ES2096033T3 - Un metodo para sintetizar zeolita beta. - Google Patents

Un metodo para sintetizar zeolita beta.

Info

Publication number
ES2096033T3
ES2096033T3 ES92304015T ES92304015T ES2096033T3 ES 2096033 T3 ES2096033 T3 ES 2096033T3 ES 92304015 T ES92304015 T ES 92304015T ES 92304015 T ES92304015 T ES 92304015T ES 2096033 T3 ES2096033 T3 ES 2096033T3
Authority
ES
Spain
Prior art keywords
zeolite beta
beta zeolite
synthesize zeolite
tetraethylammonium
tetraethylamonium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92304015T
Other languages
English (en)
Inventor
Robert Peter Leonard Absil
Jocelyn Anne Kowalski
Joseph Anthony Herbst
Mae Koenig Rubin
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mobil Oil AS
Original Assignee
Mobil Oil AS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/715,270 external-priority patent/US5164170A/en
Priority claimed from US07/715,190 external-priority patent/US5164169A/en
Priority claimed from US07/715,189 external-priority patent/US5232579A/en
Application filed by Mobil Oil AS filed Critical Mobil Oil AS
Application granted granted Critical
Publication of ES2096033T3 publication Critical patent/ES2096033T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/36—Silicates having base-exchange properties but not having molecular sieve properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/37—Acid treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

SE SINTETIZA UNA BETA ZEOLITA DE CRISTALES GRANDES QUE TIENE UNA GAMA AMPLIA DE RELACIONES SILICE-ALUMINA, ES DECIR 20-1000, CON UN AGENTE QUELANTE EN FORMA DE ALCANOLAMINA TERCIARIA, COMO LA TRIETANOLAMINA, EN LA MEZCLA DE LA SINTESIS JUNTO CON UN AGENTE DE ENCAMINAMIENTO ORGANICO, COMO EL HIDROXIDO DE TETRAETILAMONIO, EL BROMURO DE TETRAETILAMONIO Y EL FLUORURO DE TETRAETILAMONIO. LA BETA ZEOLITA ALTAMENTE SILICEA ES UTIL COMO CATALIZADOR DE PIROLISIS CATALITICA A PRESION, PARTICULARMENTE CUANDO SE TRATA CON UN COMPUESTO DE FOSFORO.
ES92304015T 1991-06-14 1992-05-05 Un metodo para sintetizar zeolita beta. Expired - Lifetime ES2096033T3 (es)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US07/715,270 US5164170A (en) 1991-06-14 1991-06-14 Synthesis of zeolite Beta
US07/715,190 US5164169A (en) 1991-06-14 1991-06-14 Zeolite Beta
US07/715,189 US5232579A (en) 1991-06-14 1991-06-14 Catalytic cracking process utilizing a zeolite beta catalyst synthesized with a chelating agent

Publications (1)

Publication Number Publication Date
ES2096033T3 true ES2096033T3 (es) 1997-03-01

Family

ID=27418932

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92304015T Expired - Lifetime ES2096033T3 (es) 1991-06-14 1992-05-05 Un metodo para sintetizar zeolita beta.

Country Status (8)

