ES2081031T3 - Preparacion de un catalizador para hidrotratamiento. - Google Patents

Preparacion de un catalizador para hidrotratamiento.

Info

Publication number
ES2081031T3
ES2081031T3 ES92201239T ES92201239T ES2081031T3 ES 2081031 T3 ES2081031 T3 ES 2081031T3 ES 92201239 T ES92201239 T ES 92201239T ES 92201239 T ES92201239 T ES 92201239T ES 2081031 T3 ES2081031 T3 ES 2081031T3
Authority
ES
Spain
Prior art keywords
metal
catalyst
group
carrier
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92201239T
Other languages
English (en)
Inventor
Eugene Nebesh
Steven L Mcmahon
Robert A Plundo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Catalysts LLC
Original Assignee
Engelhard Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26867907&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2081031(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US07/172,267 external-priority patent/US4900711A/en
Priority claimed from US07/197,455 external-priority patent/US4957895A/en
Application filed by Engelhard Corp filed Critical Engelhard Corp
Application granted granted Critical
Publication of ES2081031T3 publication Critical patent/ES2081031T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • B01J27/12—Fluorides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10—Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)

Abstract

UN CATALIZADOR HIDROTRATADOR, UTIL PARA LA PRODUCCION DE ACEITES LUBRICANTES A PARTIR DE RESERVAS DE ACEITE DE HIDROCARBUROS CRUDO, QUE CONTIENE AL MENOS UN METAL DEL GRUPO VI, OXIDO METALICO O SULFURO METALICO Y AL MENOS UN METAL DEL GRUPO VIII, OXIDO METALICO O SULFURO METALICO, SE PREPARA (A) PREPARANDO UN PORTADOR DE CATALIZADOR QUE CONTENGA HALOGENO, SILICE Y ALUMINA; (B) IMPREGNANDO DICHO PORTADOR CON UNA SOLUCION QUE CONTENGA AL MENOS UNA SAL METALICA DEL GRUPO VI Y AL MENOS UNA SAL METALICA DEL GRUPO VIII; (C) SECANDO EL PORTADOR IMPREGNADO ; Y (D) CALCINANDO EL PORTADOR IMPREGNADO SECO. EL CATALIZADOR RESULTANTE SE PUEDE SULFURAR ANTES DE USARLO. PREFERENTEMENTE, EL CATALIZADOR CONTIENE DE UN 10% A UN 35% EN PESO DE UN METAL COMBINADO Y LA RELACION ATOMICA DEL METAL DEL GRUPO VIII Y EL METAL DEL GRUPO VI ES DE 0,5:1 A 2:1; EL PORTADOR CONTIENE DE UN 0,5 A UN 10 POR CIENTO EN PESO DE HALOGENO, DE UN 0,5 A UN 5% EN PESO DE SILICE Y DE UN 85 A UN 99% DE ALUMINA; Y EL CATALIZADOR TIENEUN RADIO DE PORO MEDIO DE 30 A 65 ANGSTROMS Y UN AREA DE SUPERFICIE DE 120 A 180 M (AL CUADRADO) /G.
ES92201239T 1988-03-23 1989-03-22 Preparacion de un catalizador para hidrotratamiento. Expired - Lifetime ES2081031T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/172,267 US4900711A (en) 1988-03-23 1988-03-23 Hydrotreating catalyst
US07/197,455 US4957895A (en) 1988-05-23 1988-05-23 Hydrotreating catalyst and process

Publications (1)

Publication Number Publication Date
ES2081031T3 true ES2081031T3 (es) 1996-02-16

Family

ID=26867907

Family Applications (3)

Application Number Title Priority Date Filing Date
ES92201240T Expired - Lifetime ES2106128T3 (es) 1988-03-23 1989-03-22 Preparacion de un soporte para un catalizador de hidrotratamiento.
ES92201239T Expired - Lifetime ES2081031T3 (es) 1988-03-23 1989-03-22 Preparacion de un catalizador para hidrotratamiento.
ES89302880T Expired - Lifetime ES2043004T3 (es) 1988-03-23 1989-03-22 Catalizador y procedimiento de hidrotratamiento.

