ES2074482T3 - Sintesis de cis-olefinas. - Google Patents
Sintesis de cis-olefinas.Info
- Publication number
- ES2074482T3 ES2074482T3 ES90100594T ES90100594T ES2074482T3 ES 2074482 T3 ES2074482 T3 ES 2074482T3 ES 90100594 T ES90100594 T ES 90100594T ES 90100594 T ES90100594 T ES 90100594T ES 2074482 T3 ES2074482 T3 ES 2074482T3
- Authority
- ES
- Spain
- Prior art keywords
- cis
- reaction product
- olefinas
- synthesis
- steps
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 239000007795 chemical reaction product Substances 0.000 abstract 5
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical class [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 1
- -1 SULPHONYL HALIDE COMPOUND Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003960 organic solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/08—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds
- C07C5/09—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation of carbon-to-carbon triple bonds to carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C11/00—Aliphatic unsaturated hydrocarbons
- C07C11/02—Alkenes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
- C07C1/32—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen
- C07C1/325—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom
- C07C1/326—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from compounds containing hetero-atoms other than or in addition to oxygen or halogen the hetero-atom being a metal atom the hetero-atom being a magnesium atom
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
UN PROCESO PARA LA SINTESIS DE CIS-OLEFINAS DE ALCOHOLES CIS-OLEFINICOS, COMPUESTO ESENCIALMENTE DE LOS SIGUIENTES PASOS: (A)REACCIONAR UN ALCOHOL CIS-OLEFINICO CON UNA FUENTE DE UN ALCOHOL ALCALINO METALICO SELECCIONADO DEL GRUPO COMPUESTO DE IONES DE LITIO Y SODIO, PARA FORMAR UN PRIMER PRODUCTO DE REACCION, (B)PONER ENTONCES EN CONTACTO DICHO, ASI FORMADO, PRIMER PRODUCTO DE REACCION CON UN COMPUESTO SULFONILO HALURO PARA FORMAR UN SEGUNDO PRODUCTO DE REACCION, (C) PONER A CONTINUACION EN CONTACTO DICHO, ASI FORMADO, SEGUNDO PRODUCTO DE REACCION, CON UN COMPUESTO ALQUILO MAGNESICO Y UNA SAL DE COBRE PARA FORMAR UN TERCER PRODUCTO DE REACCION, COMPRENDIENDO UNA CIS-OLEFINA, EN DONDE, DICHOS PASOS SE REALIZAN EN UN DISOLVENTE ORGANICO ADECUADO.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/297,640 US4922049A (en) | 1989-01-13 | 1989-01-13 | Synthesis of cis-olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2074482T3 true ES2074482T3 (es) | 1995-09-16 |
Family
ID=23147150
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90100594T Expired - Lifetime ES2074482T3 (es) | 1989-01-13 | 1990-01-12 | Sintesis de cis-olefinas. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4922049A (es) |
| EP (1) | EP0383016B1 (es) |
| JP (1) | JPH02270828A (es) |
| KR (1) | KR950006789B1 (es) |
| CA (1) | CA2005830A1 (es) |
| DE (1) | DE69019839T2 (es) |
| ES (1) | ES2074482T3 (es) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2725919B1 (fr) * | 1994-10-24 | 1996-12-13 | Inst Francais Du Petrole | Composition catalytique et procede pour l'alkylation d'hydrocarbures aliphatiques |
| KR100848074B1 (ko) * | 2006-11-06 | 2008-07-24 | 한국화학연구원 | 시스-9-트리코센의 제조방법 |
| JP7037519B2 (ja) * | 2019-05-16 | 2022-03-16 | 信越化学工業株式会社 | (7z)-7-トリコセンの製造方法 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1428393A (en) * | 1972-06-26 | 1976-03-17 | Meresz O | Process for the synthesis of pure isomers of long chain olefinic compounds |
| US4006065A (en) * | 1972-06-26 | 1977-02-01 | Otto Meresz | Process for the synthesis of pure isomers of long chain alkenes |
| US4018844A (en) * | 1972-06-26 | 1977-04-19 | Otto Meresz | Long chain internally unsaturated alkenes |
| US3798273A (en) * | 1972-11-29 | 1974-03-19 | Research Corp | Intermediate for synthesis of housefly sex attractant |
| US3940425A (en) * | 1973-09-06 | 1976-02-24 | Bayer Aktiengesellschaft | Process for the production of polyunsaturated compounds |
| US3948803A (en) * | 1974-05-28 | 1976-04-06 | Zoecon Corporation | Catalyst |
| DE2512741A1 (de) * | 1975-03-22 | 1976-09-23 | Huels Chemische Werke Ag | Verfahren zur herstellung von tricosen-(9) und heneicosen-(9) |
| LU80093A1 (fr) * | 1978-08-08 | 1980-04-21 | Airwick Ag | Procede de fabrication d'alcenes superieurs |
| US4609498A (en) * | 1985-03-14 | 1986-09-02 | Phillips Petroleum Company | Preparation of gossyplure |
| US4740627A (en) * | 1987-05-21 | 1988-04-26 | Phillips Petroleum Company | Synthesis of E,Z-11-tetradecen-1-al |
| US4749818A (en) * | 1987-09-30 | 1988-06-07 | Phillips Petroleum Company | Synthesis of cis-9-tricosene |
-
1989
- 1989-01-13 US US07/297,640 patent/US4922049A/en not_active Expired - Fee Related
- 1989-12-18 CA CA002005830A patent/CA2005830A1/en not_active Abandoned
-
1990
- 1990-01-10 KR KR1019900000239A patent/KR950006789B1/ko not_active Expired - Fee Related
- 1990-01-11 JP JP2004414A patent/JPH02270828A/ja active Pending
- 1990-01-12 DE DE69019839T patent/DE69019839T2/de not_active Expired - Fee Related
- 1990-01-12 ES ES90100594T patent/ES2074482T3/es not_active Expired - Lifetime
- 1990-01-12 EP EP90100594A patent/EP0383016B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| EP0383016B1 (en) | 1995-06-07 |
| KR900011692A (ko) | 1990-08-01 |
| JPH02270828A (ja) | 1990-11-05 |
| EP0383016A1 (en) | 1990-08-22 |
| US4922049A (en) | 1990-05-01 |
| DE69019839D1 (de) | 1995-07-13 |
| DE69019839T2 (de) | 1995-12-21 |
| KR950006789B1 (ko) | 1995-06-22 |
| CA2005830A1 (en) | 1990-07-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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