ES2117279T3 - Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. - Google Patents

Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso.

Info

Publication number
ES2117279T3
ES2117279T3 ES94919175T ES94919175T ES2117279T3 ES 2117279 T3 ES2117279 T3 ES 2117279T3 ES 94919175 T ES94919175 T ES 94919175T ES 94919175 T ES94919175 T ES 94919175T ES 2117279 T3 ES2117279 T3 ES 2117279T3
Authority
ES
Spain
Prior art keywords
polymerization
metalochene
olephins
catalytical
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES94919175T
Other languages
English (en)
Inventor
Terry John Burkhardt
Jeffrey Lawrence Brinen
Gregory George Hlatky
Walter Spaleck
Andreas Winter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hoechst AG
ExxonMobil Chemical Patents Inc
Original Assignee
Hoechst AG
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hoechst AG, Exxon Chemical Patents Inc filed Critical Hoechst AG
Application granted granted Critical
Publication of ES2117279T3 publication Critical patent/ES2117279T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927—Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912—Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/639—Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63916—Component covered by group C08F4/62 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/15—Isotactic

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

LA INVENCION SE REFIERE A SISTEMAS CATALIZADORES DE METALOCENO SOPORTADOS, OPCIONALMENTE POLIMERIZADOS CON MONOMEROS OLEFINICOS, PREFERIBLEMENTE ETILENO O PROPILENO, UTILES EN LA POLIMERIZACION DE ETILENO A POLIPROPILENO ISOTACTICO. EL POLIPROPILENO ISOTACTICO OBTENIDO GENERALMENTE POSEE UN PESO MOLECULAR DE APROXIMADAMENTE 100000 G/M O MAYOR, UN PUNTO DE FUNDICION DE APROXIMADAMENTE 140 GRADOS C O MAYOR Y UNA MORFOLOGIA GRANULAR. EL SISTEMA CATALIZADOR SOPORTADO POSEE GENERALMENTE UNA ACTIVIDAD CATALITICA ELEVADA, Y AL SER UTILIZADO EN UN REACTOR DE POLIMERIZACION RESULTA EN UN PROCESO CON UN BLOQUEO, DETERIORO, ETC. DEL REACTOR MINIMO O NULO.
ES94919175T 1993-05-25 1994-05-20 Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso. Expired - Lifetime ES2117279T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US6674093A 1993-05-25 1993-05-25

Publications (1)

Publication Number Publication Date
ES2117279T3 true ES2117279T3 (es) 1998-08-01

Family

ID=22071387

Family Applications (1)

Application Number Title Priority Date Filing Date
ES94919175T Expired - Lifetime ES2117279T3 (es) 1993-05-25 1994-05-20 Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso.

Country Status (14)

Country Link
EP (1) EP0705281B1 (es)
JP (1) JP3626186B2 (es)
KR (1) KR100314971B1 (es)
CN (1) CN1043474C (es)
AU (1) AU683899B2 (es)
CA (1) CA2163789C (es)
DE (1) DE69408989T2 (es)
ES (1) ES2117279T3 (es)
FI (1) FI114640B (es)
NO (1) NO308952B1 (es)
RU (1) RU2126017C1 (es)
TW (1) TW270091B (es)
WO (1) WO1994028034A1 (es)
ZA (1) ZA943595B (es)

