ES2092411T3 - Proceso para la separacion de hcn de mezclas de gases y catalizador para la descomposicion de hcn. - Google Patents

Proceso para la separacion de hcn de mezclas de gases y catalizador para la descomposicion de hcn.

Info

Publication number
ES2092411T3
ES2092411T3 ES94918351T ES94918351T ES2092411T3 ES 2092411 T3 ES2092411 T3 ES 2092411T3 ES 94918351 T ES94918351 T ES 94918351T ES 94918351 T ES94918351 T ES 94918351T ES 2092411 T3 ES2092411 T3 ES 2092411T3
Authority
ES
Spain
Prior art keywords
hcn
catalyst
pct
decomposition
date
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94918351T
Other languages
English (en)
Inventor
Wolfgang Forg
Gerhard Ranke
Michael Heisel
Dietrich Maschmeyer
Robert Walter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huels AG
Linde GmbH
Original Assignee
Huels AG
Linde GmbH
Chemische Werke Huels AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6490042&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2092411(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Huels AG, Linde GmbH, Chemische Werke Huels AG filed Critical Huels AG
Application granted granted Critical
Publication of ES2092411T3 publication Critical patent/ES2092411T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/26Chromium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8603Removing sulfur compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8621Removing nitrogen compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58Separation of hydrogen or hydrogen-containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10KPURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00Purifying combustible gases containing carbon monoxide
    • C10K1/34Purifying combustible gases containing carbon monoxide by catalytic conversion of impurities to more readily removable materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/308Carbonoxysulfide COS
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/408Cyanides, e.g. hydrogen cyanide (HCH)
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435Catalytic purification
    • C01B2203/045Purification by catalytic desulfurisation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0475Composition of the impurity the impurity being carbon dioxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0485Composition of the impurity the impurity being a sulfur compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Industrial Gases (AREA)

Abstract

LA INVENCION SE REFIERE A UN PROCESO PARA LA ELIMINACION DE HCN A PARTIR AL MENOS DE MEZCLAS QUE CONTIENEN HCN Y COMPUESTOS DE AZUFRE, EN PARTICULAR MEZCLAS DE GASES OBTENIDAS A PARTIR DE LA OXIDACION PARCIAL DE HIDROCARBUROS, MEDIANTE DESCOMPOSICION CATALITICA DEL HCN. LA INVENCION SE REFIERE TAMBIEN A UN CATALIZADOR PARA LA DESCOMPOSICION DEL HCN. LA INVENCION PROPONE QUE LA MEZCLA DE GAS SEA PUESTA EN CONTACTO CON UN CATALIZADOR QUE DESCOMPONE EL HCN MEDIANTE HIDROGENACION Y/O HIDROLISIS, AL MENOS DESCOMPONIENDOSE ALGO DE COS EN LA MEZCLA SOBRE EL CATALIZADOR MEDIANTE HIDROLISIS. CON PREFERENCIA EL CATALIZADOR UTILIZADO COMPRENDE OXIDO DE TITANIO Y/O OXIDO DE ZIRCONIO COMO MATERIAL SOPORTE Y OXIDO DE CROMO COMO COMPONENTE ACTIVO. ADICIONALMENTE EL CATALIZADOR ES REDUCIDO CON PREFERENCIA CUANDO HA SIDO ELABORADO O INMEDIATAMENTE ANTES DE SU USO, POR MEDIO DE H{SUB, 2} Y/O OTRO AGENTE DE REDUCCION GASEOSO A UNA TEMPERATURA POR ENCIMA DE LA TEMPERATURA EN QUE SE REALIZA LA REACCION DE DESCOMPOSICION CATALITICA.
ES94918351T 1993-06-09 1994-05-20 Proceso para la separacion de hcn de mezclas de gases y catalizador para la descomposicion de hcn. Expired - Lifetime ES2092411T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4319234A DE4319234A1 (de) 1993-06-09 1993-06-09 Verfahren zur Entfernung von HCN aus Gasgemischen und Katalysator zur Zersetzung von HCN

Publications (1)

Publication Number Publication Date
ES2092411T3 true ES2092411T3 (es) 1996-11-16

Family

ID=6490042

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94918351T Expired - Lifetime ES2092411T3 (es) 1993-06-09 1994-05-20 Proceso para la separacion de hcn de mezclas de gases y catalizador para la descomposicion de hcn.

Country Status (8)

Country Link
US (1) US5660807A (es)
EP (1) EP0702592B1 (es)
JP (1) JPH09500319A (es)
KR (1) KR960702765A (es)
AT (1) ATE143286T1 (es)
DE (2) DE4319234A1 (es)
ES (1) ES2092411T3 (es)
WO (1) WO1994029004A1 (es)

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DE4431788A1 (de) * 1994-09-07 1996-03-14 Huels Chemische Werke Ag Katalysator und Verfahren zur Zersetzung von HCN in Gasen
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US6162373A (en) * 1995-10-03 2000-12-19 Exxon Research And Engineering Company Removal of hydrogen cyanide from synthesis gas (Law322)
CA2250803C (en) * 1996-04-23 2005-04-12 Exxon Research And Engineering Company Process for removal of hydrogen cyanide from synthesis gas
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Also Published As

Publication number Publication date
US5660807A (en) 1997-08-26
KR960702765A (ko) 1996-05-23
JPH09500319A (ja) 1997-01-14
EP0702592B1 (de) 1996-09-25
WO1994029004A1 (de) 1994-12-22
DE59400748D1 (de) 1996-10-31
EP0702592A1 (de) 1996-03-27
ATE143286T1 (de) 1996-10-15
DE4319234A1 (de) 1994-12-15

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