ES2106128T3 - Preparacion de un soporte para un catalizador de hidrotratamiento. - Google Patents

Preparacion de un soporte para un catalizador de hidrotratamiento.

Info

Publication number
ES2106128T3
ES2106128T3 ES92201240T ES92201240T ES2106128T3 ES 2106128 T3 ES2106128 T3 ES 2106128T3 ES 92201240 T ES92201240 T ES 92201240T ES 92201240 T ES92201240 T ES 92201240T ES 2106128 T3 ES2106128 T3 ES 2106128T3
Authority
ES
Spain
Prior art keywords
metal
catalyst
carrier
weight
metallic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92201240T
Other languages
English (en)
Inventor
Eugene Nebesh
Steven L Mcmahon
Robert A Plundo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Catalysts LLC
Original Assignee
Engelhard Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=26867907&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2106128(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US07/172,267 external-priority patent/US4900711A/en
Priority claimed from US07/197,455 external-priority patent/US4957895A/en
Application filed by Engelhard Corp filed Critical Engelhard Corp
Application granted granted Critical
Publication of ES2106128T3 publication Critical patent/ES2106128T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12Silica and alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04Sulfides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/08Halides
    • B01J27/12Fluorides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/125Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06Halogens; Compounds thereof
    • B01J27/132Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/633Pore volume less than 0.5 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64Pore diameter
    • B01J35/6472-50 nm
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/10Lubricating oil

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Lubricants (AREA)

Abstract

UN PORTADOR PARA UN CATALIZADOR HIDROTRATADOR, UTIL PARA LA PRODUCCION DE ACEITES LUBRICANTES A PARTIR DE RESERVAS DE ACEITE DE HIDROCARBUROS CRUDO, SE PREPARA MEZCLANDO ALUMINA Y UNA SOLUCION DE ACIDO FLUOSILICICO Y UN ACIDO MINERAL SEGUIDO DE UN PROCESO DE EXTRUSION, SECADO Y CALCINACION. EL PORTADOR RESULTANTE SE PUEDE IMPREGNAR CON UNA SOLUCION DE COMPONENTES METALICAS Y SE PUEDE CALCINAR DESPUES Y SULFURAR OPCINALMENTE, PARA OBTENER UN CATALIZADOR QUE CONTENGA AL MENOS UN METAL DEL GRUPO VI, OXIDO METALICO O SULFURO METALICO Y AL MENOS UN METAL DEL GRUPO VIII, OXIDO METALICO O SULFURO METALICO, SOPORTADOS SOBRE EL PORTADOR, EN DONDE (A) EL CATALIZADOR CONTIENE DE UN 10% A UN 35% EN PESO DE UN METAL COMBINADO Y LA RELACION ATOMICA ENTRE EL METAL DEL GRUPO VIII Y METAL DEL GRUPO VI ES DE 0,5:1 A 2:1; (B) EL PORTADOR CONTIENE DE UN 0,5 A UN 10 POR CIENTO EN PESO DE FLUOR, DE UN 0,5 A UN 5% EN PESO DE SILICE Y DE UN 85 A UN 99% DE ALUMINA; Y (C) EL CATALIZADOR TIENE UN RADIO DE PESO MEDIODE 30 A 65 ANGSTROMS Y UN AREA DE SUPERFICIE DE 120 A 180 M (AL CUADRADO) /G.
ES92201240T 1988-03-23 1989-03-22 Preparacion de un soporte para un catalizador de hidrotratamiento. Expired - Lifetime ES2106128T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/172,267 US4900711A (en) 1988-03-23 1988-03-23 Hydrotreating catalyst
US07/197,455 US4957895A (en) 1988-05-23 1988-05-23 Hydrotreating catalyst and process

Publications (1)

Publication Number Publication Date
ES2106128T3 true ES2106128T3 (es) 1997-11-01

Family

ID=26867907

Family Applications (3)

Application Number Title Priority Date Filing Date
ES92201240T Expired - Lifetime ES2106128T3 (es) 1988-03-23 1989-03-22 Preparacion de un soporte para un catalizador de hidrotratamiento.
ES89302880T Expired - Lifetime ES2043004T3 (es) 1988-03-23 1989-03-22 Catalizador y procedimiento de hidrotratamiento.
ES92201239T Expired - Lifetime ES2081031T3 (es) 1988-03-23 1989-03-22 Preparacion de un catalizador para hidrotratamiento.

