ES2077522A2 - Material para catodos empleados en pilas de combustible de carbonatos fundidos y procedimiento para su fabricacion. - Google Patents
Material para catodos empleados en pilas de combustible de carbonatos fundidos y procedimiento para su fabricacion.Info
- Publication number
- ES2077522A2 ES2077522A2 ES09302509A ES9302509A ES2077522A2 ES 2077522 A2 ES2077522 A2 ES 2077522A2 ES 09302509 A ES09302509 A ES 09302509A ES 9302509 A ES9302509 A ES 9302509A ES 2077522 A2 ES2077522 A2 ES 2077522A2
- Authority
- ES
- Spain
- Prior art keywords
- lanthanide
- nickel
- fuel cells
- cathodes
- molten carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title abstract 3
- 239000000446 fuel Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000463 material Substances 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 7
- 229910052747 lanthanoid Inorganic materials 0.000 abstract 4
- -1 lanthanide salt Chemical class 0.000 abstract 3
- 150000002602 lanthanoids Chemical group 0.000 abstract 3
- 229910052759 nickel Inorganic materials 0.000 abstract 3
- 238000000354 decomposition reaction Methods 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 abstract 2
- 239000007864 aqueous solution Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000001704 evaporation Methods 0.000 abstract 1
- 230000008020 evaporation Effects 0.000 abstract 1
- 230000036571 hydration Effects 0.000 abstract 1
- 238000006703 hydration reaction Methods 0.000 abstract 1
- 238000010348 incorporation Methods 0.000 abstract 1
- 229910044991 metal oxide Inorganic materials 0.000 abstract 1
- 150000004706 metal oxides Chemical class 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 229910000480 nickel oxide Inorganic materials 0.000 abstract 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inert Electrodes (AREA)
- Powder Metallurgy (AREA)
Abstract
MATERIAL PARA CATODOS EMPLEADOS EN PILAS DE COMBUSTIBLE DE CARBONATOS FUNDIDOS Y PROCEDIMIENTO PARA SU FABRICACION. LA INVENCION SE REFIERE A CATODOS POROSOS DE NIQUEL, UTILIZABLES EN LAS PILAS DE COMBUSTIBLE DE CARBONATOS FUNDIDOS QUE MEJORAN SU RESISTENCIA A LA CORROSION MEDIANTE ELDOPAJE DEL SUBSTRATO DE NIQUEL CON OXIDOS DE METALES DEL GRUPO DE LOS LANTANIDOS, EN UN PORCENTAJE COMPRENDIDO ENTRE EL 0,1 Y EL 10%. EL DOPAJE COMPRENDE LAS SIGUIENTES ETAPAS: (A) INCORPORACION DEL LANTANIDO MEZCLANDO INTIMAMENTE EL POLVO NIQUEL DE UN TAMAÑO COMPRENDIDO ENTRE 1 Y 10 MI, CON UNA SOLUCION ACUOSA DE UNA SAL DEL LANTANIDO, EN LA QUE SE DISPERSA EL NIQUEL; (B) EVAPORACION, PREFERENTEMENTE A VACIO, HASTA SEQUEDAD; (C) CALENTAMIENTO, EN ATMOSFERA INERTE, DEL PRODUCTO SECO HASTA LA TEMPERATURA DE DESCOMPOSICION DEL HIDRATO DE LA SAL DEL LANTANIDO, HASTA LA ELIMINACION DEL AGUA DE HIDRATACION; (D) CALENTAMIENTO, EN ATMOSFERA INERTE, HASTA LA TEMPERATURA DE DESCOMPOSICION DE LA SAL DEL LANTANIDO; (E) CAMBIO A UNA ATMOSFERA REDUCTORA (PREFERENTEMENTE EQUIMOLECULAR DE H2/N2), MANTENIENDO LA TEMPERATURA, DURANTE EL TIEMPO SUFICIENTE PARA REDUCIR EL OXIDO DE NIQUEL QUE SE PUDIERA HABER FORMADO EN LAS OPERACIONES ANTERIORES; (F) ENFRIAMIENTO DEL PRODUCTO EN ATMOSFERA REDUCTORA. POR SINTERIZACION DEL POLVO SE OBTIENEN LOS CATODOS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES09302509A ES2077522B1 (es) | 1993-11-30 | 1993-11-30 | Material para catodos empleados en pilas de combustible de carbonatos fundidos y procedimiento para su fabricacion. |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| ES09302509A ES2077522B1 (es) | 1993-11-30 | 1993-11-30 | Material para catodos empleados en pilas de combustible de carbonatos fundidos y procedimiento para su fabricacion. |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| ES2077522A2 true ES2077522A2 (es) | 1995-11-16 |
| ES2077522R ES2077522R (es) | 1997-05-01 |
| ES2077522B1 ES2077522B1 (es) | 1998-01-01 |
Family
ID=8283785
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09302509A Expired - Lifetime ES2077522B1 (es) | 1993-11-30 | 1993-11-30 | Material para catodos empleados en pilas de combustible de carbonatos fundidos y procedimiento para su fabricacion. |
Country Status (1)
| Country | Link |
|---|---|
| ES (1) | ES2077522B1 (es) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0061775A1 (en) * | 1981-03-31 | 1982-10-06 | Hitachi, Ltd. | Molten carbonate fuel cell |
| US4659379A (en) * | 1985-04-16 | 1987-04-21 | Energy Research Corporation | Nickel anode electrode |
| US4721513A (en) * | 1982-01-28 | 1988-01-26 | The United States Of America Represented By The United States Department Of Energy | Cathode preparation method for molten carbonate fuel cell |
| EP0327887A1 (en) * | 1988-01-25 | 1989-08-16 | Hitachi, Ltd. | A fuel cell, electrode for the cell and method of preparation thereof |
-
1993
- 1993-11-30 ES ES09302509A patent/ES2077522B1/es not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0061775A1 (en) * | 1981-03-31 | 1982-10-06 | Hitachi, Ltd. | Molten carbonate fuel cell |
| US4721513A (en) * | 1982-01-28 | 1988-01-26 | The United States Of America Represented By The United States Department Of Energy | Cathode preparation method for molten carbonate fuel cell |
| US4659379A (en) * | 1985-04-16 | 1987-04-21 | Energy Research Corporation | Nickel anode electrode |
| EP0327887A1 (en) * | 1988-01-25 | 1989-08-16 | Hitachi, Ltd. | A fuel cell, electrode for the cell and method of preparation thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2077522R (es) | 1997-05-01 |
| ES2077522B1 (es) | 1998-01-01 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EC2A | Search report published |
Date of ref document: 19951116 Kind code of ref document: R Effective date: 19951116 |
|
| FA2A | Application withdrawn |
Effective date: 19980803 |