ES2093528T3 - Composiciones que incluyen un hexafluoropropano. - Google Patents
Composiciones que incluyen un hexafluoropropano.Info
- Publication number
- ES2093528T3 ES2093528T3 ES94909844T ES94909844T ES2093528T3 ES 2093528 T3 ES2093528 T3 ES 2093528T3 ES 94909844 T ES94909844 T ES 94909844T ES 94909844 T ES94909844 T ES 94909844T ES 2093528 T3 ES2093528 T3 ES 2093528T3
- Authority
- ES
- Spain
- Prior art keywords
- hexafluoropropane
- cyclopropane
- isobutane
- butane
- compositions including
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title abstract 4
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 title abstract 3
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 abstract 10
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 abstract 8
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 abstract 6
- LVZWSLJZHVFIQJ-UHFFFAOYSA-N Cyclopropane Chemical compound C1CC1 LVZWSLJZHVFIQJ-UHFFFAOYSA-N 0.000 abstract 5
- 239000001273 butane Substances 0.000 abstract 5
- 239000001282 iso-butane Substances 0.000 abstract 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 abstract 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 abstract 5
- 239000001294 propane Substances 0.000 abstract 4
- SUAMPXQALWYDBK-UHFFFAOYSA-N 1,1,1,2,2,3-hexafluoropropane Chemical compound FCC(F)(F)C(F)(F)F SUAMPXQALWYDBK-UHFFFAOYSA-N 0.000 abstract 1
- ZXVZGGVDYOBILI-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)(F)C(F)F ZXVZGGVDYOBILI-UHFFFAOYSA-N 0.000 abstract 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- A—HUMAN NECESSITIES
- A62—LIFE-SAVING; FIRE-FIGHTING
- A62D—CHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
- A62D1/00—Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
- A62D1/0028—Liquid extinguishing substances
- A62D1/0057—Polyhaloalkanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2207/00—Foams characterised by their intended use
- C08J2207/04—Aerosol, e.g. polyurethane foam spray
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/11—Ethers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/05—Use of one or more blowing agents together
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Combustion & Propulsion (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Business, Economics & Management (AREA)
- Emergency Management (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Detergent Compositions (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
COMPOSICIONES QUE INCLUYEN COMPOSICIONES DE HEXAFLUOROPROPANO Y BUTANO, CICLOPROPANO, ISOBUTANO, PROPANO O ETER DE DIMETIL, INCLUYENDO MEZCLAS DE 1,1,2,2,3,3-HEXAFLUOROPROPANO Y BUTANO, CICLOPROPANO, ISOBUTANO O PROPANO; 1,1,1,2,2,3-HEXAFLUOROPROPANO Y BUTANO, CICLOPROPANO, ETER DE DIMETIL, ISOBUTANO O PROPANO; 1,1,2,3,3,3,-HEXAFLUOROPROPANO Y BUTANO, CICLOPROPANO, ETER DE DIMETIL, ISOBUTANO O PROPANO; Y 1,1,1,3,3,3-HEXAFLUOROPROPANO Y ETER DE DIMETIL, BUTANO, CICLOPROPANO, ISOBUTANO O PROPANO.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US2501793A | 1993-03-02 | 1993-03-02 | |
| US14118493A | 1993-10-26 | 1993-10-26 | |
| US18793494A | 1994-01-27 | 1994-01-27 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2093528T3 true ES2093528T3 (es) | 1996-12-16 |
Family
ID=27362446
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES94909844T Expired - Lifetime ES2093528T3 (es) | 1993-03-02 | 1994-02-22 | Composiciones que incluyen un hexafluoropropano. |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US5645754A (es) |
