ES2119902T3 - Sintesis de peliculas de zeolita unidas a substratos, estructuras y utilizaciones de estas peliculas. - Google Patents
Sintesis de peliculas de zeolita unidas a substratos, estructuras y utilizaciones de estas peliculas.Info
- Publication number
- ES2119902T3 ES2119902T3 ES93915489T ES93915489T ES2119902T3 ES 2119902 T3 ES2119902 T3 ES 2119902T3 ES 93915489 T ES93915489 T ES 93915489T ES 93915489 T ES93915489 T ES 93915489T ES 2119902 T3 ES2119902 T3 ES 2119902T3
- Authority
- ES
- Spain
- Prior art keywords
- zeolite
- films
- synthesis
- utilizations
- substrates
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000758 substrate Substances 0.000 title abstract 4
- 230000015572 biosynthetic process Effects 0.000 title abstract 2
- 238000003786 synthesis reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 abstract 3
- 229910021536 Zeolite Inorganic materials 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract 2
- 239000010457 zeolite Substances 0.000 abstract 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000013078 crystal Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 235000013348 organic food Nutrition 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9481—Catalyst preceded by an adsorption device without catalytic function for temporary storage of contaminants, e.g. during cold start
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/321—Catalytic processes
- C07C5/324—Catalytic processes with metals
- C07C5/325—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
- C07C5/3337—Catalytic processes with metals of the platinum group
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C7/00—Purification; Separation; Use of additives
- C07C7/12—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
- C07C7/13—Purification; Separation; Use of additives by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers by molecular-sieve technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2251/00—Reactants
- B01D2251/20—Reductants
- B01D2251/206—Ammonium compounds
- B01D2251/2062—Ammonia
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/10—Noble metals or compounds thereof
- B01D2255/102—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
- B01J2229/60—Synthesis on support
- B01J2229/64—Synthesis on support in or on refractory materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Water Supply & Treatment (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Separation Of Gases By Adsorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
UN METODO PARA SINTETIZAR UNA ZEOLITA UNIDA A UN SUSTRATO, UTILIZA UNA MEZCLA DE REACCION, QUE TIENE UNA PROPORCION MOLAR DE H2O/YO2 DE, AL MENOS, 25 E Y ES ELEMENTO TETRAVALENTE, ESPECIALMENTE SILICIO. UNA ESTRUCTURA HECHA CONFORME A ESTE METODO INCLUYE UNA PELICULA DE CRISTALES DE ZEOLITA INTERCONECTADOS, UNIDOS A UN SUSTRATO, Y LA ESTRUCTURA SE CARACTERIZA POR UN VALOR R, REPRESENTANDO EL MG DE ZEOLITA/CM2 DE SUPERFICIE DEL SUSTRATO, Y UN VALOR 2, REPRESENTANDO LA EFICACIA DEL REVESTIMIENTO COMO MG DE ZEOLITA UNIDA/MG DE YO2 INICIALMENTE EN LA MEZCLA DE SINTESIS; DONDE R ES AL MENOS 0''5 Y E ES AL MENOS 0''05. SE FACILITAN PROCESOS PARA SEPARACION, SORBCION, CONVERSION DE PRODUCTOS ALIMENTICIOS ORGANICOS Y CONVERSION DE NOX SOBRE LA ESTRUCTURA.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/910,861 US5310714A (en) | 1992-07-08 | 1992-07-08 | Synthesis of zeolite films bonded to substrates, structures and uses thereof |
