ES2110556T3 - Procedimiento para estabilizar ligandos de fosfito. - Google Patents

Procedimiento para estabilizar ligandos de fosfito.

Info

Publication number
ES2110556T3
ES2110556T3 ES93115650T ES93115650T ES2110556T3 ES 2110556 T3 ES2110556 T3 ES 2110556T3 ES 93115650 T ES93115650 T ES 93115650T ES 93115650 T ES93115650 T ES 93115650T ES 2110556 T3 ES2110556 T3 ES 2110556T3
Authority
ES
Spain
Prior art keywords
phosphite
leagues
stabilize
procedure
reaction mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES93115650T
Other languages
English (en)
Inventor
James Edward Babin
John Michael Maher
Ernst Nmn Billig
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Union Carbide Chemicals and Plastics Technology LLC
Original Assignee
Union Carbide Chemicals and Plastics Technology LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Union Carbide Chemicals and Plastics Technology LLC filed Critical Union Carbide Chemicals and Plastics Technology LLC
Application granted granted Critical
Publication of ES2110556T3 publication Critical patent/ES2110556T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/78—Separation; Purification; Stabilisation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/025—Purification; Separation; Stabilisation; Desodorisation of organo-phosphorus compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/185—Phosphites ((RO)3P), their isomeric phosphonates (R(RO)2P=O) and RO-substitution derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/323—Hydrometalation, e.g. bor-, alumin-, silyl-, zirconation or analoguous reactions like carbometalation, hydrocarbation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0261—Complexes comprising ligands with non-tetrahedral chirality
    • B01J2531/0266—Axially chiral or atropisomeric ligands, e.g. bulky biaryls such as donor-substituted binaphthalenes, e.g. "BINAP" or "BINOL"
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/822—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

ESTA INVENCION PRESENTA UN PROCESO PARA LA ESTABILIZACION DE UN LIGANDO DE FOSFITO CONTRA LA DEGRADACION EN UNA MEZCLA DE REACCION HOMOGENEA QUE CONTIENE UN GRUPO CATALIZADOR METALICO DE TRANSICION DEL GRUPO VIII Y EL LIGANDO DE FOSFITO, CONSISTIENDO DICHO PROCESO EN AÑADIR A LA MEZCLA DE REACCION UN EPOXIDO EN UNA CANTIDAD ENTRE UN 0,001 Y UN 5 POR CIENTO EN PESO EN BASE AL PESO TOTAL DE LA MEZCLA DE REACCION PARA REDUCIR LA DEGRADACION DEL LIGANDO.
ES93115650T 1992-09-29 1993-09-28 Procedimiento para estabilizar ligandos de fosfito. Expired - Lifetime ES2110556T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/953,015 US5364950A (en) 1992-09-29 1992-09-29 Process for stabilizing phosphite ligands in hydroformylation reaction mixtures

Publications (1)

Publication Number Publication Date
ES2110556T3 true ES2110556T3 (es) 1998-02-16

Family

ID=25493465

Family Applications (1)

Application Number Title Priority Date Filing Date
ES93115650T Expired - Lifetime ES2110556T3 (es) 1992-09-29 1993-09-28 Procedimiento para estabilizar ligandos de fosfito.

Country Status (16)

Country Link
US (1) US5364950A (es)
EP (1) EP0590611B1 (es)
JP (1) JP2707402B2 (es)
KR (1) KR940007047A (es)
CN (1) CN1092058A (es)
AU (1) AU4864293A (es)
BR (1) BR9303936A (es)
CA (1) CA2107173A1 (es)
DE (1) DE69315791T2 (es)
ES (1) ES2110556T3 (es)
GR (1) GR3026097T3 (es)
MX (1) MX9305980A (es)
PL (1) PL300523A1 (es)
RO (1) RO111194B1 (es)
SI (1) SI9300506A (es)
ZA (1) ZA937193B (es)