| EP (1) | EP0687286B1 (es) |
| JP (1) | JP2714486B2 (es) |
| DE (1) | DE69400752T2 (es) |
| ES (1) | ES2093528T3 (es) |
| WO (1) | WO1994020587A1 (es) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5558810A (en) * | 1994-11-16 | 1996-09-24 | E. I. Du Pont De Nemours And Company | Pentafluoropropane compositions |
| US5824604A (en) * | 1996-01-23 | 1998-10-20 | Mattson Technology, Inc. | Hydrocarbon-enhanced dry stripping of photoresist |
| TW472081B (en) * | 1996-09-17 | 2002-01-11 | Merck Patent Gmbh | Optical retardation film |
| IT1293327B1 (it) * | 1997-07-11 | 1999-02-16 | Ausimont Spa | Composizioni refrigeranti |
| US6379576B2 (en) | 1997-11-17 | 2002-04-30 | Mattson Technology, Inc. | Systems and methods for variable mode plasma enhanced processing of semiconductor wafers |
| MXPA03000964A (es) * | 2000-08-02 | 2004-02-17 | Mj Res & Dev L P | Sistema de aceite lubricante y refrigerante. |
| US7951449B2 (en) | 2002-06-27 | 2011-05-31 | Wenguang Ma | Polyester core materials and structural sandwich composites thereof |
| BRPI0619713B1 (pt) * | 2005-11-01 | 2018-02-06 | E. I. Du Pont De Nemours And Company | Método de produção de aquecimento ou resfriamento e método de substituição de composição refrigerante ou fluido de transferência de calor original |
| US8044015B2 (en) * | 2010-03-12 | 2011-10-25 | Honeywell International Inc. | 3-chloro 1,1,1,6,6,6-hexafluoro-2,4-hexadiene and solvent compositions containing the same |
| KR101366644B1 (ko) | 2012-10-24 | 2014-03-17 | 인하대학교 산학협력단 | 알씨270과 알이170을 사용하는 2원 혼합냉매 |
| CN107694001B (zh) * | 2017-09-29 | 2019-07-02 | 山东科技大学 | 一种热气溶胶灭火剂及其制备方法 |
Family Cites Families (56)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3173872A (en) * | 1962-03-12 | 1965-03-16 | Allied Chem | Compositions of fluorocarbons |
| US3470101A (en) * | 1963-10-03 | 1969-09-30 | Allied Chem | Fluorinated hydrocarbon compositions |
| US3418242A (en) * | 1965-05-18 | 1968-12-24 | Du Pont | Refrigerant composition |
| US3881949A (en) * | 1973-02-27 | 1975-05-06 | Du Pont | Vapor degreaser process employing trichlorotrifluoroethane and ethanol |
| US3922228A (en) * | 1973-03-22 | 1975-11-25 | Phillips Petroleum Co | Azeotropic composition consisting of difluoromethyl trifluoromethylether and dimethyl ether |
| NL7708731A (nl) * | 1976-08-13 | 1978-02-15 | Montedison Spa | Werkwijze voor de bereiding van nieuwe drijf- middelsamenstellingen voor aerosolen. |
| US4170564A (en) * | 1977-10-06 | 1979-10-09 | Milliken Research Corporation | Refrigerants colored for leak indication with substituted anthraquinone dyes |
| US4369120A (en) * | 1981-05-21 | 1983-01-18 | Racon Incorporated | Refrigeration liquid with leak indicator and process of using same |
| JPS59140233A (ja) * | 1983-01-31 | 1984-08-11 | Shin Etsu Chem Co Ltd | 合成樹脂成形品の表面処理方法 |
| JPS59184360A (ja) * | 1983-04-04 | 1984-10-19 | Fuji Photo Film Co Ltd | 電子写真用感光体 |
| EP0127365A3 (en) * | 1983-05-20 | 1988-03-16 | Imperial Chemical Industries Plc | Heat pumps |
| GB8321569D0 (en) * | 1983-08-10 | 1983-09-14 | Ici Plc | Heat pumps |
| DE3331570A1 (de) * | 1983-09-01 | 1985-03-21 | Chemische Werke Hüls AG, 4370 Marl | Verfahren zum steuern der groesse der perlen bei der herstellung von expandierbaren styrolpolymerisaten durch suspensionspolymerisation |
