ES2084187T3 - Catalizadores ionicos para la produccion de poli(alfa-olefinas) con tacticidad controlada. - Google Patents

Catalizadores ionicos para la produccion de poli(alfa-olefinas) con tacticidad controlada.

Info

Publication number
ES2084187T3
ES2084187T3 ES91918527T ES91918527T ES2084187T3 ES 2084187 T3 ES2084187 T3 ES 2084187T3 ES 91918527 T ES91918527 T ES 91918527T ES 91918527 T ES91918527 T ES 91918527T ES 2084187 T3 ES2084187 T3 ES 2084187T3
Authority
ES
Spain
Prior art keywords
alpha
metallocene
olephins
poli
production
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91918527T
Other languages
English (en)
Inventor
Howard William Turner
Gregory George Hlatky
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Application granted granted Critical
Publication of ES2084187T3 publication Critical patent/ES2084187T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

LAS POLI-(ALFA)-OLEFINAS SINDIOTACTICAS SE PRODUCEN MEDIANTE LA POLIMERIZACION DE MONOMEROS DE ALFA-OLEFINAS EN LA PRESENCIA DE UN SISTEMA CATALIZADOR QUE COMPRENDE UN PRODUCTO DE REACCION IONICA DE UN COMPUESTO DE METAL DEL GRUPO IV-B DE BIS(CICLOPENTADIENIL) DE UNA ESTRUCTURA ESPECIFICA Y UN COMPUESTO ACTIVADOR QUE REACCIONE CON UN LIGANTE DIFERENTE DEL CICLOPENTADIENIL DEL METALOCENO Y UN ANION QUE SEA COMPATIBLE Y NO COORDINANTE CON RESPECTO AL CATION DE METALOCENO GENERADO EN LA REACCION DEL METALOCENO CON DICHO COMPUESTO ACTIVADOR.
ES91918527T 1990-09-14 1991-09-16 Catalizadores ionicos para la produccion de poli(alfa-olefinas) con tacticidad controlada. Expired - Lifetime ES2084187T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US58270290A 1990-09-14 1990-09-14

Publications (1)

Publication Number Publication Date
ES2084187T3 true ES2084187T3 (es) 1996-05-01

Family

ID=24330190

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91918527T Expired - Lifetime ES2084187T3 (es) 1990-09-14 1991-09-16 Catalizadores ionicos para la produccion de poli(alfa-olefinas) con tacticidad controlada.

Country Status (8)

Country Link
EP (1) EP0548274B1 (es)
JP (1) JPH06501047A (es)
AT (1) ATE134658T1 (es)
AU (1) AU8852591A (es)
CA (1) CA2090962A1 (es)
DE (1) DE69117520T2 (es)
ES (1) ES2084187T3 (es)
WO (1) WO1992005208A1 (es)

Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2101217T3 (es) * 1992-10-23 1997-07-01 Shell Int Research Composicion catalitica para oligomerizacion y co-oligomerizacion de alquenos.
ES2313762T3 (es) 1994-06-13 2009-03-01 Basell Polyolefine Gmbh Compuestos de metales de transicion.
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
IT1282666B1 (it) 1996-02-22 1998-03-31 Enichem Spa Catalizzatore metallocenico sostituito per la (co) polimerizzazione delle olefine
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US6211300B1 (en) 1998-04-10 2001-04-03 Chisso Corporation Propylene-ethylene block copolymer compositions and processes for production thereof
IT1313599B1 (it) * 1999-08-05 2002-09-09 Enichem Spa Complessi metallici utilizzabili nella catalisi per la (co)polimerizzazione delle alfa-olefine
US6858767B1 (en) 2000-08-11 2005-02-22 Uniroyal Chemical Company, Inc. Process for producing liquid polyalphaolefin polymer, metallocene catalyst therefor, the resulting polymer and lubricant containing same
US6930160B2 (en) * 2000-08-22 2005-08-16 Idemitsu Petrochemical Co. Ltd. 1-Butene polymer and molded product consisting of the polymer
TWI263645B (en) 2000-08-22 2006-10-11 Idemitsu Kosan Co 1-butene based polymer and product formed therefrom
US6878790B2 (en) 2000-11-30 2005-04-12 The Procter & Gamble Company High molecular weight polyolefin and catalyst and process for polymerizing said polyolefin
AU2002243244A1 (en) * 2000-11-30 2002-07-24 The Procter And Gamble Company High molecular weight polyolefin and catalyst and process for polymerising said polyolefin
WO2002100908A1 (en) * 2001-06-12 2002-12-19 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
AU2003233542B2 (en) 2002-05-13 2009-03-05 S.C. Johnson & Son, Inc. Coordinated emission of fragrance, light, and sound
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
US7534848B2 (en) 2002-12-04 2009-05-19 Basell Polyolefine Gmbh 1-butene copolymers and process for preparing them
CN1820543B (zh) 2003-02-07 2010-11-17 约翰逊父子公司 具有发光二极管夜灯的散射器
USD542400S1 (en) 2005-03-31 2007-05-08 S.C. Johnson & Son, Inc. Diffuser
US7643734B2 (en) 2005-03-31 2010-01-05 S.C. Johnson & Son, Inc. Bottle eject mechanism
USD541922S1 (en) 2005-03-31 2007-05-01 S.C. Johnson & Son, Inc. Diffuser
US7589340B2 (en) 2005-03-31 2009-09-15 S.C. Johnson & Son, Inc. System for detecting a container or contents of the container
ITMI20122199A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto
ITMI20122206A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-immino-piridinico di cobalto
ITMI20122201A1 (it) 2012-12-20 2014-06-21 Versalis Spa Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI20122203A1 (it) 2012-12-20 2014-06-21 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto
ITMI20131828A1 (it) 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
ITMI20131830A1 (it) 2013-11-05 2015-05-06 Versalis Spa Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica
HUE047413T2 (hu) 2014-09-17 2020-04-28 Versalis Spa Cirkónium piridin komplexe, a cirkónium említett komplexét tartalmazó katalitikus rendszer, és eljárás konjugált diének (ko)polimerizálására
ITUB20152581A1 (it) 2015-07-29 2017-01-29 Versalis Spa Complesso azotato di titanio, sistema catalitico comprendente detto complesso azotato di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
ITUA20163932A1 (it) 2016-05-30 2017-11-30 Versalis Spa Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati
IT201700109176A1 (it) 2017-09-29 2019-03-29 Versalis Spa Complesso bis-imminico di titanio, sistema catalitico comprendente detto complesso bis-imminico di titanio e procedimento per la (co)polimerizzazione di dieni coniugati
US20240352159A1 (en) * 2021-08-11 2024-10-24 Sabic Global Technologies B.V. Process for preparing polyalpha-olefins

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL85097A (en) * 1987-01-30 1992-02-16 Exxon Chemical Patents Inc Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes
US5155080A (en) * 1988-07-15 1992-10-13 Fina Technology, Inc. Process and catalyst for producing syndiotactic polyolefins
EP0423100A3 (en) * 1989-10-10 1991-08-07 Fina Technology, Inc. Process and catalyst for producing syndiotactic polymers
EP0426637B2 (en) * 1989-10-30 2001-09-26 Fina Technology, Inc. Preparation of metallocene catalysts for polymerization of olefins
ES2086397T5 (es) * 1989-10-30 2005-07-16 Fina Technology, Inc. Adicion de alkiloaluminio para un catalizador metaloceno mejorado.

Also Published As

Publication number Publication date
DE69117520T2 (de) 1996-08-01
CA2090962A1 (en) 1992-03-15
DE69117520D1 (de) 1996-04-04
ATE134658T1 (de) 1996-03-15
WO1992005208A1 (en) 1992-04-02
EP0548274A1 (en) 1993-06-30
AU8852591A (en) 1992-04-15
EP0548274B1 (en) 1996-02-28
JPH06501047A (ja) 1994-01-27

Similar Documents

Publication Publication Date Title
AU8852591A (en) Ionic catalyst for the production of poly-alpha-olefins of controlled tacticity
HUT51651A (en) Cathalizator for polimerization of olefines
ES2156106T3 (es) Procedimiento para producir polimeros sindiotacticos.
PT990003E (pt) Novos sistemas de catalisador para reaccoes de (co-)polimerizacao halogenetos de metalocenamida e sua utilizacao
ES2141797T3 (es) Catalizadores ionicos de metalocenos soportados para la polimerizacion de olefinas.
DE59712813D1 (de) Metallocene
ES2157445T3 (es) Procedimiento para la preparacion y empleo de un catalizador de metaloceno-alumoxano soportado.
ES2101765T3 (es) Catalizadores para la polimerizacion de alfa-olefinas de ciclopentadienil-metal del grupo 6b y proceso para polimerizar alfa-olefinas.
CA2131298A1 (en) Polymerization Process
NO953017L (no) Katalysatorsystem og fremgangsmåte for polymerisasjon av olefiner
ES2079213T3 (es) Catalizador para la polimerizacion de olefinas, procedimiento para su produccion y su empleo.
NO961413L (no) Fremgangsmåte ved polymerisering av et olefin i nærvær av et katalysatorsystem omfattende et halogenmetallocen
MX164614B (es) Proceso para preparar un polimero que contiene almidon
FI862625A0 (fi) Polymerisationskatalysator.

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 548274

Country of ref document: ES