Family Applications After (2)

Application Number Title Priority Date Filing Date
ES89302880T Expired - Lifetime ES2043004T3 (es) 1988-03-23 1989-03-22 Catalizador y procedimiento de hidrotratamiento.
ES92201239T Expired - Lifetime ES2081031T3 (es) 1988-03-23 1989-03-22 Preparacion de un catalizador para hidrotratamiento.

Country Status (7)

Country Link
EP (3) EP0497436B1 (es)
JP (1) JP2888536B2 (es)
KR (1) KR0129544B1 (es)
AT (2) ATE130358T1 (es)
CA (1) CA1334194C (es)
DE (3) DE68907361T2 (es)
ES (3) ES2106128T3 (es)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5292426A (en) * 1991-10-18 1994-03-08 Texaco Inc. Wax conversion process
JP2806701B2 (ja) * 1992-06-01 1998-09-30 出光興産株式会社 水素化処理用触媒の製造法とその触媒を用いた重質油の水素化処理方法
JPH08503651A (ja) * 1992-11-18 1996-04-23 アクゾ ノーベル ナムローゼ フェンノートシャップ 二酸化硫黄含有ガス流から二酸化硫黄を除去する方法
EP0775739B1 (en) * 1995-11-21 2003-08-13 Fina Technology, Inc. Dewaxing with nickel-silicalite catalyst
EP0870817A1 (en) 1997-04-11 1998-10-14 Akzo Nobel N.V. Process for effecting deep HDS of hydrocarbon feedstocks
IT1295300B1 (it) * 1997-10-09 1999-05-04 Agip Petroli Procedimento per l'idroisomerizzazione di n-paraffine a catena lunga e catalizzatore adatto allo scopo
US6333294B1 (en) 1998-05-22 2001-12-25 Conoco Inc. Fischer-tropsch processes and catalysts with promoters
US6365544B2 (en) 1998-05-22 2002-04-02 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided alumina supports
JP5305589B2 (ja) * 2006-12-25 2013-10-02 Jx日鉱日石エネルギー株式会社 潤滑油組成物
EP3200916B1 (en) * 2014-09-30 2020-01-08 Chevron U.S.A. Inc. Hydroisomerization catalyst manufactured using high nanopore volume alumina supports and hydroisomerization process
CN108067256B (zh) * 2016-11-15 2019-07-12 中国石油化工股份有限公司 一种硫化型加氢催化剂的制备方法
CN116064103B (zh) * 2021-10-29 2025-03-11 中国石油化工股份有限公司 一种生产轻质白油和工业白油的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL274088A (es) * 1900-01-01
US3078238A (en) * 1959-07-24 1963-02-19 Gulf Research Development Co Hydrogenation catalyst and method of preparation
NL6702572A (es) * 1967-02-21 1968-08-22
US3493493A (en) * 1968-10-01 1970-02-03 Gulf Research Development Co Process for enhancing lubricating oils and a catalyst for use in the process
GB1468160A (en) * 1973-10-05 1977-03-23 Shell Int Research Hydrocarbon conversion process
NL7611940A (nl) * 1976-10-28 1978-05-03 Shell Int Research Werkwijze voor de bereiding van smeerolien.

Also Published As

Publication number Publication date
EP0497435A3 (en) 1993-02-03
DE68907361T2 (de) 1993-10-14
DE68928303D1 (de) 1997-10-09
DE68924855D1 (de) 1995-12-21
KR0129544B1 (ko) 1998-04-06
EP0497436A3 (en) 1993-02-03
EP0497436A2 (en) 1992-08-05
EP0335583B1 (en) 1993-06-30
JPH01310743A (ja) 1989-12-14
EP0497436B1 (en) 1997-09-03
EP0497435A2 (en) 1992-08-05
ATE157564T1 (de) 1997-09-15
DE68928303T2 (de) 1998-03-26
EP0497435B1 (en) 1995-11-15
DE68907361D1 (de) 1993-08-05
KR890014162A (ko) 1989-10-23
ES2081031T3 (es) 1996-02-16
DE68924855T2 (de) 1996-06-05
EP0335583A1 (en) 1989-10-04
CA1334194C (en) 1995-01-31
ATE130358T1 (de) 1995-12-15
JP2888536B2 (ja) 1999-05-10
ES2043004T3 (es) 1993-12-16

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