Families Citing this family (117)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW454020B (en) † 1994-08-09 2001-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst
EP0797598B1 (en) 1994-12-15 2001-03-14 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
ATE223929T1 (de) * 1995-05-16 2002-09-15 Univation Tech Llc Herstellung von polyethylen unter verwendung eines stereoisomeren metallocens
UA47394C2 (uk) * 1995-05-16 2002-07-15 Юнівейшн Текнолоджіз, Ллс Етиленовий полімер, який має підвищену придатність до обробки та вирiб, що містить етиленовий полімер
CA2223258A1 (en) * 1995-07-06 1997-01-23 Exxon Chemical Patents, Inc. Method for producing prepolymerized, supported metallocene catalyst systems
JP3176932B2 (ja) * 1995-10-18 2001-06-18 チッソ株式会社 オレフィン（共）重合体組成物とその製造方法及びオレフィン（共）重合用触媒とその製造方法
DE19548288A1 (de) 1995-12-22 1997-06-26 Hoechst Ag Geträgertes Katalysatorsystem, Verfahren zu seiner Herstellung und seine Verwendung zur Polymerisation von Olefinen
FI104825B (fi) 1996-01-26 2000-04-14 Borealis As Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö
FI104826B (fi) * 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
EP0909279B1 (de) 1996-07-04 2001-04-25 Basf Aktiengesellschaft Verfahren zur herstellung von geträgerten übergangsmetallkatalysatoren
WO1998013393A1 (en) * 1996-09-24 1998-04-02 Exxon Chemical Patents Inc. Improved method for preparing supported metallocene catalyst systems
US6245856B1 (en) 1996-12-17 2001-06-12 Exxon Chemical Patents, Inc. Thermoplastic olefin compositions
DE19703502A1 (de) 1997-01-31 1998-08-06 Basf Ag Nicht selbstentzündlicher Feststoff
DE69808243T2 (de) 1997-02-07 2003-05-08 Exxonmobil Chemical Patents Inc., Baytown Thermoplastische,elastomere zusammensetzungen aus verzweigten olefincopolymeren
TW425414B (en) * 1997-02-18 2001-03-11 Chisso Corp Preactivated catalyst for olefin (co)polymerization, catalyst for olefin (co)polymerization and olefin (co)polymer composition and their manufacturing method
DE19757563A1 (de) * 1997-03-07 1999-07-08 Targor Gmbh Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen
US6231804B1 (en) 1997-04-02 2001-05-15 Chisso Corporation Modified olefin (co)polymer composition, process for preparing the same, and modified olefin (co)polymer composition molding
US6143683A (en) * 1997-04-09 2000-11-07 Fina Technology, Inc. Metallocene catalyst and catalyst system for polymerizing an olefin having at least 3 carbon atoms
US6303696B1 (en) 1997-04-11 2001-10-16 Chisso Corporation Propylene (co)polymer composition using metallocene catalyst
TW504515B (en) 1997-08-07 2002-10-01 Chisso Corp Olefin (co)polymer composition
DE69810781T2 (de) 1997-08-15 2003-09-25 Chisso Corp., Osaka Polydisperses propylenpolymer und verfahren zu dessen herstellung
US6420501B1 (en) * 1997-10-22 2002-07-16 Chisso Corporation Supported metallocene catalyst, process for preparing the same, and process for producing olefin polymers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
JP2001527097A (ja) * 1997-12-23 2001-12-25 エクソンモービル・ケミカル・パテンツ・インク 液体反応媒体中でのエチレン重合方法
DE19811934A1 (de) 1998-03-19 1999-09-23 Basf Ag Ethylencopolymere mit enger Comonomerverteilung
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
CA2327497A1 (en) 1998-05-13 1999-11-18 Exxon Chemical Patents, Inc. Propylene homopolymers and methods of making the same
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
DE19821949A1 (de) 1998-05-15 1999-11-18 Basf Ag Verfahren zur Herstellung geträgerter Katalysatoren
DE19833170A1 (de) 1998-07-23 2000-01-27 Targor Gmbh Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz
CA2341167A1 (en) 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Branched polypropylene compositions
DE19949235A1 (de) 1998-10-16 2000-05-11 Chisso Corp Propylen/Ethylen/alpha-Olefin-Terpolymere und Verfahren zu ihrer Herstellung
GB9826874D0 (en) 1998-12-07 1999-01-27 Borealis As Process
KR100662954B1 (ko) * 1999-01-21 2006-12-28 이데미쓰 고산 가부시키가이샤 알파-올레핀 제조용 촉매 및 알파-올레핀의 제조 방법
KR100367463B1 (ko) * 1999-03-03 2003-01-14 주식회사 엘지화학 메탈로센 화합물 및 이를 이용한 올레핀 중합
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
DE19927766A1 (de) 1999-06-17 2000-12-21 Basf Ag Trägerkatalysator zur Olefinpolymerisation