Families Citing this family (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9119955D0 (en) * 1991-09-18 1991-10-30 Imperial College Treatment of aqueous supplies containing organic material
EP0730574B1 (en) * 1993-11-23 1998-08-19 E.I. Du Pont De Nemours And Company Processes and catalyst compositions for hydrocyanation of monoolefins
US5756855A (en) * 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
US5648554A (en) * 1995-04-12 1997-07-15 Mitsubishi Chemical Corporation Method for producing aldehydes
KR970703805A (ko) * 1995-05-01 1997-08-09 유니온 카바이드 케미칼즈 앤드 플라스틱스 테크놀러지 코포레이션 막 분리방법(Membrane Separation)
JPH0977713A (ja) * 1995-09-19 1997-03-25 Mitsubishi Chem Corp アルデヒド類の製造方法
JP3812095B2 (ja) 1997-10-28 2006-08-23 三菱化学株式会社 アルデヒド類の製造方法及びこれに用いるビスホスファイト
US6090987A (en) * 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
CN1163463C (zh) 1998-12-10 2004-08-25 三菱化学株式会社 醛的制备方法
JP3928315B2 (ja) * 1998-12-14 2007-06-13 三菱化学株式会社 アルデヒドの製造方法
DE19954510A1 (de) 1999-11-12 2001-05-17 Oxeno Olefinchemie Gmbh Verfahren zur katalytischen Herstellung von Aldehyden aus Olefinen unter Einsatz von Ligandenmischungen
DE10206697A1 (de) * 2001-02-19 2002-08-29 Basf Ag Hydroformylierungsverfahren
US6693219B2 (en) * 2001-06-02 2004-02-17 Eastman Chemical Company Epoxide stabilization of fluorophosphite-metal catalyst system in a hydroformylation process
KR20040050999A (ko) * 2002-12-11 2004-06-18 한국화학연구원 로듐포스파이트 착물 촉매 및 이의 제조방법 그리고 이를이용한 알데하이드의 선택적 제조 방법
CN1997616B (zh) * 2003-07-03 2011-01-19 陶氏技术投资有限责任公司 配体降解产物的最小化,或其向有用的膦配体的转化
GB0322247D0 (en) * 2003-09-23 2003-10-22 Exxonmobil Chem Patents Inc Improvement in or relating to an isobutylene containing stream
GB0322246D0 (en) * 2003-09-23 2003-10-22 Exxonmobil Chem Patents Inc Improvement in or relating to isobutylene
CN1993311B (zh) 2004-08-02 2010-06-23 陶氏技术投资有限责任公司 加氢甲酰基化过程的稳定化
CN101657407B (zh) * 2007-03-20 2014-02-12 陶氏技术投资有限公司 改善对产物同分异构体的控制的加氢甲酰基化方法
MX2010014570A (es) 2008-07-03 2011-08-15 Dow Technology Investments Llc Proceso para controlar pesados en una corriente de catalizador de reciclado.
CA2756936A1 (en) 2009-03-31 2010-10-14 Dow Technology Investment Llc Hydroformylation process with a doubly open-ended bisphosphite ligand
EP2488539B2 (en) 2009-10-16 2023-12-20 Dow Technology Investments LLC Gas phase hydroformylation process
EP2516371B2 (en) 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
CA2784943C (en) 2009-12-22 2016-09-06 Dow Technology Investments Llc Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the syngas partial pressure
CN102741210B (zh) 2009-12-22 2016-02-24 陶氏技术投资有限责任公司 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
CN103153462B (zh) 2010-10-05 2016-06-01 陶氏技术投资有限责任公司 加氢甲酰基化方法
RU2601416C2 (ru) 2010-11-12 2016-11-10 Дау Текнолоджи Инвестментс Ллс Снижение загрязнения в процессах гидроформилирования посредством добавления воды
KR101309918B1 (ko) * 2010-12-02 2013-09-17 주식회사 엘지화학 반응 중 촉매의 안정성이 개선된 하이드로포밀화 방법
US8513468B2 (en) * 2010-12-30 2013-08-20 Eastman Chemical Company Process for removing degradation acids from hydroformylation reactions
SA112330271B1 (ar) 2011-04-18 2015-02-09 داو تكنولوجى انفستمنتس ال ال سى تخفيف التلوث في عمليات هيدروفورملة عن طريق إضافة الماء
JP6097299B2 (ja) 2011-10-07 2017-03-15 アメリカン パシフィック コーポレイション ブロモフルオロカーボン組成物
CN103814006B (zh) * 2012-06-04 2015-08-12 Lg化学株式会社 在反应中具有改善的催化剂稳定性的氢甲酰化方法
RU2634719C2 (ru) 2012-06-04 2017-11-03 Дау Текнолоджи Инвестментс Ллс Способ гидроформилирования
US9539566B2 (en) 2012-08-29 2017-01-10 Dow Technology Investments Llc Catalyst preparation process
RU2639156C2 (ru) 2012-09-25 2017-12-20 Дау Текнолоджи Инвестментс Ллс Способ стабилизации фосфитного лиганда против деградации
