ES2088456T3 - Catalizador soportado para la polimerizacion y la copolimerizacion de compuestos olefinicamente insaturados y un procedimiento de (co)polimerizacion que lo utiliza. - Google Patents

Catalizador soportado para la polimerizacion y la copolimerizacion de compuestos olefinicamente insaturados y un procedimiento de (co)polimerizacion que lo utiliza.

Info

Publication number
ES2088456T3
ES2088456T3 ES91200594T ES91200594T ES2088456T3 ES 2088456 T3 ES2088456 T3 ES 2088456T3 ES 91200594 T ES91200594 T ES 91200594T ES 91200594 T ES91200594 T ES 91200594T ES 2088456 T3 ES2088456 T3 ES 2088456T3
Authority
ES
Spain
Prior art keywords
polymerization
copolymerization
supported catalyst
unsaturated compounds
olefinically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91200594T
Other languages
English (en)
Inventor
Francesco Masi
Renzo Invernizzi
Antonio Carbonaro
Lorenzo Costa
Angelo Moalli
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Versalis SpA
Original Assignee
Polimeri Europa SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Polimeri Europa SpA filed Critical Polimeri Europa SpA
Application granted granted Critical
Publication of ES2088456T3 publication Critical patent/ES2088456T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Catalysts (AREA)

Abstract

SE DESCRIBE UN CATALIZADOR SOPORTADO PARA LA POLIMERIZACION Y COPOLIMERIZACION DE COMPUESTOS NO SATURADOS POR OLEFINA, QUE CONTIENE UN COMPUESTO ORGANOMETALICO DE ALUMINIO Y UN SEGUNDO COMPONENTE OBTENIDO AL PONER EN CONTACTO UN COMPUESTO DE MAGNESIO Y/O UN COMPUESTO DE TITANIS, VANADIO O CROMO Y POSIBLEMENTE POR LO MENOS UN COMPUESTO DE UN SEGUNDO METAL ELEGIDO ENTRE V, AL, ZR, HF, MO Y ND, CON UN SOPORTE POROSO FORMADO POR MICROPERLAS DE AEROGELES DE UNO O MAS OXIDOS INORGANICOS DISTINGUIDOS POR SU BAJA DENSIDAD, POROSIDAD ALTA Y POR EL HECHO DE QUE POR LO MENOS EL 90 % DE LOS POROS TIENE UN DIAMETRO QUE SE EXTIENDE DENTRO DE UN MARGEN MUY ESTRECHO DE VALORES. TAMBIEN SE DESCRIBE EL PROCESO PARA LA POLIMERIZACION O COPOLIMERIZACION DE COMPUESTOS NO SATURADOS POR OLEFINA BASADO EN EL USO DE DICHO CATALIZADOR.
ES91200594T 1990-03-26 1991-03-19 Catalizador soportado para la polimerizacion y la copolimerizacion de compuestos olefinicamente insaturados y un procedimiento de (co)polimerizacion que lo utiliza. Expired - Lifetime ES2088456T3 (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT19816A IT1240613B (it) 1990-03-26 1990-03-26 Catalizzatore supportato per la polimerizzazione e la copolimerizzazione di composti olefinicamente insaturi, e procedimento di (co) polimerizzazione impiegante lo stesso
CA002050814A CA2050814A1 (en) 1990-03-26 1991-09-06 Supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds, and a (co)polymerization process which uses it

Publications (1)

Publication Number Publication Date
ES2088456T3 true ES2088456T3 (es) 1996-08-16

Family

ID=25674781

Family Applications (1)

Application Number Title Priority Date Filing Date
ES91200594T Expired - Lifetime ES2088456T3 (es) 1990-03-26 1991-03-19 Catalizador soportado para la polimerizacion y la copolimerizacion de compuestos olefinicamente insaturados y un procedimiento de (co)polimerizacion que lo utiliza.

Country Status (19)