JP2003511493A (ja) * 1999-10-02 2003-03-25 ボレアリス テクノロジー オイ オレフィン重合用修飾担持触媒
ES2210015T3 (es) 1999-11-04 2004-07-01 Exxonmobil Chemical Patents Inc. Espumas de copolimero de propileno y su uso.
DE19957384A1 (de) 1999-11-29 2001-05-31 Targor Gmbh Hochmolekulares Polypropylen mit breiter Molekulargewichtsverteilung und geringer isotaktischer Sequenzlänge
WO2001092269A2 (de) 2000-05-31 2001-12-06 Basell Polyolefine Gmbh Verfahren zur herstellung von übergangsmetallverbindungen und deren verwendung zur polymerisation von olefinen
GB0023662D0 (en) 2000-09-27 2000-11-08 Borealis Tech Oy Supported catalyst
DE10057009A1 (de) 2000-11-17 2002-05-29 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
ATE487744T1 (de) 2001-06-22 2010-11-15 Borealis Tech Oy Metallocenkatalysatoren mit einer in 4-, 5-, 6- oder 7-stellung mit siloxy oder germyloxy substitutierten indenylgruppe
DE10130229A1 (de) 2001-06-22 2003-01-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
JP2005522406A (ja) 2001-06-29 2005-07-28 エクソンモービル・ケミカル・パテンツ・インク メタロセン及び該メタロセン由来の触媒組成物
ES2321806T3 (es) 2001-12-19 2009-06-12 Borealis Technology Oy Produccion de catalizadores soportados para la polimerizacion de olefinas.
EP1323747A1 (en) 2001-12-19 2003-07-02 Borealis Technology Oy Production of olefin polymerisation catalysts
EP1860130A1 (en) * 2002-01-31 2007-11-28 Mitsubishi Chemical Corporation Soft propylene-based resin composition
DE10208252A1 (de) 2002-02-26 2003-09-04 Celanese Ventures Gmbh Konvalent fixierte Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
DE10213191A1 (de) 2002-03-23 2003-10-02 Celanese Ventures Gmbh Non-Metallocene, Verfahren zur Herstellung von diesen und deren Verwendung zur Polymerisation von Olefinen
CA2483684C (en) 2002-05-13 2010-07-06 S. C. Johnson & Son, Inc. Coordinated emission of fragrance, light, and sound
US6884749B2 (en) * 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
ES2403514T3 (es) 2003-02-07 2013-05-20 S.C. Johnson & Son, Inc. Difusor con iluminación nocturna de LED (diodo emisor de luz)
US7285608B2 (en) 2004-04-21 2007-10-23 Novolen Technology Holdings C.V. Metallocene ligands, metallocene compounds and metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7169864B2 (en) 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
EA012018B1 (ru) 2004-12-31 2009-06-30 Бореалис Текнолоджи Ой Способ получения катализатора полимеризации олефинов
US7728086B2 (en) * 2005-03-23 2010-06-01 Basell Polyolefine Gmbh Process for the polymerization of olefins
US7281811B2 (en) 2005-03-31 2007-10-16 S. C. Johnson & Son, Inc. Multi-clarity lenses
US7589340B2 (en) 2005-03-31 2009-09-15 S.C. Johnson & Son, Inc. System for detecting a container or contents of the container
USD541922S1 (en) 2005-03-31 2007-05-01 S.C. Johnson & Son, Inc. Diffuser
USD542400S1 (en) 2005-03-31 2007-05-08 S.C. Johnson & Son, Inc. Diffuser
US7643734B2 (en) 2005-03-31 2010-01-05 S.C. Johnson & Son, Inc. Bottle eject mechanism
US7232869B2 (en) 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
US8034886B2 (en) 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
DE102005052654A1 (de) * 2005-11-04 2007-05-16 Ticona Gmbh Verfahren zur Herstellung von ultrahochmolekularen Polymeren unter Verwendung von speziellen verbrückten Metallocen-Katalysatoren
US7598329B2 (en) 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
EP1803743B1 (en) 2005-12-30 2016-08-10 Borealis Technology Oy Catalyst particles
US20090017710A1 (en) * 2006-02-02 2009-01-15 Basell Polyolefine Gmbh Propylene Melt Blown Resins, Propylene Melt Blown Resin Fibers and Non-Woven Fabric Made From the Same, and Methods of Making the Same
ATE421760T1 (de) 2006-07-10 2009-02-15 Borealis Tech Oy Elektrischer isolierfilm
EP1886806B1 (en) 2006-07-10 2010-11-10 Borealis Technology Oy Biaxially oriented polypropylene film
EP1967547A1 (en) 2006-08-25 2008-09-10 Borealis Technology OY Extrusion coated substrate
ATE439393T1 (de) 2006-08-25 2009-08-15 Borealis Tech Oy Geblasene polypropylenfolie
EP1900764B1 (en) 2006-08-25 2009-04-01 Borealis Technology Oy Polypropylene foam
ATE462189T1 (de) 2006-09-25 2010-04-15 Borealis Tech Oy Koaxiales kabel
ATE424424T1 (de) 2006-12-28 2009-03-15 Borealis Tech Oy Verfahren zur herstellung von verzweigtem polypropylen
