ES2108199T3 - Procedimiento para la preparacion de polialquil tetrahidronaftalenos. - Google Patents
Procedimiento para la preparacion de polialquil tetrahidronaftalenos.Info
- Publication number
- ES2108199T3 ES2108199T3 ES93120996T ES93120996T ES2108199T3 ES 2108199 T3 ES2108199 T3 ES 2108199T3 ES 93120996 T ES93120996 T ES 93120996T ES 93120996 T ES93120996 T ES 93120996T ES 2108199 T3 ES2108199 T3 ES 2108199T3
- Authority
- ES
- Spain
- Prior art keywords
- definite
- reaction
- expressions
- compound
- carried out
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 6
- 150000001875 compounds Chemical class 0.000 abstract 3
- 238000006243 chemical reaction Methods 0.000 abstract 2
- 238000005727 Friedel-Crafts reaction Methods 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 239000002841 Lewis acid Substances 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 150000007517 lewis acids Chemical class 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
- C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
- C07C2/72—Addition to a non-aromatic carbon atom of hydrocarbons containing a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
- C07C2527/126—Aluminium chloride
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
SE DESCRIBE UN PROCESO PARA LA PRODUCCION DE TETRAHIDRONAFTALENOS POLIALQUILOS DONDE SE PRODUCE UNA REACCION DE CICLIALQUILACION ENTRE UN COMPUESTO OLEFINICO DE FORMULA GENERAL (I), DONDE R4,R5,R6 Y R7 SON INDEPENDIENTEMENTE DEFINIDOS Y CADA UNO ES UN SUSTITUYENTE QUE NO INTERFIERE SUSTANCIALMENTE CON LA REACCION FRIEDEL-CRAFTS, Y UN COMPUESTO DE BENZONA SUSTITUIDO. EL PROCESO SE LLEVA A CABO EN PRESENCIA DE UN HALIDO ALQUILO O EN ALGUNAS EXPRESIONES, HALIDO HIDROGENO, UN ACIDO LEWIS Y UN AGENTE DE TRANSFERENCIA DE FASE. EN ALGUNAS EXPRESIONES, EL PROCESO SUJETO SE LLEVA A CABO ESPECIFICAMENTE EN AUSENCIA DE UNA IODINA ELEMENTAL. EL PROCESO, QUE PUEDE PRACTICARSE EN UN DISOLVENTE DE HIDROCARBONO NO-HALOGENADO, PRODUCE LOS COMPUESTOS DESEADOS SORPRENDENTEMENTE DE GRAN RIQUEZA, ALTA SELECTIVIDAD Y MEJOR INDICE DE REACCION, UTILIZANDO UNA METODOLOGIA MAS CONVENIENTE Y MENOS CARA QUE MUCHOS PROCESOS YA CONOCIDOS.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/303,365 US4877916A (en) | 1989-01-27 | 1989-01-27 | Process for preparing polyalkyl tetrahydronaphthalenes |
| US07/303,366 US4877910A (en) | 1989-01-27 | 1989-01-27 | Process for preparing polyalkyl tetrahydronaphthalenes |
| US07/303,419 US4877914A (en) | 1989-01-27 | 1989-01-27 | Process for preparing polyalkyl tetrahydronaphthalenes |
| US07/303,422 US4877911A (en) | 1989-01-27 | 1989-01-27 | Process for preparing polyalkyl tetrahydronaphthalenes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2108199T3 true ES2108199T3 (es) | 1997-12-16 |
Family
ID=27501827
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93120996T Expired - Lifetime ES2108199T3 (es) | 1989-01-27 | 1990-01-23 | Procedimiento para la preparacion de polialquil tetrahidronaftalenos. |
| ES90300678T Expired - Lifetime ES2087125T3 (es) | 1989-01-27 | 1990-01-23 | Procedimiento para preparar polialquiltetrahidronaftalenos. |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES90300678T Expired - Lifetime ES2087125T3 (es) | 1989-01-27 | 1990-01-23 | Procedimiento para preparar polialquiltetrahidronaftalenos. |
Country Status (5)
| Country | Link |
|---|---|
| EP (2) | EP0390308B1 (es) |
| JP (1) | JPH02247130A (es) |
| CA (1) | CA2008365A1 (es) |
| DE (2) | DE69027146D1 (es) |
| ES (2) | ES2108199T3 (es) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN118616092B (zh) * | 2024-05-22 | 2025-05-13 | 松滋谷润科技有限公司 | 络合物催化剂及在制备吐纳麝香中间体中的应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6034929B2 (ja) * | 1979-09-04 | 1985-08-12 | 高砂香料工業株式会社 | 1,1,3,4,4,6−ヘキサメチルテトラヒドロナフタレンの製造方法 |
| JPS5740420A (en) * | 1980-08-25 | 1982-03-06 | Nitto Riken Kogyo Kk | Preparation of 1,1,3,4,4,6-hexamethyl-1,2,3,4- tetrahydronaphthalene |
| US4551373A (en) * | 1983-11-04 | 1985-11-05 | Conlon Thomas J | Label construction |
| US4551573A (en) * | 1984-10-01 | 1985-11-05 | Phillips Petroleum Company | Alkylation of aromatic compounds |
| US4877911A (en) * | 1989-01-27 | 1989-10-31 | Union Camp Corporation | Process for preparing polyalkyl tetrahydronaphthalenes |
-
1990
- 1990-01-23 ES ES93120996T patent/ES2108199T3/es not_active Expired - Lifetime
- 1990-01-23 EP EP90300678A patent/EP0390308B1/en not_active Expired - Lifetime
- 1990-01-23 EP EP93120996A patent/EP0594225B1/en not_active Expired - Lifetime
- 1990-01-23 DE DE69027146T patent/DE69027146D1/de not_active Expired - Lifetime
- 1990-01-23 ES ES90300678T patent/ES2087125T3/es not_active Expired - Lifetime
- 1990-01-23 CA CA002008365A patent/CA2008365A1/en not_active Abandoned
- 1990-01-23 DE DE69031469T patent/DE69031469T2/de not_active Expired - Fee Related
- 1990-01-29 JP JP2016292A patent/JPH02247130A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP0594225A1 (en) | 1994-04-27 |
| EP0390308B1 (en) | 1996-05-29 |
| ES2087125T3 (es) | 1996-07-16 |
| DE69031469D1 (de) | 1997-10-23 |
| JPH02247130A (ja) | 1990-10-02 |
| DE69027146D1 (de) | 1996-07-04 |
| EP0594225B1 (en) | 1997-09-17 |
| DE69031469T2 (de) | 1998-01-29 |
| EP0390308A1 (en) | 1990-10-03 |
| CA2008365A1 (en) | 1990-07-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG2A | Definitive protection |
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