| US08/047,137 US5316661A (en) | 1992-07-08 | 1993-04-16 | Processes for converting feedstock organic compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| ES2119902T3 true ES2119902T3 (es) | 1998-10-16 |
| ES2119902T5 ES2119902T5 (es) | 2003-10-01 |
Family
ID=26724662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES93915489T Expired - Lifetime ES2119902T5 (es) | 1992-07-08 | 1993-06-29 | Sintesis de peliculas de zeolita unidas a substratos, estructuras y utilizaciones de estas peliculas. |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US5316661A (es) |
| EP (1) | EP0649387B2 (es) |
| JP (1) | JPH07509687A (es) |
| AU (1) | AU4545493A (es) |
| DE (1) | DE69320195T3 (es) |
| DK (1) | DK0649387T4 (es) |
| ES (1) | ES2119902T5 (es) |
| WO (1) | WO1994001365A1 (es) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5869013A (en) * | 1993-11-04 | 1999-02-09 | Osaka Gas Company Limited | Process and catalyst for reducing Nox in exhaust combustion gases |
| ATE278454T1 (de) * | 1993-11-04 | 2004-10-15 | Enitecnologie Spa | Katalysator zur reduktion von nox in verbrennungsabgasen |
| JPH11221469A (ja) * | 1995-03-17 | 1999-08-17 | Osaka Gas Co Ltd | 窒素酸化物還元用触媒及び排ガス中の窒素酸化物の還元方法 |
| US5672388A (en) * | 1994-07-08 | 1997-09-30 | Exxon Research & Engineering Company | Membrane reparation and poer size reduction using interfacial ozone assisted chemical vapor deposition |
| US5871650A (en) * | 1994-07-08 | 1999-02-16 | Exxon Research And Engineering Company | Supported zeolite membranes with controlled crystal width and preferred orientation grown on a growth enhancing layer |
| US5824617A (en) * | 1994-07-08 | 1998-10-20 | Exxon Research & Engineering Company | Low alkaline inverted in-situ crystallized zeolite membrane |
| US5763347A (en) * | 1994-07-08 | 1998-06-09 | Exxon Research And Engineering Company | In-situ crystallized zeolite containing composition (LAI-ISC) |
| DE69533513T2 (de) * | 1994-07-08 | 2005-11-17 | Exxon Research And Engineering Co. | Zeolith schichten mit einer kontrollierten kristallbreite und einem wachstum mit bevorzugter orientierung auf einer wachstumsfördernden schicht |
| JP3664502B2 (ja) * | 1994-10-28 | 2005-06-29 | 旭化成ケミカルズ株式会社 | 低級オレフィン及び単環芳香族炭化水素の製造法 |
| NO950854L (no) * | 1995-03-03 | 1996-09-04 | Norsk Hydro As | Selektiv katalytisk reduksjon av nitrogenoksider |
| ES2162642T3 (es) * | 1995-04-17 | 2002-01-01 | Enitecnologie Spa | Catalizador de reduccion de oxidos de nitrogeno y procedimiento para la reduccion de oxidos de nitrogeno en un gas de escape. |
| EP0766992B1 (en) * | 1995-10-06 | 2003-07-30 | ENITECNOLOGIE S.p.a. | Nitrogen oxides reduction catalyst and process for reducing nitrogen oxides in exhaust gas |
| US5905180A (en) * | 1996-01-22 | 1999-05-18 | Regents Of The University Of Minnesota | Catalytic oxidative dehydrogenation process and catalyst |
| US6254807B1 (en) | 1998-01-12 | 2001-07-03 | Regents Of The University Of Minnesota | Control of H2 and CO produced in partial oxidation process |
| US6143681A (en) * | 1998-07-10 | 2000-11-07 | Northwestern University | NOx reduction catalyst |
| JP3994862B2 (ja) * | 2002-06-17 | 2007-10-24 | 住友金属鉱山株式会社 | 排ガス浄化触媒及び浄化方法 |
| US20040042947A1 (en) * | 2002-08-28 | 2004-03-04 | John Hoard | Method for NOx reduction |
| GB0220645D0 (en) | 2002-09-05 | 2002-10-16 | Johnson Matthey Plc | Exhaust system for a lean burn ic engine |
| US20050100494A1 (en) | 2003-11-06 | 2005-05-12 | George Yaluris | Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking |
| US7304011B2 (en) | 2004-04-15 | 2007-12-04 | W.R. Grace & Co. -Conn. | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