ATE438666T1 (de) 2007-05-08 2009-08-15 Borealis Tech Oy Folie zur elektrischen isolierung
BRPI0703586B1 (pt) 2007-10-19 2018-02-06 Braskem S.A Catalisador metaloceno suportado, e, copolímeros de etileno com alfa-olefinas de alto e ultra alto peso molecular
US8299287B2 (en) 2007-10-25 2012-10-30 Lammus Novolen Technology GmbH Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo- and copolymers
EP2235071A2 (en) 2007-10-25 2010-10-06 Novolen Technology Holdings, C.V. Metallocene compounds, catalysts comprising them, process for producing an olefin polymer by use of the catalysts, and olefin homo and copolymers
KR101278336B1 (ko) 2007-10-25 2013-06-25 루머스 노보렌 테크놀로지 게엠베하 안사-메탈로센 화합물의 라세모선택적 합성, 안사-메탈로센 화합물, 이를 포함하는 촉매, 그 촉매를 이용한 올레핀 폴리머 제조 공정, 그리고 올레핀 호모- 및 코폴리머
EP2075284B1 (en) 2007-12-17 2013-05-29 Borealis Technology OY Heterophasic polypropylene with high flowability and excellent low temperature impact properties
PL2072546T5 (pl) 2007-12-18 2013-05-31 Borealis Tech Oy Heterofazowy polipropylen o wysokiej udarności
EP2113541A1 (en) 2008-04-28 2009-11-04 Borealis AG Adhesive propylene polymer composition suitable for extrusion coating of paper substrates
EP2133389A1 (en) 2008-06-12 2009-12-16 Borealis AG Polypropylene composition
US7897705B2 (en) 2008-08-08 2011-03-01 Sumitomo Chemical Company, Limited Process for producing olefin polymer
US7960486B2 (en) 2008-08-08 2011-06-14 Sumitomo Chemical Company, Limited Process for producing olefin polymer
US20100036068A1 (en) 2008-08-08 2010-02-11 Sumitomo Chemical Company, Limited Hydrogenation catalyst and process for producing olefin polymer
KR100992715B1 (ko) 2008-08-21 2010-11-05 삼성토탈 주식회사 폴리올레핀 중합용 촉매의 제조방법 및 그를 이용한 폴리올레핀 중합체 제조방법
JP2010065068A (ja) 2008-09-08 2010-03-25 Sumitomo Chemical Co Ltd ポリオレフィンの製造装置および製造方法
EP2355927B1 (en) 2008-11-07 2015-03-04 Borealis AG Solid catalyst composition
EP2184301A1 (en) 2008-11-07 2010-05-12 Borealis AG Process for the preparation of a hafnium catalyst system
ES2359761T3 (es) 2008-11-18 2011-05-26 Borealis Ag Copolímero aleatorio de propileno-hexeno producido en presencia de un catalizador metalocénico.
EP2316882A1 (en) 2009-10-29 2011-05-04 Borealis AG Heterophasic polypropylene resin
EP2319885B1 (en) 2009-10-29 2011-12-21 Borealis AG Heterophasic polypropylene resin with long chain branching
PL2325248T3 (pl) 2009-11-16 2012-11-30 Borealis Ag Włókna pneumotermiczne typu melt blown z kompozycji polipropylenowych
EP2330136B1 (en) 2009-12-07 2013-08-28 Borealis AG Process for the preparation of an unsupported, solid metallocene catalyst system and its use in polymerization of olefins
US8859451B2 (en) 2009-12-18 2014-10-14 Basell Polyolefine Gmbh Process for the preparation of supported catalysts
WO2011076443A1 (en) 2009-12-22 2011-06-30 Borealis Ag Preparation of polypropylene in the presence of a single-site catalyst
ES2535323T3 (es) 2009-12-22 2015-05-08 Borealis Ag Preparación de catalizadores de sitio único
EP2338920A1 (en) 2009-12-22 2011-06-29 Borealis AG Preparation of single-site catalysts
EP2341086A1 (en) 2009-12-30 2011-07-06 Borealis AG Bopp-film
EP2341088B1 (en) 2009-12-30 2012-06-20 Borealis AG BOPP with homogeneous film morphology
EP2385073A1 (en) 2010-05-07 2011-11-09 Borealis AG Process for the preparation of a solid metallocene catalyst system and its use in polymerisation of olefins
EP2386584A1 (en) 2010-05-11 2011-11-16 Borealis AG Polypropylene composition suitable for extrusion coating
EP2418237A1 (en) 2010-08-12 2012-02-15 Borealis AG Easy tear polypropylene film without notch
EP2743293B1 (en) 2010-08-12 2016-11-30 Borealis AG Easy tear polypropylene film without notch
EP2426171A1 (en) 2010-08-30 2012-03-07 Borealis AG Heterophasic polypropylene with high flowability and enhanced mechanical properties
EP2492293B1 (en) 2011-02-28 2017-09-20 Borealis AG Polypropylene composition suitable for extrusion coating
EP2520425B1 (en) 2011-05-02 2017-11-08 Borealis AG Polypropylene for foam and polypropylene foam
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
WO2018091653A1 (en) 2016-11-18 2018-05-24 Borealis Ag Catalyst
KR102225972B1 (ko) * 2016-12-06 2021-03-09 주식회사 엘지화학 폴리프로필렌의 제조 방법
CN112409515B (zh) * 2019-08-23 2023-10-20 中国石油化工股份有限公司 茂金属聚丙烯催化剂的制备方法

