ES2100752T3 - Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador. - Google Patents

Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador.

Info

Publication number
ES2100752T3
ES2100752T3 ES95102479T ES95102479T ES2100752T3 ES 2100752 T3 ES2100752 T3 ES 2100752T3 ES 95102479 T ES95102479 T ES 95102479T ES 95102479 T ES95102479 T ES 95102479T ES 2100752 T3 ES2100752 T3 ES 2100752T3
Authority
ES
Spain
Prior art keywords
metalochene
hetero
functional groups
catalyst systems
cyclopentadienyl system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES95102479T
Other languages
English (en)
Inventor
Franz Dr Langhauser
David Dr Fischer
Jurgen Dr Kerth
Gunther Dr Schweier
Elke Barsties
Hans-Herbert Prof Brintzinger
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2100752T3 publication Critical patent/ES2100752T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63908—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)

Abstract

LA INVENCION SE REFIERE A UN SISTEMA DE CATALIZADOR SOPORTADO, OBTENIBLE POR MEDIO DE A) TRANSFORMACION DE UN PORTADOR FINAMENTE DIVIDIDO CON UN COMPUESTO ALFA - TRISALCOXISILIL - OMEGA - HALOGENALQUIL, B) ADICION DE UN COMPLEJO METALOCENO CON GRUPO HETEROFUNCIONALES EN EL SISTEMA CICLOPENTADIENO, C) TRANSFORMACION CON UN AGENTE DE CUATERNIZACION Y D) EVENTUALMENTE ADICION DE UN COMPUESTO ALUMOXANO EN LA SUCESION EN SERIE DADA PREVIAMENTE.
ES95102479T 1994-03-03 1995-02-22 Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador. Expired - Lifetime ES2100752T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4406964A DE4406964A1 (de) 1994-03-03 1994-03-03 Geträgerte Metalloxenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem als Katalysatorsysteme

Publications (1)

Publication Number Publication Date
ES2100752T3 true ES2100752T3 (es) 1997-06-16

Family

ID=6511704

Family Applications (1)

Application Number Title Priority Date Filing Date
ES95102479T Expired - Lifetime ES2100752T3 (es) 1994-03-03 1995-02-22 Complejos de metaloceno soportados con grupos heterofuncionales en el sistema de ciclopentadienilo como sistemas de catalizador.

Country Status (7)

Country Link
US (1) US5627246A (es)
EP (1) EP0670336B1 (es)
JP (1) JPH0834812A (es)
DE (2) DE4406964A1 (es)
ES (1) ES2100752T3 (es)
TW (1) TW346493B (es)
ZA (1) ZA951725B (es)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
ES2120868B1 (es) * 1995-08-03 2000-09-16 Repsol Quimica Sa Sistema de catalizadores hetereogeneos tipo metalogeno, para procesos de obtencion de poliolefinas.
BR9611772A (pt) * 1995-11-27 1999-02-23 Dow Chemical Co Suporte para uso na preparação de catalisadores para polimerizações por adição catalisador suportado e processo de polimerização por adição
FI961511L (fi) * 1996-04-03 1997-10-04 Mikrokemia Oy Menetelmä olefiinien polymerointikatalyyttien valmistamiseksi
ES2129323B1 (es) * 1996-04-18 2000-09-16 Repsol Quimica Sa Procedimiento para la obtencion de un sistema catalitico para la polimerizacion de alpha-olefinas en suspension en fase gas a bajas y altas temperaturas o en masa a altas presiones y altas o bajas temperaturas
IT1283010B1 (it) * 1996-05-15 1998-04-03 Enichem Spa Complesso metallocenico supportato e procedimento per la sua prepa- razione
DE19622481A1 (de) 1996-06-05 1997-12-11 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
CN1231668A (zh) * 1996-08-08 1999-10-13 陶氏化学公司 含2－杂原子取代的环戊二烯基金属配合物和烯烃聚合方法
US6635778B1 (en) 1996-10-30 2003-10-21 Repsol Quimica S.A. Catalysts systems for the polymerization and copolymerization of alpha-olefins
DE69703728T2 (de) * 1996-10-31 2001-06-28 Repsol Quimica S.A., Madrid Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
US6100214A (en) * 1997-06-05 2000-08-08 Exxon Chemical Patents Inc. Polymeric supported catalysts for olefin polymerization
DE19813656A1 (de) 1998-03-27 1999-09-30 Aventis Res & Tech Gmbh & Co Übergangsmetallverbindung
DE69914012T2 (de) 1998-04-27 2004-12-09 Repsol Quimica S.A. Katalysatorsysteme für die Polymerisation und Copolymerisation von Alpha-Olefinen
DE69916358T2 (de) * 1998-04-29 2005-04-21 Repsol Quimica Sa Verfahren und Verwendung von heterogenen Katalysatorbestandteilen für die Olefinpolymerisation
US6194343B1 (en) * 1999-03-11 2001-02-27 University Of Waterloo Bridged “tethered” metallocenes
US6908876B2 (en) * 2003-04-16 2005-06-21 Saudi Basic Industries Corporation Supported metallocene catalyst system for olefin polymerization, method for making and using the same

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1268754A (en) * 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
DE3782243T2 (de) * 1986-08-26 1993-03-04 Mitsui Petrochemical Ind Katalysator zur polymerisierung von alpha-olefin und verfahren.
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
TW300901B (es) * 1991-08-26 1997-03-21 Hoechst Ag
ATE150037T1 (de) * 1992-05-26 1997-03-15 Hoechst Ag Verfahren zur herstellung von polyolefinwachsen
ATE198207T1 (de) * 1992-08-03 2001-01-15 Targor Gmbh Verfahren zur herstellung eines olefinpolymers unter verwendung spezieller metallocene

Also Published As

Publication number Publication date
ZA951725B (en) 1996-09-02
US5627246A (en) 1997-05-06
DE59500200D1 (de) 1997-06-05
DE4406964A1 (de) 1995-09-07
TW346493B (en) 1998-12-01
JPH0834812A (ja) 1996-02-06
EP0670336B1 (de) 1997-05-02
EP0670336A1 (de) 1995-09-06

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