 (en) * | 2006-12-14 | 2016-01-28 | Ppg Industries Ohio, Inc. | Polyurethanes, articles and coatings prepared therefrom and methods of making the same |
| US8270089B2 (en) * | 2007-04-05 | 2012-09-18 | Essilor International (Compagnie Generale D'optique) | Thermoplastic polyurethane lenses with a specified weight percentage of urethane repeating units |
| TW200946551A (en) * | 2008-03-31 | 2009-11-16 | Toyo Kohan Co Ltd | Polyurethane resins containing cycloaliphatic and/or aromatic component and phase difference films using them |
| US20100222524A1 (en) * | 2009-02-27 | 2010-09-02 | Bayer Materialscience Llc | High modulus transparent thermoplastic polyurethanes characterized by high heat and chemical resistance |
| JP2011074296A (ja) * | 2009-09-30 | 2011-04-14 | Toyo Kohan Co Ltd | ウレタン樹脂フィルムの製造方法 |
| WO2012078322A1 (en) | 2010-12-07 | 2012-06-14 | Dow Global Technologies Llc | Polyurethane elastomers made using mixtures of aliphatic diol chain extender and secondary amine |
| US8979669B2 (en) * | 2010-12-30 | 2015-03-17 | Taylor Made Golf Company, Inc. | Polymer cover layer for golf club face |
| ITTO20120669A1 (it) | 2012-07-27 | 2012-10-26 | Torino Politecnico | Poliuretani anfifilici termosensibili e soluzione acquosa iniettabile a base di tale materiale. |
| DE102013217661B4 (de) * | 2013-09-04 | 2023-01-12 | Leibniz-Institut Für Polymerforschung Dresden E.V. | Verfahren zur Herstellung von Blends aus thermoplastischen Polyurethanen und Kautschuken und damit hergestellte Blends |
| CR20180455A (es) * | 2016-03-31 | 2019-01-14 | Lubrizol Advanced Mat Inc | Composiciones de poliuretano termoplástico para la fabricación de forma libre sólida de componentes y dispositivos médicos y para el cuidado bucal |
| PL3601401T3 (pl) * | 2017-03-24 | 2023-01-16 | Covestro Intellectual Property Gmbh & Co. Kg | Materiały typu solid surface z matrycą poliuretanową |
| TW202248261A (zh) | 2021-04-19 | 2022-12-16 | 美商貝伊材料有限責任公司 | 具有改良的應力保持性及耐濕性的聚氨酯組成物 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1169122A (en) * | 1967-11-30 | 1969-10-29 | Optipatent Ag | Use of Polyurethane Resins for Casting Spectacle Frames or Parts Thereof |
| GB1240116A (en) * | 1968-06-07 | 1971-07-21 | Ici Ltd | Improvements in or relating to the manufacture of synthetic elastomers |
| BE794206A (fr) * | 1972-01-19 | 1973-07-18 | Monsanto Co | Intercalaire en polyurethane pour verre de securite feuillete |
| US3900446A (en) * | 1972-12-08 | 1975-08-19 | Monsanto Co | Polyurethane interlayer for laminated safety glass |
| CA1029494A (en) * | 1973-07-27 | 1978-04-11 | Fritz Ehrhard | Shaped polyurethane articles and a method for making them |
| US4101529A (en) * | 1976-02-04 | 1978-07-18 | Ppg Industries, Inc. | Hard, optically clear polyurethane articles |
| JPS5936800B2 (ja) * | 1976-08-30 | 1984-09-05 | 沖エンジニアリング株式会社 | 車輌分離識別装置 |
| DE2817457A1 (de) * | 1978-04-21 | 1979-10-31 | Bayer Ag | Thermoplastische polyurethane fuer die verarbeitung in extrudern oder/und auf kalandern |
| DE2854386A1 (de) * | 1978-12-16 | 1980-07-03 | Bayer Ag | Verfahren zur herstellung von thermoplastischen chemiewerkstoffen |