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU427022A1 (ru) * 1972-03-16 1974-05-05 Способ получения карбоцепных линейных полимеров
KR920006464B1 (ko) * 1988-09-14 1992-08-07 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀중합용 촉매성분, 올레핀중합용 촉매 및 이 올레핀중합용 촉매를 사용한 올레핀의 중합방법
DE3916553A1 (de) * 1989-05-20 1990-11-22 Hoechst Ag Syndio- isoblockpolymer und verfahren zu seiner herstellung
DE3942364A1 (de) * 1989-12-21 1991-06-27 Hoechst Ag Verfahren zur herstellung einer polypropylen-formmasse
EP0485822B1 (de) * 1990-11-12 1996-07-03 Hoechst Aktiengesellschaft Verfahren zur Herstellung eines hochmolekularen Olefinpolymers
DE4119343A1 (de) * 1991-06-12 1992-12-17 Basf Ag Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
TW300901B (es) * 1991-08-26 1997-03-21 Hoechst Ag
FI112233B (fi) * 1992-04-01 2003-11-14 Basell Polyolefine Gmbh Katalyytti olefiinipolymerointia varten, menetelmä sen valmistamiseksi ja sen käyttö
JP3193110B2 (ja) * 1992-04-15 2001-07-30 三菱化学株式会社 プロピレン重合体の製造法
US5240894A (en) * 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
TW294669B (es) * 1992-06-27 1997-01-01 Hoechst Ag