Country Link
EP (1) EP0523829B1 (es)
JP (1) JPH05201722A (es)
KR (1) KR930000382A (es)
AU (1) AU642817B2 (es)
CA (1) CA2067630A1 (es)
DE (1) DE69215445T2 (es)
DK (1) DK0523829T3 (es)
ES (1) ES2096033T3 (es)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0987220A1 (en) * 1998-09-17 2000-03-22 Technische Universiteit Delft Mesoporous amorphous silicate materials and process for the preparation thereof
US5554356A (en) * 1995-06-07 1996-09-10 Arco Chemical Technology, L.P. Method of making essentially silicic zeolite beta
JP3830566B2 (ja) 1995-10-04 2006-10-04 日本碍子株式会社 排ガス浄化システム
DE69826768T2 (de) 1997-07-02 2006-03-09 Tosoh Corp., Shinnanyo Adsorbens für Kohlenwasserstoff und Katalysator zur Abgasreinigung
JP3986186B2 (ja) * 1997-11-07 2007-10-03 日本碍子株式会社 高耐熱性β−ゼオライト及びそれを用いた自動車排ガス浄化用吸着材
US6294150B2 (en) 1997-11-07 2001-09-25 Ngk Insulators, Ltd. Highly heat resistant β-zeolite and absorbent for automobile exhaust gas purification and adsorbent for automobile exhaust gas purification
CA2384090C (en) * 1999-09-07 2009-02-03 Technische Universiteit Delft Inorganic oxides with mesoporosity or combined meso-and microporosity and process for the preparation thereof
JP3755038B2 (ja) 2003-03-10 2006-03-15 国立大学法人岐阜大学 ｎ−パラフィンの異性化用触媒組成物及びｎ−パラフィンの異性化方法
JP4446032B2 (ja) * 2004-03-22 2010-04-07 日揮触媒化成株式会社 イソパラフィン−オレフィンアルキル化用ゼオライト触媒および該触媒を用いたアルキル化法
JP5124927B2 (ja) * 2005-09-16 2013-01-23 東ソー株式会社 β型ゼオライトを含んでなる炭化水素の吸着除去剤およびそれを用いた炭化水素の吸着除去方法
CN101134913B (zh) * 2006-08-31 2011-05-18 中国石油化工股份有限公司 一种烃类催化转化方法
CN101134172B (zh) 2006-08-31 2010-10-27 中国石油化工股份有限公司 一种烃类转化催化剂
JP5082361B2 (ja) 2006-09-27 2012-11-28 東ソー株式会社 ＳＣＲ触媒用β型ゼオライト及びそれを用いた窒素酸化物の浄化方法
JP5142123B2 (ja) * 2007-03-28 2013-02-13 義弘 杉 ベータ（β）−ゼオライトの合成方法
JP5549839B2 (ja) 2008-08-19 2014-07-16 東ソー株式会社 高耐熱性β型ゼオライト及びそれを用いたＳＣＲ触媒
JP5351216B2 (ja) 2010-07-01 2013-11-27 日本化学工業株式会社 ゼオライトの製造方法
JP7488073B2 (ja) * 2020-03-16 2024-05-21 三井金属鉱業株式会社 排気ガス浄化用触媒組成物及びｂｅａ型ゼオライトの製造方法
CN111847473A (zh) * 2020-07-31 2020-10-30 江苏国瓷新材料科技股份有限公司 一种程序升温法合成大晶粒Beta分子筛的方法
CN116022804B (zh) * 2021-10-26 2025-08-12 中国石油化工股份有限公司 大晶粒β分子筛及其制备方法
CN120229735B (zh) * 2025-03-27 2026-02-06 大连理工大学 一种基于局部结构重建方法大量制备Ti-Beta沸石的绿色工艺

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2862096D1 (en) * 1977-12-23 1982-12-30 British Petroleum Co Plc Method for producing aluminosilicates and their use as catalysts and supports
US4377502A (en) * 1979-12-26 1983-03-22 Standard Oil Company (Indiana) Synthesis of crystalline aluminosilicate molecular sieves
US4642226A (en) * 1984-04-16 1987-02-10 Mobil Oil Corporation Process for the preparation of zeolite Beta using dibenzyldimethylammonium ions and the product produced
AU572991B2 (en) * 1984-06-11 1988-05-19 Mobil Oil Corp. 30-70 per cent crystalline zeolite beta
EP0202797B1 (en) * 1985-05-14 1993-01-27 Mobil Oil Corporation A method for the synthesis of zeolites

Also Published As

Publication number Publication date
EP0523829B1 (en) 1996-11-27
DE69215445D1 (de) 1997-01-09
AU1524292A (en) 1992-12-17
DE69215445T2 (de) 1997-03-27
DK0523829T3 (da) 1997-05-05
KR930000382A (ko) 1993-01-15
CA2067630A1 (en) 1992-12-15
JPH05201722A (ja) 1993-08-10
EP0523829A1 (en) 1993-01-20
AU642817B2 (en) 1993-10-28

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