DE102013219510A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch von Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
EP2906573B1 (de) 2012-10-12 2016-11-23 Evonik Degussa GmbH Gemisch von bisphosphiten und dessen verwendung als katalysatorgemisch in der hydroformylierung
DE102013219506A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Unsymmetrisches Bisphosphit
DE102013219508A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemische konstitutionsisomerer Bisphosphite
DE102013219512A1 (de) 2012-10-12 2014-04-17 Evonik Degussa Gmbh Gemisch aus verschiedenen unsymmetrischen Bisphosphiten und dessen Verwendung als Katalysatorgemisch in der Hydroformylierung
EP2928855A1 (en) 2012-12-06 2015-10-14 Dow Technology Investments LLC Hydroformylation process
DE102012223572A1 (de) 2012-12-18 2014-06-18 Evonik Industries Ag Steuerung der Viskosität von Reaktionslösungen in Hydroformylierungverfahren
DE102013214378A1 (de) 2013-07-23 2015-01-29 Evonik Industries Ag Phosphoramiditderivate in der Hydroformylierung von olefinhaltigen Gemischen
JP2016540780A (ja) 2013-12-19 2016-12-28 ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー ヒドロホルミル化プロセス
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
US10131608B2 (en) 2014-03-31 2018-11-20 Dow Technology Investments Llc Hydroformylation process
US10501486B2 (en) 2014-05-14 2019-12-10 Dow Technology Investments Llc Stabilized organophosphorous compounds
MY184826A (en) 2014-12-04 2021-04-24 Dow Technology Investments Llc Hydroformylation process
TWI709566B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
TWI709568B (zh) 2015-09-30 2020-11-11 美商陶氏科技投資公司 用於製造有機磷化合物的方法
CN105498855A (zh) * 2015-12-08 2016-04-20 中国海洋石油总公司 提高醚后c4羰基合成反应铑-双膦催化剂稳定性的方法
US9975833B2 (en) 2016-08-31 2018-05-22 Eastman Chemical Company Efficient catalyst for the formation of polyaryl hydrocarbons suitable as precursors for polydentate organophosphorus catalyst ligands
US9687837B1 (en) 2016-08-31 2017-06-27 Eastman Chemical Company Stable hydroformylation catalyst for preparation of high N/Iso ratio aldehyde product
CN109535197B (zh) * 2018-12-19 2020-04-21 山东新和成维生素有限公司 一种稳定亚磷酸盐配体的方法及其应用
US20220143590A1 (en) 2019-06-27 2022-05-12 Dow Technology Investments Llc Process to prepare solution from hydroformylation process for precious metal recovery
US11981629B2 (en) * 2019-07-05 2024-05-14 Perstorp Ab Method for reducing heavy end formation and catalyst loss in a hydroformylation process
SE543296C2 (en) * 2019-07-05 2020-11-17 Perstorp Ab A use of epoxide in order to reduce the formation of heavy ends in a hydroformylation process
SE1930249A1 (en) * 2019-07-18 2020-11-17 Perstorp Ab USE OF A METHOD FOR REDUCTION OF HEAVY END FORMATION AND CATALYST LOSS IN A HYDROFORMYLATION PROCESS COMPRISING A BIDENTATE PHOSPHITE LIGAND
US11976017B2 (en) 2019-12-19 2024-05-07 Dow Technology Investments Llc Processes for preparing isoprene and mono-olefins comprising at least six carbon atoms
CN114075244B (zh) * 2020-08-18 2024-06-04 中国石油化工股份有限公司 一种双齿亚磷酸酯及其纯化方法和应用
CN114433240A (zh) * 2020-11-02 2022-05-06 中国石油化工股份有限公司 一种利用高碳数烯烃生产高碳醛的方法
CN115246765B (zh) * 2021-04-26 2024-07-05 广东欧凯新材料有限公司 螺环二酚及其双亚膦酸酯制备方法和应用
CN114027296A (zh) * 2021-11-10 2022-02-11 山东农业大学 用于防治松材线虫及其媒介昆虫的纳米农药制剂
US20250137091A1 (en) 2021-11-11 2025-05-01 Dow Technology Investments Llc Processes for recovering rhodium from hydroformylation processes
CN120282943A (zh) 2022-12-13 2025-07-08 陶氏技术投资有限责任公司 通过利用降解产物使多膦使用最小化的方法
WO2024228768A1 (en) 2023-05-04 2024-11-07 Dow Technology Investments Llc Hydroformylation process
KR20260045840A (ko) 2023-08-03 2026-04-03 다우 테크놀로지 인베스트먼츠 엘엘씨. 하이드로포르밀화 공정