| US20050232839A1 (en) | 2004-04-15 | 2005-10-20 | George Yaluris | Compositions and processes for reducing NOx emissions during fluid catalytic cracking |
| US7597864B2 (en) * | 2004-07-16 | 2009-10-06 | Breen Energy Solutions | Control of mercury and other elemental metal emissions using reaction stabilization device |
| DE102004052976A1 (de) | 2004-10-29 | 2006-05-04 | Sortech Ag | Verfahren zur Herstellung eines mit einer Zeolith-Schicht beschichteten Substrats |
| DE102005019000A1 (de) | 2005-04-22 | 2006-10-26 | Degussa Ag | Katalytisch beschichteter Träger, Verfahren zu dessen Herstellung und damit ausgestatteter Reaktor sowie dessen Verwendung |
| EP1888231A1 (en) | 2005-04-27 | 2008-02-20 | W.R. Grace & Co.-Conn. | Compositions and processes for reducing nox emissions during fluid catalytic cracking |
| US8071037B2 (en) * | 2008-06-25 | 2011-12-06 | Cummins Filtration Ip, Inc. | Catalytic devices for converting urea to ammonia |
| DE102008050926A1 (de) | 2008-10-10 | 2010-04-15 | Nanoscape Ag | Adsorberelement und Verfahren zur Herstellung eines Adsorberelements |
| US8783043B2 (en) * | 2009-07-15 | 2014-07-22 | Siemens Aktiengesellschaft | Method for removal of entrained gas in a combined cycle power generation system |
| US20130034482A1 (en) * | 2011-08-05 | 2013-02-07 | Chevron U.S.A Inc. | Reduction of oxides of nitrogen in a gas stream using molecular sieve ssz-23 |
| EP3368195A1 (en) | 2015-10-29 | 2018-09-05 | Volvo Truck Corporation | Reactive filter for motor vehicle |
| US10604413B2 (en) * | 2018-03-09 | 2020-03-31 | Chevron U.S.A. Inc. | Synthesis of *MRE framework type molecular sieves |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| USRE28341E (en) * | 1964-05-01 | 1975-02-18 | Marshall dann | |
| US3308069A (en) * | 1964-05-01 | 1967-03-07 | Mobil Oil Corp | Catalytic composition of a crystalline zeolite |
| US3702886A (en) * | 1969-10-10 | 1972-11-14 | Mobil Oil Corp | Crystalline zeolite zsm-5 and method of preparing the same |
| US3709979A (en) * | 1970-04-23 | 1973-01-09 | Mobil Oil Corp | Crystalline zeolite zsm-11 |
| US3832449A (en) * | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
| US3900554A (en) * | 1973-03-16 | 1975-08-19 | Exxon Research Engineering Co | Method for the reduction of the concentration of no in combustion effluents using ammonia |
| US4016245A (en) * | 1973-09-04 | 1977-04-05 | Mobil Oil Corporation | Crystalline zeolite and method of preparing same |
| US3941871A (en) * | 1973-11-02 | 1976-03-02 | Mobil Oil Corporation | Crystalline silicates and method of preparing the same |
| US4220632A (en) * | 1974-09-10 | 1980-09-02 | The United States Of America As Represented By The United States Department Of Energy | Reduction of nitrogen oxides with catalytic acid resistant aluminosilicate molecular sieves and ammonia |
| US4046859A (en) * | 1974-11-29 | 1977-09-06 | Mobil Oil Corporation | Crystalline zeolite and method of preparing same |
| CA1064890A (en) * | 1975-06-10 | 1979-10-23 | Mae K. Rubin | Crystalline zeolite, synthesis and use thereof |
| US4229424A (en) * | 1979-04-09 | 1980-10-21 | Mobil Oil Corporation | Crystalline zeolite product constituting ZSM-5/ZSM-11 intermediates |
| US4397827A (en) * | 1979-07-12 | 1983-08-09 | Mobil Oil Corporation | Silico-crystal method of preparing same and catalytic conversion therewith |
| IL68265A (en) * | 1983-03-30 | 1987-03-31 | Yeda Res & Dev | Crystallized glass preparation and use in catalytic alkylation |