| US4393186A (en) * | 1979-06-19 | 1983-07-12 | Lord Corporation | Thermoplastic polyurethanes prepared by reacting polyisocyanate, polyester polyol, cycloaliphatic diol and a monofunctional chain-terminating compound |
| US4376834A (en) * | 1981-10-14 | 1983-03-15 | The Upjohn Company | Polyurethane prepared by reaction of an organic polyisocyanate, a chain extender and an isocyanate-reactive material of m.w. 500-20,000 characterized by the use of only 2-25 percent by weight of the latter material |
| US4567236A (en) * | 1983-07-18 | 1986-01-28 | The Upjohn Co. | Novel polymer blends |
| JPS6096551A (ja) * | 1983-10-28 | 1985-05-30 | Sekisui Chem Co Ltd | 積層ガラス |
| DE3405531A1 (de) * | 1984-02-16 | 1985-08-29 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von thermoplastischen polyurethanelastomeren und ihre verwendung |
| US4659747A (en) * | 1986-05-15 | 1987-04-21 | The Dow Chemical Company | Cyclohexanedimethanol/diamine mixtures as RIM extenders |
| JPS62280214A (ja) * | 1986-05-28 | 1987-12-05 | Dainippon Ink & Chem Inc | ポリウレタン樹脂組成物 |
| JPH0696551A (ja) * | 1992-09-11 | 1994-04-08 | Kao Corp | 磁気ディスクカートリッジ |
-
1987
- 1987-12-17 US US07/134,262 patent/US4822827A/en not_active Expired - Lifetime
-
1988
- 1988-11-30 AU AU26411/88A patent/AU616707B2/en not_active Ceased
- 1988-12-09 NZ NZ227265A patent/NZ227265A/xx unknown
- 1988-12-14 PT PT89217A patent/PT89217B/pt not_active IP Right Cessation
- 1988-12-15 AT AT88121022T patent/ATE124968T1/de not_active IP Right Cessation
- 1988-12-15 EP EP88121022A patent/EP0320946B1/en not_active Expired - Lifetime
- 1988-12-15 DE DE3854150T patent/DE3854150T2/de not_active Expired - Fee Related
- 1988-12-15 JP JP63315194A patent/JPH01259023A/ja active Pending
- 1988-12-15 ES ES88121022T patent/ES2074434T3/es not_active Expired - Lifetime
- 1988-12-15 BR BR888806715A patent/BR8806715A/pt not_active Application Discontinuation
- 1988-12-16 MX MX014225A patent/MX166817B/es unknown
- 1988-12-16 KR KR1019880016765A patent/KR910008319B1/ko not_active Expired
- 1988-12-16 DK DK700188A patent/DK700188A/da not_active Application Discontinuation
- 1988-12-16 FI FI885822A patent/FI885822L/fi not_active Application Discontinuation
- 1988-12-16 CA CA000586145A patent/CA1334607C/en not_active Expired - Fee Related
- 1988-12-16 NO NO88885596A patent/NO885596L/no unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR8806715A (pt) | 1989-08-29 |
| AU2641188A (en) | 1989-06-22 |
| PT89217B (pt) | 1993-07-30 |
| FI885822A0 (fi) | 1988-12-16 |
| FI885822A7 (fi) | 1989-06-18 |
| NO885596L (no) | 1989-06-19 |
| PT89217A (pt) | 1989-12-29 |
| FI885822L (fi) | 1989-06-18 |
| EP0320946A3 (en) | 1990-08-29 |
| DK700188D0 (da) | 1988-12-16 |
| EP0320946A2 (en) | 1989-06-21 |
| ATE124968T1 (de) | 1995-07-15 |
| JPH01259023A (ja) | 1989-10-16 |
| AU616707B2 (en) | 1991-11-07 |
| DE3854150D1 (de) | 1995-08-17 |
| EP0320946B1 (en) | 1995-07-12 |
| DK700188A (da) | 1989-06-18 |
| MX166817B (es) | 1993-02-08 |
| NO885596D0 (no) | 1988-12-16 |
| KR910008319B1 (ko) | 1991-10-12 |
| DE3854150T2 (de) | 1996-02-01 |
| KR890010011A (ko) | 1989-08-05 |
| NZ227265A (en) | 1991-09-25 |
| CA1334607C (en) | 1995-02-28 |
| US4822827A (en) | 1989-04-18 |
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