Also Published As

Publication number Publication date
EP0705281A1 (en) 1996-04-10
CN1130912A (zh) 1996-09-11
AU7041394A (en) 1994-12-20
JPH08511044A (ja) 1996-11-19
NO954780L (no) 1996-01-15
FI955687L (fi) 1996-01-24
CA2163789C (en) 2006-10-24
NO954780D0 (no) 1995-11-24
RU2126017C1 (ru) 1999-02-10
EP0705281B1 (en) 1998-03-11
DE69408989T2 (de) 1998-11-05
KR100314971B1 (ko) 2002-07-03
KR960702484A (ko) 1996-04-27
TW270091B (es) 1996-02-11
NO308952B1 (no) 2000-11-20
JP3626186B2 (ja) 2005-03-02
CA2163789A1 (en) 1994-12-08
WO1994028034A9 (en) 1999-07-29
AU683899B2 (en) 1997-11-27
FI114640B (fi) 2004-11-30
FI955687A0 (fi) 1995-11-24
CN1043474C (zh) 1999-05-26
WO1994028034A1 (en) 1994-12-08
ZA943595B (en) 1995-12-14
DE69408989D1 (de) 1998-04-16

Similar Documents

Publication Publication Date Title
ES2117279T3 (es) Sistemas cataliticos de metaloceno soportados para la polimerizacion de olefinas, su preparacion y uso.
ES2166524T8 (es) Procedimiento para producir polietilenos que tienen una amplia distribución de pesos moleculares, y sistema catalítico usado en este procedimiento.
ES2164114T3 (es) Sistemas cataliticos para estereoselectividad mejorada y distribucion de peso molecular mas amplia en polimerizacion de olefinas.
ES2117065T3 (es) Catalizador para la polimerizacion de olefinas, procedimiento para su obtencion y su empleo.
CA2087289A1 (en) Process for the gas-phase polymerization of olefins
ES2113448T3 (es) Catalizador de polimerizacion de olefinas, procedimiento para su preparacion y su utilizacion.
RU94033101A (ru) Способ получения полимеров этилена и продукты, полученные из них
BR0209401A (pt) Processo para a preparação de um polìmero de propileno, polìmero e copolìmero de propileno, artigo de polìmero de propileno, e, uso de um copolìmero
MX9302668A (es) Catalizador soportado para la (co) polimerizacion de 1-olefinas.
AR011387A1 (es) Una composicion catalitica y un procedimiento para la polimerizacion de una olefina
ES2046983T3 (es) Modificador del peso molecular a utilizar con catalizadores de tipo lantanidos y actinidos.
BR9106841A (pt) Catalisadores suportados para polimerizacao de olifinas de metal de trancicao de metal de transicao de monociclopentadienila
ES2064871T3 (es) Procedimiento catalitico de carbonilacion.
MX9604229A (es) Compuesto de metaloceno, procedimiento para su preparacion y su uso en catalizadores para la polimerizacion de olefinas.
NO930349L (no) Katalysatorbestanddeler og katalysatorer for anvendelse ved polymerisasjon av olefiner
BR9609046A (pt) Polímero e oligômero de adição policíclicos mistura de reação para formar um polímero de adição policíclico e processo para polimerizar um polímero de adição policíclico
ES2196395T3 (es) Copolimeros cicloolefinicos, su empleo y articulos moldeados preparados a partir de ellos.
MX9100015A (es) Catalizador de vanadio y zirconio coimpregnado novedoso para producir polietileno con distribucion de peso molecular (mw) amplia o bimodal.
BR0004493A (pt) Composto, uso do mesmo, sistema de catalisador, uso do mesmo, e, processo para preparar poliolefinas
ES2133888T3 (es) Solido catalitico para la (co)polimerizacion de etileno, procedimiento para su preparacion, sistema catalitico para la (co)polimerizacion de etileno y procedimiento de (co)polimerizacion de etileno.
MX9302547A (es) Sistema catalitico para la polimerizacion de olefinas, procedimiento para esta polimerizacion y polimeros asi obtenidos.
BR9202677A (pt) Componente catalisador solido para a (co)polimerizacao de etileno,processo para a preparacao do mesmo e processo para a preparacao de polimeros de etileno com peso molecular ultra-elevado
BR0214604A (pt) Processo para preparar sistemas de catalisador do tipo ziegler-natta, sistema de catalisador, processo para polimerizar ou copolimerizar olefinas, uso de um sistema de catalisador, e, copolìmero de etileno
BR0016146A (pt) Compostos catalisadores, sistemas catalisadores dos mesmos e seus usos em um processo de polimerização
GB1014205A (en) Fluidisation reactor

Legal Events

Date Code Title Description
FG2A Definitive protection

Ref document number: 705281

Country of ref document: ES