| JPS6028826A (ja) * | 1983-07-26 | 1985-02-14 | Hiroshi Suzuki | かご型ゼオライト薄膜表層を有する複合膜及びその製造法 |
| US4556477A (en) * | 1984-03-07 | 1985-12-03 | Mobil Oil Corporation | Highly siliceous porous crystalline material ZSM-22 and its use in catalytic dewaxing of petroleum stocks |
| US4615995A (en) * | 1985-01-03 | 1986-10-07 | The Asbestos Institute | Zeolite catalysts |
| EP0202797B1 (en) * | 1985-05-14 | 1993-01-27 | Mobil Oil Corporation | A method for the synthesis of zeolites |
| US4778665A (en) * | 1986-09-09 | 1988-10-18 | Mobil Oil Corporation | Abatement of NOx in exhaust gases |
| JPH07106317B2 (ja) * | 1987-02-13 | 1995-11-15 | 触媒化成工業株式会社 | 炭化水素油の接触分解用触媒組成物の製造方法 |
| US4771029A (en) * | 1987-05-18 | 1988-09-13 | W. R. Grace & Co.-Conn | Monolith washcoat having optimum pore structure and optimum method of designing the washcoat |
| US4800187A (en) * | 1987-10-28 | 1989-01-24 | Corning Glass Works | Method of crystallizing a zeolite on the surface of a monolithic ceramic substrate |
| US5023220A (en) * | 1988-11-16 | 1991-06-11 | Engelhard Corporation | Ultra high zeolite content FCC catalysts and method for making same from microspheres composed of a mixture of calcined kaolin clays |
| US4980052A (en) * | 1988-12-05 | 1990-12-25 | Mobil Oil Corporation | Catalytic cracking of hydrocarbons |
| US4961917A (en) * | 1989-04-20 | 1990-10-09 | Engelhard Corporation | Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts |
| WO1991006508A1 (en) * | 1989-10-31 | 1991-05-16 | Mitsubishi Jukogyo Kabushiki Kaisha | Catalyst for nitrogen oxide decomposition and method of cleaning nitrogen oxide-containing exhaust gas |
| US4973399A (en) * | 1989-11-03 | 1990-11-27 | Mobil Oil Corporation | Catalytic cracking of hydrocarbons |
| US5271913A (en) * | 1989-12-28 | 1993-12-21 | Mitsubishi Jukogyo Kabushiki Kaisha | Denitration catalyst for high-temperature exhaust gas |
| US5019263A (en) * | 1990-06-05 | 1991-05-28 | Mobil Oil Corp. | Membrane composed of a pure molecular sieve |
| US5260043A (en) * | 1991-08-01 | 1993-11-09 | Air Products And Chemicals, Inc. | Catalytic reduction of NOx and carbon monoxide using methane in the presence of oxygen |
| US5279997A (en) * | 1991-10-07 | 1994-01-18 | Ford Motor Company | Selective reduction of NOx |
-
1993
- 1993-04-16 US US08/047,137 patent/US5316661A/en not_active Expired - Lifetime
- 1993-06-29 AU AU45454/93A patent/AU4545493A/en not_active Abandoned
- 1993-06-29 DK DK93915489T patent/DK0649387T4/da active
- 1993-06-29 JP JP6503386A patent/JPH07509687A/ja active Pending
- 1993-06-29 WO PCT/US1993/006190 patent/WO1994001365A1/en not_active Ceased
- 1993-06-29 DE DE69320195T patent/DE69320195T3/de not_active Expired - Fee Related
- 1993-06-29 EP EP93915489A patent/EP0649387B2/en not_active Expired - Lifetime
- 1993-06-29 ES ES93915489T patent/ES2119902T5/es not_active Expired - Lifetime
- 1993-11-08 US US08/148,943 patent/US5374410A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| JPH07509687A (ja) | 1995-10-26 |
| WO1994001365A1 (en) | 1994-01-20 |
| EP0649387A4 (en) | 1995-08-16 |
| ES2119902T5 (es) | 2003-10-01 |
| EP0649387B1 (en) | 1998-08-05 |
| EP0649387B2 (en) | 2003-01-22 |
| DE69320195T2 (de) | 1998-12-10 |
| AU4545493A (en) | 1994-01-31 |
| DK0649387T4 (da) | 2003-05-19 |
| EP0649387A1 (en) | 1995-04-26 |
| DE69320195D1 (de) | 1998-09-10 |
| DE69320195T3 (de) | 2004-03-25 |
| US5316661A (en) | 1994-05-31 |
| US5374410A (en) | 1994-12-20 |
| DK0649387T3 (da) | 1998-12-14 |
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