Country Link
US (1) US5189000A (es)
EP (1) EP0449355B1 (es)
JP (1) JP3303239B2 (es)
KR (1) KR930011529B1 (es)
CN (1) CN1055184A (es)
AT (1) ATE138667T1 (es)
AU (1) AU631489B2 (es)
BR (1) BR9101191A (es)
CA (2) CA2039015C (es)
DE (1) DE69119813T2 (es)
DK (1) DK0449355T3 (es)
ES (1) ES2088456T3 (es)
FI (1) FI105557B (es)
GR (1) GR3020634T3 (es)
IT (1) IT1240613B (es)
MX (1) MX173383B (es)
NO (1) NO177388C (es)
PT (1) PT97131B (es)
ZA (1) ZA912200B (es)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1240673B (it) * 1990-04-24 1993-12-17 Tenav Microsfere di aerogels di ossidi inorganici a stretta distribuzione dei diametri dei pori e metodo per la loro preparazione
IT1251939B (it) * 1991-10-17 1995-05-27 Donegani Guido Ist Procedimento per la preparazione di materiali a base di ossidi inorganici con granulometria monodispersa e materiali cosi ottenuti.
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
EP0586168B1 (en) * 1992-09-04 2000-07-05 BP Chemicals Limited Catalyst compositions and process for preparing polyolefins
CA2116259A1 (en) * 1993-02-23 1994-08-24 Akira Sano Solid catalyst components for olefin polymerization and use thereof
DE4334045A1 (de) * 1993-10-06 1995-04-13 Bayer Ag Katalysator, dessen Herstellung und Verwendung zur Gasphasenpolymerisation von konjugierten Dienen
JP3355572B2 (ja) * 1994-08-23 2002-12-09 新日本石油株式会社 オレフィン類重合触媒およびそれを用いたポリオレフィンの製造方法
CN1078596C (zh) 1994-09-08 2002-01-30 美孚石油公司 用于单反应器中控制宽/双态树脂的mwd的混合催化剂
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
US5895770A (en) * 1995-02-28 1999-04-20 Pq Corporation Olefin polymerization catalysts with specific silica supports
US5914377A (en) * 1995-04-04 1999-06-22 Bayer Ag Method for the production of diene rubbers in the gas phase
US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
WO1998002247A1 (en) * 1996-07-15 1998-01-22 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
JP2002507533A (ja) * 1998-03-26 2002-03-12 ザ ダウ ケミカル カンパニー イオン交換されているアルミニウム−マグネシウム又はフッ素化マグネシウムシリケートエーロゲル及びそれからの触媒支持体
IT1311978B1 (it) 1999-03-25 2002-03-22 Polimeri Europa Srl Catalizzatore bimetallico per la (co) polimerizzazione dellealfa-olefine.
US6828268B1 (en) * 1999-11-05 2004-12-07 Phillips Petroleum Company Polymerization catalyst systems and processes using alkyl lithium compounds as a cocatalyst
EP1231224B1 (en) * 2001-02-07 2004-08-11 Saudi Basic Industries Corporation Catalyst composition for polymerization of olefins and method for preparing the same
BR0214577A (pt) * 2001-11-30 2004-11-03 Exxonmobil Chem Patents Inc Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e uso
US8227046B2 (en) * 2002-11-29 2012-07-24 Council Of Scientific And Industrial Research Process for preparing self-assembling nanobinary and ternary oxy/hydroxides
CN101372520B (zh) 2003-11-20 2010-12-08 联合碳化化学及塑料技术有限责任公司 喷雾干燥的混合金属齐格勒催化剂组合物
US7151073B2 (en) * 2004-01-16 2006-12-19 Exxonmobil Chemical Patents Inc. Mesoporous catalyst support, a catalyst system, and method of making and using same for olefin polymerization
JP5972574B2 (ja) 2008-08-06 2016-08-17 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー 高分子量テールを有するポリエチレンを作製するためのチーグラー・ナッタ触媒組成物、およびそれを製造する方法
ITMI20090950A1 (it) * 2009-05-29 2010-11-30 Gegussa Novara Technology Spa Processo per la preparazione di un aerogelo in pellets
WO2012166469A1 (en) * 2011-06-01 2012-12-06 Dow Global Technologies Llc Multi -metallic ziegler - natta procatalysts and catalysts prepared therefrom for olefin polymerizations
CN104448066B (zh) * 2014-12-16 2017-07-07 华东理工大学 一种负载型多金属烯烃聚合催化剂及其制备方法与应用
CN108203478B (zh) * 2016-12-20 2021-04-30 中国石油天然气股份有限公司 一种负载型含钼聚乙烯催化剂的制备方法
EP3802642A1 (en) * 2018-06-01 2021-04-14 Dow Global Technologies LLC Ziegler-natta catalyst with an electron donor compound for increasing polymer molecular weight

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL7702323A (nl) * 1977-03-04 1978-09-06 Stamicarbon Katalysator voor de bereiding van polyalkenen.
US4405495A (en) * 1980-06-30 1983-09-20 Union Carbide Corporation Catalyst impregnated on fine silica, process for preparing, and use for ethylene polymerization
IT1136627B (it) * 1981-05-21 1986-09-03 Euteco Impianti Spa Catalizzatore supportato per la polimerizzazione di etilene
JPH0725817B2 (ja) * 1986-04-23 1995-03-22 日本石油株式会社 オレフイン重合用触媒
DE3635028A1 (de) * 1986-10-15 1988-04-21 Basf Ag Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren (alpha)-monoolefinen mittels eines ziegler-katalysatorsystems
IT1230133B (it) * 1989-04-28 1991-10-14 Himont Inc Composizioni polipropileniche plasto-elastiche
FR2656314B1 (fr) * 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.

Also Published As

Publication number Publication date
FI911412A0 (fi) 1991-03-25
KR930011529B1 (ko) 1993-12-10
NO177388B (no) 1995-05-29
CA2039015A1 (en) 1991-09-27
US5189000A (en) 1993-02-23
ZA912200B (en) 1992-01-29
IT1240613B (it) 1993-12-17
NO177388C (no) 1995-09-06
MX173383B (es) 1994-02-24
DE69119813D1 (de) 1996-07-04
NO911155L (no) 1991-09-27
CN1055184A (zh) 1991-10-09
BR9101191A (pt) 1991-11-05
CA2050814A1 (en) 1993-03-07
EP0449355A3 (en) 1991-12-27
DK0449355T3 (da) 1996-09-09
GR3020634T3 (en) 1996-10-31
EP0449355A2 (en) 1991-10-02
NO911155D0 (no) 1991-03-22
DE69119813T2 (de) 1996-12-19
JP3303239B2 (ja) 2002-07-15
PT97131B (pt) 1998-07-31
FI105557B (fi) 2000-09-15
AU7382091A (en) 1991-11-14
CA2039015C (en) 2002-04-16
KR910016779A (ko) 1991-11-05
PT97131A (pt) 1991-11-29
EP0449355B1 (en) 1996-05-29
JPH04224807A (ja) 1992-08-14
ATE138667T1 (de) 1996-06-15
IT9019816A1 (it) 1991-09-26
FI911412L (fi) 1991-09-27
IT9019816A0 (it) 1990-03-26
AU631489B2 (en) 1992-11-26

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