| FR2563615B1 (fr) * | 1984-04-25 | 1987-02-13 | Inst Francais Du Petrole | Nouveau procede de production de froid et/ou de chaleur a absorption utilisant un melange de plusieurs constituants comme fluide de travail |
| US4783276A (en) * | 1987-02-19 | 1988-11-08 | Akzo N.V. | Refrigerant and a machine having a refrigerating circuit with refrigerant |
| US4810403A (en) * | 1987-06-09 | 1989-03-07 | E. I. Du Pont De Nemours And Company | Halocarbon blends for refrigerant use |
| JP2545879B2 (ja) * | 1987-09-21 | 1996-10-23 | ダイキン工業株式会社 | 冷 媒 |
| JP2545887B2 (ja) * | 1987-11-02 | 1996-10-23 | ダイキン工業株式会社 | 冷 媒 |
| DE3903336A1 (de) * | 1989-02-04 | 1990-08-09 | Bayer Ag | Verwendung von c(pfeil abwaerts)3(pfeil abwaerts)- bis c(pfeil abwaerts)5(pfeil abwaerts)-polyfluoralkanen als treibgase |
| JP2841451B2 (ja) * | 1989-04-14 | 1998-12-24 | 旭硝子株式会社 | 作動媒体 |
| US4943388A (en) * | 1989-06-28 | 1990-07-24 | Allied-Signal Inc. | Azeotrope-like compositions of pentafluoroethane; 1,1,1-trifluoroethane; and chlorodifluoromethane |
| US4978467A (en) * | 1989-09-26 | 1990-12-18 | Allied-Signal Inc. | Azeotrope-like compositions of pentafluoroethane and difluoromethane |
| US5040609A (en) * | 1989-10-04 | 1991-08-20 | E. I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
| DE3933335C2 (de) * | 1989-10-06 | 1998-08-06 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen mit geringer Wärmeleitfähigkeit und ihre Verwendung |
| US5084190A (en) * | 1989-11-14 | 1992-01-28 | E. I. Du Pont De Nemours And Company | Fire extinguishing composition and process |
| JPH03170592A (ja) * | 1989-11-30 | 1991-07-24 | Matsushita Electric Ind Co Ltd | 作動流体 |
| DE69003790T2 (de) * | 1989-11-30 | 1994-04-28 | Matsushita Electric Ind Co Ltd | Arbeitsmittel. |
| JP2579001B2 (ja) * | 1989-11-30 | 1997-02-05 | 松下電器産業株式会社 | 作動流体 |
| DE69011632T2 (de) * | 1989-11-30 | 1994-11-24 | Matsushita Electric Ind Co Ltd | Arbeitsmittel. |
| FR2658508B1 (fr) * | 1990-02-20 | 1993-09-24 | Atochem | Melanges de dimethylether et de 1,1,1,2-tetrafluoroethane et leurs applications comme fluides frigorigenes, comme propulseurs d'aerosols ou comme agents d'expansion des mousses plastiques. |
| JPH03258888A (ja) * | 1990-03-07 | 1991-11-19 | Daikin Ind Ltd | 冷媒 |
| JP2792191B2 (ja) * | 1990-04-04 | 1998-08-27 | ダイキン工業株式会社 | 冷 媒 |
| US5130345A (en) * | 1990-06-29 | 1992-07-14 | Allied-Signal Inc. | Method of preparing foam using a partially fluorinated alkane having a tertiary structure as a blowing agent |
| US5221992A (en) * | 1991-02-20 | 1993-06-22 | Park Ki K | Door viewer including inner tube encasing object lenses and ocular lens and including a rubberized flexible hood |
| EP0576550B1 (en) * | 1991-03-18 | 1996-05-22 | AlliedSignal Inc. | Non-azeotropic refrigerant compositions comprising difluoromethane; 1,1,1-trifluoroethane; or propane |
| US5182040A (en) * | 1991-03-28 | 1993-01-26 | E. I. Du Pont De Nemours And Company | Azeotropic and azeotrope-like compositions of 1,1,2,2-tetrafluoroethane |
| GB9108527D0 (en) * | 1991-04-18 | 1991-06-05 | Ici Plc | Refrigerant compositions |
| DE4119459A1 (de) * | 1991-06-13 | 1992-12-17 | Basf Ag | Verfahren zur herstellung von zellhaltigen kunststoffen nach dem polyisocyanat-polyadditionsverfahren und niedrigsiedende, fluorierte und/oder perfluorierte, tertiaere alkylamine als treibmittel enthaltende emulsionen hierfuer |