Family Applications Before (1)

Application Number Title Priority Date Filing Date
ES92201240T Expired - Lifetime ES2106128T3 (es) 1988-03-23 1989-03-22 Preparacion de un soporte para un catalizador de hidrotratamiento.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES89302880T Expired - Lifetime ES2043004T3 (es) 1988-03-23 1989-03-22 Catalizador y procedimiento de hidrotratamiento.

Country Status (7)

Country Link
EP (3) EP0335583B1 (es)
JP (1) JP2888536B2 (es)
KR (1) KR0129544B1 (es)
AT (2) ATE157564T1 (es)
CA (1) CA1334194C (es)
DE (3) DE68928303T2 (es)
ES (3) ES2106128T3 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5292426A (en) * 1991-10-18 1994-03-08 Texaco Inc. Wax conversion process
JP2806701B2 (ja) * 1992-06-01 1998-09-30 出光興産株式会社 水素化処理用触媒の製造法とその触媒を用いた重質油の水素化処理方法
DE69311576T2 (de) * 1992-11-18 1997-12-04 Akzo Nobel Nv Verfahren zur entfernung von schwefeldioxyd aus schwefeldioxyd enthaltenden gasströmen
ES2204989T3 (es) * 1995-11-21 2004-05-01 Fina Technology, Inc. Desparafinado mediante un catalizador niquel-silicalita.
EP0870817A1 (en) 1997-04-11 1998-10-14 Akzo Nobel N.V. Process for effecting deep HDS of hydrocarbon feedstocks
IT1295300B1 (it) * 1997-10-09 1999-05-04 Agip Petroli Procedimento per l'idroisomerizzazione di n-paraffine a catena lunga e catalizzatore adatto allo scopo
US6365544B2 (en) 1998-05-22 2002-04-02 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided alumina supports
US6333294B1 (en) 1998-05-22 2001-12-25 Conoco Inc. Fischer-tropsch processes and catalysts with promoters
JP5305589B2 (ja) * 2006-12-25 2013-10-02 Ｊｘ日鉱日石エネルギー株式会社 潤滑油組成物
EP3200916B1 (en) * 2014-09-30 2020-01-08 Chevron U.S.A. Inc. Hydroisomerization catalyst manufactured using high nanopore volume alumina supports and hydroisomerization process
CN108067256B (zh) * 2016-11-15 2019-07-12 中国石油化工股份有限公司 一种硫化型加氢催化剂的制备方法
CN116064103B (zh) * 2021-10-29 2025-03-11 中国石油化工股份有限公司 一种生产轻质白油和工业白油的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL274088A (es) * 1900-01-01
US3078238A (en) * 1959-07-24 1963-02-19 Gulf Research Development Co Hydrogenation catalyst and method of preparation
NL6702572A (es) * 1967-02-21 1968-08-22
US3493493A (en) * 1968-10-01 1970-02-03 Gulf Research Development Co Process for enhancing lubricating oils and a catalyst for use in the process
GB1468160A (en) * 1973-10-05 1977-03-23 Shell Int Research Hydrocarbon conversion process
NL7611940A (nl) * 1976-10-28 1978-05-03 Shell Int Research Werkwijze voor de bereiding van smeerolien.

Also Published As

Publication number Publication date
CA1334194C (en) 1995-01-31
DE68924855T2 (de) 1996-06-05
JP2888536B2 (ja) 1999-05-10
DE68907361D1 (de) 1993-08-05
DE68928303T2 (de) 1998-03-26
ATE130358T1 (de) 1995-12-15
DE68928303D1 (de) 1997-10-09
EP0497436A2 (en) 1992-08-05
EP0497435B1 (en) 1995-11-15
KR0129544B1 (ko) 1998-04-06
EP0497436B1 (en) 1997-09-03
EP0497435A3 (en) 1993-02-03
EP0497435A2 (en) 1992-08-05
ES2043004T3 (es) 1993-12-16
ATE157564T1 (de) 1997-09-15
EP0335583B1 (en) 1993-06-30
EP0335583A1 (en) 1989-10-04
DE68907361T2 (de) 1993-10-14
KR890014162A (ko) 1989-10-23
JPH01310743A (ja) 1989-12-14
EP0497436A3 (en) 1993-02-03
ES2106128T3 (es) 1997-11-01
DE68924855D1 (de) 1995-12-21

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