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH348284A (de) * 1956-11-30 1960-08-15 Geigy Ag J R Verfahren zur Stabilisierung von Estern von Säuren des drei- oder fünfwertigen Phosphors oder von solche Ester enthaltenden Gemischen
NL146830C (es) * 1960-07-22
US3510524A (en) * 1966-08-23 1970-05-05 Gulf Research Development Co Oxo process
US3499933A (en) * 1967-06-15 1970-03-10 Union Carbide Corp Hydroformylation of cyclic olefins
US3553298A (en) * 1967-10-20 1971-01-05 Hooker Chemical Corp Hydrolytic stabilized phosphite esters
US3644446A (en) * 1969-07-01 1972-02-22 Union Oil Co Preparation of rhodium and iridium hydride carbonyl complexes
ATE16475T1 (de) * 1982-06-11 1985-11-15 Davy Mckee London Hydroformylierungsverfahren.
ATE28183T1 (de) * 1982-06-11 1987-07-15 Davy Mckee London Hydroformylierungsverfahren.
DE3371067D1 (en) * 1982-06-11 1987-05-27 Davy Mckee London Hydroformylation process
CA1203047A (en) * 1982-12-08 1986-04-08 Hormoz Azizian Polymer hydrogenation process
CA1220300A (en) * 1982-12-08 1987-04-07 Polysar Limited Polymer hydrogenation process
GB8334359D0 (en) * 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) * 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US4650894A (en) * 1984-07-05 1987-03-17 Argus Chemical Corporation Tris-organophosphite compositions having improved hydrolytic stability
EP0177999B1 (en) * 1984-10-09 1989-01-18 Shell Internationale Researchmaatschappij B.V. Ethylene oligomerization process carried out in a diol-based solvent containing monohydric alcohol or water
US4737588A (en) * 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
JPH0451057Y2 (es) * 1985-02-26 1992-12-02
US4668651A (en) * 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4714773A (en) * 1987-01-09 1987-12-22 E. I. Du Pont De Nemours And Company Hydrocyanation of butadiene
US4810815A (en) * 1987-11-04 1989-03-07 E. I. Du Pont De Nemours And Company Acceleration of diene hydrocyanation
US5059710A (en) * 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
CA2000182C (en) * 1988-10-27 1999-04-06 Lynn H. Slaugh Ethylene oligomerization process and catalyst
US5210318A (en) * 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
JPH0436355A (ja) * 1990-05-31 1992-02-06 Toray Dow Corning Silicone Co Ltd シリコーンゴム組成物
DE4026406A1 (de) * 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
US5103033A (en) * 1991-06-24 1992-04-07 Dow Corning Corporation Process for preparation of β-cyanoalkylsilanes

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US5364950A (en) 1994-11-15
JPH06199729A (ja) 1994-07-19
PL300523A1 (en) 1994-04-05
JP2707402B2 (ja) 1998-01-28
KR940007047A (ko) 1994-04-26
MX9305980A (es) 1995-01-31
ZA937193B (en) 1994-04-21
CN1092058A (zh) 1994-09-14
DE69315791D1 (de) 1998-01-29
EP0590611A1 (en) 1994-04-06
RO111194B1 (en) 1996-07-30
GR3026097T3 (en) 1998-05-29
CA2107173A1 (en) 1994-03-30
DE69315791T2 (de) 1998-05-28
BR9303936A (pt) 1994-06-14
EP0590611B1 (en) 1997-12-17
AU4864293A (en) 1994-04-14
SI9300506A (en) 1994-06-30

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