| DE4121161A1 (de) * | 1991-06-27 | 1993-01-07 | Basf Ag | Verfahren zur herstellung von urethan- oder urethan- und isocyanuratgruppen enthaltenden hartschaumstoffen und treibmittel enthaltende emulsionen hierfuer |
| US5221492A (en) * | 1991-08-23 | 1993-06-22 | E. I. Du Pont De Nemours And Company | Azeotropic mixture of perfluoropropane and dimethyl ether |
| JPH0570769A (ja) * | 1991-09-13 | 1993-03-23 | Daikin Ind Ltd | フルオロアルカン混合物 |
| MX9205298A (es) * | 1991-09-17 | 1993-05-01 | Steven Carl Quay | Medios gaseosos de contraste de ultrasonido y metodo para seleccionar gases para usarse como medios de contraste de ultrasonido |
| US5409688A (en) * | 1991-09-17 | 1995-04-25 | Sonus Pharmaceuticals, Inc. | Gaseous ultrasound contrast media |
| ES2085051T3 (es) * | 1991-11-06 | 1996-05-16 | Du Pont | Usos de 1,1,1,3,3,3-hexafluoropropano. |
| JP2581384B2 (ja) * | 1991-11-15 | 1997-02-12 | ダイキン工業株式会社 | フルオロプロパンからなる発泡剤 |
| US5162381A (en) * | 1991-12-10 | 1992-11-10 | Allied-Signal Inc. | Process for preparing thermalplastic foam |
| DE4200558A1 (de) * | 1992-01-11 | 1993-07-15 | Basf Ag | Verfahren zur herstellung von polyurethan-hartschaeumen sowie treibmittelmischung hierfuer |
| JPH05230265A (ja) * | 1992-02-21 | 1993-09-07 | Asahi Glass Co Ltd | フェノール樹脂発泡体の製造方法 |
| JPH05279659A (ja) * | 1992-03-31 | 1993-10-26 | Daikin Ind Ltd | ランキンサイクル用作動流体 |
| US5254309A (en) * | 1992-07-21 | 1993-10-19 | E. I. Du Pont De Nemours And Company | Sterilant mixture and sterilization method |
| US5458798A (en) * | 1993-02-05 | 1995-10-17 | E. I. Du Pont De Nemours And Company | Azeotropic and azeotrope-like compositions of a hydrofluorocarbon and a hydrocarbon |
| US5278196A (en) * | 1993-03-25 | 1994-01-11 | Great Lakes Chemical Corp. | Hydrofluorocarbon compositions as blowing agents for cellular plastics |
| US5480572A (en) * | 1993-06-16 | 1996-01-02 | E. I. Du Pont De Nemours And Company | Compositions including a three carbon cyclic fluoroether |
| US5441659A (en) * | 1993-11-12 | 1995-08-15 | E. I. Du Pont De Nemours And Company | Compositions including a fluoroamine and a second component |
| CA2144490A1 (en) * | 1994-03-28 | 1995-09-29 | Michael J. Skowronski | Catalyst for polyisocyanurate foams made with alternative blowing agents |
| CA2219233A1 (en) * | 1995-05-16 | 1996-11-21 | Dean S. Milbrath | Azeotrope-like compositions and their use |
-
1994
- 1994-02-22 JP JP6520125A patent/JP2714486B2/ja not_active Expired - Fee Related
- 1994-02-22 ES ES94909844T patent/ES2093528T3/es not_active Expired - Lifetime
- 1994-02-22 EP EP94909844A patent/EP0687286B1/en not_active Expired - Lifetime
- 1994-02-22 DE DE69400752T patent/DE69400752T2/de not_active Expired - Fee Related
- 1994-02-22 WO PCT/US1994/002236 patent/WO1994020587A1/en not_active Ceased
- 1994-12-22 US US08/362,309 patent/US5645754A/en not_active Expired - Fee Related
-
1997
- 1997-04-21 US US08/847,981 patent/US6013194A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0687286A1 (en) | 1995-12-20 |
| JPH08507522A (ja) | 1996-08-13 |
| EP0687286B1 (en) | 1996-10-16 |
| DE69400752D1 (de) | 1996-11-21 |
| DE69400752T2 (de) | 1997-05-07 |
| US5645754A (en) | 1997-07-08 |
| JP2714486B2 (ja) | 1998-02-16 |
| US6013194A (en) | 2000-01-11 |
| WO1994020587A1 (en) | 1994-09-15 |
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